• Title/Summary/Keyword: Wurtzite

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Field emission characteristics of ZnO nanowires grown at liquid phase (액상에서 성장한 ZnO 나노와이어의 전계방출 특성연구)

  • No, I.J.;Kim, S.H.;Cho, J.W.;Park, G.B.;Kim, Y.H.;Lee, D.C.;Shin, P.K.
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1347_1348
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    • 2009
  • We fabricated FEDs based on ZnO nanowires. ZnO nanowires were synthesized on Au thin films by hydrothermal method on hot plate. After 2 hours, we obtained nanowires of chin form. The high-purity nanowires showed sharp tips geometry with a wurtzite structure. The field emission properties of the ZnO nanowires were investigated in high vacuum chamber. The turn-on field for the ZnO nanowires was found to be about 4.1 V/${\mu}m$ at a current density of $0.1{\mu}A/cm^2$.

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Synthesis of GaN nanowires using thermal chemical vapor deposition (열화학기상증착법을 이용한 GaN nanowire 합성)

  • 류승철;이태재;이철진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.931-934
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    • 2001
  • GaN nanowires has much interest as one-dimensional materials for blue light LED. GaN-based materials have been the subject of intensive research for blue light emission and high temperature/high power electronic devices. In this letter, the synthesis of GaN nanowires by the reaction of mixture of GaN nanowires by the reaction of mixture of Ga meta and GaN powder with NH$_3$ using thermal chemical vapor deposition is reported. X-ray diffraction, energy dispersive x-ray spectrometer, scanning electron microscopy, and transmission electron microscopy indicate that those GaN nanowires with hexagonal wurtzite structure were about 60nm in diameter and up to several hundreds of micrometers in length.

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Effect of substrate temperature on the properties of aluminum doped zinc oxide by DC magnetron sputtering

  • Koo, Hong-Mo;Kim, Se-Hyun;Moon, Yeon-Keon;Park, Jong-Wang;Jeong, Chang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1542-1545
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    • 2005
  • Transparent conducting aluminum-doped zinc oxide (AZO) thin films have been deposited on corning 1737 glass by DC magnetron sputter. The structural, electrical and optical properties of the films were investigated as a function of various substrate temperatures. AZO thin films were fabricated by dc magnetron sputtering with AZO ceramic target $(Al_2O_3: 2wt %)$. The obtained films were poly crystalline with a hexagonal wurtzite structure and preferentially oriented in the (002) crystallographic direction. The lowest resistivity is $6.0{\times}10^{-4}$ Ocm with the carrier concentration of $2.694{\times}10^{20}\;cm^{-3}$ and Hall mobility of $20.426cm^2/Vs$. The average transmittance in the visible range was above 90%.

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Characterization of ZnO:Al(AZO) Transparent Conduction Film produced by DC Magnetron Sputtering Method

  • Koo, Hong-Mo;Kim, Se-Hyun;Moon, Yeon-Keon;Park, Jong-Wang;Jeong, Chang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1546-1549
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    • 2005
  • Al-doped ZnO (ZnO:Al) thin films were grown on corning 1737 glass substrates by dc magnetron sputtering. The structural, electrical and optical properties of the films were investigated as a function of various discharge power. The obtained films were polycrystalline with a hexagonal wurtzite structure and preferentially oriented in the (002) crystallographic direction. The lowest resistivity is $6.0{\times}10^{-4}$ Ocm with the carrier concentration of $2.694{\times}10^{20}$ $cm^{-3}$ and Hall mobility of $20.426cm^2/Vs$. The average transmittance in the visible range was above 90%.

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ZnO Crystals with Belt and Comb Shapes Synthesized by Oxidation of ZnS in Air Atmosphere (공기 중 대기압 분위기에서 ZnS의 산화에 의해 생성된 벨트형상과 빗 형상의 ZnO 결정)

  • Lee, Geun-Hyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.11
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    • pp.920-924
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    • 2011
  • ZnO crystals with belt and comb shapes were synthesized without any catalysts through a simple thermal oxidation of ZnS powder in alumina crucible under air atmosphere. X-ray diffraction (XRD) pattern revealed that the ZnO crystals had wurtzite structure of hexagonal phase. Energy dispersive x-ray (EDX) spectra showed that the ZnO was of high purity. In the cathodoluminescece spectra obtained for the ZnO crystals with belt and comb shapes, a strong ultraviolet emission centered at 380nm was observed, which indicates the ZnO crystal has high crystalline quality.

Optical Properties of a ZnO-MgZnO Quantum-Well

  • Ahn, Do-Yeol;Park, Seoung-Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.6 no.3
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    • pp.125-130
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    • 2006
  • The optical gain and the luminescence of a ZnO quantum well with MgZnO barriers is studied theoretically. We calculated the non-Markovian optical gain and the luminescence for the strained-layer wurtzite quantum well taking into account of the excitonic effects. It is predicted that both optical gain and luminescence are enhanced for the ZnO quantum well when compared with those of InGaN-AlGaN quantum well structure due to the significant reduction of the piezoelectric effects in the ZnO-MgZnO systems.

