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Preliminary study on colloidal partitioning and speciation of trace metals in acid mine drainage

  • Kwon, Jang-Soon;Lee, Jeong-Ho;Yun, Seong-Taek;Jung, Hun-Bok;Chang, Min-Kyoung;Lee, Pyeong-Ku
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.100-101
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    • 2004
  • Many researches in Korea have been performed to understand the pollution of stream waters by acid mine drainage. However, few studies have been conducted regarding the effect of particulate and colloidal fractions on the transport of trace metals. To estimate harmful effects of trace metals, it is important to evaluate the particulate and colloidal metals as well as dissolved metals, because particulate and colloidal fractions of trace metals play an important role in transport of trace metals and may adversely affect habitats and organisms in riverine system. Colloids are solids with effective diameters in size range from 0.001 $\mu$m to 1 $\mu$m. According to Jone et al. (1974), metals in surface water, like Al, Fe, and Mn, require filtration with pore-size membranes smaller than 0.45 $\mu$m to define dissolved concentrations. The main objective of this study is to understand the effects of particulate, colloidal, and truly dissolved fractions on the transport and fate of trace metals in acid mine drainage. This study was conducted for the Onjeong creek in the Uljin mine area. Sampling was carried out in 13 sites, spatially covering the area from mine dumps to the downstream Onjeong reservoir. To examine the metal partitioning between particulate, colloidal, and truly dissolved fraction, we used successive filtration techniques consisting of conventional method (using 0.45 $\mu$m membranes) and tangential-flow ultrafiltration (using 0.001 $\mu$mm membranes). Ultrafiltration may seperate much smaller particles from aqueous phase (Josephson, 1984; Hernandez and Stallard, 1988). The analysis of metals were performed by inductively coupled plasma - atomic emission spectrometer (ICP-AES: model Perkin Elmer OPTIMA3000XL). Anions such as SO$_4$, Cl and NO$_3$ were measured with ion chromatograph (IC: model Dionex 120). Sample analysis is still in progress. The preliminary data show that the studied creek is severely polluted by Al, Fe, Mn, Pb and Zn. Toward upstream sites with relatively lower pH, less than 50% of Al and Fe occur in the sorbed form on particles or colloids, whereas more than 80% of Al and Fe occur in the sorbed form in downstream sites or tributaries with relatively higher pH. Less than 30% of Zn is present in particle or colloidal forms in the whole range of creek. Truly dissolved fraction of trace metals is negatively correlated with pH. The Kd values for Al, Fe and Zn consistently increase with increasing pH and decrease with increasing particle concentration.

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The Cenetic Implication of Hydrothermal Alteration of Epithermal Deposits from the Mugeuk Area (무극 지역 천열수 광상 열수변질대의 성인적 의미)

  • 박상준;최선규;이동은
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.3
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    • pp.265-280
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    • 2003
  • The Mugeuk mineralized area that associated with the pull-apart type Cretaceous Eumseong basin is composed of several gold-silver vein deposits that are emplaced in late Cretaceous biotite granite. The gold-silver deposits in the area show various hydrothermal alteration zones as well as Au/Ag ratios and ore mineralogy. The Geumbong mine showing relatively high gold fineness is composed of multiple veins and show alteration pattern; vein \longrightarrow phyllic \longrightarrow subphyllic \longrightarrow propylitic \longrightarrow subpropylitic zone. In contrast, The Taegeuk mines show the low fineness values, in far southern part are characterized by increasing tendency of simple and/or stockwork veins. The deposit displays alteration pattern; vein \longrightarrow propylitic \longrightarrow subpropylitic zone. Variations of alteration zone with depth show that phyllic zone are dominant in deeper level and propylitic zone sporadically overlapped by argillic zone are dominant in shallow level. The differences of alteration pattern between the gold-silver deposits are reflect the evolution of the hydrothermal fluids; the ore-forming fluids of the Geumbong mine are at relatively high temperature and salinity and highly-evolved meteoric water, developing phyllic zone, the Taegeuk mine containing greater amounts of less-evolved meteoric waters shows relatively low temperature and salinity in ore-forming fluids, developing propylitic zone. The various physicochemical environment for gold-silver mineralization in the Mugeuk mineralized area is due to proximity from heat source area (Mugeuk mine) to marginal area (Taegeuk mine) in a geothermal field. Therefore, it is suggested that the criteria for project exploration in the area are to focus on the area proximal to heat source and phyllic zone.

