• Title/Summary/Keyword: Wetting state

검색결과 59건 처리시간 0.026초

아르곤 저온 플라즈마 처리에 의한 CTA 필름의 접착성 연구 (A Study on Adhesive Properties of Cellulose Triacetate Film by Argon Low Temperature Plasma Treatment)

  • 구강;박영미
    • 한국염색가공학회지
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    • 제16권5호
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    • pp.28-34
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    • 2004
  • The polarizing film application exploits the unique physicochemical properties between PVA(Poly vinyl alcohol) film and CTA(Cellulose triacetate) film. However, hardly any research was aimed at improving the adhesion characteristics of the CTA film by radio frequency(RF) plasma treatment at argon(Ar) gaseous state. In this report, we deal with surface treatment technology for protective CTA film developed specifically for high adhesion applications. After Ar plasma, surface of the films is analyzed by atomic force microscopy(AFM), roughness parameter and peel strength. Furthermore, the wetting properties of the CTA film were studied by contact angle analysis. Results obtained for CTA films treated with a glow discharge showed that this technique is sensitive to newly created physical functions. The roughness and peel strength value increased with an increase in treatment time for initial treatment, but showed decreasing trend for continuous treatment time. The result of contact angle measurement refer that the hydrophilicity of surface was increased. AFM studies indicated that no considerable change of surface morphology occurred up to 3 minutes of treatment time, but a considerable uneven of surface structure resulted from treating time after 5 minutes.

Life Prediction of Hydraulic Concrete Based on Grey Residual Markov Model

  • Gong, Li;Gong, Xuelei;Liang, Ying;Zhang, Bingzong;Yang, Yiqun
    • Journal of Information Processing Systems
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    • 제18권4호
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    • pp.457-469
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    • 2022
  • Hydraulic concrete buildings in the northwest of China are often subject to the combined effects of low-temperature frost damage, during drying and wetting cycles, and salt erosion, so the study of concrete deterioration prediction is of major importance. The prediction model of the relative dynamic elastic modulus (RDEM) of four different kinds of modified concrete under the special environment in the northwest of China was established using Grey residual Markov theory. Based on the available test data, modified values of the dynamic elastic modulus were obtained based on the Grey GM(1,1) model and the residual GM(1,1) model, combined with the Markov sign correction, and the dynamic elastic modulus of concrete was predicted. The computational analysis showed that the maximum relative error of the corrected dynamic elastic modulus was significantly reduced, from 1.599% to 0.270% for the BS2 group. The analysis error showed that the model was more adjusted to the concrete mixed with fly ash and mineral powder, and its calculation error was significantly lower than that of the rest of the groups. The analysis of the data for each group proved that the model could predict the loss of dynamic elastic modulus of the deterioration of the concrete effectively, as well as the number of cycles when the concrete reached the damaged state.

저장 감즙을 이용한 직물의 염색 연구 (A Study on Dyeing of Fabrics Using the Preserved Parsimon Juice)

  • 정영옥;이순자;전병관
    • 한국농촌생활과학회지
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    • 제8권2호
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    • pp.73-81
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    • 1997
  • Parsimon juice dyeing is the one of the most popular natural dyeing methods which have been done traditionally among the farmers. The clothes dyed with parsimon juice has several merits, that is, it become much more durable, cool, easy to wash and wear after dyeing and these merits are the reason why people likes to wear the parsimon juice dyeing clothes as work wear. Especially in Cheju province, parsimon juice clothes became a folk costume and many people still enjoy wearing it in the hot summer days. But one of the demerits of parsimon dyeing is that the possible period of dyeing is very short. So, if parsimon juice dyeing could be done with the preserved parsimon juice, it would be possible to enlength the period. With this idea, we compared the color and colorfastness of fabrics which were dyed with 4 kinds of parsimon juice. The experimental parsimon juice 96-8 was preserved during 13 months, 96-9 was 12 months, 97-8 was 1 month and 97-9 was not preserved one. The experimental fabrics were cotton, silk. nylon and polyester fabrics. The results were as follows ; 1. The colors of fabrics dyed with experimental parsimon juice 96-9, 97-8, 97-9 were yellow-red and dyeing states were good. But the colors of fabrics dyed with 96-8 were dark and the state were bad, because the color of experimental parsimon juice 96-8 was changed during preservation. 2. The best state of dyeing could see in the fabrics dyed with experimental parsimon juice 97-8, although that was preserved 1 month. 3. There were differences of color between experimental fabrics dyed with same juice and the colors were thicker in cotton and silk than in nylon and polyester fabrics. 4. During wetting and drying process, the color changes in fabrics dyed with no preserved one were more than in fabrics dyed with preserved ones. 5. The color fastness to the light of the dyed fabrics was over 4, to the acidic perspiration was 3~4 or 4~5, to the alkaline perspiration was 2, 3 or 3~4 and to the washing was 1~2. There was no significant difference in colorfastness between the 96-9 dyed fabrics and 97-9 dyed fabrics.

