• Title/Summary/Keyword: X8

Search Result 8,975, Processing Time 0.039 seconds

Electrochemical Properties of Zr0.8Ti0.2Mn0.4V0.6Ni1-xFex Alloy Electrodes (Zr0.8Ti0.2Mn0.4V0.6Ni1-xFex 합금 전극의 전기화학적 특성)

  • Song, MyoungYoup;Kwon, IkHyun;Lee, DongSub
    • Journal of Hydrogen and New Energy
    • /
    • v.13 no.3
    • /
    • pp.181-189
    • /
    • 2002
  • A series of multicomponent $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{1-x}Fe_{x}$ (x=0.00, 0.08, 0.15, 0.22, and 0.30) alloys are prepared and their oystal structure and P-C-T curves are examined. The electrochemical properties of these allqys such as activation conditions, discharge capacity, cycling performance are also investigated. $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{1-x}Fe_{x}$ (x=0.00, 0.08, 0.15, 0.22 and 0.30) have the C14 Laves phase hexagonal structure. The electrode was activated by the hot-charging treatment. The best activation conditions were the current density 120 mA/g and the hot-charging time 12h at $80^{\circ}C$ in the case of the alloy with x=0.00. The discharge capacity increased rapidly until the fourth cycle and then decreased. The discharge capacity increased again from the 13th cycle, arriving at 234 mAh/g at the 50th cycle. The discharge capacily just after activation decreases with the increase in the amount of the substituted Fe but the cycling performance is improved. The discharge capacity after activation of the alloy with x=0.00 is 157 mAh/g at the current density 120 mA/g. $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}Fe_{0.15}$ is a good composition with a medium quantity of discharge capacities and a good cycling performance. The ICP analysis of the electrolyte for these electrodes after 50 charge-discharge cycles shows that the concentrations of V and Zr are relatively high. Another series of multicomponent $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}M_{0.15}$ (M = Fe, Co, Cu, Mo and Al) alloys are prepared. They also have the C14 Laves phase hexagonal structure. The alloys with M = Co and Fe have relatively larger hydrogen storage capacities. The discharge capacities just after activation are relatively large in the case of the alloys with M = Al and Cu. They are 212 and 170 mAh/g, respectivety, at the current density 120mA/g. The $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}Co_{0.15}$ alloy is the best one with a relatively large discharge capacity and a good cycling performance.

Low Prewwure MOCVD Growth and Characterization of $Ga_xIn_{1-x}P$ Grown on (100) GaAs Substrates (저압 MOCVD법에 의한 (100)-GaAs 기판위의 $Ga_xIn_{1-x}P$ 성장과 특성)

  • 전성란;손성진;조금재;박순규;김영기
    • Journal of the Korean Vacuum Society
    • /
    • v.3 no.1
    • /
    • pp.94-102
    • /
    • 1994
  • x- 0.51인 GaxIn1-x-P 에피층을 저압 MOCVD 성장법으로 TEGa(triethylgallium) TmIn(trimethylindium)등의 MO(metalorganic) 원료와 PH3(phosphine)를 사용하여 GaAs(100) 기판위에 성장하였다. 성장조건에 의한 표면 morphology 결정결함 성분비 PL spectra 운반자 농도와 이동도 및 DLTS spectra와 같은 성장층의 특성을 관찰하였다, $650^{\circ}C$의 성장온도와 V/III비, 즉 TEGa와 TMIn 두 원료의 유량에 대한 PH3 의유량변화에 아무런 영향을 받지 않음을 알 수 있었다. Ga0.51In0.49P에피층과 기판의 격자상수 차에 의한 격자 부정합 $\Delta$a /a0은 약 (3.7~8.9)x10-4 이었으며 실온과 5Kd서 에피층의 PL 피크 에너지는 각각 1.85eV와 1.9eV였다. 성장층의 운반자 농도와 이동도는 V/III 비에 따라 달라지 는데 그비가 120에서 220으로 증가함에 따라 농도는 1.8x1016cm-3에서 8.2x1016cm-3로 증가하였고 이동도 는 1010cm/V.sec에서 366cm/V.sec로 감소하였다.

  • PDF

The Effect of Pr Additive on Magnetostriction of Amorphous Fe-B Alloy (Pr 첨가가 Fe-B 비정질합금의 자왜에 미치는 영향)

  • 조용수;김윤배;김창석;김택기
    • Journal of the Korean Magnetics Society
    • /
    • v.4 no.2
    • /
    • pp.126-129
    • /
    • 1994
  • In order to invetigate the effect of Pr additive on the magnetostriction of amorphous Fe-B alloys, amorphous $Fe_{86-x}B_{14}Pr_{x}(2{\leq}x{\leq}8\;at.%)$ alloys were prepared by a rapid solidification process. As the Pr content increased in the as-prepared amorphous $Fe_{84}B_{14}Pr_{2}$ alloy annealed at $300^{\circ}C$ for 2 hr increased to 70 ppm. Ac power loss and permeability$(f=50\;kHz,\;B_{m}=0.1\;T)$ of the annealed amorphous $Fe_{84}B_{14}Pr_{2}$ alloy were 15 W/kg and $5.5{\times}10^{3}$, respectively.

