• Bulletin of the Korean Chemical Society
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• v.28 no.11
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• pp.2009-2014
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• 2007

The aminolysis of diphenyl thiophosphinic chloride (2) with substituted anilines in acetonitrile at 55.0 oC is investigated kinetically. Kinetic results yield large Hammett ρX (ρnuc = ?3.97) and Bronsted βX (βnuc = 1.40) values. A concerted mechanism involving a partial frontside nucleophilic attack through a hydrogen-bonded, four-center type transition state is proposed on the basis of the primary normal kinetic isotope effects (kH/kD = 1.0-1.1) with deuterated aniline (XC6H4ND2) nucleophiles. The natural bond order charges on P and the degrees of distortion of 42 compounds: chlorophosphates [(R1O)(R2O)P(=O)Cl], chlorothiophosphates [(R1O)(R2O)P(=S)Cl], phosphonochloridates [(R1O)R2P(=O)Cl], phosphonochlorothioates [(R1O)R2P(=S)Cl], chlorophosphinates [R1R2P(=O)Cl], and chlorothiophosphinates [R1R2P(=S)Cl] are calculated at the B3LYP/ 6-311+G(d,p) level in the gas phase.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2010.05a
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• pp.486-489
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• 2010

This paper describes a layered LDPC decoder which supports block length of 1,944 bits and code rate 1/2 for IEEE 802.11n WLAN standard. To reduce the hardware complexity, the min-sum algorithm and layered architecture is adopted. A novel memory reduction technique suitable for min-sum algorithm reduces memory size by 75% compared with conventional method. The designed processor has 200,400 gates and 19,400 bits memory, and it is verified by FPGA implementation. The estimated throughput is about 200 Mbps at 120 MHz clock by using Xilinx Virtex-4 FPGA device.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.375-375
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• 2007

In the conventional crystallization method, thepoly-Si TFTs show poor device-to-device uniformity because of the random location of the grain boundaries. However, our new crystallization method introduced in this paper employed substrate-embedded seeds on the highly ordered anodic alumina template to control both the location of seeds and the number of grain boundaries intentionally. In the process of excimer laser crystallization (ELC), a-Si film deposited on the anodic alumina by low pressure chemical vapor deposition (LPCVD) is transformed into fine poly-Si grains by explosive crystallization (XC) prior to primary melting. At the higher energy density, the film is nearly completely melted and laterally grown by super lateral growth (SLG) from remained small part of the fine poly-Si grains as seeds at the Si/anodic alumina interface. Resultant grain boundaries have almost linear functions of the number of seeds in concavities of anodic alumina which have a constant spacing. It reveals the uniformity of. device can be enhanced prominently by controlling location and size of pores which contains fine poly~Si seeds under artificial anodizing condition.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.228-229
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• 2006

본 연구에서는 PCB에 적용하기 위한 폴리머 타입 후막저항의 하나로서, 포토공정으로 저항 패턴의 형성이 가능한 페이스트를 제조하였다. 기존의 폴리머 후막저항은 스크린 인쇄를 패터닝의 주요 방법으로 하고 있어 패턴의 정밀성이 떨어지는 단점이 있었다. 이를 개선하여 고정밀 저항 패턴의 형성이 가능하도록 Photoimageable Resin을 저항 페이스트의 개발에 도입하였다. Acrylated oligomer 및 monomer, 그리고 Novolac Epoxy를 주 기지상 재료로서 사용하였으며, acrylate와 epoxy의 함량비에 따른 저항 페이스트의 현상성 및 시트저항을 평가하였다. 전도성 Filler 재료로 카본블랙을 이용하였는데, 그 물리적 특성차와 함량이 저항 페이스트의 현상성과 저항값에 미치는 영향을 평가하였다. 실험결과 Acrylate와 epoxy의 비가 2.5:1일 때 현상성이 가장 양호하였으며, 이 조성에 XC72R 카본블랙을 2g 첨가하였을 때 시트저항의 평균값은 약 $6\;k{\Omega}\{\square}$였다.

