• Korean Journal of Materials Research
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• v.34 no.7
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• pp.341-354
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• 2024

Today, the principles of green chemistry are being fundamentally applied in the chemical industry, such as the nitrobenzene industry, which is an essential intermediate for various commercial products. Research on the application of response surface methodology (RSM) to optimize nitrobenzene synthesis was conducted using a sulfated silica (SO₄/SiO₂) catalyst and batch microwave reactor. The nitrobenzene synthesis process was carried out according to RSM using a central composite design (CCD) design for three independent variables, consisting of sulfuric acid concentration on the silica (%), stirring time (min), and reaction temperature (℃), and the response variable of nitrobenzene yield (%). The results showed that a three-factorial design using the response surface method could determine the optimum conditions for obtaining nitrobenzene products in a batch microwave reactor. The optimum condition for a nitrobenzene yield of 63.38 % can be obtained at a sulfuric acid concentration on the silica of 91.20 %, stirring time of 140.45 min, and reaction temperature of 58.14 ℃. From the 20 experiments conducted, the SO₄/SiO₂ catalyst showed a selectivity of 100 %, which means that this solid acid catalyst can potentially work well in converting benzene to nitrobenzene.

• Journal of Crop Science and Biotechnology
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• v.11 no.1
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• pp.51-56
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• 2008

Azuki bean has never been commercially grown in Thailand, due in part to a lack of suitable varieties. A core collection of 114 azuki bean accessions, originally from different parts of China(northern, central, southern) representing the germplasm of Chinese land races, were evaluated in the experimental field of the Institute of Vegetable Crops, Jiangsu Academy of Agricultural Sciences, China from June to October 2004. The same experiment was repeated at Kamphaeng Saen campus of Kasetsart University, Thailand from February to May 2005. Yield, yield components, and agronomic traits were recorded in all accessions in order to identify certain genotypes for further investigation. The statistical parameters that were used as indicators of phenotypic variation were mean, coefficient of variability(CV), correlation coefficient(r), range, mean difference, and phenotypic clustering of the accessions. The results indicated that the azuki bean varieties planted in Kamphaeng Saen were shorter, earlier in growing duration, and lower in plant height, seed yield per plant, 100-seed weight, and pods per plant as compared to when they were grown in China. This discrepancy was caused largely by the combined effect of temperature, rainfall, and day length. The traits that were rather stable in both locations were branches per plant and seeds per pod. Azuki bean varieties from northern China showed higher response to the changing environments compared with those from central and southern China. Some agronomic traits showed high correlation coefficient between the environments in Thailand and China. The CV of agronomic traits in both locations were ranked in descending order as follows: seed yield per plant, pods per plant, branches per plant, plant height, 100-seed weight, seeds per pod, and growing duration. The CV of seeds per pod and branches per plant were almost the same in both locations. Yield per plant in China correlated well(r=0.75) with pods per plant, but not with the other traits. Based on their response to both environments, the azuki bean accessions can be broadly divided into four groups, viz. northern 1, northern 2, central, and southern. This implied that there was more diversity, but probably less stability among the accessions originating from northern China.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.67 no.2
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• pp.77-84
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• 2022

This study aimed to evaluate the growth, yield, and grain quality characteristics of rice varieties that were subjected to water stress during the tillering stage. We also sought to identify whether water stress could be indicated via the plants' response to chlorophyll fluorescence. In this study, we induced water stress by intentionally cutting off water for 30 days, starting 15 days after transplanting the rice varieties to a greenhouse. We analyzed nine rice varieties, including Ilpum, which is the most frequently cultivated variety in Gyeongsangbuk-do, South Korea. The control group was planted in a paddy field where irrigation was entirely dependent on rainfall. Our results revealed that the heading stage of the nine studied varieties occurred approximately ten days earlier in the rain shelter than in the field. Moreover, the rice yield, head rice rate, and palatability score decreased by 18.6%, 17.1%, and 8.3%, respectively, while protein content increased by 20.2% compared with the control group. The Saenuri and Haimi varieties showed the lowest reduction in yield under the water stress conditions, while the Daebo and Samkwang varieties showed the highest reduction in yield. The chlorophyll fluorescence response after re-irrigation was measured between July 30^th and August 17^th. The ratio of variable fluorescence to maximum chlorophyll fluorescence (F_V/F_M) values failed to recover to their baseline values, resulting in either no change or a reduction in fluorescent response, even after re-irrigation of Daebo and Samkwang varieties. These results can be utilized as empirical data for drought-affected farms to select resistant varieties that can respond to spring drought in the southern plains of Gyeongsangbuk-do.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.47 no.6
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• pp.471-474
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• 2002

