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Structural and Piezoelectric Properties of MnO2-Doped PZT-PSN Ceramics for Ultrasonic Vibrator (초음파 진동자용 MnO2가 Doping된 PZT-PSN 세라믹스의 구조 및 압전 특성)

  • Cha, Yoo-Jeong;Kim, Chang-Il;Kim, Kyoung-Jun;Jeong, Young-Hun;Lee, Young-Jin;Lee, Hai-Gun;Paik, Jong-Hoo
    • Korean Journal of Materials Research
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    • v.19 no.4
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    • pp.198-202
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    • 2009
  • For use in ultrasonic actuators, we investigated the structural and piezoelectric properties of $(1\;-\;x)Pb(Zr_{0.515}Ti_{0.485})O_3$ - $xPb(Sb_{1/2}Nb_{1/2})O_3$ + 0.5 wt% $MnO_2$ [(1 - x)PZT - xPSN + $MnO_2$] ceramics with a variation of x (x = 0.02, 0.04, 0.06, 0.08). All the ceramics, which were sintered at $1250^{\circ}C$ for 2 h, showed a typical perovskite structure, implying that they were well synthesized. A homogeneous micro structure was also developed for the specimens, and their average grain size was slightly decreased to $1.3{\mu}m$ by increasing x to 0.8. Moreover, a second phase with a pyrochlore structure appeared when x was above 0.06, which resulted in the deterioration of their piezoelectric properties. However, the 0.96PZT-0.04PSN+$MnO_2$ ceramics, which corresponds with a morphotropic phase boundary (MPB) composition in the (1 - x)PZT - xPSN + $MnO_2$ system, exhibited good piezoelectric properties: a piezoelectric constant ($d_{33}$) of 325 pC/N, an electromechanical coupling factor ($k_p$) of 70.8%, and a mechanical quality factor ($Q_m$) of 1779. The specimens with a relatively high curie temperature ($T_c$) of $305^{\circ}C$ also showed a significantly high dielectric constant (${\varepsilon}_r$) value of 1109. Therefore, the 0.96PZT - 0.04PSN + $MnO_2$ ceramics are suitable for use in ultrasonic vibrators.

Derepression of a Methionine Biosynthetic Gene by Utilizing a Promoter Isolated from Corynebacterium glutamicum (Corynebacterium glutamicum에서 분리된 프로모터를 이용한 메치오닌 생합성 유전자의 조절해제)

  • Park Soo-Dong;Park Ik-Hyun;Choi Jong-Soo;Kim Il-Kwon;Kim Younhee;Lee Heung-Shick
    • Korean Journal of Microbiology
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    • v.41 no.4
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    • pp.300-305
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    • 2005
  • A transcriptionally active fragment $(P_{19})$ isolated by utilizing the promoter-probe shuttle vector pSK1Cat was analyzed. By subcloning analysis, the 180 bp region $(P_{180})$ responsible for the activity was determined. Transcriptional fusion of the C. glutamicum metX gene to $P_{180}\;(P_{180}-metX)$ resulted in a 24-fold increase in MetX activity in a complex medium, while a 13-fold increase was observed with the $P_{tac}$ promoter. Additionally, the expression conferred by $P_{180}$ was not affected by methionine added to the growth medium, suggesting that the $P_{180}$ clone is useful for the deregulated expression of biosynthetic genes in C. glutamicum during amino acid fermentation. Introduction of $P_{180}-metX$ into a lysine-producing C. glutamicum resulted in the production of methionine to 0.8 g/l.

Microwave Dielectric Properties of (Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 Ceramics ((Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 세라믹스의 마이크로파 유전 특성)

  • Ju Hye Kim;Si Hyun Kim;Eung Soo Kim
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.330-336
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    • 2023
  • The effects of Ni2+ substitution for Mg2+-sites on the microwave dielectric properties of (Mg1-xNix)(Ti0.95(Mg1/3Ta2/3)0.05)O3 (0.01 ≤ x ≤ 0.05) (MNTMT) ceramics were investigated. MNTMT ceramics were prepared by conventional solid-state reaction. When the MgO / TiO2 ratio was changed from 1.00 to 1.02, MgTi2O5 was detected as a secondary phase along with the MgTiO3 main phase in the MNTMT specimens sintered at 1,400 ℃ for 4h. For the MNTMT specimens with MgO / TiO2 = 1.07 sintered at 1,400 ℃ for 4h, a single phase of MgTiO3 with an ilmenite structure was obtained from the entire range of compositions. The relative density of all the specimens sintered at 1,400 ℃ for 4h was higher than 95 %. The quality factor (Qf) of the sintered specimens depended strongly on the degree of covalency of the specimens, and the sintered specimens with x = 0.01 showed the maximum Qf value of 489,400 GHz. The dielectric constant (K) decreased with increasing Ni2+ content because Ni2+ had a lower dielectric polarizability (1.23Å3) than Mg2+ (1.32Å3). As Ni2+ content increased, the temperature coefficient of resonant frequency (TCF) improved, from -55.56 to -21.85 ppm/℃, due to the increase in tolerance factor (t) and the lower dielectric constant (K).

