• 대한화학회지
• /
• 제57권5호
• /
• pp.540-546
• /
• 2013

van der Waals식의 자유부피항, 강체구형입자에 대한 Carnahan-Starling식, 용액의 논랜덤 혼합을 고려한 Wilson식, NRTL식과 본 연구자의 식등을 사용하여 기체에 대한 여러 개의 새로운 상태방정식을 만들었다. 이 식들을 이용하여 순수 기체에 대한 압축인자를 계산하였고 이를 실험적인 Nelson-Obert 압축인자도표와 비교하였다. 분자의 논랜덤 분포를 고려하여 유도된 상태방정식들이 랜덤분포를 가정한 상태방정식보다 더 좋은 결과가 나왔다. 이를 통하여 분자의 논랜덤 분포가 상태방정식에 상당한 영향을 미친다는 것을 알 수 있다.

• 한국안전학회지
• /
• 제32권6호
• /
• pp.34-39
• /
• 2017

Vapor-liquid equilibrium calculation is required to properly design and operation of distillation process. The general calculation method is to use binary interaction parameter. Lower flash points of cyclohexanol+aniline and cyclohexanol+cyclohexanone were measured by using Seta-flash closed cup apparatus. The measured flash points were compared with those calculated by the method based on Raoult's law and the optimization method using Wilson equation. The absolute average errors(A.A.E.) of the results calculated by Raout's law are $0.25^{\circ}C$ and $1.07^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. The absolute average errors of the results calculated by the optimization method are $0.22^{\circ}C$ and $0.65^{\circ}C$ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. As can be seen from A.A.E., the calculated values based on the optimization method were found to be better than those based on the Raoult's law. The binary interaction parameters calculated by the optimization method are used to predict the dew points of cyclohexanol+aniline and cyclohexanol+cyclohexanone. The A.A.E. for these mixtures show that there is an acceptable agreement between experimental and calculated dew poins.

• Structural Engineering and Mechanics
• /
• 제45권1호
• /
• pp.95-110
• /
• 2013

In the recent decade, practical of wavelet technique is being utilized in various domain of science. Particularly, engineers are interested to the wavelet solution method in the time series analysis. Fundamentally, seismic responses of structures against time history loading such as an earthquake, illustrates optimum capability of systems. In this paper, a procedure using particularly discrete Haar wavelet basis functions is introduced, to solve dynamic equation of motion. In the proposed approach, a straightforward formulation in a fluent manner is derived from the approximation of the displacements. For this purpose, Haar operational matrix is derived and applied in the dynamic analysis. It's free-scaled matrix converts differential equation of motion to the algebraic equations. It is shown that accuracy of dynamic responses relies on, access of load in the first step, before piecewise analysis added to the technique of equation solver in the last step for large scale of wavelet. To demonstrate the effectiveness of this scheme, improved formulations are extended to the linear and nonlinear structural dynamic analysis. The validity and effectiveness of the developed method is verified with three examples. The results were compared with those from the numerical methods such as Duhamel integration, Runge-Kutta and Wilson-${\theta}$ method.

• Korean Chemical Engineering Research
• /
• 제44권5호
• /
• pp.444-452
• /
• 2006

298.15 K 및 1 atm에서 2성분계 {1,2-dichloropropane+2-(2-methoxyethoxy)ethanol} 및 {1,2-dichloropropane+2-(2-ethoxyethoxy)ethanol}에 대한 과잉몰부피와 과잉몰엔탈피를 측정하였다. 과잉몰부피를 측정하기 위한 밀도는 vibrating glass-tube 방식의 densimeter를 이용하였고, 과잉몰엔탈피는 flow mixing 형의 isothermal microcalorimeter를 이용하였다. 측정한 과잉몰부피 및 과잉몰엔탈피는 조성과 상관지어 모두 S자형을 나타내었다. 초기 2-(2-alkoxyethoxy)ethanol 의 강한 자체 회합현상으로 음의 편차를 나타내며, 할로겐화탄화수소 분자의 증가에 따라 2-(2-alkoxyethoxy)ethanol 분자간의 수소결합을 끊기 위한 에너지가 상대적 더 많이 필요함을 보여주고 있다. 실험으로부터 얻어진 $V^E_m$ 및 $H^E_m$ data는 Nelder-Mead의 simplex pattern search method를 이용하여 Redlich-Kister 다항식에 접합(fitting)하였고, Wilson, NRTL 및 UNIQUAC model을 이용하여 $V^E_m$ data와 조성과의 상관관계를 조사하였다.

