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Crystal Structure Analysis of Methyl-3-phenyl-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxylate

  • Ganapathy, Jagadeesan;Srinivasan, J.;Manickam, Bakthadoss
    • Journal of Integrative Natural Science
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    • v.8 no.3
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    • pp.184-191
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    • 2015
  • The crystal structure of the potential active methyl-3-phenyl-3H-chromeno[4,3-c]isoxazole-3a(4H)-carboxylate ($C_{18}H_{15}NO_4$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the orthorombic space group $P2_12_12_1$ with unit cell dimension $a=9.8320(17){\AA}$, $b=9.9890(18){\AA}$ and $c=15.588(3){\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=90^{\circ}$ and ${\gamma}=90^{\circ}$]. In the structure chromene, isoxazole and carboxylate are almost coplanar each other. All geometrical parameters revelled that chromene ring of pyran ring adopt sofa conformation. The crystal packing is stabilized by intermolecular C-H...O and C-H...N hydrogen bond interaction.

Dynamical transition of Josephson vortex lattice in serially stacked ${Bi_2}{Sr_2}{CaCu_2}{O_{8+x}}$ intrinsic Josephson junctions

  • Myung-Ho;Hu-Jong
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.52-55
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    • 2004
  • The inductive coupling theory in serially stacked $Bi_2$$Sr_2$$CaCu_2$$O_{8+x}$ intrinsic Josephson junctions predicts that the lattice structure of the Josephson vortices along the c axis gradually changes from the triangular to the rectangular lattice with increasing the vortex velocity. This lattice transition appears as voltage jumps or sub-branch splitting in the Josephson vortex-flow region of current-voltage characteristics (IVC). We report the IVC in external magnetic fields from 2 to 4 T. The stack, with the lateral size of 1.4${\times}$15 $u\m^2$, was fabricated by using the double-side cleaving technique. The sub-branches in the Josephson vortex-flow region, corresponding to a plasma propagation mode in serially coupled intrinsic Josephson junctions, were also observed in the range of 2∼4T. Switching from one branch to another in Josephson vortex-flow region suggests the structural transition of the moving Josephson vortex lattice.

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A Novel High Speed Frequency Sweeping Signal Generator in X-band Based on Tunable Optoelectronic Oscillator

  • Sun, Mingming;Chen, Han;Sun, Xiaohan
    • Current Optics and Photonics
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    • v.2 no.1
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    • pp.53-58
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    • 2018
  • A novel X-band high speed frequency sweep signal generator based on a tunable optoelectronic oscillator (OEO) incorporating a frequency-swept laser is presented and the theoretical fundamentals of the design are explained. A prototype of the generator with tuning range from 8.8552 GHz to 10.3992 GHz and a fine step about 8 MHz is achieved. The generated radiofrequency signal with a single sideband (SSB) phase noise lower than -100 dBc/Hz@10KHz is experimentally demonstrated within the whole tunable range, without any narrow RF band-pass filters in the loop. And the tuning speed of the frequency sweep signal generator can reach to over 1 GHz/s benefiting from applying a novel dispersion compensation modular instead of several tens of kilometers of optical fiber delay line in the system.

Synthesis and Crystal Structures of Di-nuclear Zinc(II) Diphenate Complexes with 1,10-Phenanthroline and 2,2'-Bipyridine

  • Koo, Bon-Kweon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2617-2622
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    • 2011
  • Two new Zn(II) complexes, $[Zn_2(dpa)_2(phen)_2(H_2O)_2]{\cdot}H_2O$ (1) (dpa = dephenate, phen = 1,10-phenanthroline) and [$Zn_2(dpa)_2(bpy)_2(H_2O)_2$] (2) (bpy = 2,2'-bipyridine) have been synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The X-ray analysis reveals that the structures of 1 and 2 are dinuclear zinc(II) complexes bridged by dpa dianions, respectively. The zinc ions in 1 exhibit a distorted square pyramidal environments, while the zinc ions in 2 exhibit a trigonal bipyramid geometry. In each complex, the dpa ligand is coordinated to zinc ions as a bis-monodentate.

