• Title/Summary/Keyword: Woody biomass

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A Devolatilization Model of Woody Biomass Particle in a Fluidized Bed Reactor (유동층 반응기에서의 목질계 바이오매스 입자의 탈휘발 예측 모델)

  • Kim, Kwang-Su;Leckner, Bo;Lee, Jeong-Woo;Lee, Uen-Do;Choi, Young-Tai
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.850-859
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    • 2012
  • Devolatilization is an important mechanism in the gasification and pyrolysis of woody biomass, and has to be accordingly considered in designing a gasifier. In order to describe the devolatilization process of wood particle, there have been proposed a number of empirical correlations based on experimental data. However, the correlations are limited to apply for various reaction conditions due to the complex nature of wood devolatilization. In this study, a simple model was developed for predicting the devolatilization of a wood particle in a fluidized bed reactor. The model considered the drying, shrinkage and heat generation of intra-particle for a spherical biomass. The influence of various parameters such as size, initial moisture content, heat transfer coefficient, kinetic model and temperature, was investigated. The devolatilization time linearly increased with increasing initial moisture content and size of a wood particle, whereas decreases with reaction temperature. There is no significant change of results when the external heat transfer coefficient is over 300 $W/m^2K$, and smaller particles are more sensitive to the outer heat transfer coefficient. Predicted results from the model show a similar tendency with the experimental data from literatures within a deviation of 10%.

Development of Vegetation Structure after Forest Fire in the East Coastal Region, Korea (동해안 산불 피해지에서 산불 후 경과 년 수에 따른 식생 구조의 발달)

  • 이규송;정연숙;김석철;신승숙;노찬호;박상덕
    • The Korean Journal of Ecology
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    • v.27 no.2
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    • pp.99-106
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    • 2004
  • We developed the estimation model for the vegetation developmental processes on the severely burned slope areas after forest fire in the east coastal region, Korea. And we calculated the vegetation indices as a useful parameter for the development of land management technique in the burned area and suggested the changes of the vegetation indices after forest fire. In order to estimate the woody standing biomass in the burned area, allometric equations of the 17 woody species regenerated by sprouter were investigated. According to the our results, twenty year after forest fire need for the development to the normal forest formed by 4 stratum structure, tree, sub-tree, shrub and herb layer. The height of top vegetation layer, basal area and standing biomass of woody species show a tendency to increase linearly, and the ground vegetation coverage and litter layer show a tendency to increase logarithmically after forest fire. Among vegetation indices, Ive and Ivcd show a tendency to increase logarithmically, and Hcl and Hcdl show a tendency to increase linearly after forest fire. The spatial variation of the most vegetation factors was observed in the developmental stages less than the first 5 years which were estimated secondary disaster by soil erosion after forest fire. Among vegetation indices, Ivc and Ivcd were the good indices for the representation of the spatial heterogeneity in the earlier developmental stages, and Hcl and Hcdl were the useful indices for the long-term estimation of the vegetation development after forest fire.

Heavy Metals of Landfilled Biomass and Their Environmental Standard, Including CCA-treated Wood for Eco-housing Materials (방부처리 목재를 포함한 토양매립 바이오메스의 중금속 함량과 안전성 문제)

  • Lim, Kie-Pyo;Lee, Jong-Tak;Bum, Jung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.37-45
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    • 2006
  • Recently, wood-framed houses has been built in the Korea for pension. Wood is good material for human healthy, while the construction lumbers are treated with preservative such as CCA (chromated copper arsenate), which contain some toxic elements for human body. However, if the waste woody biomass treated with various heavy metals, which has been collected from house construction or demolition, was fired in the field, and incinerated or landfilled after mass collection, such components will result in the toxic air pollutants in the burning or land fills, and spreaded into other areas. So the careful selection of wood and chemicals are required in advance for house construction, in particular, for environment-friendly housings. Therefore, this study was carried out to determine the content of toxic heavy metals in woody materials such as domestic hinoki and imported hemlock treated with CCA for housing materials, and the post-treated wood components such as organic fertilizer, sludge, dry-distilled charcoal and carbonized charcoal, to be returned finally into soil. The results are as follows. 1) The chemical analysis of toxic trace elements in various solid biomass required accurate control and management of laboratory environment, and reagents and water used, because of the error of data due to various foreign substances added in various processing and transporting steps. So a systematic analyzers was necessary to monitor the toxic pollutants of construction materials. 2) In particular, the biomass treated with industrial biological or thermal conditions such as sludge or charcoals was not fully dissolvable after third addition of $HNO_3$ and HF. 3) The natural woody materials such as organic fertilizer, sludge. and charcoals without any treatment of preservatives or heavy metal components were nontoxic in landfill because of the standard of organic fertilizers, even after thermal or biological treatments. 4) The CC A-treated wood for making the construction wood durable should not be landfilled, because of its higher contents of toxic metals than the criterion of organic fertilizer for agriculture or of natural environment. So the demolished waste should be treated separately from municipal wastes.