Contents Construction of 'Sea of Korea' Using European Antique Maps (서양고지도를 활용한 '동해' 전시 콘텐츠구성 방안)

  • Oh, Il-Whan;Lee, Seung-Su
    • The Journal of the Korea Contents Association
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    • v.10 no.7
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    • pp.208-219
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    • 2010
  • Antique maps are a cultural heritage of recorded information with distinguished pictorial and scientific value. They have been utilized in a variety of academic fields, especially in historical geography, as the most fundamental data to look into the restoration of space or historic changes of area from the past. However, there is no sufficient study on the development of contents using antique maps in the exhibitions. Furthermore, there is almost no content research on the antique maps integrating the academic programs in museums or art galleries. In particular, it is very difficult to find research on the approaches to configure or utilize the exhibition contents related to the Sea of Korea using European antique maps. This study examined the construction of educational contents in order to use the European antique maps including the Sea of Korea as well as Korea itself in the exhibitions. The results of this study may visualize the results of academic research on the territory and territorial waters of Korea and extensively acknowledge them as scientific data all over the world. Furthermore, this study aimed to create the opportunity to increase interest in the Sea of Korea and recognize it again, to find the contents construction to use European antique maps as academic data for exhibition and education in museums or cultural facilities and to provide a basic model for history education using antique maps.

Long-term corrosion-resistance of an uncoated weathering steel and its on-line and in-situ measurements (무도장 내후성강의 장기 내식성 및 그 현장즉시측정법)

  • Park, Jeong Real;Kim, Kyoo Young
    • Journal of Korean Society of Steel Construction
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    • v.16 no.4 s.71
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    • pp.415-423
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    • 2004
  • To investigate the long-term corrosion resistance of an uncoated weathering steel, an important outdoor constructional steel material, skyward surfaces of the weathering steel and a control steel initially exposed to rural and industrial atmospheres for 9 years were electrochemically tested in neutral artificial rain in terms of electrochemical potentials, impedances, and anodic potentiodynamic polarization curves. Their results were then discussed. A quite passive and stable rust layer to the artificial rain was well formed on the skyward surface of the weathering steel exposed to the industrial and rural atmospheres, and its corrosion rate in the artificial rain was measured to be about a low $3{{\mu}m}/y$. Continuous immersion of all the weathered surfaces in the artificial rain revealed the gradual degradation of the weathered corrosion layers on the steel, resulting in a cathodically controlled corrosion of the substrate steel by the electrochemical measurements. Alloy components of the weathering steel were found to retard the degradation of the weathered corrosion layers on the steel in the artificial rain. For better corrosion evaluation of the weathering steel, more electrochemical measurements of surfaces that have been exposed for more than 9 years to more closely simulated atmospheric waters are needed. These measurements are almost non-destructive and can provide online and in situ information on the corrosion rate, the development of corrosion and the conditions of rust layers on any interested surface and at any exposure time of the steel, so they can be effectively applicable to the corrosion evaluation of steel structures such as bridges, towers, and architectures by forming an electrochemical cell on an interested structural surface and by using a portable electrochemical instrument.