Effects of F-doping on perparation and superconducting characteristics of ag-sheathed Tl-1223 tapes

  • 정대영;김희권;이준호;차무경;김영철;이호섭
    • Progress in Superconductivity and Cryogenics
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    • v.2 no.1
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    • pp.1-6
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    • 2000
  • The effects of partial substitution of fluorine on physical properties were studied in Ag-sheathes tapes of $Tl_{0.8}Pb_{0.2}Sr_{1.8}Ba_{0.2} Ca_{2.2}Cu_3O_yF_x (0{\leq}x{\leq}1)$ nominal compositions. The tapes were prepared using the powder-in-tube method incorporating an in-situ reaction method. $CuF_2$ was used as a source of F. It was found that F-doping in Tl-1223 system resulted in a decrease in formation temperatire of Tl-1223 phase. and thus significantly deteriorated their superconducting properties. Such disadvantages seem to originate by the fromation of non-beneficial phases such as SrF2 in the early stage of the powder preparation process.

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Reliability of passive optic splitting devices is compared with fused fiber type optical coupler and planar lightwave guide type optical coupler

  • Choi Young-Bok;Cho Sung-Hyun;Oh Min-Chul;Kim Sang-In;Jeong Gi-Tae;Han Kwan-Hoon
    • 한국정보통신설비학회:학술대회논문집
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    • 2003.08a
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    • pp.49-51
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    • 2003
  • This test data informs to compare components from different manufactured coupler type. On the point of reliability, less than 1x8 output branching number, fuse type coupler was more stable than PLC type coupler. But more than 1x8 output branching number, PLC type coupler was more stable. This test data showed critical branching point, on the point of reliability.

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Recognition of object in the robot gripper using tactile sensor (접촉센서를 이용한 로보트 gripper 내의 부품의 형상인식)

  • 윤지섭;이재설;박병석
    • 제어로봇시스템학회:학술대회논문집
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    • 1988.10a
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    • pp.422-427
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    • 1988
  • The purpose of this research is to develope a algorithm characterizing the grasp of the randomly fed objects using the tactile sensor. The tactile sensor used is composed of the 10 x 16 arrays of optical sensors and the planar resolution is 1.8 x 1.8 mm$^{2}$. The square and circular plate are used for the investigation of the characteristics of this sensor. The result shows that the measuring performance of the square plate is superior to that of the circular plate. Based upon this result the algorithm for the assembly of the electric plug was developed and was implemented using the mini-robot.

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Foodborne Pathogen Reduction을 위한 항균제의 새로운 Delivery System인 Aerosolization

  • O, Se-Uk;Gang, Dong-Hyeon
    • Bulletin of Food Technology
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    • v.18 no.1
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    • pp.91-98
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    • 2005
  • Aims: As a preliminary experiment on new sanitizer delivery tools, the efficacy of aerosolizedsanitizer on foodborne pathogens was investigated in larger model chamber system.Methods: Peroxyacetic acid and hydrogen peroxide were aerosolized in a model system againstartificially inoculated target microorganisms on laboratory media. Cultures of 4 different foodborne pathogens were inoculated and affixed onto 3 different heights (bottom, wall, and ceiling), and 3different orientations (face-down, vertical, and face-down) inside a commercial semi-trailer cabinet(14.6 x 2.6 x 2.8 m). Sanitizer was aerosolized into 2 m droplet size fog and treated for 1 h atambient temperature.Results: Populations of Bacillus cereus, Listeria innocua, Staphylococcus aureus, and Salmonellatyphimurium were reduced by an average of 3.09, 7.69, 6.93 and 8.18 log units per plate, respectively.Interestingly, L. innocua, Staph. aureus, and Salm. typhimurium showed statistically not different (P$\leq$ 0.05) reduction patterns relative to height and orientation that were never expected in a sprayingsystemConclusion and significance: Aerosolized sanitizers diffuse like gaseous sanitizers, so it has greatpotential for use in commercial applications.

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Fabrication and Electromagnetic Characteristics of Multi-walled Carbon nanotube/Epoxy Composites (다중벽 나노튜브/에폭시 복합재의 제작과 전자기적 특성)

  • 이상의;박기연;이원준;김천곤;한재흥
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.107-110
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    • 2003
  • The electromagnetic intereference(EMI) shielding is very essential for commercial and military purposes. We fabricated multi-walled carbon nanoube(MWNT)/epoxy composites and studied the electromagnetic characteristics of the composites before we study the characteristics of MWNT-filled glass fiber-reinforced composites. After setting up the fabrication process, we measured the permittivities of MWNT/epoxy composites with process variables and MWNT concentrations in X-band(8.2GHz- 12.4GHz). Process variables changed the degree of dispersion, which influenced permittivities and permittivities increased rapidly from 0.5wt% to 1.0wt%.

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