• Title/Summary/Keyword: Weathering surface

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The Changes of Specific Surface Area of Soils after Peroxidation and Its Implication for the Calculation of Critical toads of Soil Acidification (Peroxidation 전후의 토양 비표면적 변화와 토양산성화 임계부하량 계산에의 의의)

  • Yeo, Sang-Jin;Lee, Bumhan;Soyoung Sung;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.195-204
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    • 2002
  • Mineralogy and the exposed surface area are two of the most important factors controlling dissolution and weathering rates of soils. The mixture of inorganic and organic materials of various size distributions and structures that constitute soils makes the calculation of weathering rates difficult. The surface area of soil minerals plays an important role in most of programs for calculating the weathering rates and critical loads. The Brunauer-Emmett-Teller (BET) measurement is recommended for the measurement of specific surface area. However, BET values measured without organic matter removal are in fact those far all the N2-adsorbed surface areas, including the surfaces covered and aggregated with organisms. Surfaces occupied by organisms are assumed to be more reactive to weathering by organic activities. Therefore, the BET surface area difference before and after organic removal depicts the area occupied by organisms. The present study shows that the BET values after organic matter removal using $H_2$O$_2$ are larger than those without removal by 1.68~4.87 $m^2$/g. This implies that BET measurement without organic removal excludes the reactive area occupied by organisms and that the area occupied by organisms in soils is much larger than expected. It is suggested that specific surface area measurement for calculating weathering rates of mineral soils should be made before and after organic matter removal. The results of a column experiment are presented to demonstrate the potential retarding influence that this organic matter may have on mineral dissolution and weathering.

Analysis of Conservation Scientific Deterioration Diagnosis and Conservation Environment of the Samjonbul Carved on Rock Surface in Taean, Korea (태안마애삼존불의 보존과학적 훼손도 진단과 보존환경 분석)

  • Eom, Doo-Sung;Jun, Byung-Kyu;Han, Min-Su;Lee, Jang-Jon;Song, Chi-Young
    • 보존과학연구
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    • s.29
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    • pp.19-44
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    • 2008
  • Sam-jon-bul or Three Buddha Image Carved on rock surface which is called Sam-jon-bul in Taean, state-designated national treasure No. 307, made in Baek-je Period, has two Buddha images and one Bodhisattva. The detached part of the Sam-jon-bul from wall rock has been attached through conservation treatment in 1995. Few study has been done on weathering condition of petrological point of view and damage while the surface of the Sam-jon-bul has been under serious weathering (relief) of loosing stone particles, and discoloration. In this study, it was made weathering damage maps, which show physical property of the material and state of damage of Sam-jon-bul, in order to dialogize how far the weathering has been done. It has been considered continuing on-site monitoring as necessity when Sam-jon-bul was covered with dew, which may have been caused by change in weather in and out of the protect building. It is necessary to set up detailed conservation plan for it by doing regular diagnosis on the influence of the protect building and weathering of Sam-jon-bul.

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Atmospheric Corrosion Process for Weathering Steel

  • Nagano, Hiroo;Yamashita, Masato
    • Corrosion Science and Technology
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    • v.7 no.2
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    • pp.119-124
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    • 2008
  • Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.

Modeling of Geochemical Variations and Weathering Depth on the Surface of Pelitic Rocks in Periodical Submerging Zone: Bangudae Petroglyphs (주기적 침수구역 이질암 표면의 지구화학적 변화와 풍화심도 모델링: 반구대 암각화)

  • Chan Hee Lee;Yu Gun Chun
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.583-596
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    • 2022
  • The rock surface of Bangudae petroglyphs is mainly dark brown hornfelsified shales by contact metamorphism. The surface form a weathered layer of a invariable depth, and there is a difference with mineral and chemical composition between weathered and non-weathered layers. Surface of the petroglyphs has been discolored to light brown over the face due to biological and chemical weathering. As the measuring chromaticity based on the non-weathered layer, the whiteness and yellowness increased in the weathered layer, and the color difference (ΔE) was 5.54 to 36.89 (mean 17.26). In the weathered layer of the petroglyph surface, the CaO content was reduced by about 90% compared to the non-weathered layer, and Sr also showed the same trend. In particular, the mean porosity of the non-weathered layer was 0.4%, but it was estimated as 25.0% in the weathered layer. This is interpreted as the fact that calcite reacts with water, and forms a weathered layer from the surface as it is eluted. Based on the weathering depth modeling of the petroglyphs using the penetration characteristics of X-rays, the weathering depth of rock faces was found to be 1 to 2mm. However, the area classified as 2mm or more estimated to be a maximum of 3 to 4mm, considering the weathering depth around the petroglyphs surface.

