• Journal of the Korean Vacuum Society
• /
• v.5 no.4
• /
• pp.315-326
• /
• 1996

The electronic structures of 3d and 4d core-levels of rare-earth atoms in the insulating rare-earth (Sm, Eu, Gd, and Tb) compounds were studied with x-ray photoelectron spectroscopy(XPS). It is shown that the intrinsic satellite structure due to the hybridization disappears for chemically stable-earth trivalent heavy rare-earth insulating compounds as the hybridization between f electrons of rare-earth atoms and p electrons of anion atoms decreases due to the lanthanide contraction. Eu atoms at the surface of the stable insulating trivalent Eu compounds are found to be divalent. The satellite peak of Eu 3d core-level spectra at about 10eV higher binding energy side relative the main peak comes from the multiplet structures of $\underline{3d}4f^6$ configuration. The satellite structure appearing at about 15 eV higher binding energy side relative to the main peak in all insulating rare-earth compounds is due to an energy loss process of creating a plasmon.

• Geomechanics and Engineering
• /
• v.17 no.6
• /
• pp.515-525
• /
• 2019

The calculation of active earth pressure behind retaining wall is a typical three-dimensional (3D) problem with spatial effects. With the help of limit analysis, this paper firstly deduces the internal energy dissipation power equations and various external forces power equations of the 3D retaining wall under the nonlinear strength condition, such as to establish the work-energy balance equation. The pseudo-static method is used to consider the effect of earthquake on active earth pressure in horizontal state. The failure mode is a 3D curvilinear cone failure mechanism. For the different width of the retaining wall, the plane strain block is inserted in the symmetric plane. By optimizing all parameters, the maximum value of active earth pressure is calculated. In order to verify the validity of the new expressions obtained by the paper, the solutions are compared with previously published solutions. Agreement shows that the new expressions are effective. The results of different parameters are given in the forms of figures to analysis the influence caused by nonlinear strength parameters.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2007.09a
• /
• pp.514-527
• /
• 2007

Earth reinforcement techniques are used worldwide and offer proven solutions to a wide range of geotechnical engineering problems. Here in this paper, recent developments of three major reinforced soil retaining wall methods in Japan were introduced in order to show how the current situation of this technique in Japan is. And the statistical data for the volume of the use was also shown, such as the total volume of the use, the scales of the structures, layout of the earth reinforcement, fill materials, and foundation conditions. Some of the case histories were also introduced with photographs and figures. And then, as one of recent research activity by the author, the study on the application of X-ray CT for the problem of earth reinforcement method combined with other method such as piling and soil improvement was introduced. In this study, a series of model test for several reinforced ground with geogrids was conducted using a newly developed test apparatus. Then, the behavior in the soil box was scanned after settlement using X-ray CT scanner. Based on these test results, the reinforcing effect by the geogrids and the soil arching effect over the pile heads was discussed precisely and those are done in 3-D with nondestructive condition. Finally, the effectiveness of the use of X-ray CT scanner in geotechnical engineering was promised.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.28 no.3
• /
• pp.89-98
• /
• 1986

