• Title/Summary/Keyword: Wet-strength resin

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A Study on the Durable Press Finish by Wet-Fixation Processes for Rayon Fabrics (I) - One Bath and Two Bath Processes - (레이온 직물의 Wet-Fixation에 의한 DP가공에 관한 연구(I) - 일욕법과 이욕법의 비교 -)

  • Hu Yoon Sook;Kim Eun Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.3 s.31
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    • pp.242-251
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    • 1989
  • The purpose of this study was to investigate the changes in easy-care and strength properties of the wet fixation processed viscose rayon fabrics. Rayon fabrics were treated with mixed resins of melamine formaldehyde (MF) and DMDHEU by one bath and two bath wet fixation processes. The MF/DMDHEU mixed resin concentrations were 50/100, 50/150, 100/100, 100/150 and 150/100(g/1). Magnasium chloride was used as a catalyst. Treated fabrics were evaluated by nitrogen content, DP rating, wrinkle recovery angle, breaking strength, tearing strength and abrasion resistance. The properties were compared to the fabrics treated by conventional Pad-Dry-Cure (PDC) method. Wet fixation processed fabrics showed DP ratings of higher than 3 and higher than 275 degrees of wrinkle recovery angles in all the mixed resin concentrations. Wet fixation processed fabrics showed increase in breaking strength and tearing strength but decrease in abrasion resistance. However, the decrease in abrasion resistance was much less than the conventional PDC treated fabrics. The one bath wet fixation processed fabrics showed better physical properties than the two bath processed fabrics in general. The optimum treatment condition was the mixed resin concentration of MF/DMDHEU, 100/100 g/l in one bath wet fixation process.

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Influence of Adhesion Condition on the Laminated Wood of Pinus thunbergii glued with Urea-formaldhyde Resin (요소수지접착제(尿素樹脂接着劑)를 사용(使用)한 곰솔 집성재(集成材)의 제조조건(製造條件)이 접착성질(接着性質)에 미치는 영향(影響))

  • Chung, In-Oh;So, Won-Tek;Lim, Kie-Phy
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.2
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    • pp.35-43
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    • 1984
  • This study was carried out to investigate the block shear strength of the 2ply laminated wood composed of Pinus thunbergii with ureaformaldehyde resin as adhesives according to pressure (6, 9, 12, 15kg/$cm^2$), pressing time(5, 10, 20, 30 hrs.), amount of spread(54, 108, 217, 324g/$cm^2$), hardener(10, 20, 30, 40% of 10% $NH_4CL$ on resin) and extender(0, 5, 10, 15% wheat flour on resin), and the bending strength and bending young's modulus of laminated beam according to the number of ply. The results were summarized as follows; 1. According to pressing pressure with amount of spread 217g/$cm^2$ both dry and wet shear strength of laminated wood showed the highest in 15kg/$cm^2$, and hot-cold soaking treatment showed the highest in 9kg/$cm^2$, while all shear strength of dry, wet and hot-cold soaked laminated wood have been reduced with the increasing of pressing time. 2. According to amount of spread, adhesion strength with the dry, wet and hot-cold soaking treatments revealed the highest in 217g/$cm^2$ and have been reduced under or over 217g/$cm^2$ of spread. 3. According to addition of hardener and extender, all shear strength of laminated block with the dry, wet and hot-cold soaking treatments have been reduced in increasing of addition amount of hardener and extender. The bending strength of beam according to the number of ply showed the highest in 2ply laminated wood and horizontal loading beam to glue line had the higher in strength than the vertical loading.

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Improvement of Wet-end Performance and Paper Strength with Polyvinylamine

  • Son, Dong-Jin;Kim, Bong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.63-69
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    • 2005
  • This study was performed to introduce recently developed polyvinylamine as a wet-end process and paper strength improving aids. As a retention and drainage aids, high cationic charged polyvinylamine was more effective at the BCTMP and ONP stock condition than LBKP stock condition. As a dry tensile strength aid, dual system of polyvinylamine with anionic polyacrylamide was the best at the LBKP or ONP stock conditions. On the other hand, polyvinyl amine alone was better than dual system of polyvinylamine with anionic polyacrylamide at the BCTMP condition. As a wet tensile strength aid, polyvinylamine single system and dual system of polyvinylamine with anionic polyacrylamide were good at LBKP, BCTMP and ONP stock conditions. However, poly(aminoamide)-epichlorohydrin resin was good at LBKP and ONP stock conditions but efficiency of poly(aminoamide)-epichlorohydrin resin was remarkably decreased at BCTMP stock condition.

