• Title/Summary/Keyword: X/E ratio

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Photocyclization of α-(o-Ethylphenyl)acetophenone in Zeolites

  • 노태희;최경인;권혁순;장동조;박봉서
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.539-542
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    • 1999
  • The diastereoselectivity in the photocyclization of α-(o-ethylphenyl)acetophenone(1) to 1-methyl-2-phenyl-2-indanol was studied in zeolites X and Y, and compared with that in isotropic solvents. The yields of E-diastereomer at the irradiation of 1 in protic solvents were higher than those in aprotic solvents. The ratios of E-diastereomer to Z-diastereomer in zeolites X and Y were much higher than those in isotropic solvents. The E/Z ratios at the irradiation of 1 in zeolites X were also found to be dependent on the cations present. As the cation size increased from Li+ to Cs+, the ratio decreased. However, any pattern in the E/Z ratios was not found in zeolites Y. The diastereoselectivity observed in the zeolites was interpreted by the conformational restriction imposed by the cavity size. An efficient oxidation of 1 in zeolites RbX and CsX was also observed.

THE X-RAY EMISSION FROM EARLY TYPE GALAXIES

  • Kim, Dong-Woo
    • Publications of The Korean Astronomical Society
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    • v.7 no.1
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    • pp.63-69
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    • 1992
  • We have systematically investigated the X-ray spectra of normal galaxies, by using the Imaging Proportional Counter (IPC) data in the Einstein data base. We employed the X-ray color-color plot as well as the standard model fitting method which requires higher signal to noise ratio. We discuss X-ray emission mechanisms in terms of their spectral properties and the signature of cooling flows which are most likely present in X-ray bright early type galaxies. On the average, fits to absorbed thermal spectra show that the X-ray emission temperature of spirals is higher than that of ellipticals. This is consistent with our understanding that accreting binaries are a major X-ray source in spirals, while extended gaseous halos are present in ellipticals. The emission temperature becomes lower with increasing X-ray to optical luminosity ratio in E and S0 galaxies. This result is what we would expect if the emission of X-ray faint early type galaxies consists of a large evolved stellar component, while the gaseous emission becomes dominant in X-ray brighter galaxies. We also find a cool, self-absorbed core in some early type galaxies, which directly indicates the presence of cooling flows in such galaxies.

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Electrical properties of $Pb(Zr_xTi_{1-x})O_3$ferroelectric thin films prepared by sol-gel processing (Sol-gel법에 의한 $Pb(Zr_xTi_{1-x})O_3$ 강유전 박막의 전기특성)

  • 백동수;박창엽
    • Electrical & Electronic Materials
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    • v.9 no.2
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    • pp.132-137
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    • 1996
  • Pb(Zr$_{x}$Ti$_{1-x}$ )O$_{3}$ solutions prepared by sol-gel processing with different Zr/Ti ratio were coated on Pt/SiO$_{2}$/Si substrates using spin coating method. Coated films were annealed by rapid thermal annealing at 650.deg. C for 20sec to fabricate Pb(Zr, Ti)O$_{3}$ ferroelectric thin films. Electrical properties of the films such as dielectric constant and loss, ferroelectric hysteresis, fatigue, switching time, and leakage current were measured. Hysteresis of the films with different Zr/Ti ratio yield Pr ranging 10-21.mu.C/cm$^{2}$, E$_{c}$ ranging 37.5-137.5kV/cm. Hysteresis curve was changed from square-type to slim type according to increasing Zr contents. Switching time was faster than 180ns, and leakage current was about 20.mu.A/cm$^{2}$. The film underwent above 10$^{8}$ cycles of reversed polarization showed fatigue with increased coercive field and decreased remnant polarization.tion.

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Development of the Brown Planthopper, Nilaparvata lungens Sta$\{aa}$l, Biotypes and Their Hybrid Progenies Fed on Different Cultivars of Rice with Various Resistance Gene and Damage of Different Rice Cultivars (벼멸구 생태형의 교잡종별 발육 및 수도 품종별 피해)