Structural studies of $Mn^+$ implanted GaN film

  • Shi, Y.;Lin, L.;Jiang, C.Z.;Fan, X.J.
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.56-59
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    • 2003
  • Wurtzite GaN films are grown by low-pressure MOCVD on (0001)-plane sapphire substrates. The GaN films have a total thickness of 4 $\mu$m with a surface Mg-doped p-type layer, which has a thickness of 0.5 $\mu$m. 90k eV $Mn^{+}$ ions are implanted into the GaN films at room temperature with doses ranging from $1 \times10^{15}$ to $1 \times 10^{16}\textrm{cm}^{-2}$. After an annealing step at $770^{\circ}C$ in flowing $N_2$, the structural characteristics of the $Mn^{+}$ implanted GaN films are studied by X-ray diffraction (XRD), Rutherford backscattering spectrometry (RBS) and atomic force microscopy (AFM). The structural and morphological changes brought about by $Mn^{+}$ implantation and annealing are characterized.

Effects of Annealing Temperature on Properties of Al-Doped ZnO Thin Films prepared by Sol-Gel Dip-Coating

  • Jun, Min-Chul;Koh, Jung-Hyuk
    • Journal of Electrical Engineering and Technology
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    • v.8 no.1
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    • pp.163-167
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    • 2013
  • Aluminum doped zinc oxide (AZO) thin films have been prepared on the glass substrates (Corning 1737) by sol-gel dip-coating method employing zinc acetate and aluminum chloride hexahydrate for the transparent conducting oxide (TCO) applications. 1 at% Al was doped to the ZnO thin films. The effects of post-heating temperature on the crystallization, optical and electrical properties of the AZO films have been investigated. Experimental results showed that post-heating temperature affected the microstructure, electrical resistance, and optical transmittance of the AZO films. From the X-ray diffraction analysis, all films have hexagonal wurtzite crystal structure. Optical transmittance spectra of the AZO films exhibited transmittance higher than about 80% within the visible wavelength region and the optical direct band gap ($E_g$) of these films was increased with increasing post-heating temperature. A minimum resistivity of $2.5{\times}10^{-3}{\Omega}cm$ was observed at $650^{\circ}C$.

Preparation and characterization of ZnO photocatalyst and their photocatalysis

  • Lee, Sang-Deok;Nam, Sang-Hun;Jo, Sang-Jin;Bu, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.292-292
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    • 2010
  • Among the semiconducting materials, ZnO has considerably attracted attention over the past few years due to the high activities in removing organic contaminants created from industry. In this work, ZnO nanoparticles were synthesized by spray pyrolysis method using the zinc acetate dihydrate as starting material at various synthesis temperatures. The structures of the synthesized ZnO were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Brunauer, Emmett & Teller (BET), Fourier Transformation Infrared (FT-IR), and UV-vis spectroscopy. The Miller indices of XRD patterns indicate that the synthesized ZnO nanoparticles showed a hexagonal wurtzite structure. With increasing synthesis temperature, the mean diameter of ZnO nanoparticles increased, and their crystallinity was improved. Also, the photocatalytic activity of ZnO was studied by the photocatalytic degradation of methyleneblue (MB) under UV irradiation (365 nm) at room temperature. The results show that the photocatalytic efficiency of ZnO nanoparticles was enhanced by increasing synthesis temperature.

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Effect of Ar Flow Ratio on the Characteristics of Al-Doped ZnO Grown by RF Magnetron Sputtering (마그네트론 스퍼터를 이용한 Ar 가스 유량 조절에 따른 AZO의 특성 변화)

  • Lee, Seung-Jin;Jeong, Young-Jin;Son, Chang-Sik
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.61.2-61.2
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    • 2011
  • 본 연구에서는 박막 태양전지용 투명전극으로 사용하기 위해서 Gun-type RF 마그네트론 스퍼트링을 이용하였다. 챔퍼안의 타겟은 AZO타겟(Zn: 98[wt.%], Al:2[wt.%]을 장착하였고 공정압력은 고진공을 유지하였다. 온도는 $300^{\circ}C$로 고정하였고 전력은 70W로 고정하였다. $Ar^+$ 가스유량비를 20sccm~100sccm으로 변화를 주어 기판 위에 AZO를 증착하여 AZO의 구조적 및 광학적 특성의 의존성을 알아보았다. 모든 가스변화에서 400에서 700 nm까지의 가시광 영역에서의 AZO 박막의 평균 투과도는 약 85% 이상의 우수한 투과율을 보인다. AZO 박막 내의 결정 구조는 (002)면으로 우선 배향을 하는 wurtzite 구조를 가지며, $Ar^+$변화에 의해 두께가 증가하면서 결정립의 주상 (columnar) 성장이 향상되고 결정립의 크기도 증가한다. 이러한 경향성은 $Ar^+$변화에 의해 결정성이 향상된다는 것을 의미한다. 이와 같은 구조 및 광학 특성을 가지는 유리 기판 위에 증착된 AZO는 박막 태양전지용 투명 전극으로 응용이 가능할 것이다.

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