• 대한간호학회지
• /
• 제48권1호
• /
• pp.96-108
• /
• 2018

Purpose: This study aimed to construct and test a hypothetical model of the quality of life of school-age children with asthma based on the health-related quality of life model by Wilson and Cleary. Methods: Data were collected from 205 pairs of pediatric outpatients diagnosed with asthma and their parents in Seoul and Gyeonggi-do from July 2016 to April 2017. The exogenous variables were asthma knowledge, number of accompanying allergic diseases, and social support. The endogenous variables were asthma self-efficacy, asthma symptom control, perceived health status, parental quality of life, and children's quality of life. For data analysis, descriptive statistics, factor analysis, and structural equation modeling were performed. Results: Eighteen of the twenty-four hypotheses selected for the hypothetical model were attentive and supported statistically. Quality of life was explained by asthma self-efficacy, asthma symptom control, perceived health, parental quality of life, and asthma knowledge with 83.5%. Conclusion: Strategies for promoting self-efficacy and enforcing asthma knowledge will be helpful for the improvement of health-related quality of life with school-aged asthmatic children.

• 대한토목학회논문집
• /
• 제5권3호
• /
• pp.39-47
• /
• 1985

본문(本文)은 연약점토지반(軟弱粘土地盤)에 이차원성토(二次元盛土)를 할 경우 지반(地盤)의 심하(沈下) 및 변위(變位)를 FEM으로 해석(解析)하는 프로그램의 연구에 대한 결과를 보고한 것이다. 구성방정식(構成方程式)으로서는 Cam-clay, Modified Cam-clay, 탄점소성(彈粘塑性)의 3 모델에서 각각 취하여 Biot의 압밀방정식(壓密方程式)과 결합(結合)시켜 이들간의 정도(精度)를 비교(比較)하고 또한 1982년(年) Magnan 등에 의해 불(佛)의 Cubzac-les-ponts에서 시험성토(試驗盛土)를 실시(實施)하여 실측(實測)과 해석결과(解析結果)를 발표(發表)한 바 있는데 그 결과(結果)와 비교(比較)한 것이다. 그 결과(結果)는 본(本) 프로그램이 보다 더 실측치(實測値)에 가깝다는 것이 확인되고 간극수압(間隙水壓)의 처리(處理)는 Christian-Boehmer 계(系)의 FEM 해석(解析)이 그들이 사용(使用)한 Sandhu-Wilson 계(系)보다 더 실제에 가깝고 성토부(盛土部)를 유한요소화(有限要素化)하는 것이 더 정확하다고 판단된다.

• Ocean Systems Engineering
• /
• 제11권1호
• /
• pp.17-42
• /
• 2021

Articulated loading platforms (ALPs) belongs to a class of offshore structures known as compliant. ALP motions have time periods falling in the wind excitation frequency range due to their compliant behaviour. This paper deals with the dynamic behavior of a double hinged ALP subjected to low-frequency wind forces with random waves. Nonlinear effects due to variable submergence, fluctuating buoyancy, variable added mass, and hydrodynamic forces are considered in the analysis. The random sea state is characterized by the Pierson-Moskowitz (P-M) spectrum. The wave forces on the submerged elements of the platform's shaft are calculated using Morison's Equation with Airy's linear wave theory ignoring diffraction effects. The fluctuating wind load has been estimated using Ochi and Shin wind velocity spectrum for offshore structures. The nonlinear dynamic equation of motion is solved in the time domain by the Wilson-θ method. The wind-structure interactions, along with the effect of various other parameters on the platform response, are investigated. The effect of offset of aerodynamic center (A.C.) with the center of gravity (C.G.) of platform superstructure has also been investigated. The outcome of the analyses indicates that low-frequency wind forces affect the response of ALP to a large extent, which otherwise is not enhanced in the presence of only waves. The mean wind modifies the mean position of the platform surge response to the positive side, causing an offset. Various power spectral densities (PSDs) under high and moderate sea states show that apart from the significant peak occurring at the two natural frequencies, other prominent peaks also appear at very low frequencies showing the influence of wind on the response.

