• Journal of Surface Science and Engineering
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• v.56 no.6
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• pp.420-426
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• 2023

We prepared a highly sensitive hydrogen (H₂) sensor based on Indium oxides (In₂O₃) porous nanoparticles (NPs) loaded with Platinum (Pt) nanoparticle in the range of 1.6~5.7 at.%. In₂O₃ NPs were fabricated by microwave irradiation method, and decorations of Pt nanoparticles were performed by electroless plating on In₂O₃ NPs. Crystal structures, morphologies, and chemical information on Pt-loaded In₂O₃ NPs were characterized by grazing-incident X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, respectively. The effect of the Pt nanoparticles on the H₂-sensing performance of In₂O₃ NPs was investigated over a low concentration range of 5 ppm of H₂ at 150-300 ℃ working temperatures. The results showed that the H₂ response greatly increased with decreasing sensing temperature. The H₂ response of Pt loaded porous In₂O₃ NPs is higher than that of pristine In₂O₃ NPs. H₂ gas selectivity and high sensitivity was explained by the extension of the electron depletion layer and catalytic effect. Pt loaded porous In₂O₃ NPs sensor can be a robust manner for achieving enhanced gas selectivity and sensitivity for the detection of H₂.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.419-425
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• 2017

In this study, the performance characteristics of the K-based sorbents (KEP-CO2P2, KEPCO RI, Korea) has been studied in relation with the heat exchanger structure and shape in a mixing zone of the carbonator in the bench-scale dry $CO_2$ capture process. Two types of heat exchangers (different structure and shape) were used in the carbonator as CASE 1 and CASE 2, in which the experiment has been continuously performed under the same operating conditions. During the continuous operation, working temperature of carbonator was 75 to $80^{\circ}C$, that of regenerator was 190 to $200^{\circ}C$, and $CO_2$ inlet concentration of the feed gas was 12 to 14 vol%. Especially, to compare the dynamic sorption capacity of sorbents, the differential pressure of the mixing zone in the carbonator was maintained around 400 to 500 mm $H_2O$. Also, solid samples from the carbonator and the regenerator were collected and weight variation of those samples was evaluated by TGA. The $CO_2$ removal efficiency and the dynamic sorption capacity were 64.3% and 2.40 wt%, respectively for CASE 1 while they were 81.0% and 4.66 wt%, respectively for CASE 2. Also, the dynamic sorption capacity of the sorbent in CASE 1 and CASE 2 was 2.51 wt% and 4.89 wt%, respectively, based on the weight loss of the TGA measurement results. Therefore, It was concluded that there could be a difference in the performance characteristics of the same sorbents according to the structure and type of heat exchanger inserted in the carbonator under the same operating conditions.

• Journal of the Korean Solar Energy Society
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• v.26 no.4
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• pp.55-61
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• 2006

Titanium oxide ($TiO_2$) films are deposited on the indium tin oxide (ITO) substrate in an $Ar/O_2$ atmosphere by using reactive RF (Radio Frequency) magnetron sputtering technique, and Electrochromic properties and durability of $TiO_2$ films deposited at different preparation conditions are investigated by using UV-VIS spectrophotometer and cyclic voltammetry Li+ interalation/deintercalation in $TiO_2$ films shows that the electrochromic properties and durability of as-deposited films strongly depend on gas pressure $TiO_2$ films formed in our sputtering conditions are found to remain transparent, irrespective of their Li+ ion contents. The optimum sputtering conditions for film as passive counter electrode in electrochromic devices are working pressure of $1.0\;{\times}\;10^{-2}\;torr$ and oxygen flow raes of $10{\sim}15\;sccm$, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.120-120
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• 2009

Ga doped ZnO (GZO) transparent conductive films were deposited on the glass substrates at room temperature by facing target sputtering (FTS) method. The sputtering targets were 100 mm diameter disks of GZO($Ga_2O_3$ 3.w.t%) and Zn metal. The GZO thin films were deposited as a various $PO_2$ (oxygen gas content). Base pressure was $2{\times}10^{-6}torr$, and a working pressure was 1mTorr. The properties of thin films on the electrical and optical properties of the deposited films were investigated by using a four-point probe (Chang-min), a Hall Effect measurement (Ecopia) and an UV/VIS spectrometer (HP). The minimum resistivity of film was $6.5{\times}10^{-4}[{\Omega}-cm]$ and the average transmittance of over 80% was seen in the visible range