  • 최주수;박영도
    • Journal of Life Science
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    • v.7 no.4
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    • pp.347-354
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    • 1997
  • Some attempts were made to investigate the gentic characteristics of the brown planthopper(BPH), Nilaparvata lugens Sta${\aa}$l, biotypes. In terms of egg and nymphal periods, egg hatcgability, emergence ratio, and population change of BPH and plant damage of rice cultivars by the infestation of BPH biotypes and their hybrid progenies in field conditions. The egg and nymphal periods of the three of BPH biotypes and their hybrid progenies on Dongjinbyeo with no resistance gene were shorter than on rice cultivars with resistance gene. But the periods of biotype-2(♀) X 2(♂) (E) on Samgangbyeo with Bph-1 gene and biotype-3(♀) X 3(♂)(I) on Mirying 63 with bph-2 gene were as short as on Dongjinbyeo. The egg hatchability and emergence ratio of the three Bph biotypes and their hybrid progenies on Dongjinbyeo were higher than on the other rice cultivars, and those of E on Samgangbyeo and I on Miryang 63 were as high as on Dongjinbyeo. In rice paddy field, biotype-1(♀) X 1(♂)(A)$\sim$I infested on Dongjinbyeo, E onSamgangbyeo, and I on Miryang 63 were increased their population densities remarkably in next generation. Dongjinbyeo infested by A$\sim$I, and Myryang 63 infested by I were hopperburned at 60 days after infestation and had a damage rating of 0.9. But Samgangbyeo infested by E was no hopperburn(damage rating: 7.3) though it showed high BPH population at 60 days after infestation.

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Spectroscopic Characterization of 400℃ Annealed ZnxCd1-xS Thin Films (400℃ 열처리한 삼원화합물 ZnxCd1-xS 박막의 분광학적 특성 연구)

  • Kang, Kwang-Yong;Lee, Seung-Hwan;Lee, Nam-Kwon;Lee, Jeong-Ju;Yu, Yun-Sik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.26 no.1
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    • pp.101-112
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    • 2015
  • II~VI compound semiconductors, $Zn_xCd_{1-x}S$ thin films have been synthesized onto indium-tin-oxide(ITO) coated glass substrates using thermal evaporation technique. The composition ratio x($0{\leq}x{\leq}1$) was varied to fabricate different kinds of $Zn_xCd_{1-x}S$ thin films including CdS(x=0) and ZnS(x=1) thin films. Then, the deposited thin films were thermally annealed at $400^{\circ}C$ to enhance their crystallinity. The chemical composition and electronic structure of films were investigated by using X-ray photoelectron spectroscopy(XPS). The optical energy gaps of the samples were determined by ultra violet-visible-near infrared(UV-Vis-NIR) spectroscopy and were found to vary in the range of 2.44 to 3.98 eV when x changes from 0 to 1. Finally, we measured the THz characteristics of the $Zn_xCd_{1-x}S$ thin films using THz-TDS(time domain spectroscopy) system to identify the capability for electronic and optical devices in THz region.

ON THE CATCH OF GILL NET IN THE JEJU ISLAND -Comparison of mackerel catch in monofilament and multifilament gill nets- (제주도 자망이망율에 관하여 -고등어 자망의 이망율 비교-)

  • SHON Tae Jun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.8 no.1
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    • pp.7-10
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    • 1975
  • The catches of mackerel by monofilament and multifilament net were compared by means of $x^2$ and t-test method. In order to improve the netting twine of drift nets, 6 shoots 5 different mesh and nylon-monofilament netting twines $(B\times2,\;C\;D,\;F,)$ and 2 shoe nylon-multifilament $(A\times2)$ which are using near the Jeju Island in contemporary days were used for the experiment. These gill no were connected in order of A, ,B, C, A, B, E, F and operated fly fishing boat Taeann Ho (7T) near sea of Jeju Ialand from May 1974 to August 1974. The results obtained are as follows: 1. B type nylon-monofilament gill nets were superior to nylon-multifilament gill nets in catch according to the result of $X^2$ test and t-test, and the catch ratio was $M_A:\;M_B=1:1.8$. 2. 75mm mesh size C, D nylon-monofilament gill nets were superior to 85mm mesh size nylonmonofilament gill nets, and their catch ratio were E, F: C, D=1:2.8. 3. The catch ratio C, D and E, F type nets were compared by means of t-teat, however could not recognized their relationship.

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Determination of Sperm Sex Ratio in Bovine Semen Using Multiplex Real-time Polymerase Chain Reaction

  • Khamlor, Trisadee;Pongpiachan, Petai;Sangsritavong, Siwat;Chokesajjawatee, Nipa
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.10
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    • pp.1411-1416
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    • 2014
  • Gender selection is important in livestock industries; for example, female calves are required in the dairy industry. Sex-sorted semen is commonly used for the production of calves of the desired gender. However, assessment of the sex ratio of the sorted semen is tedious and expensive. In this study, a rapid, cost effective and reliable method for determining the sex ratio was developed using a multiplex real-time polymerase chain reaction (PCR) assay. In this assay, the X and Y chromosome-specific markers, i.e., bovine proteolipid protein (PLP) gene and sex-determining region Y (SRY) were simultaneously quantified in a single tube. The multiplex real-time PCR assay was shown to have high amplification efficiencies (97% to 99%) comparable to the separated-tube simplex real-time PCR assay. The results obtained from both assays were not significantly different (p>0.05). The multiplex assay was validated using reference DNA of known X ratio (10%, 50%, and 90%) as templates. The measured %X in semen samples were the same within 95% confidence intervals as the expected values, i.e., >90% in X-sorted semen, <10% in Y-sorted semen and close to 50% in the unsorted semen. The multiplex real-time PCR assay as shown in this study can thus be used to assess purity of sex-sorted semen.