• 대한간호학회지
• /
• 제44권1호
• /
• pp.75-85
• /
• 2014

Purpose: The aim of this study was to explore how individual factors, physiologic factors, symptoms, environmental factors, functional status and health perception predict the quality of life (QOL) for older adults with osteoarthritis and to provide guidelines for interventions and strategies to improve QOL in these patients. The conceptual model was based on the Wilson and Cleary's Model. Methods: Data were analyzed using SPSS WIN 20.0 and AMOS 19.0 program. Results: The proposed model was a good fit for the data based on the model fit indices. Based on the constructed model, individual factors, social support, functional status and health perception were founded to have direct effects on QOL. Symptom had a indirect effect on QOL. Social support had a significant effect on QOL, and this model explained 63.6% of the variance in QOL. Conclusion: The results of this study suggest that nursing strategies to increase QOL in this population should contain social support to promote QOL and manage functional limitations and health perception.

• 대한간호학회지
• /
• 제45권6호
• /
• pp.879-889
• /
• 2015

Purpose: The purpose of this study was to construct and test a structural equation model of quality of work life for clinical nurses based on Peterson and Wilson's Culture-Work-Health model (CWHM). Methods: A structured questionnaire was completed by 523 clinical nurses to analyze the relationships between concepts of CWHM-organizational culture, social support, employee health, organizational health, and quality of work life. Among these conceptual variables of CWHM, employee health was measured by perceived health status, and organizational health was measured by presenteeism. SPSS21.0 and AMOS 21.0 programs were used to analyze the efficiency of the hypothesized model and calculate the direct and indirect effects of factors affecting quality of work life among clinical nurses. Results: The goodness-of-fit statistics of the final modified hypothetical model are as follows: ${\chi}^2=586.03$, ${\chi}^2/df=4.19$, GFI=.89, AGFI=.85, CFI=.91, TLI=.90, NFI=.89, and RMSEA=.08. The results revealed that organizational culture, social support, organizational health, and employee health accounted for 69% of clinical nurses' quality of work life. Conclusion: The major findings of this study indicate that it is essential to create a positive organizational culture and provide adequate organizational support to maintain a balance between the health of clinical nurses and the organization. Further repeated and expanded studies are needed to explore the multidimensional aspects of clinical nurses' quality of work life in Korea, including various factors, such as work environment, work stress, and burnout.

• 대한간호학회지
• /
• 제50권4호
• /
• pp.554-570
• /
• 2020

Purpose: This study aimed to develop and test a structural equation model of health-related quality of life among older women following bilateral total knee replacement based on a literature review and Wilson and Cleary's model of health-related quality of life. Methods: One hundred ninety three women who were diagnosed with osteoarthritis, were older than 65 years, and were between 13 weeks and 12 months of having a bilateral total knee replacement were recruited from an outpatient clinic. Data were collected from July 2017 to April 2018 using a structured questionnaire and medical records. Data were analyzed using SPSS/WIN 22.0, AMOS 22.0, and Smart PLS 3.2.4. Results: The fitness of the hypothetical model was good, with coefficients of determination (R²) ranging between .28 and .75 and predictive relevance (Q²) between .26 and .73. The standardized root mean square residual of the model fit indices for the hypothetical model was .04; which explained 64.2% of physical and 62.5% of mental health-related quality of life. Self-efficacy, symptom status, functional status, and general health perceptions had a significant direct effect on physical health-related quality of life, while social support, symptom status, and general health perceptions had a significant direct effect on participants' mental-health-related quality of life. Conclusion: To improve the physical and mental quality of life of older women who receive bilateral knee replacement, nursing-based intervention strategies that reduce symptoms, improve functional status, and increase health perceptions, self-efficacy, and social support are needed. The most important factor is the symptom status.