• Title/Summary/Keyword: Yellowing

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Effect of Yellowing Times During Yellowing Stage on Physico-chemical Properties of Immature Tobacco Leaves in Bulk Curing (Bulk건조시 미숙엽의 황변시간 조절이 잎담배 이화학성에 미치는 영향)

  • 이철환;진정의;한철수;이승철
    • Journal of the Korean Society of Tobacco Science
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    • v.21 no.1
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    • pp.10-16
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    • 1999
  • Leaves harvested were separated with visual characters into 2 classes such as immature and mature leaves. In the curing process, the prolonged yellowing treatment during yellowing stage was automatically controlled at the different stalk position, and condition of curing process after this period was all the same with conventional ones. In case of prolonged yellowing in immature leaves, increase of price per kg reached to 8 % compared with those of conventional ones. In physical properties, filling capacity and shatter index was decreased with the degree of maturity, and it was equal level in filling capacity of immature leaves between curing method, while shatter index was decreased in prolonged yellowing treatment than that of conventional ones. There was no difference in chemical components between immature leaves of prolonged yellowing and conventional ones. As to the prolonged yellowing of immature leaves, there was decreased in citric and malic acid contents of the nonvolatile organic acids, and it was equal level in all higher fatty acids content of leaves cured by prolonged yellowing treatment compared with in that of conventional curing method. The contents of key compounds such as solanone, damascenone, damascone in the essential oil were lower in prolonged yellowing of immature leaves than those of mature leaves cured by conventional ones.

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An Influence of Residual Metals on Yellowing of Indigo Dyed Bluejean after Stonewashing (스톤워싱후 잔류된 금속성분이 인디고로 선염된 블루진의 황변에 미치는 영향)

  • 양진숙;차옥선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.5
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    • pp.922-932
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    • 1997
  • Blue jeans are finished with stonewashing process to give it optimal softness and color contrast of blue and white. So, Yellowing may well be generated during storage or use and thereby, their appearance may be damaged much. So, this study was aimed at finding the solutions to reduce the yellowing problem caused by residual metals after stonewshing. To this end, sample blue jeans were made to be finished with various methods of wet-treatment and then, be subject to daylight to check their photoyellowing. The results of this test can be summarized as follows; Since the stonewashing process was found to affect the yellowing, the residual metals of stone- washed blue jeans was analyzed. And it was found that it contained such residual metal as Al, Ca, Cu, Ti, Si, K and Zn. In particular, it was conceived that Al was a prime cause affecting the yellowing. Meanwhile, when the blue jeans were treated by the metal ionchelating agent of EDTA-2Na, the residual levels of Al and Ti were reduced by about 50%, while the photoyellolving was lowered by 75%, which is suggesed that EDTA is very effective in preventing the yellowing. On the other hand, when the blue jeans were bleached by the hypochlorite, chlorine remained in blue jean accelerated the yellowing. However, when this blue jean was treated again by the sodium thiosulfate for its dechloridization, the residual of chlorine was reduced, and the yellowing was lowered by about 43%.

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Use of Polycarboxylic Acid to Inhibit Heat-and Moisture-Induced Yellowing of ECF/TCF Bleached Hardwood Kraft Pulp

  • Kawae, Ayano;Uchida, Yosuke
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.331-336
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    • 2006
  • The aim of this work was to inhibit the heat-and moisture-induced yellowing of ECF/TCF bleached hard wood kraft pulp (HBKP) retaining hexenuronic acid (HexA). We have already reported that one of the derivatives of HexA, 5-formyl-2-furancarboxylic acid (FFA), causes yellowing of HBKP in acidic paper, and that FFA might polymerize or react with pulp components to form new chromophoric groups (1). In this study, it was shown that the carboxylic base of FFA interacts with that of glucuronic acid or galacturonic acid, resulting in strong yellowing. Therefore, it seems that preventing the reaction of carboxylic bases could be effective in suppressing this yellowing. We have discovered that polycarboxylic acids (for example, citric acid, tartaric acid, etc.) are useful as a yellowing inhibitor.

