• Title/Summary/Keyword: Z. O. E.

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Theoretical Calculation and Experimental Verification of the Hf/Al Concentration Ratio in Nano-mixed $Hf_xAl_yO_z$ Films Prepared by Atomic Layer Deposition

  • Kil, Deok-Sin;Yeom, Seung-Jin;Hong, Kwon;Roh, Jae-Sung;Sohn, Hyun-Cheol;Kim, Jin-Woong;Park, Sung-Wook
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.120-126
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    • 2005
  • We have proposed a characteristic method to estimate real composition when multi component oxide films are deposited by ALD. Final atomic concentration ratio was theoretically calculated from the film densities and growth rates for $HfO_2$ and $Al_2O_3$ using ALD processed HfxAhOz mms.W e have transformed initial source feeding ratio during deposition to fins] atomic ratio in $Hf_xAl_yO_z$ films through thickness factors ($R_{HFO_2}$ ami $R_{Al_2O_3}$) ami concentration factor(C) defined in our experiments. Initial source feeding ratio could be transformed into the thickness ratio by each thickness factor. Final atomic ratio was calculated from thickness ratio by concentration factor. It has been successfully confirmed that the predicted atomic ratio was in good agreement with the actual measured value by ICP-MS analysis.

Smart Solid State Syntheses of Well-Crystallized Phase Pure Mixed Oxides for Electroceramics

  • Sennat, Mamoru
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.680-687
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    • 2006
  • An overview is given to optimize the solid state processes toward phase pure and well-crystallized fine particulates of mixed oxides, serving as electroceramic materials in various genres. Elevation of the reactivity and preservation of stoichiometry of the starting mixture are of universal importance. Mechanical activation is versatile for these purposes, particularly when an oxygen atom as a hinge promotes formation of hetero-bridging bonds between dissimilar cationic species prior to calcination. Case studies carried out recently in the author's laboratory are displayed and compared for ferroelectric materials, i.e. $PbMg_{1/3}Nb_{2/3}O_3$ $xPbTiO_3$(PMN-PT), $(1-y)Pb(Zn_xMg{1-x})_{1/3}$ $yNb_{2/3}O_3$ (PZN-PMN), $BaBi_2Ta_2O_9$ (BBT), $Ba(Mg_{1/3}Ta_{2/3})O_3$ (BMT), and ferromagnetics, i.e. M-, Y-, and Z-phases of Ba-hexaferrites.

Photochemistry of $\alpha$-(o-Alkylphenyl)indanones

  • Jeong, Soo-Young;Park, Bong-Ser
    • Journal of Photoscience
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    • v.7 no.1
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    • pp.35-37
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    • 2000
  • Photolysis of $\alpha$-(o-alkylphenyl) indanones resulted in $\alpha$-cleavage followed by disproportionation to form E-and Z- ortho-formyl stilbenes. No evidences of hydrogen abstraction reactions were collected from these indanones. The minimum rate constant of $\alpha$-cleavage in the $\alpha$-(o-alkylphenyl) indanones was estimated to be 5.5$\times$10$^{10}$ s$^{-1}$ .

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Crystal Chemistry of Hexagonal 7$\AA$ Phyllomanganate Minerals (7$\AA$ 층상구조형 산화망간 광물의 결정화학)

  • 김수진
    • Journal of the Mineralogical Society of Korea
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    • v.3 no.1
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    • pp.34-43
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    • 1990
  • Crystal-chemical study of hexagonal 7$\AA$ phyllomanganate minerals reveals that they have hexagonal layer structures with variable c dimensions which depend on the nature of interlayer cations and content of water molecules between edge-sharing [MnO6] octahedral layers. Approximately one out of nine octahedral sites is statistically vacant, leading to the general unit cell formula R2xMn4+1-xO2.nH2O, where R=Ca, Mn2+, Mg, K, Na;x=0.09-0.14 ; n-0.37-0.84. Z=1. The minerals of this formula fall under the name of rancieite group. It includes Ca-diminant (rancieite), Mn2+-dominant (takanelite), Na-dominant (birnessite), and Mg-dominant members. Minerals of the rancieite group occur predominantly in two different hydration states, i.e., n shows the values around 0.35 and 0.75. It is suggested that minerals of higher hydration state be called as species(i.e., rancieite, etc.) and those of lower hydration state be called as dehydrated varieties(i.e., dehydrated rancieite,etc.).