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VISUALIZATION AND MEASUREMENT OF A NARROW-CONE DI GASOLINE SPRAY FOR THE IMPINGEMENT ANALYSIS

  • Park, J.S.;Im, K.S.;Kim, H.S.;Lai, M.C.
    • International Journal of Automotive Technology
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    • 제5권4호
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    • pp.221-238
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    • 2004
  • Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.

용매 처리에 의한 EVA foam 표면 특성에 관한 연구 (Studies on the Characteristics of EVA Foam by Solvent Treatment)

  • 천제환;김구니;홍순영;유종선;오상택
    • 접착 및 계면
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    • 제2권3호
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    • pp.9-15
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    • 2001
  • 표면 에너지가 낮아 접착이 어려운 EVA foam을 용해도 파라미터와 표면장력이 다른 용매로 표면처리하여 표면의 상태 변화를 SEM, 접촉각 측정 등으로 조사하였으며 표면의 변화가 접착력에 미치는 영향을 고찰하였다. Zismann plot에 의해 계산된 EVA foam의 임계표면장력 (${\gamma}_{c,0}$)은 27.08 dyne/cm이었다. 용매 처리에 의해 EVA foam 표면의 형태 및 임계포면장력이 변화하였으며 EVA foam의 팽윤도가 용해도 파라미터에 의해 영향을 받는 것에 비해 표면의 변화 정도는 용매의 표면장력에 더 크게 의존하였다. 표면의 변화는 용매의 표면장력 (${\gamma}_L$)이 EVA foam의 임계표면장력 보다 낮아 wetting이 잘될수록 커지는 것으로 나타났다. 용매 처리된 EVA foam을 접착한 결과 처리하지 않은 것에 비해 접착력이 600% 이상 크게 향상되었으며, ${\gamma}_c$가 프라이머의 ${\gamma}_{L,p}$에 근접하여 ${\gamma}_c/{\gamma}_{L,p}$가 1에 가까워질수록 접착력이 증가하였다.

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Hot water oxidation 공정을 이용한 고품위 실리콘 기판 제작 (Fabrication of high-quality silicon wafers by hot water oxidation)

  • 박효민;탁성주;강민구;박성은;김동환
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.89-89
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    • 2009
  • 높은 소수반송자 수명(life-time)을 가지는 고품위 실리콘 기판은 고효율 실리콘 이종접합 태양전지 제작을 위한 중요 요소 기술 중 하나이다. 본 연구에서는 n-type c-Si 기판을 이용한 고효율 실리콘 이종접합 태양전지제작을 위해 hot water oxidation(HWO) 공정을 이용하여 고품위 실리콘 기판을 제작하였다. 실리콘 기판의 특성 분석은 Qusi-steady state photoconductance (QSSPC)를 이용하여 소수반송자 수명을 측정하였으며, 기판의 면저항 및 wetting angle을 측정하여 공정에 따른 특성변화를 분석하였다. Saw damage etching 된 기판을 웨이퍼 표면으로부터 particle, 금속 불순물, 유기물 등의 오염을 제거하기 위해 $60{\sim}85^{\circ}C$로 가열된 Ammonia수, 과산화수소수($NH_4OH/H_2O_2/H_2O$), 염산 과산화수소수($HCL/H_2O_2/H_2O$) 및 실온 희석불산(DHF) 중에 기판을 각각 10분 정도씩 침적하여, 각각의 약액 처리 후에 매회 10분 정도씩 순수(DI water)에서 rinse하여 RCA 세정을 진행한 후 HWO 공정을 통해 기판 표면에 얇은 산화막 을 형성시켜 패시베이션 해주었다. HF를 이용하여 자연산화막을 제거시 HWO 공정을 거친 기판은 매끄러운 표면과 패시베이션 영향으로 기판의 소수 반송자 수명이 증가하며, 태양전지 제작시 접촉저항을 감소시켜 효율을 증가 시킬수 있다. HWO 공정은 반응조 안의 DI water 온도와 반응 시간에 따라 life-time을 측정하여 진행하였으며, 이후 PE-CVD법으로 증착된 a-Si:H layer 및 투명전도 산화막, 금속전극을 증착하여 실리콘 이종접합 태양전지를 제작하였다.

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오프셋인쇄 축임물의 전도도가 인쇄적성에 미치는 영향에 관한 연구 (A Study on The Effect of Dampening Conductivity in the Offset Printing Printability)

  • 박찬우;이재수
    • 한국인쇄학회지
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    • 제25권1호
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    • pp.43-52
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    • 2007
  • Offset printing is one of the well known printing technique of lithographic process and consists of image area and 'non-image area on a flat image carrier. The surface tension of dampening water can be controlled by adding IPA after mixing of raw water and etching solution. The etching solution contains a surfactant for reducing surface energy, a clean agent for non-imaging area, wetting agent for protecting non-imaging area from oil components like ink and also an emulsifying agent for controlling emulsification. In this study, the present situation of dampening water maintenance has examined by collecting dampening water using at domestic companies. The pH related to dampening water, conductivity, contact angle, emulsification curve are measured to define the current situation of dampening water control of each companies and to analyze the relationship among measured properties. In the study most of companies among 16 printing companies tested controlling dampening water through pH value. However, the quality of printing has varied depending upon conductivity, contact angle, IPA content, and emulsification value. The control of dampening water should be carry at the state of the standard when adding proper ratio of etching solution. It would be more effective when pH or conductivity control carries out in parallel with controlling dampening water. Therefore the concept that pH5.5 is correct is based concept. Based on these initial tests it is defined that the standardization of dampening water control is required.

