• 한국세라믹학회지
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• 제26권2호
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• pp.267-275
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• 1989

YBa2Cu3O7-x oxide superconductors were fabricated by sintering and hotisostatic pressing (HIP), and their microstructures and properties were compared with each other. Thougha part of the second phase was observed along grain boundaries, their structures were consisted of single (123) phase and they had many porosities. But, porosities were remakably reduced by Hiping and the densification was brought about. The structure of (123) compound also showed a number of twins, which are typical of high Tc superconductors. The on-set temperature of YBa2Cu3O7-x compound sintered at 96$0^{\circ}C$ in oxygen and hipped at 88$0^{\circ}C$ was highest, but that shwoed 0 resistance at 87$^{\circ}$K, which is a little lower than the compound sintered at 96$0^{\circ}C$. HIP treatment also increased the critical current density of as-sintered compound. However, its value was low, which may be ascribed to the many pores of starting-sintered compact and partially to the second phase along grain boundaries.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1988년도 춘계학술대회 논문집
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• pp.10-12
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• 1988

High Tc Y-Ba-Cu-O Superconductors were fabricated by sintering, sintering + HIP and Hot Pressing. Specimens were sintered at $940^{\circ}C$ and $960^{\circ}C$. In case that sintered specimens were treated by HIP, the relative density was increased 5-6% in comparison with sintered ones. X-ray analysis of each specimens represented orthorhombic phase and Tc measurements showed a sharp drop in the temperature range $95-88^{\circ}K$. The relative density of hot pressed samples was lower than 80%.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1988년도 추계학술대회 논문집
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• pp.36-40
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• 1988

High TC Y-Ba-Cu-O Superconductors were fabricated by sintering, sinter+HIP encapsulation. Specimens were sintered at 920$^{\circ}C$∼960$^{\circ}C$. A part of sintered specimens were treated by HIP, and HIP conditions were 150 MPa, 880$^{\circ}C$, 30min under the Ar atmosphere. The relative density of HIP specimens was increased 5∼8% in comparison with sintered one(90∼93% relative density). X-ray analysis represented the orthorhobic-tetragonal phase transition with annealing condition. Tc measurements showed a sharp drp within 3$^{\circ}C$, 91K onset and 89K offset. Transport current density(Jc) of sintered specimens showed typically∼159A/㎤ but that of sinter+HIP encapsulation was decreased to∼89A/㎤ because of insufficient oxygen diffusion, Hardness(H) and Toughness(Kc) were increased to 38GPa; and 2.9 MPam$\^$$\frac{1}{2}$/, respectively.

• 한국전기전자재료학회논문지
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• 제16권4호
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• pp.336-342
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• 2003

(Sm/Y)$_{1.8}$B $a_{2.4}$C $u_{3.4}$$O_{7-x}$ [(Sm/Y)1.8] high $T_{c}$ superconductors were directionally grown by Rod-type Seed Melt Growth(RSMG) process in air atmosphere. The sintered polycrystalline N $d_{1.8}$B $a_{2.4}$C $u_{3.4}$$O_{7-x}$(Nd1.8) of rod-type seed crystal grown by extrusion mold process were used for achieving the ab-plane alignment haying large grains perpendicular to the center of (Sm/Y)1.8 samples. The observations using TEM micrographs of the melt-textured (Sm/Y)1.8 samples revealed that the nonsuperconducting (Sm/Y)211 inclusions are uniformly distributed in the superconducting (Sm/Y)123 matrix. The microstructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The RSMG (Sm/Y)1.8 samples showed an onset $T_{c}$ $\geq$ 90 K and sharp superconducting transition.nsition.ion.nsition.

• 한국전기전자재료학회논문지
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• 제34권5호
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• pp.333-336
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• 2021

Oxide YBCO bulk superconductors are manufactured using the melt process. Because seed crystal growth method utilizes a slow-spreading layer-by-layer reaction, a long-term heat treatment is required to manufacture a single-crystal specimen of several cm. In this study, the melt process method was applied to compensate for the shortcomings of the seed crystal growth method. The thickness of the upper and lower pellets of the YBCO bulk was molded to 40 mm, and YBCO superconductor was produced by heat treatment. The measurement results of capture magnetism was in line with the literature. This results in a relationship that the higher the growth of Y211 particle in the YBCO, the higher the superconducting properties. We analyzed the YBCO superconductor, focusing on the Y₂BaCuO₅ particle distribution.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1993년도 춘계학술대회 논문집
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• pp.134-136
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• 1993

Using the extended H$\ddot{u}$ckel molecular orbital method in connection with the tight binding model, we have studied electronic structure and related properties of superconducting $YBa_2Cu_3O_{7-x}$ crystals in which O-atoms in regular sites were selectively replaced with F atoms. The calculations are based on the crystal structure of Y-Ba-Cu-O obtained by Beno et al.. We use atomic coordinates that refer to the unrelaxed Y-Ba-Cu-O system. In analogy to the isomerism problem with molecules, we discuss all possible combinations of F-substitutions in O-sites with one, two, and four F atoms. The calculations are carried out within charged clusters model for the analogues of the YBa-free copperoxide. Our results suggest that the electronic structure of the symmetrically F-substituted or F-added compound is closer to that of the oxygen-deficient superconducting compound than that obtained from unsymmetrical substitution. This applies in particular if O is replaced with in an O(1) site. This suggests that superconductivity is very sensitive to the oxygen content of the $CuO_2$ layers.

