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Synthesis And Ionic Conductivity of Siloxane Based Polymer Electrolytes with Propyl Butyrate Pendant Groups

  • Jalagonia, Natia;Tatrishvili, Tamara;Markarashvili, Eliza;Aneli, Jimsher;Grazulevicius, Jouzas Vidas;Mukbaniani, Omar
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.36-43
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    • 2016
  • Hydrosilylation reactions of 2.4.6.8-tetrahydro-2.4.6.8-tetramethylcyclotetrasiloxane with allyl butyrate catalyzed by Karstedt's, $H_2PtCl_6$ and Pt/C catalyst were studied and 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane was obtained. The reaction order, activation energies and rate constants were determined. Ringopening polymerization of 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane in the presence of $CaF_2$, LiF, KF and anhydrous potassium hydroxide in $60-70^{\circ}C$ temperature range was carried out and methylsiloxane oligomers with regular arrangement of propyl butyrate pendant groups were obtained. The synthesized products were studied by FTIR and NMR spectroscopy. The polysiloxanes were characterized by wide-angle X-ray, gel-permeation chromatography and DSC analyses. Via sol-gel processes of oligomers doped with lithium trifluoromethylsulfonate or lithium bis (trifluoromethylsulfonyl)imide, solid polymer electrolyte membranes were obtained. The dependences of ionic conductivity of obtained polyelectrolytes on temperature and salt concentration were investigated, and it was shown that electric conductivity of the polymer electrolyte membranes at room temperature changed in the range $3.5{\times}10^{-4}{\sim}6.4{\times}10^{-7}S/cm$.

Realtime Vehicle Tracking and Region Detection in Indoor Parking Lot for Intelligent Parking Control (지능형 주차 관제를 위한 실내주차장에서 실시간 차량 추적 및 영역 검출)

  • Yeon, Seungho;Kim, Jaemin
    • Journal of Korea Multimedia Society
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    • v.19 no.2
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    • pp.418-427
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    • 2016
  • A smart parking management requires to track a vehicle in a indoor parking lot and to detect the place where the vehicle is parked. An advanced parking system watches all space of the parking lot with CCTV cameras. We can use these cameras for vehicles tracking and detection. In order to cover a wide area with a camera, a fisheye lens is used. In this case the shape and size of an moving vehicle vary much with distance and angle to the camera. This makes vehicle detection and tracking difficult. In addition to the fisheye lens, the vehicle headlights also makes vehicle detection and tracking difficult. This paper describes a method of realtime vehicle detection and tracking robust to the harsh situation described above. In each image frame, we update the region of a vehicle and estimate the vehicle movement. First we approximate the shape of a car with a quadrangle and estimate the four sides of the car using multiple histograms of oriented gradient. Second we create a template by applying a distance transform to the car region and estimate the motion of the car with a template matching method.

Effect of Guide Nozzle Shape on the Performance Improvement of a Very Low Head Cross Flow Turbine

  • Chen, Zhenmu;Singh, Patrick Mark;Choi, Young-Do
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.5
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    • pp.19-26
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    • 2014
  • The cross flow turbine attracts more and more attention for its relatively wide operating range and simple structure. In this study, a novel type of micro cross flow turbine is developed for application to a step in an irrigational channel. The head of the turbine is only H=4.3m and the turbine inlet channel is open ducted type, which has barely been studied. The efficiency of the turbine with inlet open duct channel is relatively low. Therefore, a guide nozzle on the turbine inlet is attached to improve the performance of the turbine. The guide nozzle shapes are investigated to find the best shape for the turbine. The guide nozzle plays an important role on directing flow at the runner entry, and it also decreases the negative torque loss by reducing the pressure difference in Region 1. There is 12.5% of efficiency improvement by attaching a well shaped guide nozzle on the turbine inlet.

Performance Evaluation and Design of Zoom Lens Systems (Zoom Lens계의 성능 평가 및 설계)

  • Ji, Taek Sang
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.2
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    • pp.113-121
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    • 2002
  • Nowadays, developed camera, camcorder, CCTV and copier system accept a wide angle and a telephoto lens, and have an excellent capacity. Also, it is small as using aspheric surface. In this paper, after we evaluate and analyze two-group zoom lens system and three-group zoom lens system for camera, we refer to it, and design three-group zoom lens system for camera. Therefore, when we design a zoom lens system for camera, we use a symmetrical system. As using an aspheric surface, we can try to a miniaturization and an efficient improvement. We use optical valuable measure methods, a ray intercept plot, MTF and Seidel coefficient. So, we can confirm to have a similar level to compare with reference model.

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Development of Eco-friendly Woven Floor Mat with High Resilience II - Characterization of TPU Coating Yarn and Floor Mat - (고탄성 특성을 보유한 친환경 우븐 바닥재에 관한 연구(II) - TPU 코팅사 및 바닥재의 특성-)

  • Lee, Sun-Hee
    • Fashion & Textile Research Journal
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    • v.14 no.4
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    • pp.635-640
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    • 2012
  • In this study, thermoplastic urethane (TPU) coating yarns were prepared at various extruding temperatures. The fine structure and mechanical properties of resultant TPU coating yarns examined by the wide angle X-ray diffractometer (WAXD), differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), and tensile test. TPU coating yarns (prepared at extruding temperatures at $175^{\circ}C$) were confirmed as a stable fine structure that obtained excellent tensile strength and flexibility. The C samples prepared by optimized conditions made by TPU woven floor mat. The structure of the woven mat is $4{\times}4$ basket weave and have laminated with the EVA foam to obtained final TPU woven floor mat products. The resultant TPU woven floor mat was obtained to 1.5MN of tensile strength, 22% of the elongation, and 0.2MN of tear strength. The weight loss abrasion and the resilience by the ball rebound of the TPU-woven floor mat was prior to those of the PVC subsequently, we were able to develop a woven floor mat with TPU coating yarn and produce an eco-friendly high valuable woven floor mat using an interior product.