  • PDF

Preparation, Characterization and Photoluminescence Properties of Ca1-xSrxS:Eu Red-emitting Phosphors for a White LED

  • Sung, Hye-Jin;Cho, Young-Sik;Huh, Young-Duk;Do, Young-Rag
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.8
    • /
    • pp.1280-1284
    • /
    • 2007
  • A series of Ca1-xSrxS:Eu (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0) phosphors were synthesized by solid-state reactions. The Ca1-xSrxS:Eu phosphors have a strong absorption at 455 nm, which corresponds to the emission wavelength of a blue LED. The emission peak of Ca1-xSrxS:Eu is blue shifted from 655 to 618 nm with increasing Sr content. The characteristics of Ca1-xSrxS:Eu phosphors make them suitable for use as wavelengthtunable red-emitting phosphors for three-band white LEDs pumped by a blue LED. In support of this, we fabricated a three-band white LED by coating SrGa2S4:Eu and Ca0.6Sr0.4S:Eu phosphors onto a blue LED chip, and characterized its optical properties.

An Experimental Study on the Effects of X-ray Irradiation and Hyperthermia on the Rat Testis (X-선 조사와 온열요법이 백서고환에 미치는 영향에 관한 실험적 연구)

  • Lee, Kyung-Ja
    • Radiation Oncology Journal
    • /
    • v.8 no.1
    • /
    • pp.17-27
    • /
    • 1990
  • The effects of both hyperthermia alone and X-ray irradiation combined with hyperthermia on rat testis have been investigated. The histological changes were observed on 15 and 30 days after treatment. There was no histological change of rat testis by hyperthermia alone. The earliest change by X-ray irradiation was the degeneration of the spermatogonia of the seminiferous tubule, which was appeared in 2 Gy group. Necrosis of the spermatogonia was severe in 6 Gy group and complete atrophy was developed in 8 Gy group. With increased dose of radiation, the degree of changes of tubules was increased. In combined group of X-ray irradiation and hyperthermia, the histological change of the seminiferous tubule was more severe than X-ray alone group. Necrosis and atrophy of the spermatogonia were appeared in 2 Gy and complete atrophy of spermatogonia was seen in 6 Gy group. Thermal enhancement ratio (calculated at the complete atrophy of the spermatogonia) was 1.3 in this experiment. There was no difference in observation time inverval between 15 and 30 days after each treatment in all groups.

  • PDF

Nb첨가가 Zr합금의 석출물과 산화막 특성에 미치는 영향

  • 김현길;위명용;최병권;김경호;정용한
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 1998.05b
    • /
    • pp.148-153
    • /
    • 1998
  • 핵연료 피복관용 신합금을 개발하기 위한 기초연구로서 Zr-xNb계 합금과, Zr-0.8Sn-xNb계 합금을 각각 4종씩 선정하였다. 이들 합금을 판재시편으로 가공한 뒤 Autoclave를 이용하여 36$0^{\circ}C$에서 부식 시험을 실시하였다. 부식과정에서 생성되는 산화막의 미세구조를 관찰하기 위해 천이 전 영역에서 동일두께를 갖도록 부식시편을 준비하여 산화막/금속계면에 대해 SEM관찰을 실시하였다. 또한 석출물의 크기와 부식과의 관계를 조사하기 위하여 부식전의 시편에 대해 TEM관찰을 실시하였다. Zr-xNb 2원계 합금에서는 Nb함량이 적을수록 부식저항성이 증가하는 경향을 보이는데, 0.2Nb가 첨가된 합금이 가장 우수한 부식저항성을 보였다. Zr-0.8Sn-xNb 3원계에서도 천이 전 영역에서는 2원계 합금과 마찬가지로 Nb함량이 적을수록 부식저항성이 증가하나, 천이 후 영역에서는 이런 경향이 바뀌는 것이 관찰되었다. 이는 Sn이 첨가됨으로서 Nb가 부식에 미치는 영향이 달라지기 때문이라 생각된다. 산화막 관찰결과, 순수 Zr은 결정립계를 따라서 산화막이 급격히 성장하는 반면에, Zircaloy-4합금은 매우 균일한 산화막 계면을 유지한다. Zr-xNb계 합금과 Zr-0.8Sn-xNb계 합금에서도 내식성이 우수한 합금은 균일한 산화막/금속 계면을 유지하는 것이 관찰되었다.