Structural Characterization of the Eight-Coordinated Dodecahedral Y(tpb)3(H2O)2 (8배위 12면체 Y(tpb)3(H2O)2착물의 합성과 구조)

  • Yu, Chong-Nam;Kang, Seong-Joo
    • Journal of the Korean Chemical Society
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    • v.51 no.3
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    • pp.240-243
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    • 2007
  • The eight coordinated yttrium(III) complex Y(tpb)3(H2O)2 (Htpb=4,4,4-Trifluoro-1-phenyl-1,3-butanedione) has been synthesized and structurally characterized by X-ray diffraction method. The coordination polyhedron of Y(tpb)3(H2O)2 has a dodecahedron. The angle between two trapezia, Y-O2-O1-O5-O6 and Y-O4-O3-O8-O7, is 89.59°. The O1-O5 and O3-O8 distances are 2.965 and 2.995 A whereas the O2-O6 and O4-O7 distances are 4.256 and 4.403 A.

Fabrication and Characteristics of Flat-type $L_{-}$-$B_{8}$ Mode Ultrasonic Motors (평판형 종($L_{-}$-굴곡($B_{8}$)모드 초음파 전동기의 제작과 특성)

  • U, Sang-Ho;Lee, Eun-Hak;Kim, Jin-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.7
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    • pp.292-297
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    • 2002
  • In this paper, a flat-type $L_{-}$-$B_{8}$ mode Ultrasonic Motor[USM] having the size of 80 x 20 x ${1.5}mm^3$($l{\times}\omega{\times}t$) was designed and fabricated to examine the characteristics of an ultrasonic vibration. We used ANSYS simulation program based on FEM to get the optimum design of this USM. As results of experiment, the fastest speed of revolution(v), the maximum torque(T) and the efficiency(n) were 37.5cm/s, 5.0 mN.m and 1.17% when 27.9KHz, 150N, 50V were applied respectively. And this flat-type $L_{-}$-$B_{8}$ mode USM could be controlled the speed of rotor revolution by applied voltage, frequency and pre-load of rotor as well as showed the characteristics of typical drooping torque-speed, large torque and high speed. So, we think that this flat-type $L_{-}$-$B_{8}$ mode USM has characteristics of enough torque and velocity to be usable for applications in forwarding device of an electric card or a paper, etc.

Luminescence Properties of $Eu^{2+}$-doped $Ca_2Si_5N_8$ Thin Films ($Eu^{2+}$-doped $Ca_2Si_5N_8$ 박막의 광학특성)

  • Jang, Bo-Yun;Pakr, Joo-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.25-27
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    • 2007
  • $Eu^{2+}$-doped $Ca_2Si_5N_8$ was grown on Si(100) substrate using metal-organic deposition (MOD) method and post-annealed at $900^{\circ}C$ in various atmosphere. Luminescence properties of these thin films were investigated with variations of $Eu^{2+}$-doped concentrations and annealing atmosphere. Thin film was formed with clean surface and uniform thickness of about 72 nm. From the measurements of luminescence properties of thin films, film must be post-annealed in nitrogen or mixture of nitrogen and hydrogen atmosphere to emit a sufficient light. For $Ca_{1.5}Eu_{0.5}Si_5N_8$ thin film annealed at $900^{\circ}C$ in nitrogen atmosphere, excitation band from 380 to 420 nm was detected with the maximum intensity at 404 nm and two broad emission bands from 530 to 630 nm were observed. These broad excitation and emission bands must be attributed to the nitrogen incorporations into the films. From the results, $Ca_{2-x}Eu_xSi_5N_8$ thin film has probability for next generation thin film lighting applications such as light emitting diode (LED) or electro-luminescence (EL).

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Modeling for Predicting Yield and $\alpha$-Acid Content in Hop (Humulus lupulus L.) from Meteorological Elements I. A Model for Predicting Fresh Cone Yield (기상요소에 따른 호프 (Humulus lupulus L.)의 수량 및 $\alpha$-Acid 함량 예측모형에 관한 연구 I. 생구화 수량 예측모형)

  • 박경열
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.33 no.3
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    • pp.215-221
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    • 1988
  • The hop yield prediction model developed based on meteorological elements in Hoeongseong was Y=6,042.846-17.665 $X_1$-0.919 $X_2$-96.538 $X_3$-138.105 $X_4$+86.910 $X_{5}$$X_{6}$ with MS $E_{p}$ of 25.258, $R_{p}$$^{2}$ of 0.9991, R $a_{p}$$^{2}$ of 0.9962 and $C_{p}$ of 7.00. The minimum air temperature at early growing stage ( $X_1$), the total precipitation at cone ripening stage ( $X_2$), the maximum air temperature at flower bud differentiation stage ( $X_3$) and the maximum air temperature at flowering stage ( $X_4$) influenced on hop yield as decrement weather elements. The average air temperature at early growing stage ( $X_{5}$ ) and the total sunshine hours at cone development stage ( $X_{6}$ ) influenced on hop yield as increment weather elements.lements.