• Journal of Physiology & Pathology in Korean Medicine
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• v.20 no.4
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• pp.1027-1031
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• 2006

In oriental medicine, Geijibokryunghwan(GBH) was used to improvement various symptoms created by the thrombosis. We investigated the effects of an oriental medicinal prescriptions, Geijibokryunghwan (GBH) consisting of herbs of Cinnamomi Ramufus (Geiji; 桂枝), Poria cocos (Bokrung; 茯?), Moutan Cortex Radicis(Modanpi; 牧丹皮), Paeoniae Radix (Jakyak; 芍藥) and Persicae Semen (Doin; 桃仁) on tumor growth-inhibitory activity and cancer chempreventive activity in assays representing three maior stages of carcinogenesis. Cancer chempreventive agents include nonsteroidal anti-inflammatory drugs (NSAIDS) such as indomethacin, aspirin, piroxicam, and sulindac, all of which inhibit cyclooxygenase (COX). Effects of the GBH extracts on carrageenan-induced edema Inflammation using female (C57BL/6XC3H) Fl (B6C3Fl ) mice and tumorigenesis were examined. Finally, cyclooxygenase metabolites were determined after extracts treatment. These data suggest that GBH extracts merits investigation as a potential cancer chempreventive agent in humans.

• IEMEK Journal of Embedded Systems and Applications
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• v.14 no.1
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• pp.51-61
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• 2019

There are strict evaluation processes before using new processors to satellites. Engineers evaluate processors from various viewpoints including specification, development environment, and cost. From a viewpoint of computation power, manufacturers provide benchmark results with processors, and engineers decide which processors are adequate to their satellites by comparing the benchmark results with requirements of their satellites. However, the benchmark results depends on a test environment of manufacturers, and it is quite difficult to achieve similar performance in a target environment. Therefore, it is necessary to evaluate the processors in the target environment. This paper compares performance of a processor, AT697F/LEON2, in software testbed (STB) with three development boards of XC2V/LEON3, GR712RC/LEON3, and GR740/LEON4. Seven benchmark functions of Dhrystone, Stanford, Coremark, Whetstone, Flops, NBench, and MiBench are selected. Results are analyzed with hardware and software properties: hardware properties of core architecture, number of cores, cache, and memory; and software properties of build options and compilers. Based on the analysis, this paper describes a guideline for choosing processors for next generation satellites.

• Proceedings of the Korea Information Processing Society Conference
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• 2013.11a
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• pp.1525-1527
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• 2013

본 논문에서는 저시력자의 개선된 독서 환경을 제공하는 시각보조기기를 위한 실시간 영상처리 SoC(System on Chip) 하드웨어 구조 설계에 대해서 기술한다. 기존의 시각보조기기는 화면 영상이 실제 움직임보다 늦게 출력되는 잔상 현상이 발생하며, 색 변환 기능도 제한적이다. 따라서 본 논문에서 제안하는 실시간 영상처리 SoC 하드웨어 구조는 데이터 연산을 최소화함으로써 잔상 현상이 감소되며, 저시력자를 위한 다양한 색상 모드를 지원한다. 제안하는 영상처리 SoC 하드웨어 구조는 Core-A 모듈, Memory Controller 모듈, AMBA AHB bus 모듈, ISP(Image Signal Processing) 모듈, TFT-LCD Controller 모듈, VGA Controller 모듈, CIS Controller 모듈, UART 모듈, Block Memory 모듈로 구성된다. 시각보조기기를 위한 실시간 영상처리 SoC 하드웨어 구조는 Virtex4 XC4VLX80 FPGA 디바이스를 이용하여 검증하였으며, TSMC 180nm 셀 라이브러리로 합성한 결과 동작주파수는 54MHz, 게이트 수 197k이다.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.15 no.11
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• pp.4122-4144
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• 2021