Current Researches on The Weathering of Wood (목재의 기상열화에 관한 최근의 연구 동향)

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.5
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    • pp.483-494
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    • 2017
  • This was reviewed on the characteristics (changes of color, microscopic structures, and chemical degradations) that appears on wood surface, when wood is exposed to outdoors and weathering testing methods applicable for assessment of wood weatherability in outside environment through literature reviews.

Morphology of Halloysite Particles and Aggregates in the Weathering of Anorthosite (회장암 풍화과정에서 생성되는 할로이사이트 입자 및 집합체의 형태)

  • 정기영;김영호
    • Journal of the Mineralogical Society of Korea
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    • v.9 no.2
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    • pp.64-70
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    • 1996
  • Early weathering products of anorthosite were investigated by using scanning electron microscopy in order to trace the development of halloysite particles and aggregates. Tiny short tubes or spheres precipitate on the plagioclase surface in the initial stage of weathering and form the compact globular aggregates. With continued growth, several globules are coalesced into wrinkled halloysite aggregates, and short tubes or spheres in globules grow into long tubes forming sheaf-like aggregates. Particle shape of halloysite varies with changing supersaturation degree of weathering solution, and determines the morphology of halloysite aggregates.

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Characteristics of the rocks and its weathering phenomena of the Gameunsa 3-story and Naweonri 5-story Pagodas located at the Kyeongju city, Korea (감은사지 3층 석탑(동탑)과 나원리 5층 석탑의 암석과 풍화현상의 특징에 대한 연구)

  • Lee, Sang Hun
    • Journal of Conservation Science
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    • v.5 no.1 s.5
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    • pp.20-40
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    • 1996
  • For obtaining the basic data for establishing plan on the conservation of the Gameunsa 3-story and Naweonri 5-story Pagodas located at the Kyeongju city, the characteristics of the rock and weathering phenomena have been investigated. The former consists of quartz-rlch granite containing small amount of biotite, and the latter of alkali granite with abundant perthite, These rock phases are nearly identical to the marginal phase of medium-grained hornblende-biotite granodiorite and alkali granite respectively, which are distributed around the Kyeongju city. The rock weathering may be governed mainly by chemical weathering of feldspar following physical segregation of quartz grains and pervasive moss. The feldspar easily dissolve In the solution with pH<7 to precipitate clay mineral such as a kaolinite as a secondary phase on the feldspar surface. However, the chemical weathering of feldspar may continue when the surface is washed by the rain according to removal of the reprecipitated phase. On forwarding, the weathering may be greatly Influenced by the acid rain. Exfoliation and weathering along igneous lineation resulting in exfoliating along the structural line are the characteristic weathering phenomena. Also the secondary small cracks are irregularly developed on the rocks due to different strain on places by the overall structural unbalance of the pagodas. Along these cracks, the rain water intrudes deeply into the rocks and weathering occurs intensively compared to other parts. Weathering may be artificially promoted by the grinding or sculpturing when the pagodas were made. Because it may influence on the physical properties of the rocks as well as destruct the surface of the feldspar crystals, the major constituents of the rocks, it results in providing the environment of easy chemical weathering along time. For conservation, the pagodas must be structurally balanced by compacting the soil basement and supplementing rocks on the destroyed part. On the exfoliated part it is better not to be artifically treated as using cementing material. But the cracks may be filled up by cementing material to avoid the intrusion of acidic water. To supplement the rocks on the destroyed part, it may be better to use similar rock phases from identical biotite granite and alkali granite masses around the Kyeongju city.

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Rendezvous Mission to Apophis: IV. Investigation of the internal structure - A lesson from an analogical asteroid Itokawa