This experiment was conducted to investigate the response of rice growth and grain yield to night illumination. Three cultivars Heugjubyeo (early maturing), Hwaseongbyeo (medium maturing), and Ilpumbyeo(mid-late maturing) were tested under different light intensities ranging 1.0 to 20.0 lux (0.3 to 5.6 $1\mu\textrm{W}$ $cm^{-2}$). Awn length of all cultivars became longer as night illumination intensity increased; 4.09 cm under 10-20 lux compared to 1.93cm under 2 lux in Hwaseongbyeo. However culm and spike length ere not affected by night illumination. Night illumination delayed flowering by 3 days in Heugjinjubyeo, 5 days in Hwaseongbyeo, and 9 days in Ilpumbyeo at 10-20 lux compared to that at 2 lux. Grain yield was reduced by 10.0% in Heugjinjubyeo, 17.7% in Hwaseongbyeo, and 20.7% in Ilpumbyeo at 10-20 lux compared to 2 lux condition.

• Journal of the Korean Society of Food Science and Nutrition
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• v.32 no.5
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• pp.689-694
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• 2003

Propolis obtained from honeybee hives has been used in oriental folk medicine as an anti-inflammatory, anti-carcinogenic, or immunomodulatory agent. To prepare granule depending on operational parameters, such as glucose content to total sugar (X$_1$, 0~100%), ethanol concentration (X$_2$, 20~100%) and sprayed ethanol solution content (X$_3$, 6~10%) using propolis, response surface methodology was applied to monitor the changes in yield, fragmentation rate by shaking and organoleptic properties. Yield showed high with decreasing sprayed ethanol solution content and fragmentation rate by shaking decreased with increasing sprayed ethanol solution content. The organoleptic color, flavor, taste, mouth-feel and overall palatability were dependent on the glucose content to total sugar, ethanol concentration and sprayed ethanol solution content. Overall palatability was maximized in glucose content to total sugar 47.94%, ethanol concentration 56.45% and sprayed ethanol solution content 8.04% .

• Natural Product Sciences
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• v.24 no.2
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• pp.103-108
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• 2018

The usage of wild ginseng (Panax ginseng C.A. Meyer) has been limited due to short supply and high price. Therefore, sufficient production as well as efficient extraction of mountain ginseng are required for the development as products. In this study, wild ginseng adventitious root cultures were prepared for efficient production with advantages of fast growth and stable production. Treatment of methyl jasmonate (MJ) to wild ginseng adventitious root cultures increased the extraction yield and antioxidative activity. Further investigation on effect of extraction conditions suggested the importance of ethanol concentration on antioxidative activity and extraction yield of MJ-treated wild ginseng adventitious root cultures. Optimized extraction condition of MJ-treated wild ginseng adventitious root cultures for maximum extraction yield and antioxidative activity was determined using response surface methodology with three-level-three-factor Box-Behnken design (BBD). Extraction of 1 g MJ-treated wild ginseng adventitious root culture with 30 ml of 9% ethanol at $30^{\circ}C$ produced 310.2 mg extract with 71.0% antioxidative activity at $100{\mu}g/ml$. Taken together, MJ-treated wild ginseng adventitious root culture is valuable source for wild ginseng usage and optimized extraction condition can be used for the development of functional products or folk remedies.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.301-301
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• 2017