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Preparation and Electromagnetic Properties of Ni-Zn Ferrite by Wet Method (습식합성법을 이용한 Ni-Zn Ferrite의 제조 및 전자기적 특성연구)

  • Jung, Goo-Eun;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.14 no.1
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    • pp.18-24
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    • 2004
  • Ni-Zn ferrite powder was synthesized from metal nitrates, Fe(N $O_3$)$_3$$.$9 $H_2$O, Ni(N $O_3$)$_2$$.$6 $H_2$O, Zn(N $O_3$)$_2$$.$6 $H_2$O by wet direct process to make high permeability material. The composition of the ferrite powder is (N $i_{0.284}$F $e_{0.053}$Z $n_{0.663}$)F $e_2$ $O_4$. Ni-Zn ferrite powder is compounded by precipitating metal nitrates with NaOH in vessel at 90$^{\circ}C$ synthetic temperature for 8 hours. Calcination temperature and sintering temperature were 700$^{\circ}C$ and 1150$^{\circ}C$-1250$^{\circ}C$ respectively for 2 hours. The same compound powder was extracted from metal oxide by wet ballmilling. We compared the properties of powder and the electromagnetic characteristics of the sintered cores obtained from the two different processes. Wet direct process produces smaller particle size with narrower distribution and higher purified ferrite which cores has high permeability and high magnetization.

A Study on the electric field distribution of design of LiNbO$_3$ optical waveguide (LiNbO$_3$ 광 도파로의 전계분포 및 설계에 관한 연구)

  • 강기성;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.288-293
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    • 2000
  • BPM simulation was used in order to fabricate the LiNbO$_3$optical waveguide with optical source of He-Ne laser(λ=0.6328[$\mu$m]). we observed electric field E$_{x}$, E$_{y}$ in the x,y-direction are simulated at the LiNbO$_3$substrate (X1 55[$\mu$m]$\times$Z1 5000[$\mu$m]), where the depth, width and buffer layer of waveguide are 0.2[$\mu$m],4[$\mu$m] and 0.02[$\mu$m] respectively. By applying these parameters of single waveguide to simulate a X-switch, we have chosen index change of 0.002, width of 3[$\mu$m] and angle of 0.4$^{\circ}$~0.6$^{\circ}$of optical waveguide and under these conditions, optical beam propagates cross-side at 0.4$^{\circ}$. When applied switching voltage of 25[V], optical beam of X-switch turns cross-side to bar-side at intersection angle 0.4$^{\circ}$, index change of 0.002, waveguide width of 3[$\mu$m], electrode gap 2[$\mu$m]. By the above results, we can obtain design conditions of theoretical analysis of an X-switch optical waveguide.e.e.

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The Fabrication of BaZrO3-based Proton Conductors and their Electrical Properties by Dopants (BaZrO3계 수소이온 전도체의 제조 및 첨가물에 따른 전기적 특성)

  • 권정범;유광수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.415-422
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    • 2003
  • BaZr $O_3$-based proton conductors in which B-site cations are partially substituted by Ce and Yb were fabricated by a solid state reaction method. The electrical properties of the specimens were measured by using impedance analyzer in dry air and wet air atmospheres. The electrical conductivity showed higher value in wet air than in dry air at below $600^{\circ}C$. As the Ce content increased, the electrical conductivity increased. Among four compositions, BaZ $r_{0.8}$C $e_{0.15}$Y $b_{0.05}$ $O_3$$_{-{\delta}}$ specimen showed the highest electrical conductivity,1.72$\times$10$^{-3}$ S$cm^{-1}$ /, at 80$0^{\circ}C$. In the low temperature region, the electrical conductivity was higher in wet air than in dry air. However, as the temperature increased, the proton conductivity reduced and thus the electrical conductivity showed similar value at approximately $700^{\circ}C$.

The influence of MgO on the radiation protection and mechanical properties of tellurite glasses

  • Hanfi, M.Y.;Sayyed, M.I.;Lacomme, E.;Akkurt, I.;Mahmoud, K.A.
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.2000-2010
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    • 2021
  • Mechanical moduli, such as Young's modulus (E), Bulks modulus (B), Shear modulus (S), longitudinal modulus (L), Poisson's ratio (σ) and micro Hardness (H) were theoretically calculated for (100-x)TeO2+x MgO glasses, where x = 10, 20, 30, 40 and 45 mol%, based on the Makishima-Mackenzie model. The estimated results showed that the mechanical moduli and the microhardness of the glasses were improved with the increase of the MgO contents in the TM glasses, while Poisson's ratio decreased with the increase in MgO content. Moreover, the radiation shielding capacity was evaluated for the studied TM glasses. Thus, the linear attenuation coefficient (LAC), mass attenuation coefficient (MAC), transmission factor (TF) and half-value thickness (𝚫0.5) were simulated for gamma photon energies between 0.344 and 1.406 MeV. The simulated results showed that glass TM10 with 10 mol % MgO possess the highest LAC and varied in the range between 0.259 and 0.711 cm-1, while TM45 glass with 45 mol % MgO possess the lowest LAC and vary in the range between 0.223 and 0.587 cm-1 at gamma photon energies between 0.344 and 1.406 MeV. Furthermore, the BXCOM program was applied to calculate the effective atomic number (Zeff), equivalent atomic number (Zeq) and buildup factors (EBF and EABF) of the glasses. The effective removal cross-section for the fast neutrons (ERCSFN, ∑R) was also calculated theoretically. The received data depicts that the lowest ∑R was achieved for TM10 glasses, where ∑R = 0.0193 cm2 g-1, while TM45 possesses the highest ERCSFN where ∑R = 0.0215 cm2 g-1.

