• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.170-171
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• 2021

This study compared the characteristics of the newly established JISA 5011-5 coal gasification slag fine aggregate with the characteristics of CGS generated in Korean IGCC through microscopic analysis. As a result of the study, similar results to K_CGS and J_CGS were found

• Mass Spectrometry Letters
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• v.14 no.3
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• pp.110-115
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• 2023

The reaction of (COD)PdCl₂ with new C₃-symmetric tridentate L (COD = 1,5-cyclooctadien; L = 1,3,5-tris(picolinoyloxyethyl)cyanurate) in a mixture of acetone and dichloromethane produces single crystals consisting of unprecedented monometallacyclic [PdCl₂(L)]. This cyclic compound arises from trans-chelation of two of three donating pyridyl groups of L, while the third pyridyl group remains uncoordinated. Electrospray ionization mass spectrometry (ESI-MS) data on L exhibited the major peak corresponding to [C₂₇H₂₄N₆O₉ + H⁺]⁺. Fast atom bombardment mass spectrometry (FABMS) data on [PdCl₂(L)], however, showed the mass peak corresponding to the L instead of the present palladium(II) compound species, due to the insolubility and dissociation in solution. The physicochemical properties of the present palladium(II) compound were fully characterized by means of infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy, thermal analysis, single-crystal X-ray diffraction (SC-XRD) measurement.

• Advances in materials Research
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• v.13 no.3
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• pp.195-202
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• 2024

Aluminum alloy is a material that is frequently used in the aerospace and transportation industries due to its high mechanical and corrosion resistance qualities. Unfortunately, aluminum alloys are prone to corrosion, limiting their application in some harsh situations such as when submerged in aqueous environments. The purpose of this study is to investigate how anodizing can increase the corrosion resistance of 6061 Aluminum alloy. The anodizing process was carried out using two different parameters which are voltage (5V, 10V, 15V) and electrolyte sulfuric acid (H₂SO₄) concentration (0.3M, 0.5M) for 1 hour. The anodized samples were performed using several analyses such as X-ray diffraction (XRD) analysis, morphology analysis, and corrosion test. From this study, it is found that the difference in anodizing parameters affects the corrosion resistance of the samples. Sample anodized at 15V, 0.5M gives the best corrosion resistance.

• Journal of Surface Science and Engineering
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• v.57 no.4
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• pp.331-337
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• 2024

Platinum has been utilized as an excellent electrocatalyst with low overpotential for the hydrogen evolution reaction (HER) in water splitting, despite of its high cost. In this study, platinum particles were produced using pulsed laser technology as a HER catalyst for water splitting. The colloidal platinum particles were synthesized by nanosecond pulsed laser irradiation (PLI) without reducing agents, not traditional polyol processes including reducing agents. The crystal structure, shape and size of the synthesized platinum particles as a function of pulsed laser irradiation time were investigated by XRD and SEM analysis. Additionally, the electrochemical properties for the HER in water splitting of the irradiation time-dependent platinum electrocatalysts were studied with the analysis of overpotentials in linear sweep voltammetry and Tafel slope.

• Economic and Environmental Geology
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• v.40 no.3 s.184
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• pp.263-275
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• 2007

The purpose of this study was to show the pollution characteristics of hazardous elements from roadside dust in the Gwangju city. We collected 47 samples from November to December in 2004 and separated four groups such as residential area, industrialized area, downtown area and heavy traffic area fer characteristics comparison on hazardous elements. Roadside dust mostly consisted of quartz, albite, microcline, muscovite in XRD analysis. Content of hazardous elements varied: As $3.4{\sim}11.9 ppm$, Cd $0.2{\sim}28.2 ppm$, Co $32{\sim}526 ppm$, Cr $25{\sim}526 ppm$, Cu $11{\sim}375 ppm$, Ni $14{\sim}247 ppm$, Pb $13{\sim}413 ppm$ and Zn $101{\sim}972 ppm$. Average contents of hazardous elements of Zn>Cu>Pb>Cr>Co>Ni>Cd. Content of hazardous elements was low in residential area, whereas that of heavy metal was much the same in both in heavy traffic area. Content of hazardous elements such as Cd, Co, Cr, Cu, Ni, Pb, Zn was found to be particularly high in industrialized area. According to these results it was possible to presume that industrialized area was affected by industry activity such as machinery, petrochemical, automobile and electronics industry. The SEM analysis, detected Pb, Cr, Ni, and Fe particles in samples of industrialized area contaminated by industry activity. The correlation coefficient table resulted from the samples of roadside dust showed that there was same direction increase of content between elements. In other words, when the content of Cd increase, Cr and Ni increase, as Cr increase, Cu and Ni increase, as Cu increase Ni increase and Pb increase Zn increase. Based on these results it was possible to predict and interpret similar contamination patterns in this study.

