• Title/Summary/Keyword: X8

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The Crystallographic Structure and Magnetic Properties of Mg1-xZnxFeAlO4 (Mg1-xZnxFeAlO4의 결정학적 구조 및 자기적 성질)

  • Ko Jeong-Dae;Hong Sung-Rak
    • Korean Journal of Materials Research
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    • v.15 no.6
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    • pp.393-398
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    • 2005
  • The crystal structure and magnetic properties of the $Mg_{1-x}Zn_xFeAlO_4\;(0{\leq}x\leq1.0)$ have been investigated by means of x-ray diffractometry and $M\ddot{o}ssbauer$ spectroscopy. The samples$(0{\leq}x\leq1.0)$ have been prepared by the ceramic sintering method. The x-ray diffraction pattern shows that the crystal structure of the samples is a cubic spinel type. The lattice constant has been found by extrapolation using the Nelson-Riley function and it increases slightly from $8.3496\AA\;to\;8.4128\AA$ with Zn concentration. The $M\ddot{o}ssbauer$ spectra for x<0.4 show a superposition of two sextets ana a paramagnetic doublet at room temperature. The superparamagnetic doublet for x<0.4 seems to be due to Al ion in tetrahedral site by the superparamagnetic clustering effect.

Photoluminescence of Al2O3:xCr2O3 Solid Solution and Application as the Additive for Improving CRI of Red Phosphor (Al2O3:xCr2O3 고용상의 발광특성과 적색형광체의 연색성 향상을 위한 첨가제로의 응용)

  • Chae, Ki-Woong;Cheon, Chae-Il;Kim, Jeong-Seog
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.122-126
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    • 2010
  • In this article photoluminescence of the $Al_2O_3:xCr_2O_3$ solid solutions prepared by solid state reaction method are represented. The effect of $Cr_2O_3$-activator concentration and heat treatment time on the PL characteristics have been discussed in conjunction with microstructure of phosphor samples. The $Al_2O_3:xCr_2O_3$ phosphors show the highest PL intensity at x=0.003 mole when the samples are reacted at $1600^{\circ}C$ for 5 h. The PL emission and absorption spectra show the maximum peaks at 698 nm and at 398 nm respectively. The CIE color coordinate is (x=0.646, y=0.316) at 0.003 mole $Cr_2O_3$, which value is very close to the NTSC coordinate of red color. This characteristic feature of $Al_2O_3:xCr_2O_3$ has been applied for an additive to improve the color characteristic of other red phosphor $LiEuW_2O_8$ which has a relatively poor color purity with an emission peak centered at 615 nm and with a CIE coordinate (x=0.530, y=0.280). The $Al_2O_3:0.003Cr_2O_3$ phosphor has been mixed with the $LiEuW_2O_8$ phosphor powder and the PL characteristics and CIE color coordinates are characterized. The $Al_2O_3:xCr_2O_3$ phosphor was found effective for improving the CRI (color rendering index) of $LiEuW_2O_8$ phosphor.

Electrical Conductivities of [(CeO2)1-x(ZrO2)x]0.8(SmO1.5)0.2 Solid Solution ([(CeO2)1-x(ZrO2)x]0.8(SmO1.5)0.2 고용체의 전기전도도)

  • 이충연;김영식;김남철
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.775-782
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    • 2003
  • In the study, the total conductivies in [(Ce $O_2$)$_{1-x}$ (Zr $O_2$)$_{x}$]$_{0.8}$(Sm $O_{1.5}$)$_{0.2}$ (x- 0, 0.05, 0.1, 0.2) solid solution were measured as a function of temperature and oxygen partial pressure between 80$0^{\circ}C$ and 1,00$0^{\circ}C$ using 4-probe d.c method. Under pure oxygen atmospere, the oxygen ionic conductivity of [(Ce $O_2$)$_{1-x}$ (Zr $O_2$)$_{x}$]$_{0.8}$(Sm $O_{1.5}$)$_{0.2}$ decreased with the concentration of Zr $O_2$At high oxygen partial pressure, the electrical conductivity is almost independent of oxygen partial pressure and decreased with the increase in Zr content. However, the electrical conductivity increase with decreasing oxygen partial pressure and is almost independent of Zr content at low oxygen partial pressure. Empirically, Total conductivity( $\sigma$ ) was expressed by the p$o_{2}$ -independent conductivity as $\sigma$$_{i}$, and the $p_{-1/4}$ $o_{2}$sup -dependent part as $\sigma$$_{e}$. Total, ionic and electronic conductivities fitted by data enabled to determine the transference number. The ionic transference number( $t_{i}$ ) decreased while the electronic transference( $t_{e}$ ) increase with the increase in Zr content and p$o_{2}$.

