• Title/Summary/Keyword: Y-zeolite

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Purification of Eicosapentaenoic Acid (EPA) and Docosahexaenoic Acid (DHA) Esters from Squid Oil by Silver Ion Chromatography (은 이온 크로마토그래피에 의한 오징어유로부터 eicosapentaenoic acid(EPA) 및 docosahexaenoic acid(DHA)의 분리농축)

  • Gyoung, Young-Soo;Yu, Ying-Lian;Yoon, Jung-Ro
    • Korean Journal of Food Science and Technology
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    • v.36 no.2
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    • pp.361-364
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    • 2004
  • EPA and DHA extracted from methyl esterified squid oil were purified by silver exchanged resin, silver nitrate-impregnated silica gel, silver exchanged zeolite, and silica gel column chromatography, among which column chromatography using mixture of silver exchanged resin and silica gel (10% by weight) showed the best result. By this simple purification method, EPA and DHA were concentrated from 12.5 to 27.9% (yield, 86,0%) and from 21.7 to 49.5% (yield, 87.3%), respectively. Silver exchanged resin had additional advantages of outstanding reusability and simple recovery of silver.

Screening of Spray-Dried K2CO3-Based Solid Sorbents using Various Support Materials for CO2 Capture

  • Eom, Tae Hyoung;Lee, Joong Beom;Baek, Jeom In;Ryub, Chong Kul;Rhee, Young Woo
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.115-120
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    • 2015
  • $K_2CO_3$-based dry regenerable sorbents were prepared by spray-drying techniques to improve mass produced $K_2CO_3-Al_2O_3$ sorbents (KEP-CO2P, hereafter), and then tested for their $CO_2$ sorption capacity by a $2,000Nm^3/h$ (0.5 MWe) $CO_2$ capture pilot plant built for Unit 3 of the Hadong thermal power station in 2010. Each of the sample sorbents contained 35 wt.% $K_2CO_3$ as the active materials with various support materials such as $TiO_2$, MgO, Zeolite 13X, $Al_2O_3$, $SiO_2$ and hydrotalcite (HTC). Their physical properties and reactivity were tested to evaluate their applicability to a fluidized-bed or fast transport-bed $CO_2$ capture process. The $CO_2$ sorption capacity and percentage utilization of $K_2CO_3$-MgO based sorbent, Sorb-KM2, was $8.6g-CO_2/100g$-sorbents and 90%, respectively, along with good mechanical strength for fluidized-bed application. Sorbs-KM2 and KT were almost completely regenerated at $140^{\circ}C$. No degradation of Sorb-KM by $SO_2$ added as a pollutant in flue gas was observed during a cycle test.

Subjective Hand and Preference of Washed Fabrics according to Detergent of Drum Type Washer (드럼세탁기용 세제 특성에 따른 세탁포의 주관적 태평가 및 선호도에 관한 연구)

  • Ryu, Hyo-Seon;Roh, Eui-Kyung;Ju, Jeong-Ah;Oh, Young-Kee;Cho, Kee-Heon;Kwak, Sang-Woon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.1 s.160
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    • pp.57-67
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    • 2007
  • The purpose of this study is to find out the better washing condition, especially on detergent contents to satisfy the consumer's concern on fabric hand using Drum Type Washer. The hand and preference of washed fabrics by various detergent contents were analyzed through subjective evaluation using questionnaire method in dry and wet state. Wine rank's semantic differential scale questions were developed with 27 kinds of adjective pairs and seven rank's scale questions were to evaluate preference of washed fabrics oil holistic touch, washing and rinsing effect and purchase intention of detergent. Group of trained panelists and untrained women panelists of $30{\sim}40$ years old were participated. The factors affecting consumer's taste for the washed fabrics were analyzed by SPSS 12.0. Smoothness showed relatively higher correlation with preference of washed fabrics on holistic touch, washing and rinsing effect and purchase intention of detergent. There were significant differences in preference of washed fabrics on holistic touch, washing and rinsing effect and purchase intention of detergent by detergent contents when tested in wet state. Fabrics washed with detergents of non-zeolite were appeared to be the preferred ones.

Zeolites in the Volcaniclastics of Jeju Island (제주도 화산쇄설암의 불석광물)

  • Jeong, Gi-Young;Sohn, Young-Kwan;Jeon, Yong-Mun
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.1
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    • pp.39-50
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    • 2010
  • Zeolites were formed by the alteration of volcanic glass in the volcaniclastics including tuff cone/rings and subsurface Seoguipo Formation, Jeju Island. Phillipsite and analcime were identified by X-ray diffraction and electron microprobe analysis. Si/(Si+Al) atom ratios of analcime and phillipsite were similar to that of parent basaltic glass. In comparison with the simple chemistry of analcime, phillipsite showed a range of cavity cation compositions. Na is the major cavity cations of phillipsite in the Dangsanbong and Yongmeori tuffs bearing analcime, while K and Ca in core samples of Seoguipo Formation. Microtextural analysis by scanning electron microscope showed a general sequence that early phillipsite encrustification of pores was followed by later analcime infilling. Zeolites are abundant in the older tuff cone/rings but nearly absent in the younger ones.