Subspecific difference of the percentage of white immature kernels (WIK) between japonica and indica rice cultivars was analyzed in relation to ripening temperature and yield characters. Thirty-three Chinese and 10 Japanese rice cultivars, including 32 japonica and 11 indica, were cultivated with three different cropping seasons for three years. The results were as follows: (1) Indica had less number of panicles, larger number of spikelets per panicle with higher yield, and longer and narrower kernels than japonica. In japonica, Chinese cultivars had less number of panicles and larger number of spikelets per panicle than Japanese cultivars. In addition, WIK was significantly higher in Chinese cultivars than in Japanese cultivars, because of the higher percentage of milky white kernels, even at similar temperature conditions during ripening. On the other hand, WIK in indica was not significantly different between the production areas and between the cropping seasons. (2) Regardless of subspecies, WIK in a large number of Chinese cultivars increased with increasing temperature during ripening within 20 days after heading, while this relation was uncommon in Japanese cultivars, showing the low temperature response. However, some Chinese cultivars had the low WIK with the low temperature response. (3) WIK in japonicawas positively correlated with 1000-kernel weight, spikelet density, kernel width and thickness, but negatively correlated with panicle length and grain filling percentage, while in indica it was positively correlated with panicle number per area, grain filling percentage, brown rice yield and kernel width, but negatively correlated with kernel length. These results indicated that WIK in both subspecies had a close relation to kernel size, and that WIK was high in japonica cultivars with wide and thick kernels and in indica cultivars with short and wide kernels.

• Structural Engineering and Mechanics
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• v.39 no.1
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• pp.47-75
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• 2011

An accurate substructural synthesis method including random responses synthesis, frequency-response functions synthesis and mid-order modes synthesis is developed based on rigorous substructure description, dynamic condensation and coupling. An entire structure can firstly be divided into several substructures according to different functions, geometric and dynamic characteristics. Substructural displacements are expressed exactly by retained mid-order fixed-interfacial normal modes and residual constraint modes. Substructural interfacial degree-of-freedoms are eliminated by interfacial displacements compatibility and forces equilibrium between adjacent substructures. Then substructural mode vibration equations are coupled to form an exact-condensed synthesized structure equation, from which structural mid-order modes are calculated accurately. Furthermore, substructural frequency-response function equations are coupled to yield an exact-condensed synthesized structure vibration equation in frequency domain, from which the generalized structural frequency-response functions are obtained. Substructural frequency-response functions are calculated separately by using the generalized frequency-response functions, which can be assembled into an entire-structural frequency-response function matrix. Substructural power spectral density functions are expressed by the exact-synthesized substructural frequency-response functions, and substructural random responses such as correlation functions and mean-square responses can be calculated separately. The accuracy and capacity of the proposed substructure synthesis method is verified by numerical examples.

• Tribology and Lubricants
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• v.14 no.4
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• pp.95-99
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• 1998

The electrorheological (ER) behavior of chitosan suspension in the silicone oil was investigated. Chitosan suspension showed a typical ER response, Bingham flow behavior upon application of an electric field due to the polarizability of the branched amino group of the chitosan particles. The shear yield stress exhibited a linear dependence on the volume fraction of particles and the squared electric field. On the basis of the experimental results, chitosan suspension has been correlated with the conduction models for ER response and found to be an ER fluid.

• Structural Engineering and Mechanics
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• v.26 no.4
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• pp.393-408
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• 2007

The effects of material nonhomogeneity and nonisothermal conditions on the stress response of pressurized tubes are assessed by virtue of a computational model. The modulus of elasticity, the Poisson's ratio, the yield strength, and the coefficient of thermal expansion, are assumed to vary nonlinearly in the tube. A logarithmic temperature distribution within the tube is proposed. Under these conditions, it is shown that the stress states and the magnitudes of response variables are affected significantly by both the material nonhomogeneity and the existence of the radial temperature gradient.