• The Plant Pathology Journal
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• v.17 no.6
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• pp.336-341
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• 2001

The distribution of citrusphages and phage types of Xanthomonas axonopodis pv. citri was investigated in Korea. Forty-eight strains of the bacterial pathogen and 28 bacteriophage strains were isolated from citrus leaves showing the citrus canker symptom. Only a single bacteriophage group, named CPK, was identified based on their aggressiveness to the bacterial pathogen. The bacterial strains were differentiated into two Iysotypes based on their sensitivity to CPK. Lysotype I, which was sensitive to CPK, was more predominant (96%), while only 4% belonged to Iysotype II, which was resistant to CPK. Among the 13 xanthomonads including Iysotype A and Iysotype B of X axonopodis pv. citri, CPKs were only aggressive to BC 83 (=Xc 62) strain of X. axonopodis pv, citri reported as Iysotype A. Thus, bacterial pathogens and citrusphages related to citrus plants mainly distributed in Korea were presumed as Iysotype A of X. axonopodis pv, citri, and Iysotype A-infecting CP$_1$ respectively.

• Bulletin of the Korean Chemical Society
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• v.32 no.6
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• pp.1939-1944
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• 2011

The nucleophilic substitution reactions of bis(Y-aryl) chlorophosphates (1) with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at 35.0 $^{\circ}C$. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorophosphates (2). The substrate 1 has one more identical substituent Y compared to substrate 2. The cross-interaction between Y and Y, due to additional substituent Y, is significant enough to result in the change of the sign of cross-interaction constant (CIC) from negative ${\rho}_{XY}$ = -1.31 (2) to positive ${\rho}_{XY}$ = +1.91 (1), indicating the change of reaction mechanism from a concerted $S_N2$ (2) to a stepwise mechanism with a rate-limiting leaving group departure from the intermediate (1). The deuterium kinetic isotope effects (DKIEs) involving deuterated anilines ($XC_6H_4ND_2$) show secondary inverse, $k_H/k_D$ = 0.61-0.87. The DKIEs invariably increase as substituent X changes from electron-donating to electron-withdrawing, while invariably decrease as substituent Y changes from electron-donating to electron-withdrawing. A stepwise mechanism with a rate-limiting bond breaking involving a predominant backside attack is proposed on the basis of positive sign of ${\rho}_{XY}$ and secondary inverse DKIEs.

• Bulletin of the Korean Chemical Society
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• v.32 no.6
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• pp.1945-1950
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• 2011

The pyridinolysis of methyl phenyl phosphinic chloride is investigated kinetically in acetonitrile at -20.0 $^{\circ}C$. The Hammett and Br${\o}$nsted plots for substituent X variations in the nucleophiles are biphasic concave downwards with a break point at X = H, and unusual positive ${\rho}_X$ (= 2.94) and negative ${\beta}_X$ (= -0.48) values are obtained for the strongly basic nucleophiles. A stepwise mechanism with a rate-limiting step change from bond breaking for the weakly basic pyridines to bond formation for the strongly basic pyridines is proposed on the basis of biphasic concave downward Hammett and Br${\o}$nsted plots. Unusual positive ${\rho}_X$ and negative ${\beta}_X$ values are rationalized by the isokinetic relationship. The pyridinolyses and anilinolyses of four $R_1R_2$P(=O)Cl-type substrates, dimethyl, diethyl, methyl phenyl, and diphenyl phosphinic chlorides in acetonitrile are compared to obtain systematic information on phosphoryl transfer reaction mechanism. The combination of the two ligands, Me and Ph, shows unexpected kinetic results for both the anilinolysis and pyridinolysis: greatest magnitude of $k_H/k_D$ (= 2.10) involving deuterated anilines $[XC_6H_4NH_2(D_2)]$ for the anilinolysis, and exceptionally fast rate and biphasic concave downward free energy correlation for the pyridinolysis.

