• Journal of the Korean Chemical Society
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• v.36 no.3
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• pp.351-359
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• 1992

Interaction of xenon with alkaline-earth cations in Y zeolite supercage was studied by xenon adsorption and $^{129}Xe$ NMR experiments. The CaY and the BaY samples were prepared by exchanging $Ca^{2+}$ and $Ba^{2+}$ into a high-purity NaY zeolite. Xenon adsorption isotherms of these samples were obtained by using a conventional volummetric gas adsorption apparatus in the range of 260 to 320 K and the chemical shift in the $^{129}Xe$ NMR spectrum of the adsorbed xenon was measured at 296 K. The chemical shift against pressure was quantitatively explained assuming that the xenon gas exchanged very rapidly between various adsorption sites consisting of zeolite-framework surface and alkaline-earth ion. From this analysis, it was found that the alkaline-earth ion adsorbed xenon more strongly than $Na^+$ ion and zeolite-framework surface. Baring on the difference of the adsorption strength, the number of the alkaline-earth cations present in the zeolite supercage could be estimated by analyzing the adsorption isotherm.

• Nuclear Engineering and Technology
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• v.56 no.2
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• pp.601-610
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• 2024

This paper gives an extensive analysis on the characterization of xenon isotopic ratios for various nuclear reactors and nuclear explosions through neutronic depletion codes. The results of the characterization can be used for discriminating the sources of the xenon isotopes' release among the nuclear explosions and nuclear reactors. The considered sources of the xenon radionuclides do not only include PWR, CANDU, and nuclear explosions using uranium and plutonium bombs, but also IRT-200 and 5MWe Yongbyon (MAGNOX reactor) research reactors operated in North Korea. A new data base (DB) on xenon isotopic activity ratios was produced using the results of the characterization, which can be used in discrimination of the sources of xenon isotopes. The results of the study show that 5MWe Yongbyon reactor has quite different characteristics in ¹³⁵Xe/¹³³Xe ratio from the PWRs and the nuclear reactors have different characteristics in ¹³⁵Xe/¹³³Xe ratios from the nuclear explosions.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.05b
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• pp.41-45
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• 2005

In this paper, parameters of electron temperature and density for the mercury-free lighting-source were measured to diagnosis and analyze in Xe based inductively coupled plasma(ICP). In results at several dependences of 20~100 mTorr Xenon pressure, 50~200W RF power and horizontal distribution were especially mentioned. When Xe pressure was 20mTorr and RF power was 200W, the electron temperature and density were respectively 3.58eV and $3.56{\times}10^{12}cm^{-3}$. The key parameters of Xe based ICP depended on Xe pressure more than RF power that could be verified. A high electron temperature and low electron density with a suitable Xe pressure are indispensible parameters for Xe based ICP lighting-source.

• Proceedings of the KIEE Conference
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• 2005.07c
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• pp.2418-2420
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• 2005

In this paper, parameters of electron temperature and density for the mercury-free lighting-source were measured to diagnosis and analyze in Xe based inductively coupled plasma(ICP). In results at several dependences of $20{\sim}100mTorr$ Xenon pressure, $50{\sim}200W$ RF power and horizontal distribution were especially mentioned. When Xe pressure was 20mTorr and RF power was 200W, the electron temperature and density were respectively 3.58eV and $3.56{\times}10^{12}cm^{-3}$. The key parameters of Xe based ICP depended on Xe pressure more than RF power that could be verified. A high electron temperature and low electron density with a suitable Xe pressure are indispensible parameters for Xe based ICP lighting-source.

• Journal of Radiation Protection and Research
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• v.40 no.3
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• pp.181-186
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• 2015

Measurement of xenon radioisotopes from nuclear fission is a key element for monitoring underground nuclear weapon tests. $^{131m}Xe$, $^{133}Xe$, $^{133}mXe$ and $^{135}Xe$ in the air can be detected via low background systems such as a beta-gamma coincidence counting system. Radioxenon monitoring is performed through air sampling, xenon extraction, measurement and spectrum analysis. The minimum detectable concentration of $^{135}Xe$ can be significantly variable depending on the sampling time, extraction time and data acquisition time due to its short half-life. In order to optimize the acquisition time with respect to certain experimental parameters such as sampling and xenon extraction, theoretical approach and experiment using SAUNA system were performed to determine the time to minimize the minimum detectable concentration, which the results were discussed.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1218-1220
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• 2005

We have developed laser absorption spectroscopy system for the measurement of excited Xe atoms in micro-discharged AC-PDP plasma. In this study, we have measured the absorption signals for the $1S_5$ xenon metastable state in the PDP cell with the various gas mixtures of Ne-Xe(1%), Ne-Xe(4%) and Ne-Xe(10%) under fixed gas pressure of 350 Torr and the eletrode gap distance of 50um. It is found that the maximum excited xenon densities are $1.2^{\ast}10^{12}\;cm^{-3}$, $1.8^{\ast}10^{12}\;cm^{-3}$ and $2.7^{\ast}10^{12}cm^{-3}$ for gas mixtures of Ne-Xe(1%), Ne-Xe(4%) and Ne-Xe(10%) respectively, in this experiment.