The Magnetization Behavior of Amorphous Fe84-zNb7B8+xCu1 (x0, 1, 4) Alloys

  • Kim, Kyeong-Sup;Moon, Young-Mo;Lee, Jae-Bong;Yu, Seong-Cho;Lim, Woo-Young
    • Journal of Magnetics
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    • v.4 no.1
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    • pp.10-12
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    • 1999
  • We report the salient features of the magnetic properties of amorphous$ Fe_{84-x}Nb_7B_{8+x}Cu_1$ (x=0, 1, 4) alloys. The study of dc-magnetization properties and the ac-susceptibility was carried out. The temperature dependence of the magnetization follows the predictions of spin wave excitations with long wavelengths. Especially, the addition of boron modifies the magnetic properties: the spin wave stiffness increases from 56.8 to 65.7 meV$\AA$2 and Curie temperature increases from 298 K to 352 K. This result indicates a magnetic hardening of the exchange interaction by higher exchange energy. Thus, the substitution of iron by boron favours the increase of magnetic order in this system.

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ON AN EXTENSION FORMULAS FOR THE TRIPLE HYPERGEOMETRIC SERIES X8 DUE TO EXTON

  • Kim, Yong-Sup;Rathie, Arjun K.
    • Bulletin of the Korean Mathematical Society
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    • v.44 no.4
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    • pp.743-751
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    • 2007
  • The aim of this article is to derive twenty five transformation formulas in the form of a single result for the triple hypergeometric series $X_8$ introduced earlier by Exton. The results are derived with the help of generalized Watson#s theorem obtained earlier by Lavoie et al. An interesting special cases are also pointed out.

Mild and Efficient Reduction of α,β-Unsaturated Carbonyl Compounds, α-Diketones and Acyloins with Sodium Borohydride/Dowex1-x8 System

  • Zeynizadeh, Behzad;Shirini, Farhad
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.295-298
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    • 2003
  • α,β-Unsaturated aldehydes and ketones are regioselectively reduced to the corresponding allylic alcohols with /Dowex1-x8 system in THF at room temperature. This system is also efficient for the conversion of α-diketones and acyloins to the vicinal diols in refluxing THF.

ANOTHER METHOD FOR PADMANABHAM'S TRANSFORMATION FORMULA FOR EXTON'S TRIPLE HYPERGEOMETRIC SERIES X8

  • Kim, Yong-Sup;Rathie, Arjun Kumar;Choi, June-Sang
    • Communications of the Korean Mathematical Society
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    • v.24 no.4
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    • pp.517-521
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    • 2009
  • The object of this note is to derive Padmanabham's transformation formula for Exton's triple hypergeometric series $X_8$ by using a different method from that of Padmanabham's. An interesting special case is also pointed out.

HOT GAS IN ELLIPTICAL GALAXIES

  • Kim, Dong-Woo
    • Publications of The Korean Astronomical Society
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    • v.8 no.1
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    • pp.199-206
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    • 1993
  • We review recent systematic investigation of the X-ray spectra of early type galaxies by using the Einstein data base and present new results by the ROSAT observations. The Einstein data suggested that the galaxies with low X-ray to optical luminosity ratio may have another very soft component. ROSAT observations confirm its presence and call for further study to understand the nature of this very soft emission. The X-ray bright galaxies have emission temperature of ${\sim}\;0.8\;keV$ and show radial gradients in the sense that X-ray emission is softer and more absorbed in the inner region.

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