• Title/Summary/Keyword: Yttrium iron garnet

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Synthesis of Yttrium Iron Garnet Powder by Homogeneous Precipitation and its Crystallization (균일침전법에 의한 Yttrium Iron Garnet 분말의 합성 및 결정화)

  • 안영수;한문희;김종오
    • Journal of the Korean Ceramic Society
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    • v.33 no.6
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    • pp.693-699
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    • 1996
  • YIG precursor powder was obtained by homogeneous precipitation in chloride salt solution by thermal decom-position of urea. It was found that ferric ions precipitated prior to yttrium ions. The precipitate was minute and spherical in shape. The precipitate formed consisted of the mixture of amorphous and ferric oxyhydroxide. Crystallization of YIG was proceeded by solid state reaction of intermediate YFeO3 and Fe2O3 in the temperature range of 85$0^{\circ}C$ to 140$0^{\circ}C$. Single phase of YIG was obtained by heat-treatment of the powder at 140$0^{\circ}C$ for 6 hrs in air. The powder calcined was molded into pellets and sintered in air. The maximum density of 4,92 g/cm3(95.1% of theoretical density) was obtainable for the pellet sintered at 145$0^{\circ}C$ using the powder calcined at 90$0^{\circ}C$.

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Microstructure and Magnetic Characteristics of Yttrium Iron Garnet Thin Films Prepared by RF Magnetron Sputter (고주파 마그네트론 스퍼터법에 의해 제조된 Yttrium Iron Garnet 박막의 미세구조 및 자기적 특성)

  • 박명범;김병진;조남희
    • Journal of the Korean Ceramic Society
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    • v.36 no.3
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    • pp.293-300
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    • 1999
  • 고주파 마그네트론 스퍼터법을 이용한 YIG(yttrium iron garnet)박막 제조시 기판유형, 기판온도, 스퍼터전력, 스퍼터가스 등의 증착변수와 증착후 열처리 조건이 YIG 박막의 결정성, 화학조성, 미세구조 그리고 자기적 특성에 미치는 영향에 대하여 고찰하였다. 75$0^{\circ}C$ 이상의 온도에서 수행한 증착후 열처리에 의하여 비정질 박막이 결정화되었으며, 특히 GGG(gadolinium gallium garnet)기판 위에 제조된 박막은 강한 (111)우선배향성을 나타냈다. 박막조성은 스퍼터가스 내의 산소분율에 민감하게 영향을 받았으며, 산소분율이 20%인 스퍼터가스를 사용하여 제조된 박막은 Y2.88Fe3.84O12의 조성을 나타내었다. 증착후 열처리 온도가 90$0^{\circ}C$로부터 110$0^{\circ}C$로 증가함에 따라, GGG 기판위의 박막의 표면거칠기는 2.5nm에서 40nm로 증가하였으며, 보자력과 강자성 공명 선폭은 감소하였다.

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Thermal Decomposition and Synthesis of Yttrium Iron Garnet Powder by Homogeneous Precipitation Method (균일침전법에 의한 Yttrium Iron Garnet 분말의 합성 및 열분해특성)

  • An, Yeong-Su;Han, Mun-Hui;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.6 no.3
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    • pp.275-281
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    • 1996
  • YIG 전구체 분말은 요소의 열분해반응을 이용한 균일침전법에 의해서 질산염으로부터 제조하였다. 침전은 철이온이 먼저 침전한 후 이트륨이온이 침전하는 과정으로 이루어졌다. YGI전구체 분말은 철산화물과 비정질로 구성되어 있으며 그 분말의 대략적인 화학식은 2.5Fe2O3.Y3(OH)9-2x(CO3)x.nH2O로 되어있다. YIG 전구체 분말의 열분해과정은 dehydration, 철산화물의 recrystallization, yttrium carbonate 및 yttrium oxide의 형성과 고상반응등 여러단계로 구성되어 있다. 열처리온도가 증가함에 따라 Y2O3와 Fe2O3의 고상반응에 의해 YFeO3 intermediate을 경유해서 YIG상이 형성됨을 확인하였다. 단일상의 YIG는 120$0^{\circ}C$에서 6시간 공기중에서 소성함에 의해서 얻을 수 있었다.

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Effect of Annealing for YIG Single Crystal Thick Films (YIG 단결정 후막의 열처리의 효과)

  • 김근영;윤석규;김용탁;이성문;윤대호
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.855-858
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    • 2003
  • When the PbO-based flux system is used in the Liquid Phase Epitaxy (LPE) method for Yttrium Iron Garnet (YIG) thick film, the effect of Pb ions incorporated into the grown crystal; increase the lattice parameter, changed the uniaxial magnetic anisotropy constant (Ku) or conductance of grown film. It exerts a bad influence on physical property such as increasing optical absorption of grown film. The content of the Pb ion in crystal was decreased by volatilization of Pb ion after annealing; therefore, the lattice parameter of film was reduced on an average 0.0115 ${\AA}$ by the the Pb ion.

Misfit Strain Induced Reflection of Light from Magnetic-Nonmagnetic Interfaces

  • N. N. Dadoenkova;I. L. Lyubchanskii;M. I. Lyubchanskii;Th. Rasing;Shin, Sung-Chul
    • Journal of Magnetics
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    • v.5 no.1
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    • pp.1-3
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    • 2000
  • We have theoretically investigated changes in reflection coefficients induced by misfit strain located near the interface between an iron-yttrium garnet magnetic film and a nonmagnetic gadolinium-gallium garnet substrate in a transverse magneto-optical configuration.

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NSMM을 통한 Bi:YIG박막의 Bi농도에 따른 마이크로파 특성 연구

  • Lee, Han-Ju;Yun, Yeong-Un;Kim, Tae-Dong;Yu, Hyeong-Geun;Kim, Song-Hui;Balt, Erdene;Lee, Gi-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.142-142
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    • 2009
  • Bismuth-substituted yttrium iron garnet(Bi-YIG; $Bi_xY_{3-x}Fe_5O_{12}$, x=0, 0.5, 1.0, 1.5, 2.0) thin films were fabricated on glass substrates using a metal organic decomposition (MOD) method. The dielectric property was measured by NSMM(Near-field scanning microwave microscopy) system that operating frequency is 4 Ghz. The obtained reflection coefficient $S_{11}$ of the Bi:YIG thin films with different bismuth concentration was increased as the bismuth concentration increased due to the lattice mismatch and vacancy of ions because of a lager ionic radius of bismuth ion than yttrium ion.

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