• Applied Chemistry for Engineering
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• v.9 no.2
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• pp.159-164
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• 1998

Polycarbosilane(PCS) as a SiC precursor was synthesized from the rearrangement reaction of polydimethysilane(PDMS) in an autoclave, which prepared by dehalocoupling reaction of dichlorodimethylsilane. After fractional precipitation into three fractions in n-hexane-methanol mixture, they were characterized by FT-IR, NMR, GPC, TGA/DSC and XRD, and compared with the commercial product. We found that the molecular weight distributions of the PCS depended on the reaction pressures, temperatures and the reaction times, and affected thermal property and ceramic yield of the polymer. The monodispersed PCS containing less amount of oligomers and nonsoluble products was prepared by reaction of PDMS at $420^{\circ}C$ for 10 hrs, and it also gave the greatest amount of medium molecular weight($M_n=4,000$) fraction.

• Fisheries and Aquatic Sciences
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• v.10 no.4
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• pp.205-214
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• 2007

Surface water and sediment samples collected from the Mokpo coast of Korea were analyzed for molecular markers of organic municipal wastewaters, i.e., 11 fecal sterols including coprostanol (Cop) and nonylphenolic compounds (NPs), to characterize the main routes of these wastewaters to the coast and to assess contamination levels. Concentrations of Cop ranged from 94 to 7,568 ng/L in surface water and from 43 to 38,108 ng/g dry weight in sediments. Concentrations of NPs [nonylphenol (NP) and nonylphenol mono- and di-ethoxylates ($NP_{1-2}EOs$)] ranged from 123 to 4,729 ng/L in surface water and from 4 to 2,119 ng/ng dry weight in sediments. The levels of these compounds were much higher at stations near the rivers that pass through the urban center of Mokpo and the outfall of the wastewater treatment plant (WWTP). The spatial distribution of Cop levels was statistically similar to that of NPs (r=0.809 and 0.982 in surface water and sediments, respectively), indicating that these compounds may have similar discharge points, transport, mixing, and deposition in the study area. These results suggest that considerable amounts of organic wastewater compounds are discharged through rivers and WWTP effluent to the Mokpo coast.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.6 s.237
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• pp.671-686
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• 2005

The transient nature and complex geometries of two-phase gas-liquid flows cause fundamental difficulties when measuring flow velocity using an electromagnetic flowmeter. Recently, a current-sensing flowmeter was introduced to obtain measurements with high temporal resolution (Ahn et al.). In this study, current-sensing flowmeter theory was applied to measure the fast velocity transients in slug flows. The velocity fields of axisymmetric gas-liquid slug flow in a vertical pipe were obtained using Volume-of-Fluid (VOF) method, and the virtual potential distributions for the electrodes of finite size were also computed using the finite volume method for simulating slug flow. The output signal prediction for slug flow was carried out from the velocity and virtual potential (or weight function) fields. The flowmeter was numerically calibrated to obtain the cross-sectional liquid mean velocity at an electrode plane from the predicted output signal. Two calibration parameters are proposed for this procedure: a flow pattern coefficient and a localization parameter. The flow pattern coefficient was defined by the ratio of the liquid resistance between the electrodes for two-phase flow with respect to that for single-phase flow, and the localization parameter was introduced to avoid errors in the flowmeter readings caused by liquid acceleration or deceleration around the electrodes. These parameters were also calculated from the computed velocity and virtual potential fields. The results can be used to obtain the liquid mean velocity from the slug flow signal measured by a current-sensing flowmeter.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.682-689
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• 2008