• Journal of Electrical Engineering and Technology
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• v.10 no.4
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• pp.1655-1666
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• 2015

This paper proposes a new approach of Field Programmable Gate Array (FPGA) controlled digital implementation of shunt active power filter (SAPF) under steady state and dynamic operations. Typical implementations of SAPF uses microprocessor and digital signal processor (DSP) but it limited for complex algorithm structure, absence of feedback loop delays and their cost can be exceed the benefit they bring. In this paper, the hardware resources of an FPGA are configured and implemented in order to overcome conventional microcontroller or digital signal processor implementations. This proposed FPGA digital implementation scheme has very less execution time and boosts the overall performance of the system. The FPGA controller integrates the entire control algorithm of an SAPF, including synchronous reference frame transformation, phase locked loop, low pass filter and inverter current controller etc. All these required algorithms are implemented with a single all-on chip FPGA module which provides freedom to reconfigure for any other applications. The entire algorithm is coded, processed and simulated using Xilinx 12.1 ISE suite to estimate the advantages of the proposed system. The coded algorithm is also defused on a single all-on-chip Xilinx Spartan 3A DSP-XC3SD1800 laboratory prototype and experimental results thus obtained match with simulated counterparts under the dynamic state and steady state operating conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.386-388
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• 2009

차세대 에너지로 연료전지가 각광을 받고 있는 현재, 세계 각국에서는 연료전지의 상용화를 위해 노력하고 있다. 그러나 촉매분야에서 백금계 촉매의 사용량의 문제에 따른 매장량 한계점과 귀금속이라는 문제점이 존재하기 때문에 이에 대하여 대책강구가 필요한 시점이다. 이에 백금 촉매의 활성을 증대하고자 나노 크기의 제어 연구가 진행되고 있다. 또한, 촉매의 구조적인 면에 따라 촉매의 활성이 달라지는 점을 착안하여 백금계의 나노 형상 조절 연구와 백금계 촉매를 대체할 비백금계의 촉매 개발 연구가 활발히 진행되어지고 있다. 이에 본 연구는 백금계 촉매 중 Pd을 polyol process에 의한 나노 형상 조절을 통하여 단위 질량당(or 단위 부피당) 촉매의 활성을 높이고자 하였다. Polyol process에서는 환원제, 계면활성제, 온도, 시간, 기타 첨가제에 따라 나노 형상이 다르게 조절되는데, 이에 계면활성제로 PVP를 사용하고, 반응속도 및 형상조절을 위해 다양한 첨가제를 이용하여 polygonal Pd NPs을 형성하였다. 본 나노 형상 조절에서는 첨가제와 온도가 가장 큰 영향을 미치는 요인으로 착안하여 그에 따른 polygoanl Pd NPs의 사이즈 조절을 통해 전기화학 특성이 차이의 연구에 중점을 두었다. 이에 따라 나노 형상 조절이 된 Pd촉매를 이용하여 상용화된 촉매(Pd/C(XC-72R))에 비하여 전기화학적인 특성의 차이와 Pd 촉매의 촉매적 특성의 효과를 보고자 한다.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.11
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• pp.1447-1454
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• 2018

In this paper, the design of robust DSC-PLL(Delayed Signal Cancellation Phase Locked Loop) is proposed for coping with frequency variation. This method shows significant performance for detection of fundamental positive sequence component voltage when the grid voltage is polluted by grid unbalance and frequency variation. The feedback frequency estimation of DSC-PLL is tracking the drift in the phase by unbalance and frequency variation. The robust DSC PLL is to present the analysis on method and performance under frequency variations. These compensation algorithms can correct for discrepancies of changing the frequency within maximum 193[ms] and improve traditional DSC-PLL. Linear interpolation method is adopted to reduce the discretized errors in the digital implementation of the PLL. For verification of robust characteristic, PLL methods are implemented on FPGA with a discrete fixed point based. The proposed method is validated by both Matlab/Simulink and experimental results based on FPGA(XC7Z030).