Woody Plant Species Composition, Population Structure and Carbon Sequestration Potential of the A. senegal (L.) Willd Woodland Along a Distance Gradient in North-Western Tigray, Ethiopia

  • Birhane, Emiru;Gebreslassie, Hafte;Giday, Kidane;Teweldebirhan, Sarah;Hadgu, Kiros Meles
    • Journal of Forest and Environmental Science
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    • v.36 no.2
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    • pp.91-112
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    • 2020
  • In Ethiopia, dry land vegetation including the fairly intact lowland and western escarpment woodlands occupy the largest vegetation resource of the country. These forests play a central role in environmental regulation and socio-economic assets, yet they received less scientific attention than the moist forests. This study evaluated the woody plant species composition, population structure and carbon sequestration potential of the A. senegal woodland across three distance gradients from the settlements. A total of 45 sample quadrants were laid along a systematically established nine parallel transect lines to collect vegetation and soil data across distance gradients from settlement. Mature tree dry biomass with DBH>2.5 cm was estimated using allometric equations. A total of 41 woody plant species that belong to 20 families were recorded and A. senegal was the dominant species with 56.4 IVI value. Woody plant species diversity, density and richness were significantly higher in the distant plots compared to the nearest plots to settlement (p<0.05). The cumulative DBH class distribution of all individuals had showed an interrupted inverted J-shape population pattern. There were 19 species without seedlings, 15 species without saplings and 14 species without both seedlings and saplings. A significant above ground carbon (5.3 to 12.7 ton ha-1), root carbon (1.6 to 3.6 ton ha-1), soil organic carbon (35.6 to 44.5 ton ha-1), total carbon stock (42.5 to 60.7 ton ha-1) and total carbon dioxide equivalent (157.7 to 222.8 ton ha-1) was observed consistently with an increasing of distance from settlement (p<0.05). Distance from settlement had significant and positive correlation with species diversity and carbon stock at 0.64⁎⁎ and 0.78⁎⁎. Disturbance intensity may directly influence the variation of species composition, richness and density along the A. senegal woodland. The sustainability of the A. senegal woodland needs urgent protection, conservation and restoration.

Development of Urethane Foams for Planting Media from Woodwastes (목질폐재를 이용한 식물식재용 우레탄폼의 개발)

  • Cho, Nam-Seok;Seo, Won-Sung;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.4
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    • pp.43-49
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    • 1998
  • The availability of large quantities of waste woods provides an impetus for investigating woody biomass potential uses. Polyurethane (PU) foams are prepared with reacting isocyanates and polyols, and are used. in various industry fields. Thus, lignocellulosic waste raw-materials are proposed as replacement for synthetic polyol to PU foam formulation. In this study PU foams were manufactured from liquefied woods, methanediisocyanate(MDI), catalyst, foaming stabilizer, and viscosity aids. The polyol content, isocyanate.hydroxyl group (NCO/OH) ratio, and water content were varied to evaluate their effects on the foaming and water absorption of the PU foams. Less than 400 Molecular weight. of polyethylene glycol(PEG) and 1 to 3 solvent to woody raw-material ratio were desirable for liquefying woody materials. Liquefying rate was increased with more than 3 % addition of inorganic and organic catalysts and raising reaction temperature more than $150^{\circ}C$. Addition of starch enhanced liquefying of woody materials. Fourty percents of starch resulted in about 90% liquefying rates. Foaming rates were increased with increasing moisture contents of liquefied wood. Moisture contents of 0.6% resulted in 5 time-foaming rates, and seven percents of moisture contents more than 30 time-foaming rates. But, an increase in water content may result in a decrease in cross-links between wood polyol and isocyanate, because the NCO/OH ratio is constant. Increasing moisture contents have significantly decreased density of PU foams. The optimum water content should be about 2.5% or less in this adopted condition.

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Experimental Study on Combustion of Boiler Fuel Made of Light-Oil and Bio-Oil (경유와 바이오오일 혼합연료의 연소에 대한 실험연구)

  • Yang, JeBok;Lee, InGu;Hwang, KyungRan
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.201-204
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    • 2012
  • Combustion characteristics of boiler fuels made of bio-oil and light-oil were experimentally investigated. Bio-oil was obtained by fast pyrolysis of woody biomass. Emulsion fuel made by mixing bio-oil (up to 30wt%) with light-oil and surfactant was completely burnt, resulting in the formation of combusted gas containing CO concentration less than 10ppm. Simple mixtures of bio-oil and light-oil with separate delivery lines also gave nice combustion characteristics.

