• 대한화학회지
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• 제55권2호
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• pp.183-188
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• 2011

Ni$(C_6H_{4-n}F_n)(CO)_2$ ($C_6H_4$=benzyne, n=1-4) 착물의 전자구조 및 성질을 혼성 밀도 함수 B3LYP 이론을 이용하여 조사하였다. Benzyne 고리에 대한 방향족 성질과 벤젠핵과 무관한 화학적이동(NICS)을 분석하였다. 일-, 이- 및 삼-플루오르화 착물 중에서 3-F, 3, 6-F, 및 4-H는 각기 가장 안정한 이성질체였다. 고리 중심 상단의 여러 점에서 계산한 NICS 수치는 이들 착물의 상대 에너지에 의해 구한 값들과 일치하였다. 분자-내-원자(AIM) 분석에서 얻어진 Ni-C 결합거리는 모든 화학종에 대한 고리 임계점의 전자밀도(${\rho}_{rcp}$)와 좋은 상관성을 보였다.

• Structural Engineering and Mechanics
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• 제69권2호
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• pp.221-230
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• 2019

In this paper, shear behavior of non-persistent joint surrounded in concrete and gypsum layers has been investigated using experimental test and numerical simulation. Two types of mixture were prepared for this study. The first type consists of water and gypsum that were mixed with a ratio of water/gypsum of 0.6. The second type of mixture, water, sand and cement were mixed with a ratio of 27%, 33% and 40% by weight. Shear behavior of a non-persistent joint embedded in these specimens is studied. Physical models consisting of two edge concrete layers with dimensions of 160 mm by 130 mm by 60 mm and one internal gypsum layer with the dimension of 16 mm by 13 mm by 6 mm were made. Two horizontal edge joints were embedded in concrete beams and one angled joint was created in gypsum layer. Several analyses with joints with angles of $0^{\circ}$, $30^{\circ}$, and $60^{\circ}$ degree were conducted. The central fault places in 3 different positions. Along the edge joints, 1.5 cm vertically far from the edge joint face and 3 cm vertically far from the edge joint face. All samples were tested in compression using a universal loading machine and the shear load was induced because of the specimen geometry. Concurrent with the experiments, the extended finite element method (XFEM) was employed to analyze the fracture processes occurring in a non-persistent joint embedded in concrete and gypsum layers using Abaqus, a finite element software platform. The failure pattern of non-persistent cracks (faults) was found to be affected mostly by the central crack and its configuration and the shear strength was found to be related to the failure pattern. Comparison between experimental and corresponding numerical results showed a great agreement. XFEM was found as a capable tool for investigating the fracturing mechanism of rock specimens with non-persistent joint.

• Clinical and Experimental Reproductive Medicine
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• 제49권2호
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• pp.149-158
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• 2022

Objective: Optimizing culture media for the incubation of immature oocytes is a vital strategy to increase the oocyte maturation rate during in vitro maturation (IVM) programs. This study evaluated the IVM and fertilization rates of human germinal vesicle (GV) and metaphase I (MI) oocytes using two different maturation media (commercial and homemade) with or without growth differentiation factor 9-β (GDF9-β). supplementation. Methods: Immature oocytes from intracytoplasmic sperm injection (ICSI) cycles were collected and assigned to one of two IVM culture media (commercial or homemade; cleavage-stage base). After maturation, MII oocytes were examined under an inverted microscope for the presence of the polar body, zona pellucida (ZP) birefringence, and meiotic spindle (MS) visualization after maturation in four conditions (commercial or homemade medium, with or without GDF9-β. ICSI was done for matured oocytes, and fertilization was confirmed by the visualization of two distinct pronuclei and two polar bodies. Results: No significant differences were found between the two culture media in terms of the time and rate of oocyte maturation or the rate of fertilization (p>0.05). Growth factor supplementation increased the 24-hour maturation rate for both GV and MI oocytes only in homemade medium. The maturation rate after 24 hours was higher for MI oocytes (p<0.05). Similar results were observed for MS visualization and ZP structure in both types of media (p>0.05). Conclusion: Higher rates of oocyte maturation and fertilization were observed after application of homemade medium supplemented with GDF9-β. Therefore, this combination may be recommended as an alternative for clinical IVM programs.

