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Effect of Doping on the Ionic Conductivity of Li$_2$Po$_{4-x}$N$_{x}$ thin Film (Li$_2$Po$_{4-x}$N$_{x}$ 박막의 이온전도도에 미치는 Ti 첨가)

  • 이재혁;이유기;박종완
    • Journal of Surface Science and Engineering
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    • v.30 no.4
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    • pp.255-261
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    • 1997
  • Thin film batteries can be used as a micro power source for electronic in which minute power is needed. In this study, lithium phosphorous oxynitride(LIPON) thin films were deposited as an eletrolyte for lithium ion batteries using RF magentron sputtering of lithium phosphate in N2. Ti was also added into the LIPON films as a second network former to enhance the ioinc conductivity of the films. The optimum conditions for LIPON film deposition were sought and the electrolyte with the conductivity of $2.5 \times 10^{-6}$S/cm was obtained at the condition of RF power 4.4 W/$\textrm{cm}^2$, process pressure 10 mtorr and pure nitrogen ambience. Furthermore, the conductivity of LIPON films was increased from $2.5 \times 10^{-6}$S/cm to $8.6 \times 10^{-6}$S/cm by the doping of 2.4at.% Ti. It was also found that by adding Ti to LIPON films, Li content was increased and nitrogen content that reported having the cross-linking effect on LIPON films was also increased as confirmed XPS.

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Capacitance-Voltage Characteristics of Carbon Nitride Films for Humidity Sensors According to Deposition Condition (제조 조건에 따른 습도센서용 질화탄소막의 정전용량-전압 특성)

  • Kim, Sung-Yub;Lee, Ji-Gong;Lee, Sung-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.152-155
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    • 2006
  • Carbon nitride ($CN_X$) films were prepared by reactive RF magnetron sputtering system at various deposition conditions and the C-V characteristics of MIS(metal - insulator - semiconductor) capacitors that have the structures of Al/$CN_x$/p-Si/Al and Al/$CN_x$/$Si_3N_4$/p-Si/Al were investigated. The resistivity of carbon nitride was above $2.40{\times}10^8{\Omega}{\cdot}cm$ at room temperature. The C-V plot showed a typical capacitance-voltage characteristics of semiconductor insulating layers, while it showed hysterisis due to interface charges. Amorphous carbon nitride (a-$CN_x$) films, that have relatively high resistivity and low dielectric constant could be useful as interlayer insulator materials of VLSI(very large-scale integration) and ULSI(ultra large-scale integration).

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Microwave Dielectric Properties of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ ceramics ($CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$계 세라믹스의 마이크로파 유전특성)

  • Yoon, Jung-Rag;Heo, Young-Kyu;Lee, Heon-Yong
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1459-1461
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    • 1997
  • The microwave dielectric ceramic properties of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ were investigated. The solid solution of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ had the perovskite structure in the range of all composition. The dielectric constant and temperature coefficient of resonant frequency of solid solution were decreased with the contend of $(Li_{1/2}Nd_{1/2})TiO_3$, whereas, the $Q{\times}f$ value was increased. In the $(1-X)CaTiO_3-X(Li_{1/2}Nd_{1/2})TiO_3$ system, the microwave properties could be controlled by the variation of X, X is weight fraction. Typical value of K=119, $Q{\times}f=2970$ and $TCF=14ppm/^{\circ}C$ were obtained for $0.2CaTiO_3-0.8(Li_{1/2}Nd_{1/2})TiO_3$.

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Oxidation Behavior of $Ni_xFe_{1-x}(OH)_2$ in $C\Gamma$-containing Solutions

  • Chung, Kyeong Woo;Kim, Kwang Bum
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.148-154
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    • 2003
  • The addition of Ni leads to the formation of protective rust layer on steel and subsequently high corrosion resistance of steel in $Cl^-$-containing environment. $\alpha$-FeOOH, $\beta$-FeOOH, $\gamma$-FeOOH and $Fe_3O_4$ are formed mainly on steels exposed to $Cl^-$-containing environment. As the first work of this kind, this study reports the influence of Ni on the oxidation behavior of $Ni_xFe_{1-x}(OH)_2$ in $Cl^-$-containing solution at two different pH regions(condition I under which the solution pH is allowed to decrease and condition I under which solution pH is maintained at 8) where $\gamma$-FeOOH and $Fe_3O_4$ are predominantly formed, respectively, upon oxidation of $Fe(OH)_2$, In the presence of Ni(II) in the starting solution, the formation of $\beta$-FeOOH was facilitated and the formation of $\gamma$-FeOOH was suppressed with increasing Ni(II) content and with increasing oxidation rate of Fe(II). Ni(II) was found to have $Fe_3O_4$-suppressing effect under condition II.