Pulse electric field-excited electron emission from Pb$(Zr_xTi_{1-x})O_3$ ceramics prepared by conventional solid state reaction (고상 반응법에 의해 제조된 Pb$(Zr_xTi_{1-x})O_3$ 세라믹스에서 펄스 전계에 의한 전자 방출)

  • Kwak, Sang-Hee;Kim, Tae-Heui;Park, Kyung-Bong;Kim, Chang-Soo
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1867-1869
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    • 1999
  • Pulse electric field induced electron emission from ferroelectrics has been studied with Pb$(Zr_xTi_{1-x})O_3$ ceramics with varying Zr/Ti ratio from 35/65 to 65/35, Electron emission was proved to be concentrated on the electrode edge by emission profile test and emission capture photographs. The 65/35 composition showed largest emission charge in lowest field and lowest emission threshold field. The emission characteristics are closely dependent on their ferroelectric properties in hysteresis curve. Electron emission charge increases with the polarization charge and emission threshold voltage is dependent on coercive field regardless of their composition. But dielectric constant has little relation with emission property. Electron emission charge increases exponentially with pulse electric field irrespective of composition. On the assumption that the surface potential is linear with the pulse electric field, electron emission can be regarded as a field emission at the electrode edge using Fowler-Nordheim plot of ln$(Q_e/E_{fe})$ to $1/E_{fe}$.

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Effects of the Wire-screen Rib on Heat Transfer and Friction Factors (와이어 스크린 리브이 열전달과 마찰계수에 미치는 효과)

  • Oh, Se-Kyung;Ahn, Soo-Whan;Lee, Dae-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.2
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    • pp.196-203
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    • 2011
  • Experiments to determine heat transfer coefficients and friction factors are conducted on a stationary transverse parallel wire-screen rib roughened rectangular channel. The test section consists of 198 mm (W) x 40 mm (H) x 712 mm (L). The channel has the aspect ratio of 4.95 and hydraulic diameter of $D_h$=6.66 cm. Four wire screen ribs and a solid rib are used. 0.1 mm-thick-stainless steel foil heaters and thermocouples (T type) are used to measure the heat transfer coefficients. Reynolds numbers studied range from 20,000 to 60,000. The wire-screen rib height (e) to hydraulic diameter ($D_h$) ratio ($e/D_h$) is 0.075; spacing (p) to height ratio (p/e) is 10. Results indicate that the solid rib produces the greatest Nusselt number and friction factor.

A Study on the Metal Mesh for CuNx-Cu-CuNx Multi-layer Touch Electrode by Reactive Magnetron Sputtering (Reactive Magnetron Sputtering 적용 CuNx-Cu-CuNx 적층형 Metal Mesh 터치센서 전극 특성 연구)

  • Kim, Hyun-Seok;Yang, Seong-Ju;Noh, Kyeong-Jae;Lee, Seong-Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.414-423
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    • 2016
  • In the present study, the $CuN_x-Cu-CuN_x$ layer the partial pressure ratio Cu metal of Ar and $N_2$ gas using a DC magnetron sputtering device, was generated by the In-situ method. $CuN_x$ layer was able to obtain a surface reflectance reduction effect from the advantages of the process and the external light. $CuN_x$ layer is gas partial pressure, DC the Power, the deposition time variable transmittance in response to the thickness and partial pressure ratio, the reflectance was measured. $Ar:N_2$ gas ratio 10:10(sccm), DC power 0.35 A, was derived Deposition time 90 sec optimum conditions. Thus, according to the optimal thickness and the composition ratio was derived surface reflectance of 20.75%. In addition, to derive the value of ${\Delta}$ Ra surface roughness of 0.467. It was derived $CuN_x$ band-gap energy of about 2.2 eV. Thus, to ensure a thickness and process conditions can be absorbed to maximize the light in a wavelength band in the visible light region. As a result, the implementation of the $12k{\Omega}$ base line resistance of using the Cu metal. This is, 5 inch Metal mesh TSP(L/S: $4/270{\mu}m$) is in the range of the reference operation.