  • Jin, Sunho;Kim, Yaeji;Jo, Hangbin;Yang, Hongu;Kwon, Yuna G.;Ishiguro, Masateru;Jeong, Minsup;Moon, Hong-Kyu;Choi, Young-Jun;Kim, Myung-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.58.1-59
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    • 2021
  • Exploration of asteroids' internal structure is essential for understanding their evolutional history. It also provides a fundamental information about the history of coalescence and collision of the solar system. Among several models of the internal structures, the rubble-pile model, confirmed by the near-Earth asteroid (25143) Itokawa by Hayabusa mission [1], is now widely regarded as the most common to asteroids with size ranging from 200 m to 10 km [2]. On the contrary, monolithic and core-mantle structures are also possible for small asteroids [3]. It is, however, still challenging to look through the interior of a target object using remote-sensing devices. In this presentation, we introduce our ongoing research conducted at Seoul National and propose an idea to infer the internal structure of Apophis using available instruments. Itokawa's research provides an important benchmark for Apophis exploration because both asteroids have similar size and composition [4][5]. We have conducted research on Itokawa's evolution in terms of collision and space weathering. Space weathering is the surface alteration process caused by solar wind implantation and micrometeorite bombardment [6]. Meanwhile, resurfacing via a collision acts as a counter-process of space weathering by exposing fresh materials under the matured layer and lower the overall degree of space weathering. Therefore, the balance of these two processes determine the space weathering degrees of the asteroid. We focus on the impact evidence on the boulder surface and found that space weathering progresses in only 100-10,000 years and modifies the surface optical properties (Jin & Ishiguro, KAS 2020 Fall Meeting). It is important to note that the timescale is significantly shorter than the Itokawa's age, suggesting that the asteroid can be totally processed by space weathering. Accordingly, our result triggers a further discussion about why Itokawa indicates a moderately fresh spectrum (Sq-type denotes less matured than S-type). For example, Itokawa's smooth terrains show a weaker degree of space weathering than other S-type asteroids [7]. We conjecture that the global seismic shaking caused by collisions with >1 mm-sized interplanetary dust particles induces granular convection, which hinders the progression of space weathering [8]. Note that the efficiency of seismic wave propagation is strongly dependent on the internal structure of the asteroid. Finally, we consider possible approaches to investigate Apophis's internal structure. The first idea is studying the space weathering age, as conducted for Itokawa. If Apophis indicates a younger age, the internal structure would have more voids [9]. In addition, the 2029 close encounter with Earth provides a rare natural opportunity to witness the contrast between before and after the event. If the asteroid exhibits a slight change in shape and space weathering degree, one can determine the physical structure of the internal materials (e.g., rubble-pile monolithic, thick or thin regolith layer, the cohesion of the materials). We will also consider a possible science using a seismometer.

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Variation of Chemical Composition and Relative migration of major Elements in the Weathering of Jeon-Ju granite and Rang-San granite (전북(全北) 전주지역(全州地域) 화강암(花崗岩) 및 낭산지역(郎山地域) 화강암(花崗岩)의 풍화(風化)에 따른 화학조성(化學組成)의 변화(變化)와 주요원소(主要元素)의 상대적이동(相對的移動))

  • Nam, Ki Sang
    • Economic and Environmental Geology
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    • v.8 no.4
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    • pp.211-221
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    • 1975
  • Weathering of granites has a geochemical role of great significance, because of their abundance and because of chemical instability near the surface of the earth, which is more pronounced than in most other rocks. On the other hand the granites are tectonically fragile and "react" to deformation with marked facility, giving rise to a whole gamut of deformed rocks. Therefore, the writer has studied on the weathering of granitic rocks at of Iri city and Jeonju city Jeollabukdo, Korea, The fresh and weathered rocks were used as material for the investigation. The results obtained by chemical analysis and observation are as follows. 1) The order of mobility in major elements was Ca, Na and K$H_2O$ was observed clearly and late stages of weathering processes. 3) The early stage of weathering is commenced by physical weathering and followed by chemical weathering. 4) The ratio of FeO/. $Fe_2O_3$, FeO/MgO, and $SiO_2/Al_2O_3 $ decreased uniformly from early to late stage of weathering processes. 5) It was proved that weathering potential of granite was larger than that of basaltic rocks.

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Variation of chemical Composition and Relative migration of major Elements in the weathering of Baeg-Gu Granite (백구화강암(白鷗花崗巖)의 풍화(風化)에 따른 화학조성(化學組成)의 변화(變化)와 주요원소(主要元素)의 상대적(相對的) 이동(移動))

  • Nam, Ki Sang
    • Economic and Environmental Geology
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    • v.7 no.4
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    • pp.175-184
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    • 1974
  • Weathering of granites has a great geochemical significance, because of their chemical stability near the earth surface which is more pronounced than in most other rocks. The author intended to observe the relative mobility of major elements in weathering process of the granite, distributed on outskirts of Iri city Jeolla-bugdo, Korea. He analysed fresh granites and weathered ones from the Baeg-Gu granite mass and obtained following conclusions in the triangle-diagrams and the oxidized variation diagrams of the samples. 1) The increasing phenomena of $H_2O$ was observed clearly in early and late stages of weathering process. 2) The early stage of weathering is commenced by physical weathering and followed by chemical weathering. 3) The ratio of $FeO/Fe_2O_3$, FeO/MgO, and $SiO_2/Al_2O_3$ decreased uniformly from early to late stage of weathering processes. 4) It was proved that weathering potential of granite was larger than that of basaltic rock. 5) The order of mobility in major elements was Ca, Na and K

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