Eclipse Spectrum of Her X-1 Observed by ASCA in the Low Intensity State

  • Choi, C.S.;Seon, K.I.
    • Bulletin of the Korean Space Science Society
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    • 1995.10a
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    • pp.30-30
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    • 1995
  • We present the results of analysis on the X-ray observations of the binary X-ray pulsar Her X-I. made with ASCA/SIS on August 13-14. 1993. An eclipse transition from ingress to egress was fully covered by the observations. The main findings are as follows; (1) a model of power-law plus black-body is required to interpret the entire eclipse spectrum. and the black-body component appears at < 0.7 keV. (2) the power-law continuum which has photon index ${\alpha}\;=\;{0.84^{\;+0.14}}_{\;-0.19}$ is very similar to that of detected by Ginga/LAC (${\alpha}\;=\;0.80\;{\pm}\;0.04$), (3) the calculated eclipse flux of $2^{-10}\;keV.{\;}~{\;}1.8{\pm}10^{-11}{\;}ergs{\;}cm^{-2}s^{-1}$, is consistent with the Ginga observation carried out in the high intensity state ~2.0{\pm}10^{-11}{\;}ergs{\;}cm^{-2}s^{-1}$, (4) there is no significant absorption feature. and an upper limit of the aborption column $NH{\;}\leq{\;}3{\pm}10^{20}\;cm^{-2}$ is determined at the 90% confidence limit. Based on these results, we suggest that extended matter surrounding the binary system should be existed persistently with stable conditions, and scattering of the source continuum by the matter is responsible for the eclipse emission.ission.

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Development of Inverted Organic Photovoltaics with Anion doped ZnO as an Electron Transporting Layer

  • Jeong, Jae Hoon;Hong, Kihyon;Kwon, Se-Hun;Lim, Dong Chan
    • Journal of Surface Science and Engineering
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    • v.49 no.6
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    • pp.490-497
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    • 2016
  • In this study, 3-dimensional ripple structured anion (chlorine) doped ZnO thin film are developed, and used as electron transporting layer (ETL) in inverted organic photovoltaics (I-OPVs). Optical and electrical characteristics of ZnO:Cl ETL are investigated depending on the chlorine doping ratio and optimized for high efficient I-OPV. It is found that optimized chlorine doping on ZnO ETL enhances the ability of charge transport by modifying the band edge position and carrier mobility without decreasing the optical transmittance in the visible region, results in improvement of power conversion efficiency of I-OPV. The highest performance of 8.79 % is achieved for I-OPV with ZnO:Cl-x (x=0.5wt%), enhanced ~10% compared to that of ZnO:Cl-x (x=0wt%).

An Experimental Study on Steering Performance of Tracked Vehicle on Deep-sea Cohesive Soft Soil by DOE using Orthogonal Arrays (직교배열표 실험계획법에 의한 심해저 점착성 연약지반용 무한궤도차량의 선회성능에 대한 실험 연구)

  • Choi, Jong-Su;Hong, Sup;Kim, Hyung-Woo
    • Journal of Ocean Engineering and Technology
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    • v.20 no.4 s.71
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    • pp.37-42
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    • 2006
  • This paper is concerned with experimental investigation of steering performance of a tracked vehicle on extremely soft soil. A tracked vehicle model with principal dimensions of 0.9 m(L)x0.75 m(B)x0.4 m(H) and weight of 167 kg was constructed with a pair of driving chain links, driven by two AC-servo motors. The tracks were configured with detachable grousers with variable span. A deep seabed was simulated by means of a bentonite-water mixture in a soil bin of 6.0 m(L)x3.7 m(B)x0.7 m(H). The turning radii of vehicle and driving torques of motors were measured with respect to experiment variables: steering ratio, driving speed, grouser chevron angle, grouser span, and grouser height. L8 orthogonal table is adopted for DOE (Design of experiment). The effects of experiment variables on steering performance are evaluated.