Distribution of Dinoflagellate Cysts in Surface Sediments of the Coastal Areas around Jeju Island, Korea (제주 해안주변해역 표층퇴적물 중 와편모조류 시스트 군집의 분포특성)

  • Park, Bokyung;Kim, Yoonjeong;Yoon, Yang Ho
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.4
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    • pp.310-321
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    • 2016
  • This study describes the spatial distribution of dinoflagellate cyst assemblages from the fishing ports along Jeju Island. Surface sediment samples from 22 stations revealed the occurrence of 29 species involving the Groups Protoperidinioid (44.8%), Gonyaulacoid (31.0%), Calciodineloid (10.3%), Gymnodinioid (6.9%), Diplosalid (3.5%) and Tuberculodinioid (3.5%). The cyst abundance recorded here is very low ($13{\sim}220cysts\;g-dry^{-1}$) as compared to Korean coastal regions. The abundance of heterothophic cysts increased in several fishing pots with fine sediments and anthropogenic tidal pools. And cyst abundance was well correlated with the grain-size composition of surface sediments. The dinoflagellate cyst assemblages in Jeju fishing ports were characterized by the dominant species, cyst of Gymnodinium sp., cyst of Pyrodinium bahamense and cyst of Scrippsiella trochoidea in 2012, Protoperidinium sp. (Brigantedinium sp.), cyst of Scrippsiella sp./trochoidea and cyst of Gymnodinium sp. in 2014, and Protoperidinium sp. (Echinidinium sp. and Brigantedinium sp.) in 2016. The advent of the toxic dinoflagellate, Pyrodinium bahamense were recorded for the first time in Jeju coastal waters. As a results, we are determined should be to monitoring and management measures for new toxic dinoflegallates from tropical or subtropical reigions and anthropogenic tidal pools by industrial activities.

Distribution and Pollution of Heavy Metals in the Environmental Samples of the Lake Shihwa (시화호 환경 중의 중금속 분포 특성과 오염)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Cho, Sung-Rok;Chung, Kyung-Ho;Park, Jun-Kun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.3
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    • pp.148-157
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    • 2005
  • In order to understand distribution characteristics and pollution of heavy metals in the artificial Lake Shihwa in the vicinity of Kyunggi Bay in relation with huge environmental changes, various environmental samples including seawaters, surface sediments and settling particulate matters were collected from Lake Shihwa in 2004. Due to extreme pollutant discharge from various anthropogenic sources such as the Banweol and Shihwa Industrial Complexes and cities, the highest metal concentrations in the samples such as waters, sediments and settling particulate matter were found in inner part of the lake. High metal contents (Cu, Zn and Hg) in sediments were observed at Sts. 2-4 and 9. The contents of Cr, Co, Ni, Cu, Zn and Pb in SPMs were high at St. 5 and low in the outer part of the lake. Spatial distribution of heavy metals were mainly controlled various biogeochemical factors and physical mixing as well as input of industrial and municipal wastewaters. Although tile environmental qualities of heavy metals in the lake have been improved partially due to inflow of outer seawater, it is not clear to reach a good environmental quality. Therefore, further environmental programs should be conducted continuously for environmental improvement.

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A Landscape Interpretation of Island Villages in Korean Southwest Sea (한국 서남해 섬마을의 경관체계해석 -진도군 조도군도, 신안군 비 금, 도초, 우이도 및 흑산군도를 중심으로-)