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Gasification of woody biomass in a fluidized bed reactor (유동층 반응기에서 목질계 바이오매스의 가스화반응)

  • Kim, Seung-Soo;Kim, Jinsoo;Seo, Young-Hoon;Cho, Won-Jun;Baek, Young-Soon;Song, Taek-Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.102.1-102.1
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    • 2010
  • 바이오매스(Biomass)는 지구상에서 에너지원으로 이용될 수 있는 모든 식물과 미생물을 총칭하는 의미로 사용된다. 최근 바이오매스를 에너지자원화 시키는 방법으로 주목받는 열화학적 전환(Thermo-chemical conversion) 반응은 산소가 없이 혹은 희박한 조건에서 바이오매스에 열과 압력을 가하거나 공기나 수증기 등의 가스화제와 반응하여 바이오오일(Bio-oil) 및 합성가스(Syngas)로 변화하는 프로세스를 의미한다. 바이오매스로부터 바이오 DME(Di-Methyl Ether) 생산을 위한 합성가스를 제조하기 위해서 국내 산림자원을 대상으로 열분해반응 특성연구를 수행하였다. 또한 이들 물질로부터 바이오 DME 합성을 위해 최적의 합성가스 제조를 위한 타당성 연구를 수행하였다. 반응온도 $800{\sim}900^{\circ}C$에서 가스화 수율은 78~80%, 촤 수율은 17~20%, 타르 수율은 4~10%였고, 합성가스($H_2$/CO)비는 0.9~1.6였다.

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Biological Pretreatment of Softwood Pinus densiflora by Three White Rot Fungi

  • Lee, Jae-Won;Gwak, Ki-Seob;Park, Jun-Yeong;Park, Mi-Jin;Choi, Don-Ha;Kwon, Mi;Choi, In-Gyu
    • Journal of Microbiology
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    • v.45 no.6
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    • pp.485-491
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    • 2007
  • The effects of biological pretreatment on the Japanese red pine Pinus densiflora, was evaluated after exposure to three white rot fungi Ceriporia lacerata, Stereum hirsutum, and Polyporus brumalis. Change in chemical composition, structural modification, and their susceptibility to enzymatic saccharification in the degraded wood were analyzed. Of the three white rot fungi tested, S. hirsutum selectively degraded the lignin of this sortwood rather than the holocellulose component. After eight weeks of pretreatment with S. hirsutum, total weight loss was 10.7%, while lignin loss was the highest at 14.52% among the tested samples. However, holocellulose loss was lower at 7.81 % compared to those of C. lacerata and P. brumalis. Extracelluar enzymes from S. hirsutum showed higher activity of ligninase and lower activity of cellulase than those from other white rot fungi. Thus, total weight loss and changes in chemical composition of the Japanese red pine was well correlated with the enzyme activities related with lignin- and cellulose degradation in these fungi. Based on the data obtained from analysis of physical characterization of degraded wood by X-ray Diffractometry (XRD) and pore size distribution, S. hirsutum was considered as an effective potential fungus for biological pretreatment. In particular, the increase of available pore size of over 120 nm in pretreated wood powder with S. hirsutum made enzymes accessible for further enzymatic saccharification. When Japanese red pine chips treated with S. hirsutum were enzymatically saccharified using commercial enzymes (Cellulclast 1.5 L and Novozyme 188), sugar yield was greatly increased (21.01 %) compared to non-pre treated control samples, indicating that white rot fungus S. hirsutum provides an effective process in increasing sugar yield from woody biomass.

Developing Woody Crops for the Enhancement of Ecosystem Services under Changing Climates in the North Central United States

  • Zalesny, Ronald S. Jr.;Headlee, William L.
    • Journal of Forest and Environmental Science
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    • v.31 no.2
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    • pp.78-90
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    • 2015
  • Short rotation woody crops belonging to the genera Populus L., Salix L., Pinus L., and Eucalyptus L'Her. have provided broad economic and ecological benefits throughout the world, including afforestation and reforestation along urban to rural gradients. Within the genus Populus, cottonwoods, poplars, aspens, and their hybrids (hereafter referred to as poplars) have been shown to exhibit favorable genotype ${\times}$ environment interactions, especially in the face of changing climates. Similar growth responses have been reported for Pinus, especially with white pine (Pinus strobus L.) in the North Central United States. This has led to current research priorities focused on ecosystem services for both genera. The Millennium Ecosystem Assessment (2005) defines cultural, supporting, provisioning, and regulating ecosystem services. The overarching objective of this paper was to synthesize information about the potential of poplars to provide multiple ecosystem services when grown at sites with varying soil and climate conditions across landscape gradients from urban to rural areas. Specific objectives included: 1) providing background of the United States Forest Service and its Research and Development branch, 2) integrating knowledge of current poplar breeding and development with biomass provisioning and carbon regulating ecosystem services as they relate to changing climates in the North Central United States, and 3) providing a case study illustrating this integration through comparisons of poplar with white pine. Our results were evaluated in the context of climate change mitigation, with specific focus on selection of favorable genotypes for sequestering atmospheric carbon and reducing fossil fuel carbon emissions.