• 대한화학회지
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• 제45권6호
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• pp.546-548
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• 2001

클로로술폰산을 실리카겔과 반응시키면 실리카겔 표면에 황산이 공유결합으로 고정된 실리카황산을 얻게 된다. 무용매 조건하에서 마이크로웨이브를 쪼여주면서 실리카 황산과 젖은 $SiO_2$를 함께 사용하게 되면 아세탈을 화합물로 변화시키는 효과적인 탈아세탈 시약으로 사용할 수 있다.

• 한국수학교육학회지시리즈B:순수및응용수학
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• 제25권3호
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• pp.203-218
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• 2018

An old result of Whitehead says that the set of derivations of a group with values in a crossed G-module has a natural monoid structure. In this paper we introduce derivation of crossed polymodule and actor crossed polymodules by using Lue's and Norrie's constructions. We prove that the set of derivations of a crossed polygroup has a semihypergroup structure with identity. Then, we consider the polygroup of invertible and reversible elements of it and we obtain actor crossed polymodule.

• 대한수학회보
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• 제47권4호
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• pp.743-750
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• 2010

For several Banach spaces X and Y and operator ideal $\cal{U}$, if $\cal{U}$(X, Y) denotes the component of operator ideal $\cal{U}$; according to Freedman's definitions, it is shown that a necessary and sufficient condition for a closed subspace $\cal{M}$ of $\cal{U}$(X, Y) to have the alternative Dunford-Pettis property is that all evaluation operators $\phi_x\;:\;\cal{M}\;{\rightarrow}\;Y$ and $\psi_{y^*}\;:\;\cal{M}\;{\rightarrow}\;X^*$ are DP1 operators, where $\phi_x(T)\;=\;Tx$ and $\psi_{y^*}(T)\;=\;T^*y^*$ for $x\;{\in}\;X$, $y^*\;{\in}\;Y^*$ and $T\;{\in}\;\cal{M}$.

• Kyungpook Mathematical Journal
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• 제55권4호
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• pp.827-835
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• 2015

Let U be a ${\sigma}$-square closed Lie ideal of a 2-torsion free ${\sigma}$-prime ${\Gamma}$-ring M. Let $d{\neq}1$ be an automorphism of M such that $[u,d(u)]_{\alpha}{\in}Z(M)$ on U, $d{\sigma}={\sigma}d$ on U, and there exists $u_0$ in $Sa_{\sigma}(M)$ with $M{\Gamma}u_0{\subseteq}U$. Then, $U{\subseteq}Z(M)$. By applying this result, we generalize the results of Oukhtite and Salhi respect to ${\Gamma}$-rings. Finally, for a non-zero derivation of a 2-torsion free ${\sigma}$-prime $\Gamma$-ring, we obtain suitable conditions under which the $\Gamma$-ring must be commutative.

• Journal of applied mathematics & informatics
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• 제26권5_6호
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• pp.945-959
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• 2008

n-ary $H_v$-structures is a generalisation of both n-ary structures and $H_v$-structures. A wide class of n-ary $P-H_v$-groups is the n-ary $P-H_v$-groups that is concidered in this paper. In this paper the notion of a normal subgroup of an n-ary $P-H_v$-groups is introduced and the isomorphism theorems for n-ary $P-H_v$-groups are stated and proved. Also some examples and related properties are investigated.

• 한국수학교육학회지시리즈B:순수및응용수학
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• 제21권4호
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• pp.237-246
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• 2014

Let M be a prime ${\Gamma}$-ring and let d be a derivation of M. If there exists a fixed integer n such that $(d(x){\alpha})^nd(x)=0$ for all $x{\in}M$ and ${\alpha}{\in}{\Gamma}$, then we prove that d(x) = 0 for all $x{\in}M$. This result can be extended to semiprime ${\Gamma}$-rings.

• Bulletin of the Korean Chemical Society
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• 제27권8호
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• pp.1127-1132
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• 2006

A new salicylate-selective electrode based on the complex N,N'-1,4-butylene bis(3-methyl salicylidene iminato) copper(II) as the membrane carrier was developed. The electrode exhibits a good Nernstian slope of 59.1 ${\pm}$ 1.0 mV/decade and a linear range of $1.0\;{\times}\;10^{-6}$-1.0 M for salicylate. The limit of detection was $5.0\;{\times}\;10^{-7}$ M. It has a fast response time 10 s and can be used for more than three months. The selective coefficients were determined by the fixed interference method (FIM) and could be used in the pH range 4.5-10.5. It was employed as an indicator electrode for direct determination of salicylate in pharmaceutical samples.