Effect of pMDI or HDI Content in UMF Resin on Bonding High Moisture Content Veneers

  • Xu, Guang-Zhu;Eom, Young-Geun;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.5
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    • pp.414-420
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    • 2010
  • The effect of polymeric diphenyl methane-4,4-diisocyanate (pMDI) or 1,6-hexamethylene diisocyanate (HDI) in the UMF resin was discussed for improvement of the dry and wet shear strengths of plywood manufactured from high moisture content veneers. The curing behavior of UMF resin by pMDI or HDI content was examined by DSC and TGA, and its adhesion performance was evaluated by dry and wet shear strength tests of plywood. With the increase of pMDI content in the UMF resin, the curing temperature, reaction enthalpy (${\Delta}H$), and thermal stability consistently increased. With the increase of HDI content in the UMF resin, however, the curing temperature and reaction enthalpy (${\Delta}H$) decreased consistently and the thermal stability slightly increased in the range of 200 to $400^{\circ}C$ but decreased beyond $400^{\circ}C$. Also, the dry tensile shear strength increased up to the pMDI content of 5% and then decreased with its further addition but the wet tensile shear strength showed slight tendency to increase with the increase of pMDI content in the UMF resin. As the HDI content increased, however, the dry and wet tensile shear strengths of plywood consistently increased.

A study on the utilization of potato, sweet potato, and jelusalem artichoke flour as an extender of urea formaldehyde resin for plywood (고구마, 감자 및 돼지감자 분말(粉末)을 이용(利用)한 합판용(合板用) 요소수지(尿素樹脂)의 증량(增量)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Lee, Wha-Hyung
    • Journal of the Korean Wood Science and Technology
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    • v.1 no.2
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    • pp.11-15
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    • 1973
  • This study was carried out to utilize sweet potato, and jerusalem artichoke flour as an extender of urea formaldehyde resin for plywood manufacture. The results obtained are summarized as follows: 1) In dry and wet test of plywood, sweet potato flour extended in urea formaldehyde resin was shown better strength than those of wheat flour. 2) Sweet potato flour was shown good results up to 200 percent extension in the dry test, and there was not shown significant difference between 100 percent and 150 percent extension in the wet test. 3) In the case of 100 percent extension, potato flour was shown best dry shear strength(400 psi) and sweet potato flour was shown best wet shear strength (212 psi).

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Performance of Epoxy Resins for Repairing of Cracks in Concrete with Application Conditions (콘크리트 균열 보수용 에폭시의 시공조건에 따른 성능)

  • Lee, Chan-Young;Shim, Jae-Won;Kim, Hong-Bae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.813-816
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    • 2004
  • This study was performed to investigate bonding performance of epoxy resins for repairing of cracks in concrete, as a part of project to establish quality control standard for epoxy resins. In the slant shear strength test for hard and soft type epoxy, hard type was higher about 3 times than soft one. From the results, it is thought that hard type is suitable for load carrying. Injection of epoxy resin in the notch made flexural strength increase about $47\%$ over the specimen that epoxy resin is not injected. There were no differences in bonding performances with viscosity. Application of epoxy resin on the wet concrete surface made slant shear strength decrease about $46\%$, but similar performance to the case of application on the dry surface appeared by using epoxy resin for wet condition.

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Synthesis and Characterization of Polyurethane for Artificial Leather Using Bio Polyol (바이오 폴리올을 이용한 인공피혁 코팅용 폴리우레탄의 합성 및 특성)

  • Sur, Suk-Hun;Choi, Pil-Jun;Ko, Jae-Wang;Lee, Jae-Yeon
    • Textile Coloration and Finishing
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    • v.30 no.4
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    • pp.321-328
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    • 2018
  • Wet polyurethane resin was synthesized by using polytrimethylene ether glycol prepared from 1,3-propanediol produced by fermentation from corn sugar as bio polyol and polyether-polyol(PTMG). Physical properties and cell characteristics by wet coagulation were investigated using the synthesized wet polyurethane resin. The tensile strength of wet polyurethane resin decreased with increasing content of bio polyol as copolymer polyol, but it tended to increase elongation at break and tear strength. As a result of thermal characteristic analysis, it was found that the glass transition temperature was slightly increased as the content of bio polyol increased. As a result of comparing the cell characteristics by the wet coagulation method, it was found that the shape of the cell was good when the ether polyol and the bio polyol were used alone.