This study was carried out for the settlement and camber of earth dam by the changes of the density. The testing material was taken five kinds of Soil used as banking material and it was compacted by 100, 95, 90, 85 and 80% compaction degree. The results of the settlement of earth dam whose height ranges from 10m to 50m are as follows. 1.The more the fine particle (n) increases, the higher the liquid limit (WL) and the lower the dry density (rd) becomes as follows; rd=2. 22-0. 0052n (gr/cm$_3$) rd=2. 394-0. 0164WL rd=2. 185-(5. 8n-2. 5WL)X10-$_3$ 2. The higher the optimum moisture content (Wo) becomes, the lower the density becomes as follows; rt,=2. 68-0. 028Wo rd=2. 578-0. 04Wo 3. 3.Most of the consolidation occurs immediately by loading and the more the fine particle increases, the lower the coefficient of consolidation becomes. 4.The more the fine particle increases and lower the compaction degree (D) becomes,the lower the pre-consolidation load (Pc) becomes but on the contrary the compression index (Cc) becomes higher. Those equation is as follows. Pc=3. 32-(4. 3n-3. 0D) X10-2 (kg/cm$^2$) Cc=0. 41+(1. 33n-4. 44D) X10-$^3$ 5.The more the consolidation load (P) increases, the lower the coefficient of volume change (mv) becomes with mv=ap-b, the higher the consolidation ratio (u) becomes with U= (0. 6~1. 35)PO.4 6.The more the fine particle (n) increases, the more the settlement of dam occurs with U=anb and 60-80% of the settlement occurs under construction. 7.The camber of dam has higher value in condition that has more fine particle, poorer compaction and higher height of dam. In the dam construction about twice value of table 7 is required for dam safety.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.1
• /
• pp.1-10
• /
• 2020

The atomic structures of silicate liquids at high pressure provide insights into the transport properties including thermal conductivities or elemental partitioning behavior between rocks and magmas in Earth's interior. Whereas the local electronic structure around silicon may vary with the arrangement of the nearby oxygens, the detailed nature of such relationship remains to be established. Here, we explored the atomic origin of the pressure-induced changes in the electronic structure around silicon by calculating the partial electronic density of states and L₃-edge X-ray absorption spectra of SiO₂ polymorphs. The result showed that the Si PDOS at the conduction band varies with the crystal structure and local atomic environments. Particularly, d-orbital showed the distinct features at 108 and 130 eV upon the changes in the coordination number of Si. Calculated Si XAS spectra showed features due to the s,d-orbitals at the conduction band and varied similarly with those observed in s,d-orbitals upon changes in the crystal structures. The calculated Si XAS spectrum for α-quartz was analogous to the experimental Si XRS spectrum for SiO₂ glass, implying the overall similarities in the local atomic environments around the Si. The edge energies at the center of gravity of XAS spectra were closely related to the Si-O distance, thus showing the systematic changes upon densification. Current results suggest that the Si L_2,3-edge XRS, sensitive probe of the Si-O distance, would be useful in unveiling the densification mechanism of silicate glasses and melts at high pressure.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.16 no.4
• /
• pp.361-372
• /
• 2014

A measurement of tunnel displacement plays an important role for stability analysis and prediction of possible fault zone ahead of tunnel face. In this study, we evaluated characteristics of tunnel behaviour due to the existence and orientation of fault zone based on 3-dimensional finite element numerical analysis. The crown settlement representing tunnel behaviour is acquired at 5 m away from tunnel face in combination with x-Rs control chart analysis based on statistics for trend line and L/C (longitudinal/crown displacement) ratio in order to propose risk management method for fault zone. As a result, x-Rs control chart analysis can enable to predict fault zone in terms of existence and orientation in tunnelling.

• Analytical Science and Technology
• /
• v.6 no.5
• /
• pp.463-469
• /
• 1993

HDBPDA ion exchange resin, {(4, 5) : (13, 14)-Dibenzo-6, 9, 12-trioxa-3, 15, 21, -triazabicyclo [15. 3. 1]heneicosa-(1, 17, 19)(18, 20, 21) triene ion exchange resin : HDBPDA ion exchange resin} had a capacity of 3.8meq/g dry resin. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA and strongly acidic cation exchange resin, Dowex 50W-X8(200-400mesh) in water, and the various concentrations of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions for the HDBPDA ion exchange resin, but generally the distribution coefficient slightly increased with decreasing concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those in various hydrochloric acid concentration. The distribution coefficients of alkali and alkaline earth metal ions for the Dowex 50W-X8 ion exchange resin increased with decreasing hydrochloric acid concentration. Especially, the distribution coefficients of alkaline earth metal ions increased rapidly compared to those for alkali metal ions. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA ion exchange resin increased in a linear manner with decreasing acid concentration, and the slope, d log Kd/d log $M_{HCl}$ is about -0.2. Of the distribution cofficients of alkali metal ions on Dowex 50W-X8, at range of moderate hydrochloric acid concentration, the slope is about -1, while the slope for alkaline earth metal ions is about -2. However, at very low hydrochloric acid concentration, the linear variation between distribution coefficient and acid concentration was not occurred, but the slope was deviated from above values at low acid concentration.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.378-378
• /
• 2010