Directivity Characteristics of Non-Linear Array for Wide-Band One-Shot Beamforming (광대역 단일빔형성을 위한 비선형배열의 지향 특성)

  • 도경철;손경식
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.3
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    • pp.27-34
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    • 1999
  • This paper proposes an algorithm to design the non-linear array so as to form efficiently the one-shot beam with relatively less sensors for acoustic measurement. In this algorithm, according to the spatial sampling theory the part for high frequency(HF) band has equispaced sensor array and the sensor distances below the HF band are decided as a function of number of HF sensors. As the results of the simulations, the mean and variances of directivity index(DI) of non-linear array which has less sensors are similar to those of linear array. and the DI variation for beam steering angle is very small. And the beam width at -2dB point is 6.8°. Thus it is confirmed that the design algorithm for non-linear array which is proposed to have less sensors can be efficiently used in acoustic measurement.

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Broadband metamaterial absorber using resistive layers

  • Kim, Y.J.;Yoo, Y.J.;Hwang, J.S.;Son, H.M.;Rhee, J.Y.;Kim, K.W.;Lee, Y. P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.359.1-359.1
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    • 2016
  • The electromagnetic (EM) properties of media, such as propagation, focusing and scattering, strongly rely on the electric permittivity and the magnetic permeability of media. Recently, artificially-created metamaterials (MMs) composed of periodically-arranged unit cells with tailored electric permittivity and magnetic permeability have drawn wide interest due to their capability of adjusting the EM response. MM absorbers using the conventional sandwich structures usually have very high absorption at a certain frequency, and the absorption properties of MMs can be adjusted simply by changing the geometrical parameters of unit cell. In this work, we suggested an incident-angle-independent broadband perfect absorber based on resistive layers. We analyze the absorption mechanism based on the impedance matching with the free space and the distribution of surface currents at specific frequencies. From the simulation, the absorption was expected to be higher than 96% in 1.4-6.0 GHz. The corresponding experimental absorption was found to be higher than 96% in 1.4-4.0 GHz, and the absorption turned out to be slightly lower than 96% in 4.0-6.0 GHz owing to the irregularity in the thickness of resistive layers.

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A Novel Transflective-type LTPS-LCD with Cap-Divided VA-Mode

  • Kang, Seung-Gon;Kim, Seong-Ho;Song, Seock-Cheon;Park, Won-Sang;Yi, Chung;Kim, Chi-Woo;Chung, Kyu-Ha
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.831-833
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    • 2004
  • A novel transflective-type LC mode with good display performance has been developed In order to drive both transmissive and reflective modes simultaneously without any modulation of gamma in a single-gap structure, we have introduced a new design concept in the reflective region, where the capacitance is separated into liquid crystal($C_{LC}$} and organic layer($C_{OL}$), playing a key role as a voltage divider in our cap-divided VA-mode. With this cap-divided method having both merits of simplifying process and good legibility, we have achieved good optical characteristics such as high contrast ratio and wide viewing angle in a single-gap homeotropic panel design.

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Development of OCB mode with impulsive driving scheme for improving moving picture quality

  • Kim, J.L.;Lee, C.H.;Park, S.Y.;Yoo, S.W.;Oh, J.H.;Lee, S.H.;Chai, C.C.;Park, C.W.;Ban, B.S.;Ahn, S.H.;Hong, M.P.;Chung, K.H.;Lim, S.K.;Kim, K.H.;Souk, J.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1049-1052
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    • 2004
  • In general, contrary to the CRTs with impulsive emission, liquid crystal displays have motion artifacts such as blurring. ghost image, decrease of dynamic CR(contrast ratio), and stroboscopic motion due to hold type driving method. In this paper, to improve motion picture quality of LCDs. impulsive driving method of black data insertion was applied to the OCB mode which is well known for its fast LC response time and wide viewing angle properties. Subject evaluation was carried out with CRT, TN, SIPS(Super IPS). and impulsive driving OCB. Moving picture image quality near CRT was obtained in impulsive OCB driving mode

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Templated Formation of Silver Nanoparticles Using Amphiphilic Poly(epichlorohydrine-g-styrene) Film

  • Park, Jung-Tae;Koh, Joo-Hwan;Seo, Jin-Ah;Roh, Dong-Kyu;Kim, Jong-Hak
    • Macromolecular Research
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    • v.17 no.5
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    • pp.301-306
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    • 2009
  • This work has demonstrated that a novel amphiphilic poly(epichlorohydrine)-graft-polystyrene (PECH-g-PS) copolymer at 34:66 wt% was synthesized via atom transfer radical polymerization (ATRP) of styrene using PECH as a macroinitiator. The structure of the graft copolymer was characterized by nuclear magnetic resonance ($^1H$ NMR) and FTIR spectroscopy, demonstrating that the "grafting from" method using ATRP was successful. The self-assembled graft copolymer was used as a template film for the in-situ growth of silver nanoparticles from $AgCF_3SO_3$ precursor under UV irradiation. The in situ formation of silver nanoparticles with 6-8 nm in average size in the solid state template film was confirmed by transmission electron microscopy (TEM), UV-visible spectroscopy and wide angle X-ray scattering (WAXS). Differential scanning calorimetry (DSC) also displayed the selective incorporation and the in situ formation of silver nanoparticles within the hydrophilic PECH domains, probably due to stronger interaction of the silvers with the ether oxygens of PECH backbone than that with hydrophobic PS side chains.