A STUDY ON THE FRACTURE STRENGTH OF TEETH RESTORED WITH A CARBON FIBER POST UNDER CYCLIC LOADING (반복하중하에서의 carbon fiber post의 파절강도에 관한 연구)

  • Yi, Yang-Jin
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.5
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    • pp.640-649
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    • 2000
  • In the restoration of endodontically treated teeth, carbon fiber post was recently introduced. The purpose of this in vitro study was to investigate the fracture strength of teeth restored with a pre-fabricated carbon fiber post in comparison with teeth restored with a prefabricated titanium post & custom cast gold post after cyclic loading in the different environment. A total of 30 recently extracted human central incisors of similar dimension with crowns removed were used. All teeth were placed into acrylic blocks and every steps for post and core fabrication were made accord-ing to manufacture's instruction. The post length and core dimensions were standardizd. All teeth were divided into 6 groups: 1) carbon fiber post / atmosphere, 2) titanium post / atmosphere, 3) gold post / atmosphere, 4) carbon fiber post / wet, 5) titanium post / wet, 6) gold post / wet. Carbon fiber post and titanium post were cemented in place using resin cement and cores were fabricated with Ti-Core. Custom cast gold post was made from Duralay pattern resin and cemented using resin cement, too. All specimens were thermocycled 10,000 times. After 50,000 cyclic loading, failure strength was measured using Instron testing machine. Kruskal-Wallis test followed by Mann-Whitney test was used to compare the mean fracture strength. Results were as follows : 1. All specimens showed lower fracture strength in wet environment after cyclic loading than in atmosphere condition, but did not reveal a significant difference. 2. There was no significant difference between carbon fiber post specimen and titanium post specimen in the same environment. 3. Gold cast post specimen showed significant different greater fracture strength than those of others in the same environment. 4. Carbon fiber post specimen showed no root fracture.

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Curing Behavior and Adhesion Performance of Urea-Melamine-Formaldehyde (UMF) Resin by Staged Addition of Melamine (멜라민 첨가 순서에 따른 UMF 접착제의 경화거동과 접착력의 영향)

  • Xu, Guang-Zhu;Eom, Young-Geun;Lee, Young-Kyu;Lim, Dong-Hyuk;Lee, Byoung-Ho;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.10 no.2
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    • pp.84-89
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    • 2009
  • The objective of this research was to investigate the curing behavior and adhesion performance of urea-melamine-formaldehyde (UMF) resin for the four types of UMF-1, UMF-2, UMF-3, and UMF-4 which synthesized by the staged addition of melamine. Also, various network structures of these resin types were discussed based on their different curing behavior and adhesion performance. The curing behavior was evaluated by DMTA and thermal stability was checked by TGA. Adhesion performance was evaluated by dry and wet shear strengths and the pH value of each cured resin was checked to see its effect on the adhesion performance. The results indicated that the UMF-1 resin type by the addition of melamine initially with the urea and formaldehyde at the same F/(U+M) rate showed the lowest thermal stability, rigidity (${\Delta}E^{\prime}$), temperature of tan ${\delta}$ maximum ($T_{tan}\;_{\delta}$), and wet shear strength, and pH value of cured resin. In wet shear strength, however, the UMF-4 resin type appears to be slightly higher than UMF-1 resin type.

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A study on the Durable Press finish by Wet-Fixation Process for Rayon Fabrics (II) - Effect of Treatment Temperature and Time - (레이온 직물의 Wet-Fixation에 의한 DP가공에 관한 연구(II) -처리온도 및 시간의 영향-)

  • Hu Yoon Sook;Kim Eun Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.4
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    • pp.357-369
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    • 1989
  • The purpose of this study was to investigate the effects of treatment temperature and time on the, of easy-care and strength properties of the wet fixation processed rayon fabrics. Viscose rayon fabrics were treated with mixed resins of melamine formaldehyde (MF) and DMDHEU by one bath and two bath wet fixation processes. The MF/DMDHEU mixed resin concentrations were 50/100, 50/150, 100/100 and 100/150(g/1). Magnasium chloride was used as a catalyst. The wet fixation conditions were 24hrs at room temperature,20 mins at $75^{\circ}C$ and 5 mins at $105^{\circ}C$ Wet fixation processed fabrics did not show the difference in the resin add-one, DP ratings and wrinkle recovery angles by the different treatment temperatures and times. DP ratings were in the order of $105^{\circ}C>75^{\circ}C>room$ temp, in one bath and two bath wet fixation. Breaking and tearing strength of one bath processed fabrics showed in the order of $75^{\circ}C>room\;temp>105^{\circ}C$ The breaking strength of two bath processed fabrics showed in the order of $105^{\circ}C>75^{\circ}C>room$ temp. Tearing strength showed in the order of $75^{\circ}c>105^{\circ}C>room$ temp. Abrasion resistances were in the order of $75^{\circ}C>105^{\circ}C>room$ temp. in one bath and two bath processes.

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