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Catechin Dimer (Catechin 이합체)

  • Ahn, Byung-Zun
    • Korean Journal of Pharmacognosy
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    • v.10 no.2
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    • pp.41-53
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    • 1979
  • A 6', 8a-bonded catechin dimer was synthesized by action of phenoloxidase on 2mol (+)-catechins. The same dimer and other two dimers which are also 6', 8a-bonded were isolated from the fresh cortex of Quercus robur. The 4, 8a-bonded and the etherified 4, 8a-bonded dimers were isolated from it. It was discussed about the meaning of the enzymatically produced 6', 8a-bonded dimers in plant cell. The isolated dimers are as following: 1. 6', 8a-bonded dimers: (+)-catechin-(+)-catechin-6', 8a-dimer(IX), (+)-catechin-(+)-gallocatechin-6', 8a-dimar (XIII), (+)-gallocatechin-(+)-catechin-6', 8a-dimer(XIV). 2. 4, 8a-bonded dimers: (+)-catechin-(+)-catechin-4, 8a-dimer(X), (-)-epicatechin-(+)-catechin-4, 8a-dimer (XI), (+) -galloatechin-(+)-catechin-4, 8a-dimer (XII). 3. 4,8a-bonded dimers with ether linkage: etherified(+)-catechin-(+)-catechin-4, 8a-dimer (XV), etherifid (+)-catechin-(+)-gallocatechin-4, 8a-dimer (XVI), etherified (+)-gallocatechin-(+)-catechin-4, 6a-dimer (XVII).

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Spectra of Optical-field Ionized Gases by a Femtosecond Ti:Sapphire Laser

  • Mock, Tomas;Shin, Hyun-Joon;Cha, Yong-Ho;Lee, Dong-Gun;Hong, Kyung-Han;Nam, Chang-Hee
    • Journal of the Optical Society of Korea
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    • v.2 no.2
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    • pp.50-53
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    • 1998
  • We report on the spectroscopic investigation of optical-field ionized plasmas in the soft X-ray spectral region. The experiment was carried out by focusing pulses of the high-power Ti:Sapphire laser with an energy of ~ 40 mJ and time duration of ~30 fs into a gas jet of krypton, xenon, and argon from a pulsed nozzle. Strong soft X-ray emission on lines from ionic stages of $Kr^{7+} , Kr^{8+} , Xe^{7+} , Ar^{7+} , and Ar^{8+}$ is reported. The experimental result was found to be in good agreement with theoretical prediction.

Refinement of the Structure of Alclofenac, 4-Allyloxy-3-Chlorophenyl acetic acid ($C_{11}H_{11}O_{3}CI$)

  • Kim, Yang-Bae;Kim, Sung-Jae;Koo, Chung-Hoe
    • Archives of Pharmacal Research
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    • v.9 no.4
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    • pp.223-227
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    • 1986
  • The structure of alclofenac was determined by single crystal X-ray diffraction analysis. The compound was recrystallized from chloroform solution in monoclinic system space group $C_{2}$/c, with Z = 8, a = 8, a = 23.349(9), b =14.295 (3), c = 7.192 (2) $\AA$, $\beta$ = 111.32 (3)$^{\circ}$, and $d_{dbs}$ = 1.29, $d_{caic}$ = 1.30. The structure was solved by direct method and refined by least-squares procedure to the final R-value being 0.044 for 1055 reflections (F ${\geq}6${\sigma}$(F)). The molecules are dimerized by OH..O type hydrogen bonds related by two-fold axis.

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Data Rate Analysis Using the Link Budget and Lunar Exploration Case Studies (달 탐사 사례 분석과 링크버짓 이용한 데이터 전송속도 분석)

  • Moon, Sang-Man;Kim, In-Kyu
    • Aerospace Engineering and Technology
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    • v.13 no.1
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    • pp.108-119
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    • 2014
  • In this paper, through the example of international lunar exploration mission the equipment was to investigate, and the amount of data transferred per day were identified. Data storage and the data transfer rate (8.4Mbps less) for the satisfaction of the value within the range of available S and X bands was confirmed by using the communication link budget. The result is to define the range of the sensor information can be obtained, as well as from the values of the parameters calculated for the transmission communication systems will be able to define the specifications.

Green Synthesis of Silver and Gold Nanoparticles Using Lonicera Japonica Flower Extract

  • Nagajyothi, P.C.;Lee, Seong-Eon;An, Minh;Lee, Kap-Duk
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2609-2612
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    • 2012
  • A simple green method was developed for rapid synthesis of silver and gold nanoparticles (AgNPs and AuNPs) has been reported using Lonicera japonica flower extract as a reducing and a capping agent. AgNPs and AuNPs were carried out at $70^{\circ}C$. The successful formation of AgNPs and AuNPs have been confirmed by UV-Vis spectro photometer, fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy dispersive X-ray Analysis (EDAX), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). To our knowledge, this is the first report where Lonicera japonica flower was found to be a suitable plant source for the green synthesis of AgNPs and AuNPs.