• Nuclear Engineering and Technology
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• v.52 no.6
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• pp.1131-1136
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• 2020

Xenon behaves differently in molten salt reactors (MSRs) compared to solid fuel reactors. This behavior needs exploring due to the large reactivity effect of the ¹³⁵Xe isotope, given the current interest in MSR power plant development for commercial deployment. This paper focuses on select topics in xenon transport, reviews relevant past works, and proposes specific research questions to advance the state of the art in each of the focus areas. Specifically, the paper discusses the issue of xenon solubility in MSRs, the behavior of particulates circulating in MSR fuel salt and its influence on the xenon transport, the possibility of ionization of xenon atoms which changes its effective size and thus affects its mass transport, and finally the issue of circulating void fraction and how it is measured. This work presents specific recommendations for MSR designers to research the limits of Henry's law validity, circulating particulate scrubbers, validity of mass transport coefficients in high radiation fields, and the effects of pump speed on circulating void fraction.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.415-415
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• 2010

면방전 구조의 AC-PDP는 페닝 혼합 기체 중에서 Xe 플라스마에서 발생되는 VUV (Vacuum Ultra Violet) 에 의해 들뜬 형광체로부터 가시광이 발생된다. Xe 여기종은 828 nm의 공명준위를 거쳐 147 nm의 진공자외선을 방출하며 823 nm의 준안정준위에서 분자선을 거쳐 173 nm의 진공 자외선을 낸다. 이러한 Xe 여기종의 밀도를 측정하기 위해서는 828 nm와 823 nm의 레이저를 외부에서 인위적으로 조사하여 측정하면 IR (Infrared)의 흡수전과 흡수후의 빛의 세기로 Xe 여기종의 밀도 및 분포를 계산할 수 있다. 본 실험에서는 823 nm에 초점을 두었으며 LAS (Laser Absorption Spectroscopy) 기법을 통하여 He-Ne-Xe(15%, 20 %, 30%) 400Torr의 3종 기체의 Xe 함량에 따른 시공간의 Xe($1s_5$) 여기종 밀도 분포와 방전효율을 관측하였다. 최근 3전극 면방전형 AC-PDP 효율 향상을 위해 3종 기체의 Xe함량비의 방전기체에 대한 연구가 수행되고 있다. 이러한 기초 데이터는 혼합기체 조건에 따른 면방전 구조의 3전극 AC-PDP의 발광 효율을 개선하는 데 유용한 자료로 활용될 것이다.

• 한국정보디스플레이학회:학술대회논문집
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• 2007.08b
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• pp.1577-1579
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• 2007

Xe content is one of important factors related to characteristics of the mercury-free flat fluorescent lamp. The electro-optical properties of lamp were investigated for wide range of Xe content in Xe-Ne mixing gas. The maximum luminance of $9,289\;cd/m^2$ and efficacy of 3 lm/W was obtained with Xe 90 %.

• Bulletin of the Korean Chemical Society
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• v.21 no.1
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• pp.75-80
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• 2000

The positions of Xe atoms encapsulated in the molecular-dimensioned cavities of fully dehydrated Na-A have been determined. Na-A was exposed to 1050atm of xenon gas at 400 $^{\circ}C$ for seven days, followed by cooling at pressure to encapsulate Xe atoms. The resulting crystal structure of Na-A(7Xe) (a = 12.249(1) $\AA$, $R_1$ = 0.065, and $R_2$ = 0.066) were determined by single-crystal X-ray diffraction techniques in the cubic space group Pm3m at 21(1) $^{\circ}C$ and 1 atm. In the crystal structure of Na-A(7Xe), seven Xe atoms per unit cell are distributed over four crystallographically distinct positions: one Xe atom at Xe(1) lies at the center of the sodalite unit, two Xe atoms at Xe(4) are found opposite four-rings in the large cavity, and four Xe atoms, two at Xe(2) and others at Xe(3), respectively, occupy positions opposite and between eight- and six-rings in the large cavity. Relatively strong interactions of Xe atoms at Xe(2) and Xe(3) with $Na^+$ ions of four-, eight-, and six-rings are observed:Na(1)-Xe(2) = 3.09(6), Na(2)-Xe(3) = 3.11(2), and Na(3)-Xe(2) = 3.37(8) $\AA$. In each sodalite unit, one Xe atom is located at its center. In each large cavity, six Xe atoms are found, forming a distorted octahedral arrangement with four Xe atoms, at equatorial positions (each two at Xe(2) and Xe(3)) and the other two at axial positions (at Xe(4)). With various reasonable distances and angles, the existence of $(Xe)_6$ cluster is proposed (Xe(2)-Xe(3) = 4.78(6) and 4.94(7), Xe(2)-Xe(4) = 4.71(6) and 5.06(6), Xe(3)-Xe(4) = 4.11(3) and 5.32(4) $\AA$, Xe(2)-Xe(3)-Xe(2) = 93(1), Xe(3)-Xe(2)-Xe(3) = 87(1), Xe(2)-Xe(4)-Xe(2) = 91(4), Xe(2)-Xe(4)-Xe(3) = 55(2), 59(1), 61(1), and 68(1), and Xe(3)-Xe(4)-Xe(3) = 89($^{\circ}1$)). These arrangements of the encapsulated Xe atoms in the large cavity are stabilized by alternating dipoles induced on Xe(2), Xe(3), and Xe(4) by eight- and six-ring $Na^+$ ions as well as four-ring oxygens, respectively.