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.696-701
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• 2001

The performance and the internal flow of the impeller of the centrifugal chiller compressor with refrigerant R12 as working fluid were studied numerically, using CFD code, CFX-Tascflow, which is commercially available. In this numerical study, the thermodynamic and transport properties of the refrigerant gas were generated by the property program of NIST and linked with main program to extend the capability of the code to refrigerant gases. Numerical study was applied to several mass flow rates near the design mass flow rate at constant rotating speed. Overall performance and flow characteristics of the impeller at impeller exit were investigated. The results were physically reasonable and showed good agreement with experimental measurement at the design flow rate.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2002.02a
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• pp.67-70
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• 2002

The Stirling cryocooler with helium refrigerant has been widely used for the cooling of the infrared detector, and the alternatives of the helium in the Stirling cryocooler are nitrogen and hydrogen gas. In this study, the performance experiment of the small FPFD(Free Piston and Free Piston) type Stirling cooler and the moving coil type, dual acting linear compressor was performed when the nitrogen and helium is used for the working fluid The results show that the nitrogen refrigerant has small cooling capacity compared with the helium, but the performance characteristics of the linear compressor does not greatly changed.

• International Journal of Air-Conditioning and Refrigeration
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• v.14 no.1
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• pp.28-39
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• 2006

Two-phase flow through a T-junction has been studied by numerous researchers so far. The dividing characteristics of the gas and liquid phases at the T-junction are very complicated due to a lot of related variables. The prediction models have been suggested by using experimental data for a specific condition or working fluid. But, they showed the application limitation for the most of the other conditions or fluids. Since most of them are applicable for their own experimental range, the generalized model for the wide range of conditions and fluids is needed. Even though it's not available now, some of the models developed for air-water flow at a T-junction might be applicable for the part of refrigerants with some modifications. Especially, for the two-phase flow of refrigerants at the T-junction, very few studies have been performed. Further experimental study is required to be performed for the wide range of test conditions and fluids to predict properly the two-phase flow distribution and phase separation through the T-junction.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.9
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• pp.870-878
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• 2000

An experimental study and a modeling are peformed to investigate the pressure drop of combining junctions in two-phase flows. Experiments on tripod geometry used in a condenser or an evaporator, are conducted with inlet mass fluxes from 200 to$ 400 kg/m^2$s, and pipe diameters of 7 m and 9.52 m. The working fluid is R22. The result shows that the pressure drop increases as the quality does, but the effect of the increase of the pressure decreases when the diameter of a pipe increases. When the mass flux increases, the pressure drop linearly does. Furthermore, when the pipe diameter decreases, the pressure drop has a quadratic increase.

• 유체기계공업학회:학술대회논문집
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• 2002.12a
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• pp.331-336
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• 2002

Recently the critical nozzles with small diameter are being extensively used to measure mass flow in a variety of industrial fields and these have different configurations depending on operation condition and working gas. The curvature radius of the critical nozzle throat is one of the most important configuration factors promising a high reliability of the critical nozzle. In the present study, computations using the axisymmetric, compressible, Navier-Stokes equations are carried out to investigate the effect of the nozzle curvature on critical flows. The diameter of the critical nozzle employed is D=0.3mm and the radius of curvature of the critical nozzle throat is varied in the range from 1D to 3D. It is found that the discharge coefficient is very sensitive to the curvature radius(R) of critical nozzle, leading to the peak discharge coefficient at R = 2.0D and 2.5D, and that the critical pressure ratio increases with the curvature radius.

• Journal of Hydrogen and New Energy
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• v.31 no.4
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• pp.363-371
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• 2020

Recently, the technologies to utilize the cold energy of liquefied natural gas (LNG) have attracted significant attention. In this paper, thermodynamic performance analysis of combined cycles consisting of ammonia Rankine cycle (AWR) and organic Rankine cycle (ORC) with LNG Rankine cycle to recover low-grade heat source and the cold energy of LNG. The mathematical models are developed and the effects of the important system parameters such as turbine inlet pressure, ammonia mass fraction, working fluid on the system performance are systematically investigated. The results show that the thermal efficiency of AWR-LNG cycle is higher but the total power production of ORC-LNG cycle is higher.