The purpose of this study was to find out the variation between molecular size distribution (MSD) of natural organic matter (NOM) in raw waters after different water treatment processes like conventional process (coagulation, flocculation, filtration) followed by advanced oxidation process (ozonation, GAC adsorption). The MSD of NOM of Suji pilot plant were determined by Liquid Chromatography-Organic Carbon Detection (LC-OCD) which is a kine of high-performance size-exclusion chromatography (HPSEC) with nondispersive infrared (NDIR) detector and $UV_{254}$ detector. Five distinct fractions were generally separated from water samples with the Toyopearl HW-50S column, using 28 mmol phosphate buffer at pH 6.58 as an eluent. Large and intermediate humic fractions were the most dominant fractions in surface water. High molecular weight (HMW) matter was clearly easier to remove in coagulation and clarification than low molecular weight (LMW) matter. Water treatment processes removed the two largest fractions almost completely shifting the MSD towards smaller molecular size in DW. No more distinct variation of MSD was observed by ozone process after sand filtration but the SUVA value were obviously reduced during increase of the ozone doses. UVD results and HS-Diagram demonstrate that ozone induce not the variation of molecular size of humic substance but change the bond structure from aromatic rings or double bonds to single bond. Granular activated carbon (GAC) filtration removed 8~9% of organic compounds and showed better adsorption property for small MSD than large one.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.41 no.1
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• pp.61-67
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• 2008

Acoustic technology is commonly used to estimate the biomass and distribution of fisheries resources in coastal areas and the open ocean. Acoustic surveys were conducted on 24-26 May and 20-21 June, 2005, and 15-18 June and 27-30 July, 2006, near the Tongyoung, Geojae, and Namhae anchovy fishing grounds using a dual beam echo sounder. Information was obtained on the distributions of adult and juvenile anchovy (depth and position). We calculated and compared anchovy biomass using simple summation. In this study, all backscatter was attributed to anchovy. We assumed that the average target strength of anchovy was -70 dB and the average body weight was 3 g in May and June 2005, and that the target strength of anchovy was -65 dB and the average body weight was 5 g for pelagic individuals in July 2006. The anchovy biomass in May 2005 was estimated to be 0.147 million tons using the traditional method, while using the summation method, the estimated anchovy biomass was 0.062 million tons in June 2005, 0.21 million tons in June 2006, and in 0.43 million tons in July 2006.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.32 no.4
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• pp.66-73
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• 2000

Alkaline sulfite-anthraquinone(AS-AQ) cooking process has been applied to unground pine bark. The properties of the spent liquor such as molecular weight distributions, sulfonic equivalent weights, degree of sulfonation, phenolic hydroxyl groups and kaolin dispersing ability have been investigated to evaluate the possibility of using this liquor as concrete additives or binders. In the case of ground bark meal, more than 90% delignification was achieved at the optimal cooking conditions. However, applying these conditions on unground bark the delignification was slightly retarded. The decrease in the degree of delignification may be attributed to less penetration and diffusion of chemicals during the cooking of the bark. Increasing the cooking temperature only by $5^{\circ}C$ improved the delignification of the bark and about 90% delignification can be achieved. These results indicate that bark can be used successfully during AS-AQ cooking without any mechanical or physical pretreatment. The properties of lignin or polyphenol sulfonates in the spent liquor after AS-AQ cooking of the bark were compared with Sunflo-R, which is commercial lignosulfonate(CLS) prepared from wood. The weight average molecular weights(Mws) estimated by gel-filteration chromatography was found to be ranging from 1,200~1,800. These are considerably lower than those in CLS. Lignin or polyphenol sulfonates in the spent liquor of bark and CLS have similar degree of sulfonation, but the phenolic hydroxyl group was 1.8 times higher than CLS. Moreover, the dispersing abilities of the spent liquors were better than that of CLS, especially after 0.1% addition to kaolin suspension.

• Polymer(Korea)
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• v.24 no.5
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• pp.638-645
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• 2000

Linear and star-shaped, poly(lactic acid) (PLA) stereo-block copolymers were synthesized by sequential polymerization of DL-lactic acid and L-lactide in the presence of diol or polyol compounds. The molecular weight of block copolymers could be controlled to some extent by the variation of alcohol content. These block copolymers had relatively narrow molecular weight distributions. The glass transition temperature and melting temperature of block copolymers appeared at around 5$0^{\circ}C$ and 100~14$0^{\circ}C$, respectively. The block copolymers were found to crystallize even at the high D-stereoisomer concentration of 35 mol%, in contrast to the amorphous nature of the random copolymer with similar composition. Also we could observe the crystallinity of PLA stereo-block copolymers varying with annealing temperature and time.