Preparation Nanosized TPA-Silicalite-1 with Different Silica Sources and Promoters (다양한 실리카 원과 결정화 촉진제를 이용한 나노크기의 TPA-Silicalite-1 제조)

  • Jung, Sang-Jin
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.286-291
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    • 2014
  • In this study, nanosized TPA-silicalite-1 was synthesized with a suitable molar composition of TPAOH: $SiO_2$: $H_2O$ for the development of zeolite ceramic membranes to utilize as gas separation. As silica sources, TEOS, LUDOX AS-40 and CAB-O-SIL were used with the starting material of TPAOH. $NaH_2PO_4$, and a variety of acids and bases were used as promoters after TPAOH, $SiO_2$, $H_2O$ gel synthesis. To decrease synthesis time, a two step temperature change method was applied to the synthesis of TPA-silicalite-1 at a low temperature. TPA-silicalite-1 synthesized was analyzed with XRD, SEM, BET and TGA. As a result, TPA-silicalite-1 powders with a particle size of 100 nm and a specific surface area of $416m^2/g$ were obtained as optimum synthesis conditions when the two stage temperature change method was used with $NaH_2PO_4$ as promoter.

Characteristics of Leaves, Roots, and Fruit as Influenced by Energized-Functional Water Supply in Fuji Apple Trees (Energized 기능수 처리에 따른 후지사과의 잎, 뿌리 및 과실특성)

  • Kim, Wol Soo;Chung, Soon Ju
    • Horticultural Science & Technology
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    • v.16 no.2
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    • pp.233-235
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    • 1998
  • Energized-functional water (EFW) and powder (EFP) were manufactured by Kyungwon Institute of Life Science, Seoul, through a series of processes; tap water ultra-purification energy imprinting with catalysts in platinum columns mixing energy-imprinted water + activated zeolites + photosynthetic bacteria fermenting at $25^{\circ}C$ filtering EFW and/or EFP. A single application of EFP to soil under tree canopy before bud burst, combined with three EFW applications to soil during growth of 'Fuji' apples (Malus domestica Borkh.) resulted in a higher Ca concentrations in fruit skins and flesh, and lower Ca and N concentrations in leaves and shoot-bark tissues. EFW also stimulated the net photosynthesis of leaves and root activity. Soluble solid concentrations (SSC) and anthocyanin levels of fruits were also significantly increased at harvest, producing greater firmness and less core browning during storage at $0^{\circ}C$. However, there was no significant difference in titratable acidity of fruit juice between the EFW treatment and the controls.

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Mono-granular Compound Fertilizer Acting Slow Release for the Crops Under Vinyl Mulching Cultivation -I. Effect of formulation and granulation on slow release (비닐멀칭작물재배용(作物栽培用) 지효성(遲效性) 전용복비(專用複肥) 개발(開發) -I. 제립(製粒)이 지효성(遲效性)에 미치는 영향(影響))

  • Shin, Jae-Sun;Lim, Dong-Kyu;Seong, Ki-Seog;Kim, Bok-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.2
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    • pp.97-100
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    • 1987
  • Medium grade mongranular compound fertilizers for the crops under vinyl mulching cultivation were formulated using the principal materials of urea, DAP and MOP in combination with various fillers of zeolite, gypsum and treated human waste and granulated with waste liquid of glutamic acid fermentation as binder. The ratios of $N-P_2O_5-K_2O$ of trial products were 12-10-11.5 for red pepper, 8-8-6 for sesame and 4-9-14 for peanut. The rate of dissolution of trial products was comparatively low in water. The product for red pepper had N dissolution rate of 80 percent during 24 hrs. 70 for peanut and 55 for seasame. The optimum dissolution rate has reported to be 50 percent by the standard laboratory dissolution test for 24 hrs. in water. Therefore, the slowly released characteristics were obtained with the products that had 24 hrs. dissolution of 70 to 60 percent. One time basal application of trial products could readily be justified under muching cultivation.