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Yellowing of Chemical Pulp by Adding Glucuronoxylan

  • Yoon, Byung-Ho;Kim, Young-Seok
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.361-364
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    • 2006
  • Generally, aging of paper is evaluated by folding endurance and degree of yellowing. It was known as that lignin, hemicellulose and metallic ion affect yellowing of mechanical or chemical pulps. Among these elements, especially, the study of hemicellulose that affect at yellowing of pulp is insufficient. In this study, we examined into the influence that glucuronoxylan or glucomannan and metallic ion($Cu^{2+},\;Fe^{2+},\;Fe^{3+},Mn^{2+}$) residued in pulp get each or when mixed at yellowing. Filter paper was treated with each metallic ion, glucuronoxylan and the mixture of glucuronoxylan and metal ions, and brightness and CIE $L^*a^*b^*$ was measured after accelerated aging. As the results of measurements, the filter paper processed by 10% glucuronoxylan was dropped 2-3% on the brightness after accelerated aging for 24 hours. Also, the filter paper treated with glucuronoxylan and $Fe^{2+}$ was dropped 7% on the brightness.

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EFFECT OF TEMPERATURE AND HUMIDITY ON THE LEAF COLOR AND CHEMICAL COMPONENTS DURING THE YELLOWING STAGE OF FLUE-CURING (황색종 연초 건조중 황변기 온습도차가 잎담배 색상 및 화학성분에 미치는 영향)

  • Hwang, Keon-Joong;Seok, Yeong-Seon;Lee, Han-Seok
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.2
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    • pp.129-139
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    • 1985
  • cent was carried out to study on the effect of temperature and humidity to chemical tobacco leaves during the yellowing stage. The results were follows : In the condition of high humidity and low temperature, yellowing time was delayed ; leaf color appeared lack clearness. In the higher temperature and the lower humidity during the yellowing stage : total sugar, reducing sugar and malic acid content were increased. Decomposition of nitrogenous components elevated in $38^{\circ}C$, 85%RH. Changes of total nitrogen content correlated with total curing time. Adecrease of linolenic acid with a corresponding increase of chlorogenic acid proceeded in the condition of low temperature and high humidity. In a view of tobacco quality by chemical components, the low temperature and high humidity during the yellowing stage decreased quality of tobacco leaves. It is considered to control of the proper condition of temperature and humidity during the yellowing.

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Characterization of Lignin Structure in Chemithermomechanical Pulp Predicting Photo-Yellowing Level by Pyrolysis-Gas Chromatography with Tetrabuthylammonium Hydroxide

  • Ona, Toshihiro;Yoshioka, Aki;Kojima, Yasuo;Seino, Teruyuki;Mizumoto, Miho;Nozaki, Hideo;Ishida, Yasuyuki;Ohtani, Hajime
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.173-176
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    • 2006
  • Pyrolysis-gas chromatography (Py-GC) in the presence of organic alkali of tetrabutylammonium hydroxide (TBAH) was applied to characterize the polyphenol fragments with a carbonyl group causing different magnitude of photo-yellowing in chemithermomechanical pulp (CTMP) papers. Two different origin of CTMP papers prepared from different individuals of Eucalyptus globulus trees showing high and low yellowing after photo-irradiation was compared before photo-irradiation. As a result, 7 peaks assigned to a series of phenol compounds with a carbonyl group, derived mainly from lignin, gave significant amount of phenol compounds with a carbonyl group for the paper sample of latent high yellowing, i.e., butoxy-and syringaldehyde, butoxy-and syringylacetone, butoxy-acetoguaiacone, butoxy-acetosyringone, butoxy-acetoethylsyringone, 3-methoxy-4-butoxy butyl ester, and 3,5-dimethoxy-4-butoxy butyl ester, using Py-GC/mass spectrometry (MS). The Py-GC method combined with TBAH successfully characterized polyphenol fragments with a carbonyl group causing differ high photo-yellowing in CTMP papers using a microgram order of samples.