Branched DNA-based Synthesis of Fluorescent Silver Nanocluster

  • Park, Juwon;Song, Jaejung;Park, Joonhyuck;Park, Nokyoung;Kim, Sungjee
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1105-1109
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    • 2014
  • While single strand DNAs have been widely used for the scaffold of brightly fluorescent silver nanoclusters (Ag NCs), double strand DNAs have not been as successful. Herein, we report a novel synthetic approach for bright Ag NCs using branched double strand DNAs as the scaffolds for synthesis. X-shaped DNA (X-DNA) and Y-shaped DNA (Y-DNA) effectively stabilized Ag NCs, and both X-DNA and Y-DNA resulted in brightly fluorescent Ag NCs. The concentration and molar ratio of silver and DNA were found important for the fluorescence efficiency. The brightest Ag NC with the photoluminescence quantum efficiency of 19.8% was obtained for the reaction condition of 10 ${\mu}M$ X-DNA, 70 ${\mu}M$ silver, and the reaction time of 48 h. The fluorescence lifetime was about 2 ns for the Ag NCs and was also slightly dependent on the synthetic condition. Addition of Cu ions at the Ag NC preparations resulted in the quenching of Ag NC fluorescence, which was different to the brightening cases of single strand DNA stabilized Ag NCs.

The Effects of Copolymer Additives for Drag Reduction on Turbulent Flow (합성고분자첨가제의 난류마찰저항 감소효과 연구)

  • Kim, N.S.;Kim, C.B.;Kim, I.S.;Choi, H.J.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.3
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    • pp.207-216
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    • 1993
  • Experimental investigations have been carried out to find the effect of drag reduction caused by effective polymer additives in turbulent flows. The experiments were undertaken with a test section of 9.8mm pipe diameter and 3500 mm pipe length(L/D=357) in a closed loop, and Copolymer-X and Polyacrylamide(PAAM) were used as polymer additives for comparisons. The tests were carried out under different polymer concentrations, and the temperatures of the flow considered were $26^{\circ}C$, $60^{\circ}C$ at the flow velocity of 5.3 m/s. The rate of drag reduction obtained by Copolymer-X is found to be considerably higher than that of PAAM in turbulent flows. Copolymer-X is also found to be very reliable for mechanical degradation, which has not been the case in any other additives. It is concluded that Copolymer-X is considered to be one of the most effective agents as an additive especially for long time hydraulic transports. It is also found that polymer degradation in more likely at lower polymer concentrations in the turbulent flows.

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Unbounded Scalar Operators on Banach Lattices

  • deLaubenfels, Ralph
    • Honam Mathematical Journal
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    • v.8 no.1
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    • pp.1-19
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    • 1986
  • We show that a (possibly unbounded) linear operator, T, is scalar on the real line (spectral operator of scalar type, with real spectrum) if and only if (iT) generates a uniformly bounded semigroup and $(1-iT)(1+iT)^{-1}$ is scalar on the unit circle. T is scalar on [0, $\infty$) if and only if T generates a uniformly bounded semigroup and $(1+T)^{-1}$ is scalar on [0,1). By analogy with these results, we define $C^0$-scalar, on the real line, or [0. $\infty$), for an unbounded operator. We show that a generator of a positive-definite group is $C^0$-scalar on the real line. and a generator of a completely monotone semigroup is $C^0$-scalar on [0, $\infty$). We give sufficient conditions for a closed operator, T, to generate a positive-definite group: the sequence < $\phi(T^{n}x)$ > $_{n=0}^{\infty}$ must equal the moments of a positive measure on the real line, for sufficiently many positive $\phi$ in $X^{*}$, x in X. If the measures are supported on [0, $\infty$), then T generates a completely monotone semigroup. On a reflexive Banach lattice, these conditions are also necessary, and are equivalent to T being scalar, with positive projection-valued measure. T generates a completely monotone semigroup if and only if T is positive and m-dispersive and generates a bounded holomorphic semigroup.

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