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불포화 함수특성의 경로의존성을 고려한 현장사면 수리거동 예측 (Predicted Hydraulic Behavior in In-Situ Soil Slope Using the Path-Dependent Soil Water Characteristic Curve)

  • 박현수;송영석;박성완
    • 한국지반공학회논문집
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    • 제33권4호
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    • pp.25-34
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    • 2017
  • 불포화상태 지반의 흡수력과 응력변화를 반영한 토사사면의 전체 안정성 평가에서 매우 중요한 상태평가 입력변수로 함수특성곡선이 활용되고 있다. 함수특성의 경로의존성은 일반적으로 건조와 습윤과정으로 이력현상을 내포하는데 현장계측결과는 주로 실내실험의 습윤과정에 가깝게 나타난다. 본 연구에서는 이를 비정상류 해석에 적용하여 해석과 현장 계측된 결과들을 비교 검토하였다. 또한 심도가 증가할수록 강우의 영향이 작고 습윤과정을 적용해 산정된 값에 근접하였다. 따라서 불포화 토사사면 해석 시에 경로의존 함수특성곡선을 적용하여 안정성을 판단하는 것이 보다 합리적인 결과로 판단된다.

보리의 Aspergillus parasiticus 감수성(感受性) (Susceptibility to Infection by Aspergillus parasiticus in Barley)

  • 장학길;P. 마카키스;김창식
    • 한국균학회지
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    • 제10권2호
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    • pp.89-92
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    • 1982
  • 보리품종별(品種別) aflatoxin오염(汚染)과 aflatoxin생성균(生成菌)의 감수성(感受性)을 조사(調査)하였다. 공시(供試)된 모든 시료(試料)에시는 aflatoxin이 검출(檢出)되지 않았으나 25%로 가수처리(加水處理)된 보리를 2주간(週間) $25^{\circ}C$에서 100% RH 상태하(狀態下)에서 저장(貯藏)하였을때 2개품종(個品種)을 제외(除外)하고는 aflatoxin $B_1$$G_1$이 미량검출(微量檢出)되었으며$B_2$$G_2$는 검출(檢出)되지 않았다. Aspergillus parasiticus에 의(依)한 aflatoxin 생성(生成)에 대(對)한 보리의 감염(感染) 감수성(感受性)은 대단히 컸으며, 겉보리가 쌀보리보다 aflatoxin의 생성(生成) 및 축적(蓄積)이 더욱 높았다.

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치과용 지르코니아 이장재 처리에 따른 지르코니아와 도재의 전단결합강도 비교 (Shear bond strength of a layered zirconia and porcelain according to treatment of zirconia liner)

  • 서정일;박원욱;김양근
    • 대한치과기공학회지
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    • 제39권1호
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    • pp.43-52
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    • 2017
  • Purpose: Physical and chemical properties of gold is most suitable to be restored of teeth to its original state. Recently zirconia was used instead of gold because of esthetical and intimacy of human body. Because of high strength and high abrasion resistance of zirconia, all zirconia artificial tooth lead to wear the original tooth of opposite site. To preserve this original tooth, zirconia artificial tooth covered with dental ceramic glass was used. When joining the zirconia core and dental ceramic glass, difference of their thermal expansion coefficient and wetting ability is generated the residual stress at interface lead to crack. In order to solve this problem, intermediate layer what is called zir-liner was imported to decrease the residual stress and increase the bonding strength. Methods: In this study, to identify the optimum conditions for manufacturing process, various methods to rough the surface of zirconia core were adopted, and vary the thickness of interlayer, and analyzed bond strength. Results: Bond strength of sanding specimens group showed higher than that of non-sanding specimens group, and once applied intermediate layer with sanding specimens showed highest bond strength with 28 MPa. SEM photomicrographs of zirconia cores fired at $1500^{\circ}C$ showed parallel straight lines in sanding and pockmarked surface in blasting surfaces as abrasion traces. Observation of the destruction section after shear test by SEM were carried out. Liner applied non-sanding group and non-liner applied sanding group all showed interfacial crack. Sandblasting group with non-liner showed remained dental ceramic glass on the surface of zirconia. Sandblasting group with once applied liner showed partially remained liner and dental ceramic glass on the surface of zirconia. XRD analysis revealed that sandblasting group showed higher monoclinic peaks than other specimens group and this result was due to the high collision energy for stress induced phase transformation. Conclusions: A study on the improvement of bonding strength between zirconia and dental ceramic glass steadily carried out for the future to practical use.