• Elastomers and Composites
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• v.44 no.2
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• pp.156-163
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• 2009

Our objective is to increase the flowability of Polypropylene(PP) compounds and achieve flow mark free surface in injection molded specimen. We have investigated flowabilities of PP compounds which were composed of PP, rubber, talc, and trace amount of additives. Flowability measurement was performed with four types PPs of which molecular weight distributions(MWD) and melt indexes(MI) were different. Rheological properties of the PP compounding materials, such as spiral flow(SF) length, MI, and shear viscosity, were evaluated. When PP with the broad MWD was used, there were remarkable cases where the spiral flow length of low MI PP compound was longer than that of higher MI PP compound. The PP compound having low MI but broad MWD PP has more flowability than the compound with only high MI.

• Journal of Community Nutrition
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• v.1 no.2
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• pp.81-87
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• 1999

Body mass index(BMI) is recognized as one of the most useful indexes for adiposity in children and adults. This study was conducted to provide information on BMI distribution by age and sex in Korean children, and to identify sociodemographic factors that affected BMI among children. The study was conducted on 2376 children(boys 1184, girls 1192) living in a middle-size city in Korea. Subjects were selected from the primary schoolchildren in grades 1-6 using the two-stage sampling method. Their mean age was 9.4 years. The percentile of BMI tended to increase as age increased in both sexes. The 85th percentile for boys, aged 6-12 years, was 19.8kg/㎡, and the 95th percentile was 22.5kg/㎡. The 85th percentile for girls, aged 6-12 years, was 18.9kg/㎡, and the 95th percentile was 21.5kg/㎡. Multiple regression analysis was carried out to predict BMI from percent ideal body weight (PIBW), age and sex. After adjusting PIBW and age, BMI for boys was 0.062kg/㎡ lower than that for girls. One year of age increased BIM by 0.55kg/㎡. The prevalence rate of overweight and obesity based on PIBW was 15.8% and 15.0% for boys, and 14.0% and 11.0% for girls, respectively. Demographic factors such as sex, age, and parents' obesity influenced children's BMI. After adjusting for sex, age and parents' BMI, the presence of another children in family, and mother's employment status showed a strong effect on children's BMI. The results suggest an age-sex specific BMI distribution of Korean children. The present study also provides direct evidence of a correlation between early life environmental factors, such as presence of siblings or mother's employment, and BMI level in Korean children.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1951-1956
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• 2004

The transient nature and complex flow geometries of two-phase gas-liquid flows cause fundamental difficulties when measuring flow velocity using an electromagnetic flowmeter. Recently, a current-sensing flowmeter was introduced to obtain measurements with high temporal resolution (Ahn et $al.^{(1)}$). In this study, current-sensing flowmeter theory was applied to measure the fast velocity transients in slug flows. To do this, the velocity fields of axisymmetric gas-liquid slug flow in a vertical pipe were obtained using Volume-of-Fluid (VOF) method and the virtual potential distributions for the electrodes of finite size were also computed using the finite volume method for the simulated slug flow. The output signal prediction for slug flow was carried out from the velocity and virtual potential (or weight function) fields. The flowmeter was numerically calibrated to obtain the cross-sectional liquid mean velocity at an electrode plane from the predicted output signal. Two calibration parameters are required for this procedure: a flow pattern coefficient and a localization parameter. The flow pattern coefficient was defined by the ratio of the liquid resistance between the electrodes for two-phase flow with respect to that for single-phase flow, and the localization parameter was introduced to avoid errors in the flowmeter readings caused by liquid acceleration or deceleration around the electrodes. These parameters were also calculated from the computed velocity and virtual potential fields. The results can be used to obtain the liquid mean velocity from the slug flow signal measured by a current-sensing flowmeter.