  • 김한배
    • Journal of the Korean Institute of Landscape Architecture
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    • v.18 no.4
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    • pp.45-71
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    • 1991
  • The landscape systems in Korean island settlements can be recognized as results of ingabitants' ecological adptation to the isolated environment with the limited natural resources. Both the fishery dominant industry in island society and ecological nature of its environments seem to have influenced on inhabitants' environmental cognition as well as the physical landscape of island villages such as its location, spatial pattern in each village, housing form and so on. This study was done mainly by both refering to the related documents and direct observations in case study areas, and results of the study can be summarized as follows. 1. In general, the landscape of an individual island seems to take more innate characteristics of island's own, corresponding to the degree of isolation from mainland. That is, while the landscape of island in neighboring waters takes both inland-like and island-innate landscape character at the same time, the one in the open sea far from land takes more innate landscape character of all island's own in the aspects of village location, land use and housing density etc. 2. The convex landform of most islands brings about more centrifugal village allocation than centripetal allocation in most inland villages. And thus most villages in each island face extremely diverse directions different from the south facing preference in most inland rural villages. 3. Most island villages tend to be located along the ecologically transitional strip between land and sea, so called 'line of life', rather than between hilly slope and flat land as being in most inland village locations. So they are located with marine ecology bounded fishing ground ahead and land ecology bounded agricultural site at the back of them. 4. The settlement pattern of the island fishing villages shows more compact spatial structure than that of inland agricultural villages, due to the absolute limits of usable land resources and the adaptation to the marine environment with severe sea winds and waves or for the easy accessability to the fishing grounds. And also the managerial patterns of public owned sea weed catching ground, which take each family as the unit of usership rather than an individual, seem to make the villagescape more compact and the size of Individual residence smaller than that of inland agricultural village. 5. The folk shrine('Dand') systems, in persrective of villagescape, represent innate environmental cognition of island inhabitants above all other cultural landscape elements in the island. Usually the kinds and the meanings of island's communal shrine and its allocative patternsin island villagescape are composed of set with binary opposition, for example 'Upper shrine(representing 'earth', 'mountain' or 'fire')' and 'Lower Shrine(representing 'sea', 'dragon' or 'water') are those. They are usually located at contrary positions in villagescape each other. That is, they are located at 'the virtical center or visual terminus(Upper shrine at hillside behind the village)' and 'the border or entrance(Lower Shrine at seashore in front of the village)'. Each of these shirines' divinity coincides with each subsystem of island's natural eco-system(earth sphere vs marine sphere) and they also contribute to ecological conservation, bonded with the 'Sacred Forest(usually with another function of windbreak)' or 'Sacred Natural Fountain' nearby them, which are representatives of island's natural resources.

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Some Considerations on the Establisment of the Exclusive Economic Zone in Korea (한국의 배타적 경제수역 설정에 관한 연구)

  • 이윤철
    • Journal of the Korean Institute of Navigation
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    • v.17 no.4
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    • pp.1-21
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    • 1993
  • The purpose of this paper is to search for reasonable and fair principles applicable to the delimitation of the Exclusive Economic Zone(which is called the EEZ, hereinafter) around the Korean Peninsula th-rought the comprehensive study of maritime boundary, which is one of the most important issues in the law of the Sea. So far, the sea has been exploited for activities such as fishery, transport and military stratedy, and en-vironmental policy and so on. From this time on, however, it becomes important to us as the major trea-sure-house of various resources which will be developed and used for diversified purposes. For these rea-sons, nowadays, more and more countries of the world are competing to secure waters as much as possible within their jurisdiction. And the regime of the EEZ was created as a result of this international trend. At last, it has been institutionalized as the 200-mile EEZ of a legal notion in the Convention on the Law of the Sea, which was adopted at the Third United Nations Conference on the Law of the Sea, in Jamaica on December 10, 1982. In adapting to this EEZ institution, Korea is faced with several complicated problems as it is bounded on three sides by the sea and all of its neighboring countries such as the PRC, the DPRK, Japan, Russia etc are less than 400 miles away between opposite countries. Therefore, when trying to delimit the boun-dary for the EEZ, it appears necessary to analyze applicable principles and rules of international law for delimitation mainly through the Convention on the Law of the Sea, and studies the trends of actual State practices and recent international precedents. It is hoped that such knowledge will enable Korea to secure sufficient resources and other sovereign rights without conflicting with the neighboring countries concer-ned. For the achievement of the above mentioned object. I analyzed the necessities of the establishment of the EEZ in Korea, the difficulties and practices of Korea's neighbors, and the changes and forthcoming trends in Korea's relations with its neighbors concerned on the basis of the general explanation of the EEZ regime. In conclusion, it is my opinion that for the establishment of the EEZ delimitation which neighbors around the Korean Peninsula should be applied reasonable and equitable principles considering the rele-vant circumstances which characterize the area definitely as well as the UN Convention on the Law of the Sea, 1982.