Co(Ⅲ) Complexes of Glycine Methyl Ester (Ⅰ). Preparation and Characterization (Co(Ⅲ) Glycine Methyl Ester 착물에 관한 연구 (제1보). 착물의 합성과 구조규명)

  • Ja Hong Kim;Sang Chul Shim
    • Journal of the Korean Chemical Society
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    • v.24 no.5
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    • pp.356-360
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    • 1980
  • Octahedral Co(Ⅲ) complexes of the glycine methyl ester have been prepared and characterized by elemental analysis, infrared, and NMR spectrum. Co(Ⅲ) glycine methyl ester complex has been isolated from the reaction of glycine and glycine methyl ester in aqueous solution by cation exchange resin, Dowex 50W-X8 (hydrogen form). It has been observed that the complexes have $C_1-cis(0-0), C_2-cis(0-0), trans(0-0)$ geometry.

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RE-ACCELERATION MODEL FOR THE 'TOOTHBRUSH' RADIO RELIC

  • KANG, HYESUNG
    • Journal of The Korean Astronomical Society
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    • v.49 no.3
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    • pp.83-92
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    • 2016
  • The Toothbrush radio relic associated with the merging cluster 1RXS J060303.3 is presumed to be produced by relativistic electrons accelerated at merger-driven shocks. Since the shock Mach number inferred from the observed radio spectral index, Mradio ≈ 2.8, is larger than that estimated from X-ray observations, MX ≲ 1.5, we consider the re-acceleration model in which a weak shock of Ms ≈ 1.2 - 1.5 sweeps through the intracluster plasma with a preshock population of relativistic electrons. We find the models with a power-law momentum spectrum with the slope, s ≈ 4.6, and the cutoff Lorentz factor, γe,c ≈ 7-8×104 can reproduce reasonably well the observed profiles of radio uxes and integrated radio spectrum of the head portion of the Toothbrush relic. This study confirms the strong connection between the ubiquitous presence of fossil relativistic plasma originated from AGNs and the shock-acceleration model of radio relics in the intracluster medium.

Changes of Surface Properties by Plasma Treatment on the Surface of Semiconductive Silicone Rubber (반도전성 실리콘 고무의 플라즈마 처리에 따른 표면의 특성변화)

  • Lee, Ki-Taek;Huh, Chang-Su
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.8
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    • pp.696-701
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    • 2005
  • This paper was investigated the changes of surface properties of high-temperature-vulcanized (HTV) semiconductive silicone rubber due to oxygen plasma discharge. The modifications produced on the silicone rubber surface by oxygen plasma were accessed using Fourier transform infrared spectroscopy(FTIR), X-ray photoelectron spectroscopy(XPS), contact angle and Surface Roughness Tester. The results of the chemical analysis Showed that C-H bonds were broken due to plasma discharge and Silica-like bonds (SiOx, x=$3\~4$) increased. It is thought that the above changes lead to the increase of surface energy of high-temperature-vulcanized (HTV) semiconductive silicone rubber also, Surface roughness was increased with cleavage of side-chains and oxidation process, it confirmed change as the SEM. The micromorphology of surface and hydrophobicity due to plasma discharge based on our results were discussed.

Effect of $ZrO_2$ Addition on the Synthesis and Microwave Dielectric Properties of $Ba_2Ti_9O_{20}$ Fabricated by Oxalate method (수산염법에 의한 $Ba_2Ti_9O_{20}$의 합성과 유전특성에 미치는 $ZrO_2$ 첨가의 영향)

  • 박재원;이헌식;이병하
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.835-840
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    • 1994
  • In this study, the synthesis of Ba2Ti9O20 powder having chemically homogeneous and highly pure fine particle size distribution was attempted by the oxalate method. And the effects of ZrO2 addition was investigated. The four compositions (X=0, 0.028, 0.048, 0.068) of Ba2(Ti9-x, Zrx)O20 were prepared by precipitation reaction of BaCl2, TiCl4, and ZrOCl2, with oxalic acid and NH4OH acting as a precipitating agent and a pH regulator respectively, in aqueous solution. In case of 4.8 mol% ZrO2 addition, the single phase Ba2Ti9O20 was obtained at 120$0^{\circ}C$ and its dielectric properties was excellent showing K=40.5, Q=4621 at 5.4 GHz.

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A CASE REPORT OF PLEOMORPHIC ADENOMA OF BUCCAL MUSOCA (협점막에 발생한 혼합선종의 치험예)

  • Heo, Cheol;Kim, Jin-Ho;Lee, Chung-Guk;Sin, Jong-Ho
    • The Journal of the Korean dental association
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    • v.14 no.8
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    • pp.679-682
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    • 1976
  • This 32 year-old male army officer was admitted with complaints of thumb size mass on buccal musoca which onterfere with mastication. Routine laboratory test revealed W.N.L. and the results of the excisional biopsy was Plemorphic Adenoma of salivary gland origin which was on the left buccal musoca( of 21 year-old male army officer). The size of tumor mass was 1.0 x 1.2 x 0.8cm, hard, encapsulated and seperated completely from surrounding tissue when enucleated surgically. Wound was healed unventfully and the result was good.

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