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Natural radioactivity level in fly ash samples and radiological hazard at the landfill area of the coal-fired power plant complex, Vietnam

  • Loan, Truong Thi Hong;Ba, Vu Ngoc;Thien, Bui Ngoc
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1431-1438
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    • 2022
  • In this study, natural radioactivity concentrations and dosimetric values of fly ash samples were evaluated for the landfill area of the coal-fired power plant (CFPP) complex at Binh Thuan, Vietnam. The average activity concentrations of 238U, 226Ra, 232Th and 40K were 93, 77, 92 and 938 Bq kg-1, respectively. The average results for radon dose, indoor external, internal, and total effective dose equivalent (TEDE) were 5.27, 1.22, 0.16, and 6.65 mSv y-1, respectively. The average emanation fraction for fly ash were 0.028. The excess lifetime cancer risks (ELCR) were recorded as 20.30×10-3, 4.26×10-3, 0.62×10-3, and 25.61×10-3 for radon, indoor, outdoor exposures, and total ELCR, respectively. The results indicated that the cover of shielding materials above the landfill area significantly decreased the gamma radiation from the ash and slag in the ascending order: Zeolite < PVC < Soil < Concrete. Total dose of all radionuclides in the landfill site reached its peak at 19.8 years. The obtained data are useful for evaluation of radiation safety when fly ash is used for building material as well as the radiation risk and the overload of the landfill area from operation of these plants for population and workers.

Structural Study of Selenium Sorption Complex of Fully Dehydrated, Partially Ca2+-exchanged Zeolite A (완전히 탈수되고 부분적으로 칼슘 이온으로 교환된 제올라이트 A의 셀레늄 수착 화합물의 구조 연구)

  • Kim, Hu Sik;Park, Jong Sam;Lim, Woo Taik
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.251-258
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    • 2020
  • Single crystal of fully dehydrated and partially Ca2+-exchanged zeolites A (|Ca4Na4|[Si12Al12O48]-LTA) was brought into contact with Se in fine pyrex capillary at 523 K for 5 days. Crystal structure of Se-sorbed |Ca4Na4|[Si12Al12O48]-LTA has been determined by single-crystal X-ray diffraction techniques at 294 K in the cubic space group $Pm{\bar{3}}m$ (a = 12.2787(13) Å). The crystal structure of yellow |Ca4Na4Se4|[Si12Al12O48]-LTA has been refined to the final error indices of R1/wR2 = 0.0960/0.3483 with 327 reflections for which Fo > 4s(Fo). In this structure, 4 Na+ and 4 Ca2+ ions fill every 6-ring site: These ions are all found at three crystallographic positions, on 3-fold axes equipoints of opposite 6-rings. Selenium atoms are found at three crystallographically distinct positions: 2 Se atoms per unit cell at Se(1) are located opposite 6-rings in the sodalite cavity (Se(1)-Na(1) = 2.53(5) Å) and 1 at Se(2) opposite 4-rings (Se(2)-O(1) = 2.76(10) Å) and 1 at Se(3) opposite 6-rings in the large cavity (Se(3)-Na(1) = 2.48(5) Å). Two molecular of Se2 (Se(1)-Se(1) = 2.37(7) or 2.90(8) Å and Se(2)-Se(3) = 2.91(5) ) Å) are found in all sodalite cavity and large cavity. Other clusters such as Se4 and Se8 could be existed in large cavity. The inter-selenium distances turned out to be longer that of gases Se2 molecule.

Effects of Livestock Compost and Soil Conditioner Application on Greenhouse Gases Emission in Paddy Soil (가축분퇴비 및 토양개량제 처리가 온난화 가스 배출에 미치는 영향)

  • Lee, Kyeong-Bo;Kim, Jong-Gu;Shin, Yong-Kwang;Lee, Deog-Bae;Lee, Sang-Bok;Kim, Jae-Duk
    • Korean Journal of Environmental Agriculture
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    • v.24 no.2
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    • pp.117-122
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    • 2005
  • To find out reducing way of methane emission from a paddy field monitoring on the greenhouse gases emissions were carried out in the paddy soil with livestock compost and soil conditioner. The seasonal variations of methane emission were high at 36 days and 86 days after rice transplanting, on the other hand those of nitrous oxide emission were high at 64 days after that day. Methane emission by cow compost application, pig compost application and chicken compost application were 331, 282 and 294 kg $ha^{-1}$, respectively. Otherwise, nitrous oxide emissions by cow compost application, pig compost application and chicken compost application were 1.60, 1.78 and 1.78 kg $ha^{-1}$ respectively. The total emission rate of greenhouse gases equivalent to $CO_2$ emission rate (GWP) was 7,447 kg $ha^{-1}$ in cow compost application, 6,474 kg $ha^{-1}$ in pig compost application and 6,726 kg $ha^{-1}$ in chicken compost application. Methane emission by Ca, $SiO_2$ and artificial zeolite application were 373, 264, 239 kg $ha^{-1}$, respectively. The total emission rate of greenhouse gases equivalent to $CO_2$ emission rate (GWP) was 8,295 kg $ha^{-1}$ in Ca application 5,978 kg $ha^{-1}$ in $SiO_2$ application and 5,447 kg $ha^{-1}$ in artificial zeolite application.