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Improvement of Model based on Inherent Optical Properties for Remote Sensing of Cyanobacterial Bloom (고유분광특성을 이용한 남조류 원격 추정 모델 개선)

  • Ha, Rim;Nam, Gibeom;Park, Sanghyun;Kang, Taegu;Shin, Hyunjoo;Kim, Kyunghyun;Rhew, Doughee;Lee, Hyuk
    • Korean Journal of Remote Sensing
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    • v.33 no.2
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    • pp.111-123
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    • 2017
  • The phycocyanin pigment (PC) is a marker for cyanobacterial presence in eutrophic inland water. Accurate estimation of low PC concentration in turbid inland water is challenging due to the optical complexity and criticalforissuing an early warning of potentialrisks of cyanobacterial bloom to the public. To monitor cyanobacterial bloom in eutrophic inland waters, an approach is proposed to partition non-water absorption coefficient from measured reflectance and to retrieve absorption coefficient of PC with the aim of improving the accuracy in remotely estimated PC, in particular for low concentrations. The proposed inversion model retrieves absorption spectra of PC ($a_{pc}({\lambda})$) with $R^2{\geq}0.8$ for $a_{pc}(620)$. The algorithm achieved more accurate Chl-a and PC estimation with $0.71{\leq}R^2{\leq}0.85$, relative root mean square error (rRMSE) ${\leq}39.4%$ and mean relative error(RE) ${\leq}78.0%$ than the widely used semi-empirical algorithm for the same dataset. In particular, low PC ($PC{\leq}50mg/m^3$) and low PC: Chl-a ratio values of for all datasets used in this study were well predicted by the proposed algorithm.

Metabolomes and transcriptomes revealed the saponin distribution in root tissues of Panax quinquefolius and Panax notoginseng

  • Wei, Guangfei;Yang, Feng;Wei, Fugang;Zhang, Lianjuan;Gao, Ying;Qian, Jun;Chen, Zhongjian;Jia, Zhengwei;Wang, Yong;Su, He;Dong, Linlin;Xu, Jiang;Chen, Shilin
    • Journal of Ginseng Research
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    • v.44 no.6
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    • pp.757-769
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    • 2020
  • Background: Panax quinquefolius and Panax notoginseng are widely used and well known for their pharmacological effects. As main pharmacological components, saponins have different distribution patterns in the root tissues of Panax plants. Methods: In this study, the representative ginsenosides were detected and quantified by desorption electrospray ionization mass spectrometry and high-performance liquid chromatography analysis to demonstrate saponin distribution in the root tissues of P. quinquefolius and P. notoginseng, and saponin metabolite profiles were analyzed by metabolomes to obtain the biomarkers of different root tissues. Finally, the transcriptome analysis was performed to demonstrate the molecular mechanisms of saponin distribution by gene profiles. Results: There was saponin distribution in the root tissues differed between P. quinquefolius and P. notoginseng. Eight-eight and 24 potential biomarkers were detected by metabolome analysis, and a total of 340 and 122 transcripts involved in saponin synthesis that were positively correlated with the saponin contents (R > 0.6, P < 0.05) in the root tissues of P. quinquefolius and P. notoginseng, respectively. Among them, GDPS1, CYP51, CYP64, and UGT11 were significantly correlated with the contents of Rg1, Re, Rc, Rb2, and Rd in P. quinquefolius. UGT255 was markedly related to the content of R1; CYP74, CYP89, CYP100, CYP103, CYP109, and UGT190 were markedly correlated with the Rd content in P. notoginseng.