  • PDF

Survey on Online Continuing Education Requirements according to Practical Experience of Nurses at Small and Medium Sized Hospitals (중소병원 간호사의 실무 경험에 따른 온라인 보수교육 요구도 조사)

  • Eun, Young;Kang, Han Sol;Jeon, Mi Yang
    • Journal of muscle and joint health
    • /
    • v.23 no.3
    • /
    • pp.197-205
    • /
    • 2016
  • Purpose: The purpose of this study was to conduct a comparison analysis on requirements of online continuing education requirements according to practical experience of nurses at small and medium-sized hospitals. Methods: Data had been collected with 236 nurses from May to June, 2015. The data were analyzed with the use of SPSS. Results: Among them, 45.8% participated in online continuing education. Nurses in beginning level required musculoskeletal diseases (20.9%), care for injuries and stomas (5.8%), and surgical disease and operation care (4.7%). Competent nurses required musculoskeletal diseases (19.7%), cerebrovascular diseases (9.9%), emergency care and CPR (8.5%), and medical nursing (8.5%). Skillful nurses required cerebrovascular diseases (13.9%), care for internal diseases (8.9%), and rehabilitation care (8.9%). Among the educational contents of diseases, the items that were significantly different according to practical experience were operation management ($x^2$=23.92, p<.001) and drug care ($x^2$=7.85, p=.020). Among continuing education methods, the items that were significantly different were video ($x^2$=16.81, p<.001), webtoon ($x^2$=8.96, p=.011), and test ($x^2$=10.56, p=.005). Among continuing education evaluation methods, the items that were significantly different were multiple-choices ($x^2$=9.43, p=.009) and OX ($x^2$=6.47, p=.039) based quizzes. Conclusion: Based on the study results, it is necessary to develop a differentiated continuing education program according to practical experience of nurses.

A cytotaxonomic study of Vicia L. (Fabaceae) in Korea (한국산 나비나물속(콩과)의 세포분류학적 연구)

  • Nam, Bo Mi;Park, Myung Soon;Oh, Byoung Un;Chung, Gyu Young
    • Korean Journal of Plant Taxonomy
    • /
    • v.42 no.4
    • /
    • pp.307-315
    • /
    • 2012
  • Somatic chromosome numbers for 10 taxa and karyotypes analysis for 6 taxa of Korean Vicia were investigated. Somatic chromosome numbers of treated taxa were 2n = 12, 14 or 24 and therefore they proved to be diploid or tetraploid with basic chromosome numbers of x = 6 or 7. The chromosome number of V. hirticalycina (2n = 2x = 12) was reported for the first time in this study. The chromosome numbers of nine taxa were the same as in previous studies; V. angustifolia (2n = 2x = 12), V. cracca (2n = 4x = 24), V. hirsuta (2n = 2x = 14), V. tetrasperma (2n = 2x = 14 + 2B), V. amurensis (2n = 2x = 12), V. chosenensis (2n = 2x = 12, 12 + 2B), V. unijuga (2n = 4x = 24), V. unijuga f. minor (2n = 4x = 24), V. venosa var. cuspidata (2n = 4x = 24). The karyotypes of V. cracca, V. amurensis, V. hirticalycina, V. unijuga, V. unijuga f. minor, V. venosa var. cuspidata were observed as 2 m + 8 sm + 2 st, 2 m + 2 sm + 2 st, 3 m + 1 sm + 2 st, 4 m + 6 sm + 2 st, 4 m + 6 sm + 2 st, 4 m + 8 sm, respectively.

A study on the Frequency Dependence of Dynamic Pyroelectric Properties for $Pb_{l-x}La_{x}Ti_{l-x/4}O_3$ (x=0.1) (PLT(10)) Ferroelectric Thin Film ($Pb_{l-x}La_{x}Ti_{l-x/4}O_3$ (x=0.1) (PLT(10)) 강유전체 박막에서 동적 초전특성의 주파수의존성에 관한 연구)

  • 차대은;장동훈;강성준;윤영섭
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.39 no.12
    • /
    • pp.1008-1015
    • /
    • 2002
  • The fabricated La-modified lead titanate (PLT) thin film without poling treatment was investigated for modulation frequency dependence of pyroelectric properties by the dynamic method. $Pb_{l-x}La_{x}Ti_{l-x/4}O_3$(x=0.1) (PLT(10)) thin film haying 10 mol% La content was deposited on a Pt/$TiO_{x}$/$SiO_2$/Si substrate by sol-gel method. The PLT(10) thin film exhibits a relatively excellent dielectric property. The pyroelectric coefficient (p) of the PLT(10) thin film is 6.6 x $10^{-9}C$$textrm{cm}^2$$.$K without frequency dependence. The figure of merits for the voltage responsivity and specific detectivity are 1.03 x $10^{-11}C$.cm/J and 1.46 x $10^{-10}C$.cm/J, respectively The PLT(10) thin film has voltage responsivity (RV) of 5.IS V/W at 8 Hz. Noise equivalent power (NEP) and specific detectivity ($D^{*}$) of the PLT(10) thin film are 9.93 x $10^{-8}$W/$Hz^{1/2}$ and 1.81 x $10^{6}$cm.$Hz^{1/2}$/W at the same frequency of 100 Hz,, respectively The results means that PLT thin film having 10 mol% La content is suitable for the sensing materials of pyroelectric IR sensors.