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Near-Infrared and Blue Emissions of LuNbO4:Yb3+, Tm3+ Phosphors (LuNbO4:Yb3+, Tm3+ 형광체의 근적외선 및 청색 발광 특성)

  • Im, Min Hyuk;Kim, Young Jin
    • Korean Journal of Materials Research
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    • v.28 no.6
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    • pp.355-360
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    • 2018
  • $LuNbO_4:0.2Yb^{3+},xTm^{3+}$ powders were prepared using a solid-state reaction process. The effects of the amount of Tm on up-conversion(UC) and down-conversion(DC) luminescence properties are investigated. X-ray diffraction patterns confirm that $Yb^{3+}$ and $Tm^{3+}$ ions are successfully incorporated into Lu sites. Under 980 nm excitation, the UC spectra of the powders predominantly exhibit strong near-infrared emission bands that peak at 805 nm, whereas weak 480 nm emission bands are observed as well. The emission bands are assigned to the $^1G_4{\rightarrow}^3H_6$ (480 nm) and 3 $^3H_4{\rightarrow}^3H_6$ (805 nm) transitions of the $Tm^{3+}$ ions via an energy transfer from $Yb^{3+}$ to $Tm^{3+}$; two- and three-photon UC processes are responsible for the 805 and 480 nm emissions, respectively. The DC emission spectra exhibit blue emission ($^1D_2{\rightarrow}^3F_4$) of $Tm^{3+}$ at 458 nm. The amount of Tm affects the emission intensity with the strongest emissions at x = 0.007 and 0.02 for the UC and DC luminescence, respectively. The results demonstrate that $LuNbO_4:Yb^{3+},Tm^{3+}$ phosphors are suitable for bio-applications.

Optimization of a Passively Q-switched Yb:YAG Laser Ignitor Pumped by a Laser Diode with Low Power and Long Pulse Width

  • Kim, Jisoo;Moon, Soomin;Park, Youngin;Kim, Hyun Su
    • Current Optics and Photonics
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    • v.4 no.2
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    • pp.127-133
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    • 2020
  • We successfully constructed a passively Q-switched Yb:YAG laser ignitor pumped by a diode laser with low power and long pulse width. To the best of our knowledge, this is the first study to achieve a quasi-MW output power from an optimized Q-switch Yb:YAG laser ignitor by using a pumping diode laser module emitting at under a power of 23 W. The output pulse energy of our optimized laser is 0.98 mJ enclosed in a 1.06 ns pulse width, corresponding to a peak power of 0.92 MW.

Near IR Spectroscopic Studies on the Interaction between Acetamide and Lu$(dpm)_3$ in Carbon Tetrachloride

  • 최영상;김홍순;유정아;이상원;박정희;윤창주
    • Bulletin of the Korean Chemical Society
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    • v.17 no.6
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    • pp.511-514
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    • 1996
  • The interactions between Ln(dpm)3 [Ln3+=Eu3+, Yb3+, Pr3+, Sm3+, Tb3+and Ho3+; dpm=tris 2,2,6,6-tetramethylheptane-3,5-dionate] and acetamide in CCl4 solution were investigated using near IR absorption spectroscopy. From the measured 2 νC=O+ amide Ⅲ combination band of acetamide in the region of 2130-2180 nm(4695-4587 cm-1), it was found that acetamide is coordinating through its carbonyl oxygen atom to Ln(dpm)3[C=O…Ln(dpm)3)] and forms only 1 : 1 stoichiometric Ln(dpm)3- acetamide complex. The ΔHo values for the formation of Ln(dpm)3-acetamide obtained from the temperature studies are -39.1, -28.4, -25.5, -24.7, -21.1 and -17.7 kJ mol-1 for Eu(dpm)3, Yb(dpm)3, Pr(dpm)3, Sm(dpm)3, Tb(dpm)3 and Ho(dpm)3, respectively, which are larger than those of the hydrogen bond between amide and various hydrogen acceptors. Except Eu(dpm)3 and Yb(dpm)3, -ΔHovalue increases as the ionic size increases.

High-power Quasi-continuous Wave Operation of Incoherently Combined Yb-doped Fiber Lasers

  • Jeon, Minjee;Jung, Yeji;Park, Jongseon;Jeong, Hoon;Kim, Ji Won;Seo, Hongseok
    • Current Optics and Photonics
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    • v.1 no.5
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    • pp.525-528
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    • 2017
  • High-energy, high-power, quasi-continuous wave (QCW) operation of double-clad Yb fiber lasers incorporating an incoherent signal combiner is reported. We constructed four efficient, high-power Yb fiber lasers, each of which produced rectangular pulses at 1080 nm with a pulse energy greater than 15 J, and a pulse duration of 10 ms at a repetition rate of 10 Hz, corresponding to an average power of over 150 W and a peak power of over 1.5 kW for ~200 W of incident pump power at 915 nm. These laser outputs were combined by a homemade incoherent fiber signal combiner with low loss, yielding a maximum peak power of ~6.0 kW in a beam with $M^2{\approx}12.5$. The detailed laser characteristics and prospects for further power scaling in QCW operation are discussed.

Microwave Sol-Gel Process for Microcystalline Ho3+/Yb3+/Tm3+ Tri-Doped NaY(WO4)2 Phosphors and Their Upconversion Photoluminescence Properties

  • Lim, Chang Sung
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.757-763
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    • 2016
  • $Ho^{3+}/Yb^{3+}/Tm^{3+}$ tri-doped $NaY_{1-x}(WO_4)_2$ phosphors with proper doping concentrations of $Ho^{3+}$, $Yb^{3+}$ and $Tm^{3+}$ ($x=Ho^{3+}+Yb^{3+}+Tm^{3+}$, $Ho^{3+}$=0.04, 0.03, 0.02, 0.01, $Yb^{3+}$=0.35, 0.40, 0.45, 0.50 and $Tm^{3+}$=0.01, 0.02, 0.03, 0.04) were successfully synthesized via the microwave sol-gel route, and their upconversion properties were investigated. Well-crystallized microcrystalline particles showed fine and homogeneous microcrystalline morphology with particle sizes of $1-2{\mu}m$. The optical properties were comparatively examined using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the doped particles exhibited white emissions based on blue, green and red emission bands, which correspond to the $^1G_4{\rightarrow}^3H_6$ transitions of $Tm^{3+}$ in the blue region, the $^5S_2/^5F_4{\rightarrow}^5I_8$ transitions of $Ho^{3+}$ in the green region, the $^5F_5{\rightarrow}^5I_8$ transitions of $Ho^{3+}$, and the $^1G_4{\rightarrow}^3F_4$ and $^3H_4{\rightarrow}^3H_6$ transitions of $Tm^{3+}$ in the red region. The pump power dependence of the upconversion emission intensity and the Commission Internationale de L'Eclairage chromaticity coordinates of the phosphors were evaluated in detail.