• Resources Recycling
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• v.30 no.6
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• pp.43-52
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• 2021

In this study, the optimal nitration process for selective lithium leaching from powder of a spent battery cell (LiNi_xCo_yMn_zO₂, LiCoO₂) was studied using Taguchi method. The nitration process is a method of selective lithium leaching that involves converting non-lithium nitric compounds into oxides via nitric acid leaching and roasting. The influence of pretreatment temperature, nitric acid concentration, amount of nitric acid, and roasting temperature were evaluated. The signal-to-noise ratio and analysis of variance of the results were determined using L₁₆(4⁴) orthogonal arrays. The findings indicated that the roasting temperature followed by the nitric acid concentration, pretreatment temperature, and amount of nitric acid used had the greatest impact on the lithium leaching ratio. Following detailed experiments, the optimal conditions were found to be 10 h of pretreatment at 700℃ with 2 ml/g of 10 M nitric acid leaching followed by 10 h of roasting at 275℃. Under these conditions, the overall recovery of lithium exceeded 80%. X-ray diffraction (XRD) analysis of the leaching residue in deionized water after roasting of lithium nitrate and other nitrate compounds was performed. This was done to determine the cause of rapid decrease in lithium leaching rate above a roasting temperature of 400℃. The results confirmed that lithium manganese oxide was formed from lithium nitrate and manganese nitrate at these temperatures, and that it did not leach in deionized water. XRD analysis was also used to confirm the recovery of pure LiNO₃ from the solution that was leached during the nitration process. This was carried out by evaporating and concentrating the leached solution through solid-liquid separation.

• Korean Journal of Materials Research
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• v.26 no.8
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• pp.444-448
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• 2016

In this study, the recently developed Al 2013 alloy was T8-tempered and, to improve the strength and corrosion-resistance, slight amounts of Zr of 0.2 wt% and 0.5 wt%, respectively, were added and the mechanical properties were analyzed. For microstructure and precipitate analysis, OM observation, XRD analysis, and TEM analysis were performed, and for the mechanical property analysis, hardness and tensile strength tests were done. Also, in order to determine the corrosion rate according to the Zr content, a potentiodynamic polarization test was performed and the properties were compared and analyzed. The size of the precipitate varied with the content of Zr and was finest at Zr content of 0.2 wt%; it grew larger at 0.5 wt%, at which point the hardness value accordingly showed the same trend. On the other hand, as calculated from the aspect of chemical bonding among atoms, it was confirmed that the tensile strength and the corrosion-resistance increased with the same trend.

• Journal of Conservation Science
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• v.32 no.2
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• pp.189-202
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• 2016

To figure out the material characteristics about slag and raw materials which are founded in iron product sites in Seosan area, we used XRF, EDS to analysis chemical compositions. Also we observe the microstructure by microscope and SEM. To identify the mineral component, XRD analysis was used and to assume the provenance of the raw material, lead isotope ratio analysis was used. From the results, we figure out that slags are non-ferrous created when metal was refined. Also, main tissue of slags were Fayalite, Galena, Magnetite, and raw materials were identified as mineral of Galena, Anglesite, Pyrite etc. From the result about lead isotope ratio analysis, we found out most samples are classified as the Western Gyeonggi massif in South Korea. Especially three of raw materials and slag samples which collected in the Seosan Doseongri was presumed to be the provenance. We figure out that slags we analyzed were made in non-ferrous metal smelting process and especially that were more likely to smelt from Seosan Doseongri. If various slags in this area are analysed by someone, It will contribute understanding non-ferrous metal refining process as well as metal refining which are composed.

• Journal of the Korean Geosynthetics Society
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• v.19 no.2
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• pp.23-33
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• 2020

This study determines the basic properties and acid rock drainage generation capacity of Pohang tertiary mudstone through laboratory experiments. According to X-ray fluorescence (XRF) analysis results, the mudstone of this area mostly comprised of SiO₂ with a proportion of approximately 60%, followed in order by Al₂O₃ and Fe₂O₃. As such, it is clear that there is an abundance of aluminosilicates with a high probability of generating acid rock drainage. The XRD analysis showed that the mudstone contains pyrite (FeS₂), it is highly likely to generate acid rock drainage, and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analysis results showed that the mudstone samples contained a high amount of Fe²⁺ ions. As a result of anion analysis measured by ion chromatography (IC), all mudstone samples were measured to have high SO^2-₄ concentrations. According to elemental analysis, the total sulfur (S) content was high, which in turn indicates a high risk of acid rock drainage generation reflected by a maximum potential acidity (MPA) higher than 1%. All in all, although there were slight deviations between the tertiary mudstone samples, overall, the samples exhibited high acid rock drainage generation capacities.

• The Journal of the Convergence on Culture Technology
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• v.9 no.1
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• pp.539-544
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• 2023

The subject of this study is the Maae Buddha statue in granodiorite of the Mesozoic Cretaceous period, which is concerned about stability as a standing stone cultural property located in ◯◯-dong, Gyeongsangbuk-do. For stability analysis, three-dimensional face mapping, geological properties of joints, three-dimensional scanning, ultrasonic velocity, polarization microscopy, electron microscopy analysis and XRD analysis were performed. In addition, the safety factor of the Maaebul was calculated by analyzing the damage status investigation, stereographic projection analysis, rock classification, and limit equilibrium analysis. The types and scales of damage and possible collapse by section depend on the degree of weathering of the rock and the orientation and characteristics of the joints, but wedge-failure and toppling-failure are expected to be small-scale. The safety factor of Maaebul in dry and wet conditions is less than 1.2, so stability is concerned. The types of damage were mainly observed, such as exfoliation, cracking, granular decomposition, and vegetation growth. The Maaebul rock is granodiorite, and the surface discoloration materials are K, Fe, and Mg. The 4 sets of joints are developed, J1 is tensile joint and the others are shear joint. The uniaxial compressive strength estimated by ultrasonic exploration is 514kgf/cm2, which corresponds to most soft rocks and some weathered rocks. Rock classification(RMR) is estimated to be grade 5, very poor rock mass. These technique along with the existing methods of safety diagnosis of cultural properties are expected to be a reasonable tool for objective interpretation and stability review of stone cultural properties.