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Genetic Studies on Some Quantitative Characters of Rice in Diallel Crosses 1. Degree of Heterosis in $F_1$ and $F_2$ Generations of Various Characters (이면교잡에 의한 수도의 양적형질의 유전분포 제 1 보 세대별 각형질의 Heterosis정도의 차이)

  • Kwon-Yawl Chang;Byung-Tae Jun;Yong-Ho Kwak
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.23 no.2
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    • pp.25-33
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    • 1978
  • 7 parent varieties and 21 $_{x}\textrm{F}_1 and $_{x}\textrm{F}_2 hybrids from 7 X 7 partial diallel crosses were used as the materials, and degree of heterosis was studied in 9 agronomic characters of rice. Degree of heterosis was more remarkable in $_{x}\textrm{F}_1 hybrids than $_{x}\textrm{F}_2 hybrids. and significant differences were showed in many hybrid generations. and also over dominance could be shoo wed in eight characters except 1000 kernel weight of rice.

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Mossbauer Studies of Perovskite $Gd_{1-x}Sr_xFeO_{3-y}$ (X = 0.0, 0.5) (Perovskite $Gd_{1-x}Sr_xFeO_{3-y}$ (X = 0.0, 0.5)의 Mossbauer연구)

  • 엄영랑;김철성;서정철;오영제
    • Journal of the Korean Magnetics Society
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    • v.8 no.2
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    • pp.67-73
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    • 1998
  • Crystallographic and magnetic properties of perovskite $Gd_{1-x}Sr_xFeO_{3-y}$ (x=0.0, 0.5) substituted $Sr^{2+}$ having larger inoic radius than $Gd^{3+}$ at GdFeO$_3$have been studied by x-ary diffraction, M$\ "{o}$ssbauer spectroscopy, and VSM. The cystal structures are found to be orthorhombic with the lattice parameters : $a_o=5.53\;{\AA},\;b_o=5.608\;{AA},\;C_o=7.724\;{\AA}$ for $Gd_{0.5}Sr_{0.5}FeO_{3-y}$ (x=0.0, 0.5) have been investigated over temperature range from 4.2 to 690 K using the M$\ "{o}$ssbauer technique. The Neel temperatuer of $Gd_{1-x}Sr_xFeO_{3-y}$ system is 690 K with x value of 0.0 and 515 K with x value of 0.5. Analysis of M$\ "{o}$ssbauer spectra Mohr's salt analysis for $Gd_{1-x}Sr_xFeO_{3-y}$ demonstrated the existence of the mixed valence states of iron and the coordination state of $Fe^{3+}$ and $Fe^{4+}$ ions. The Corresponding hyperfine parameters for GdFeO$_3$ are compatible with S=5/2 $Fe^{3+}$ in octahedral cooedination.l cooedination.

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Effect of Soil Physical Characteristics on Rhizome Rot Incidence of Platycodon grangiflorus (토양 물리적특성이 도라지 근경부패병에 미치는 영향)

  • Lee, Young-Han;Choi, Yong-Jo;Park, Sang-Ryeol;Kim, Min-Keun;Cho, Soo-Jeong;Yun, Han-Dae
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.1
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    • pp.24-31
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    • 2000
  • This study was conducted to determine the effect of soil physical characteristics on rhizome rot incidence of platycodon. Sampling sites were Keochang 4, Kimhae 7, Haman 6, Chinju 6 and Koseong 3 fields in Kyongnam province and Hongcheon 6 fields in Kangwon province. The root disease incidence rate was correlated with soil depth Y=-0.747X+88.19($R^2=0.394^{***}$), soil hardness Y=4.36X+8.93($R^2=0.201^*$), bulk density Y=104.7X-80.99($R^2=0.295^{**}$), clay content Y=1.24X+14.14($R^2=0.196^*$), porosity Y=-3.11X+215.9($R^2=0.220^*$) and silt content Y=-0.75X+67.85($R^2=0.178^*$). The yield was correlated with soil depth Y=0.263X+0.971($R^2=0.105^*$), clay content Y=-0.688X+32.74($R^2=0.158^*$), porosity Y=1.974X-93.19($R^2=0.231^{**}$) and silt content Y=53.05X-108.65($R^2=0.232^*$), The optimum cultivated land of perennial platycodon was soil depth over 1m, soil hardness under $5kg\;cm^{-2}$, bulk density $1.0Mg\;m^{-3}$, moisture content 13~17%. clay content 5~10%, porosity 58~63%, silt content 38~64% and soil texture of silt loam.

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