THE EFFECT OF CANAL FILLING SEALER TO RESIN CEMENT IN POST CEMENTATION (근관충전용 sealer의 성분이 포스트 세멘트시 레진 세멘트에 미치는 영향)

  • Lee, Cheong-Hee;Jo, Kwang-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.32 no.1
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    • pp.1-8
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    • 1994
  • The purpose of this study was to evaluate the effect of the canal filling sealer to resin cement When posts were cemented in the endodontically treated teeth, 86 incisors were used. The coronal portion of the teeth were removed at the cemento-enamel junction, every tooth was done treatment of canal. And the teeth was divided was into 12 groups. G : I a n : 7 Treatment : Z.P.C (1 day after Z.O.E. sealer) G : I b n : 7 Treatment : All-Bond (3 day after sealer) G : II a n : 8 Treatemt : Z.P.C (3 day after sealer) G : II b n : 7 Treatemt : All-Bond (3 day after sealer) G : III a n : 8 Treatemt : Z.P.C (7 day after sealer) G : III b n : 8 Treatemt : All-Bond (7 day after sealer) G : IV a n : 7 Treatemt : Z.P.C (1 day after Apexit sealer) G : IV b n : 7 Treatemt : All-Bond (1 day after sealer) G : V a n : 7 Treatemt : Z.P.C (3 day after sealer) G : V b n : 7 Treatemt : All-Bond (3 day after sealer) G : VI a n : 7 Treatemt : Z.P.C (7 day after sealer) G : VI a n : 7 Treatemt : All-Bond (7 day after sealer) Ready made stainless steel Para-post(PD-K-3) was cemented with Z.P.C. in subgroup a, and cemented with All-Bond & composite resin cement in subgroup b to depth 7mm. After 5 days at cementation of post, teeth with cemented posts were mounted on a retention jig and the failure loads of the specimens were measured by an Instron Universal Testing Machine. The results were as follows. 1. The results of failure loads were $15.5{\pm}7.1kg$ in group I b, $21.6{\pm}5.4kg$ in group II b and $20.1{\pm}18.1kg$ in group III b, and there was no statistically significant , difference between each group(p>0.05). 2. The results of failure loads were $19.0{\pm}6.7kg$ in group IV b, $17.3{\pm}6.5kg$ in group V b.and $18.9{\pm}7.9kg$ in group VI b and there was no significant difference between each other(p>0.05). 3. In same condition, the failure load of subgroup a was largely higher the subgroup b. But there was no significant difference between each other(p>0.05).

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Sex Pheromone Composition for Field-trapping of Dichocrocis punctiferalis (Lepidoptera: Pyralidae) Males (최적의 야외유인을 위한 복숭아명나방(Dichocrocis punctiferalis)의 성페로몬 조성)

  • 정진교;한경식;최광식;부경생
    • Korean journal of applied entomology
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    • v.39 no.2
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    • pp.105-110
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    • 2000
  • Sex pheromone composition was analyzed for Dichocrocis punctiferalis, which attacksapple, peach, chestnut fruits, etc., and its behavioral and field trapping studies were conducted to developa monitoring system with its sex pheromone. Virgin females showed maximum mating behavior andhairpencil extrusion behavior between 4-5 hrs after lights-off under 16L18D photoperiod and 26rf 1 "C.During this period, two sex pheromone components, ElO-hexadecenal and ZlO-hexadecenal, weredetected by GC analysis in the hexane extract of abdominal tips of virgin females. The best attraction ofmales to various synthetic sex pheromone blends was obtained at the 70 : 30 ratio of ElO-hexadecenal andZ10-hexadecenal for hair pencil extrusion and at the 80 : 20 ratio for flying upwind response. The highestattractiveness in fields was obtained between 70 : 30 and 80 : 20 from several tests in apple, peach andchestnut orchards.and chestnut orchards.

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