In this fast-paced technological world, the Internet of Things is a ground breaking technology which finds an immense role in the present electronic world which includes different embedded sensors, devices and most other things which are connected to the Internet. The IoT devices are designed in a way that it helps to collect various forms of data from varied sources and transmit them in digitalized form. In modern era of IoT technology data security is a trending issue which greatly affects the confidentiality of important information. Keeping the issue in mind a novel light encryption strategy known as LCB is designed for IoT devices for optimal security. LCB exploits the benefits of Feistel structure and the architectural benefits of substitution permutation network both to give more security. Moreover, this newly designed technique is tested on (Virtex-7) XC7VX330T FPGA board and it takes much little area of 224 GE (Gate Equivalent) and is extremely fast with very less combinational path delay of 0.877 ns. An in-depth screening confirms the proposed work to promise more security to counter cryptographic attacks. Lastly the Avalanche Effect (AE) of LCB showed as 63.125% and 63.875% when key and plaintext (PT) are taken into consideration respectively.

• 제어로봇시스템학회:학술대회논문집
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• 2003.10a
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• pp.1066-1070
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• 2003

Recently technologies have created new principle and theory but the PID control system remains its popularity as the PID controller contains simple structure, including maintenance and parameter adjustment being so simple. Thus, this paper proposes auto tune PID by fuzzy logic controller based on FPGA which to achieve real time and small size circuit board. The digital PID controller design to consist of analog to digital converter which use chip TDA8763AM/3 (10 bit high-speed low power ADC), digital to analog converter which use two chip DAC08 (8 bit digital to analog converters) and fuzzy logic tune digital PID processor embedded on chip FPGA XC2S50-5tq-144. The digital PID processor was designed by fundamental PID equation which architectures including multiplier, adder, subtracter and some other logic gate. The fuzzy logic tune digital PID was designed by look up table (LUT) method which data storage into ROM refer from trial and error process. The digital PID processor verified behavior by the application program ModelSimXE. The result of simulation when input is units step and vary controller gain ($K_p$, $K_i$ and $K_d$) are similarity with theory of PID and maximum execution time is 150 ns/action at frequency are 30 MHz. The fuzzy logic tune digital PID controller based on FPGA was verified by control model of level control system which can control level into model are correctly and rapidly. Finally, this design use small size circuit board and very faster than computer and microcontroller.

• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1625-1629
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• 2011

Kinetic studies of the reactions of O,O-diphenyl Z-S-aryl phosphorothioates with X-benzylamines have been carried out in dimethyl sulfoxide at 55.0 $^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}_X$) and Bronsted [log $k_2$ vs $pK_a(X)$] plots for substituent X variations in the nucleophiles are biphasic concave downwards with a maximum point at X = H, and the unusual positive ${\rho}_X$ and negative ${\beta}_X$ values are obtained for the strongly basic benzylamines. The sign of the cross-interaction constant (${\rho}_{XZ}$) is negative for both the strongly and weakly basic nucleophiles. Greater magnitude of ${\rho}_{XZ}$ value is observed with the weakly basic nucleophiles (${\rho}_{XZ}$ = -2.35) compared to with the strongly basic nucleophiles (${\rho}_{XZ}$ = -0.03). The deuterium kinetic isotope effects ($k_H/k_D$) involving deuterated benzylamines [$XC_6H_4CH_2ND_2$] are primary normal ($k_H/k_D$ > 1). The proposed mechanism is a concerted $S_N2$ involving a frontside nucleophilic attack with a hydrogen bonded, four-center-type transition state for both the strongly and weakly basic nucleophiles. The unusual positive ${\rho}_X$ and negative ${\beta}_X$ values with the strongly basic benzylamines are rationalized by through-space interaction between the ${\pi}$-clouds of the electron-rich phenyl ring of benzylamine and the phenyl ring of the leaving group thiophenoxide.