• 동굴
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• 제76호
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• pp.49-55
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• 2006

The submicron $YBa_2Cu_3O_x$ powder was prepared by the sol-gel method. The particle size is distributed from 0.2 to 1.0 ${\mu}m$, which benefits to eliminate the micro-cracks formed in the $YBa_2Cu_3O_x$ films deposited by electrophoresis. The powder was single phase of $YBa_2Cu_3O_x$ examined by X-ray diffraction. In the sol-gel process the citrate gel was formed from citric acid and nitrate solution of $Y_2O_3$, $Ba(NO_3)_2$ and CuO. When pH values were adjusted to 6.4-6.7, $Ba(NO_3)_2$ could be dissolved in the citrate solution completely. Appropriate evaporative temperature of the sol-gel formation is discussed. Acetone is used as electrophoreticsolution, in which some water and iodine (0.2 g/1) and polyethylene glycol (2 vol. %) are added. The concentrations of $YBa_2Cu_3O_x$ powders is 20g/l. The thickness of deposited film could be more than 50 ${\mu}m$ in 3 minutes of depositing time. The most EPD films could be 90K zero resistance and the Jc values were over 1000A/cm2 (0 H, 77 K).

• 대한화학회지
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• 제36권1호
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• pp.16-23
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• 1992

고온초전도체 $YBa_2Cu_3O_{7-{\delta}}$에서 Y를 Eu로 치환시킨 $(Y_{1-x}Eu_x)Ba_2Cu_3O_{7-{\delta}}$ (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0)를 제조한 후 물성변화를 관찰하였다. X-선 회절분석결과 모든 시료가 사방정계 구조를 갖고 있었으며 x값이 증가함에 따라 격자상수 a, b 및 c도 증가하였다. 전기저항과 자화율측정으로부터 순수한 90K 이상의 고온초전도상이 생성되었음을 알았으며, x값이 커짐에 따라 임계온도가 상승하였다. 주사전자현미경을 사용하여 구한 낟알크기와 자화측정결과로부터 각각의 시료들에 대한 부피 반자성자화율을 구하였으며, x값이 커질수록 이 값은 감소하였다. Eu의 농도가 증가함에 따라 결정격자내의 Ba의 양이 감소됨을 EPMA로 확인하였으며, 이것은 부피반자성 자화율의 감소에 직접적인 영향을 주는 것으로 판단된다.

• 한국초전도ㆍ저온공학회논문지
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• 제13권1호
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• pp.6-11
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• 2011

The $BaHfO_3$ (BHO) buffer layer on the IBAD MgO template was turned to be effective for a successful fabrication of $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) films with high critical current density ($J_c$). Both the BHO buffer layers and GdBCO films were prepared by pulsed laser deposition (PLD). The effects of the PLD conditions, including substrate temperature ($T_s$), oxygen partial pressure ($PO_2$), and deposition time on the in-plane texture, surface roughness, and microstructures of the BHO buffer layers on the IBAD MgO template were systematically studied for processing optimization. The c-axis oriented growth of BHO layers was insensitive to the deposition temperature and the film thickness, while the in-plane texture and surface roughness of those were improved with increasing $T_s$ from 700 to $800^{\circ}C$. On the optimally processed BHO buffer layer, the highest $J_c$ value (77 K, self-field) of 3.68 $MA/cm^2$ could be obtained from GdBCO film deposited at $780^{\circ}C$, representing that BHO is a strong candidate for the buffer layer on the IBAD MgO template.

• 한국전기전자재료학회논문지
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• 제20권6호
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• pp.550-554
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• 2007

Large and single-grain Y-Ba-Cu-O(YBCO) bulk superconductors have been fabricated by using a seeded infiltration and growth method. $Y_2BaCuO_5$(Y211) precursor pellets and $YBa_2Cu_3O_x$(Y123) liquid source pellets were prepared using commercial powder and were processed by infiltration and growth method to achieve low pore and high trapped field property. The superconductor properties of the single crystal are measured and analyzed in relation with the density and size of the Y211 particle in the Y123 matrix. An optimum processing condition is suggested based on the analyzed results.