We report the electronic structure of CoFeO-R (R=Hf, La, Nb) thin films studied by x-ray absorption spectroscopy (XAS). These ferrites thin films were prepared by pulsed laser deposition method and characterized by XAS measurements at O K-, Co and Fe L-edges. The O K-edge spectra suggest that there is a strong hybridization between O 2p and 3d electrons of transition metal cations and Fe $L_{3,2}$-edge spectra indicate that Fe-ions exist in $Fe^{2+}$ with tetrahedral site of the spinel structure. Divalent Co ions is also distributed in tetrahedral site with rare earth ions goes to octahedral sites of spinel structure. X-ray magnetic circular dichroism (XMCD) is also used to explain the symmetry and magnetic nature dependence on rare-earth ions.

• Journal of Korean Society for Atmospheric Environment
• /
• v.24 no.5
• /
• pp.584-593
• /
• 2008

The surface $O_3,\;CO,\;NO_x,\;and\;SO_2$ were measured at Gosan in Jeju Island from May 2004 to April 2005. Over this period, the mean concentrations $({\pm}s.d.)$ of each gas was 40.06 $({\pm}16.01)$ ppbv for $O_3,\;264.92({\pm}115.73)ppbv\;for\;CO,\;1.98({\pm}2.73)ppbv\;for\;SO)_2,\;and\;4.64 ({\pm}3.24) ppbv\;for\;NO_x$. The monthly variations and the diurnal variations of these gases show that the Gosan site is situated in a relatively clean region. However, there were episodic simultaneous peaks in CO and $SO_2$, especially in winter and early spring. Using cluster analysis with air mass back- ward trajectory analysis, we suggest that these episodes are due to the influence of transportation of polluted air mass from polluted regions. In the cluster, which was under the dominant influence of clean maritime air mass, low levels of $O_3,\;CO,\;and\;SO_2$ were observed. The levels of these species were elevated in the other two clusters which had the air mass influenced by polluted continental regions. In addition, ratios of the chemical species such as $CO/NO_x,\;SO_2/NO_x,\;and\;CO/SO_2$ revealed the somewhat different characteristics of emission sources influencing each cluster. The differences in concentration of trace gases among clusters with different origin and transport pathways imply that Gosan is under the effect of pollution transported from other regions.

• Journal of the Mineralogical Society of Korea
• /
• v.23 no.4
• /
• pp.305-313
• /
• 2010

Mineralogical characteristics of Cu-Co ores from the Central African Copperbelt in the Democratic Repblic of Congo are studied using powder X-ray diffractometer, general area detector X-ray diffractometer, and electron proble microanalyzer. Black ores are mainly composed of heterogenite (cobalt oxide/hydroxide mineral) and malachite (copper carbonate mineral), whereas green ores are only composed of malachite. Heterogenite shows very bright white color under the reflected microscope, and belongs to 3R polytype, because it has d-spacings at $4.39{\AA}$ and $2.316{\AA}$. Since NiO and $Fe_20_3$ content of heterogenite are lower than those of 3R polytype from other localities, it cannot completely exclude the presence of 2H polytype in heterogenite from this study. Malachite is light grey color under the reflected microscope with approximate chemical formula of $Cu_{1.97}Co_{0.02}Fe^{2+}{_{0.01}}CO_3(OH)_2$. Heterogenite and malachite were probably formed at the supergene emichment stage, the last mineralization stage in the Central African Copperbelt. Cobalt seems to be much more emiched in the black supergene (oxy)hydroxide ore than those in the primary sulfide ore.