• Journal of Institute of Control, Robotics and Systems
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• v.16 no.6
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• pp.559-565
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• 2010

In this paper, we present a transformation method of source code from a POSIX (Portable Operating System Interface) based source code into an OSEK/VDX (Offene Systeme und deren Schnittstellen fur die Elektronik in Kraftfahrzeugen/Vehicle Distributed eXecutive) source code. As the electronic parts of automobile systems increase, the use of embedded software in automobile systems is also growing. Accordingly, many electronic systems are designed in automobile system with OSEK/VDX. Otherwise, one of the major problems of embedded software would be portability to other OS's. To enhance the portability and interoperability of embedded software, we propose a source code transformation method from POSIX to OSEK/VDX based on API (Application Programming Interface) translation method. Considering the characteristics of the OSEK/VDX which uses OIL (OSEK/VDX Implementation Language) standard, transformation process is performed with source code transformation and OIL code generation. For the validity of the proposed method, the transformation experiment is given using Micro-C OS II and OSEK/VDX with XC167CI micro-controller.

• Journal of Korean Academy of Oral and Maxillofacial Radiology
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• v.24 no.1
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• pp.137-147
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• 1994

A digital imaging system using Machintosh Ⅱ ci computer, high resolution Sony XC-77 CCD camera, Quickcapture Frame Grabber Board was evaluated for quantitative analysis of standardized periapical film with aluminum step wedge. The results were as follows: 1. Correlation between Al thickness and gray level was high-positively associated(r²=0.99, p<0.001). 2. Correlation between measured weight of experimental lesion and estimated relative lesion volume by digital subtracted radiography was also high-positively associated (r²=0.98, p<0.001). 3. As exposure time was increased, mean gray level was decreased(p<0.01) and slope of regression line between Al thickness and gray level was also decreased (p<0.01). And when the exposure time was shorter than 0.2 second, the value of r² was relatively low. On the basis of the above results, it is considered that this digital imaging system using a Macintosh Ⅱ ci computer & a high resolution CCD monochrome camera will be useful in evaluating digitized image from standardized periapical film quantitatively.

• Bulletin of the Korean Chemical Society
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• v.29 no.1
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• pp.191-196
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• 2008

Kinetic studies of the reactions of a-bromoacetanilides [YC6H4NHC(=O)CH2Br] with substituted benzylamines (XC6H4CH2NH2) have been carried out in dimethyl sulfoxide at 35.0 oC. The Hammett plots for substituent (Y) variations in the substrate (log kN vs. sY) are biphasic concave upwards/downwards with breaks at Y = 4-Cl (sY = 0.23). The Hammett coefficients rY and the cross-interaction constant rXY (= +0.16) are positive for sY 0.23, while the rY values are positive/negative [rY > 0 for X = (4-MeO and 4-Me) and rY < 0 for X = (H, 4-Cl and 3-Cl)] and the rXY (= -1.51) value is negative for sY ³ 0.23. Based on these and other results, the benzylaminolyses of a-bromoacetanilides are proposed to proceed through rate-limiting expulsion of the bromide leaving group from a zwitterionic tetrahedral intermediate, T, with a bridged transition state for s Y 0.23, while the reaction proceeds through concerted mechanism with an enolate-like TS in which the nucleophile attacks the a-carbon for s Y ³ 0.23.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4304-4308
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• 2011

Kinetic studies of the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-benzylamines have been carried out in dimethyl sulfoxide at $85.0^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}_X$) and Br$\ddot{o}$nsted [log $k_2$ vs $pK_a$(X)] plots for substituent X variations in the nucleophiles are discrete with a break region between 4-Me and H, while the Hammett plots (log $k_2$ vs ${\sigma}_Z$) for substituent Z variations in the leaving groups are linear. The sign of the cross-interaction constant (${\rho}_{XZ}$) is positive for both the strongly and weakly basic nucleophiles. Greater magnitude of ${\rho}_{XZ}$ (= 2.54) value is observed with the weakly basic nucleophiles compared to with the strongly basic nucleophiles (${\rho}_{XZ}$ = 0.17). The deuterium kinetic isotope effects ($k_H/k_D$) involving deuterated benzylamines [$XC_6H_4CH_2ND_2$] are primary normal ($k_H/k_D$ > 1). The proposed mechanism is a stepwise with a rate-limiting leaving group expulsion from the intermediate involving a frontside nucleophilic attack with a hydrogen bonded, four-center-type transition state for both the strongly and weakly basic nucleophiles.