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A Study of the Yellowing Phenomenon in the Laser Patterning of Silver Nanowire (은 나노와이어 레이저 패터닝 시 발생하는 황변 현상에 대한 연구)

  • Hwang, June Sik;Park, Jong Eun;Yang, Min Yang
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.1
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    • pp.94-97
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    • 2015
  • In this study, we introduce a yellowing phenomenon in silver nanowire laser patterning and attempt to understand the cause of this phenomenon. Silver nanowire is a promising alternative to indium tin oxide as a transparent electrode owing to its flexibility. Additionally, silver nanowire can be easily patterned by laser ablation, which is free of dangerous chemicals. However, a yellowish color change reducing visibility is observed on the patterned area of the silver nanowires, and this yellowing phenomenon prevents the use of silver nanowire as a transparent electrode material. We concluded that resolidified debris of melted and evaporated silver nanowires after laser ablation causes the color change of the electrode. Further research is needed to determine a means of mitigating this yellowing phenomenon.

Influence of Oxygen Plasma Treatments on Yellowing of Polyester Fabrics (산소 플라즈마 처리가 폴리에스테르 직물의 황변에 미치는 영향)

  • 권영아
    • Textile Coloration and Finishing
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    • v.10 no.6
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    • pp.1-9
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    • 1998
  • The effects of oxygen plasma treatments at different discharge power, reaction pressure, treatment time on yellowing of polyester fabrics were studied. Surface characteristics of the treated fabrics were also investigated by means of SEM and ESCA. The results were as follows : The yellowing of fabrics increases as the power and the treatment time are increased, and decreases as the pressure is increased. The plasma treatment of 100 Watt, 200 mTorr, 5 min. is the optimal condition which is most effective in holding whiteness as well as high weight loss of fabrics.

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Application of Image Analysis to the Evaluation of Natural Soils (천연오염 평가에 대한 화상분석의 응용)

  • 이일심;차옥선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.1
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    • pp.194-205
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    • 1997
  • The typical instrumental assessment of ununiform natural soils has been carried out by yellowing of the specimens instead of the surface reflectance or the calculated formula. However, the regular instrumental area of sample holder is necessary for the measure of yellowing. Therefore, this study attempted to apply image analysis which had full color image by scanning of one time without limitation of instrumental area. The test samples were analyzed pseudo and full color image. This paper evaluated soil with hue of yellowing and gradation of gray level with color image analysis. Then, it was studied propriety of image analysis with correlation of yellowing, hue and gray level. Ultimately, the proposed image analysis in this paper was advanced method against the typical instrumental assessment.

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Effect of Residual Soils on Yellowing of White Cotton Fabrics after Repeated Home Laundry (가정세탁에서 잔류오구가 백색 면직물의 황변에 미치는 영향)

  • 이일심
    • Journal of the Korean Home Economics Association
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    • v.35 no.2
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    • pp.137-145
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    • 1997
  • The effect of accumulated residual soils in wear and wash tests on yellowing of white dress shirt was studied. The test samples after repeated home laundry at 20 households for six months were measured residual soils, $\Delta$b*.As well as, correlation between residual soils and yellowing was also examined. As a result, residual soils increased with number of wear and wash cycles, a little decreased in using with enzyme detergent. The b* value of test samples with fluorescent whitening agent were distributed -12.850~0.291. Correlation coefficient between sebum soils, protein soils and $\Delta$b* was 0.98, 0.58. Ultimately, residual sebum soils have more higher correlation than residual protein soils. Hence, residual sebum soils have more effect on yellowing than residual protein soils. therefore, effective a device as improvement of laundry condition and textile development needs for decrease of sebum soils.

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