• Journal of Surface Science and Engineering
• /
• v.54 no.6
• /
• pp.307-314
• /
• 2021

Diamond-like carbon (DLC) is difficult to achieve sufficient adhesion because of weak bonding between DLC film and the substrate. The purpose of this study is to improve the adhesion between substrate and DLC film. DLC film was deposited on AISI H13 using linear ion source. To improve adhesion, the substrate was treated by dual post plasma nitriding. In order to define the mechanism of the improvement in adhesive strength, the gradient layer between substrate and DLC film was analyzed by Glow Discharge Spectrometer (GDS) and Scanning Electron Microscope (SEM). The microstructure of the DLC film was analyzed using a micro Raman spectrometer. Mechanical properties were measured by nano-indentation, micro vickers hardness tester and tribology tester. The characteristic of adhesion was observed by scratch test. The adhesion of the DLC film was enhanced by active screen plasma nitriding layer.

• Journal of the Korean Physical Society
• /
• v.73 no.11
• /
• pp.1787-1793
• /
• 2018

The power conversion efficiency of perovskite solar cells has reached 23.3%. Although significant developments have been made through intensive studies, the stability issue is still challenging. Passivation of perovskite solar cells with a transparent polymer provides better stability; however, there are a few disadvantages of organic polymer such as low thermal stability, weak adhesion and the lack of water retention ability. In this work, we prepared a dual Parylene-F/C layer with 3-methacryloxypropyltrimethoxysilane, A-174, to combine the advantages of organic and inorganic materials. As a result, A-174 treated dual Parylene-F/C layer demonstrated improved passivation effects compared to a single Parylene layer due to the strong binding of Parylene and the water retention ability by $SiO_2$ formed from A-174. This synergetic effects can be expanded to the combination of other organic materials and organosilane compounds.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.49 no.1
• /
• pp.61-73
• /
• 2016

Water mass distribution and currents were investigated off the east coast of Korea near the Hupo Bank using the CTD and ADCP data from June to August 2010. The typical water masses were: (1) Tsushima Surface Water (TSW) from the East Korean Warm Current (EKWC) in the surface layer, (2) a shallow thermocline at 20-30 m depth, (3) Tsushima Middle Water (TMW) of high salinity (>34.2) below the pycnocline, (4) North Korean Cold Water (NKCW) of low salinity (<34.05) and low temperature (<4°C) in the lower layer. In June, a double eddy was observed in which a cold filament intruded cyclonically from the south around a pre-existing cold-core eddy. A burst of strong southward current was recorded in mid-August due to a warm filament from the meandering EKWC. Current in the N-S direction was predominant due to topographic effects, and the direction of the northward EKWC was frequently reversed in its direction due to the eddy-filament activity, whereas the influence of the wind was not noticeable. The vertical structure of the current was of a two-layer system, with the northward EKWC in the upper layer and weak southward flows corresponding to the North Korean Cold Current (NKCC) in the deeper layer.

• Progress in Superconductivity and Cryogenics
• /
• v.18 no.2
• /
• pp.5-7
• /
• 2016

We present an experimental investigation of the superconducting transition temperatures, $T_c$, of superconductor/ferromagnet bilayers with varying the thickness of ferromagnetic layer. FeN was used for the ferromagnetic (F) layer, and NbN and Nb were used for the superconducting (S) layer. The results were obtained using three different-thickness series of the S layer of the S/F bilayers: NbN/FeN with NbN thickness, $d_{NbN}{\approx}9.3nm$ and $d_{NbN}{\approx}10nm$, and Nb/FeN with Nb thickness $d_{Nb}{\approx}15nm$. $T_c$ drops sharply with increasing thickness of the ferromagnetic layer, $d_{FeN}$, before maximal suppression of superconductivity at $d_{FeN}{\approx}6.3nm$ for $d_{NbN}{\approx}10nm$ and at $d_{FeN}{\approx}2.5nm$ for $d_{Nb}{\approx}15nm$, respectively. After shallow minimum of $T_c$, a weak $T_c$ oscillation was observed in NbN/FeN bilayers, but it was hardly observable in Nb/FeN bilayers.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2008.10a
• /
• pp.310-313
• /
• 2008

Recently, study on the weak interaction energy between the soft polymer surface and liquid crystals has been a primary topic for new LC device applications. In this paper, to understand the switching property of nematic liquid crystals (LCs) at the interface with a weak anchoring boundary, we investigate experimentally the rotation property of surface nematic director by electric field on non-treated Poly-Methylmethacrylate (PMMA, $T_g=110^{\circ}C$, Sigma Aldrich) film observed under various temperatures including the glass transition temperature ($T_g$) of the polymer layer.

• Journal of Environmental Science International
• /
• v.14 no.6
• /
• pp.577-582
• /
• 2005

Enormous apartment complexes in urban areas, temporary inversion state and heat island effect occur due to the strong sunshine and weak wind speeds which hinders the dispersion of air pollutants that are emitted from neighboring areas of apartment complexes. In this study, analysis were conducted by using the Fluent code based on the CFD(Computation Fluid Dynamics), including building layout, material, building height from the ground surface, the heat, analysis of flow field in the apartment complex. It was estimated that the temporal radiation inversion phenomenon during the daytime, which was caused by the weak wind speed and higher temperatures in the upper level, contributed to the stagnation of the air pollutants in the lower layer of the apartment complex.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.43 no.7
• /
• pp.1025-1035
• /
• 2014

This study assessed the effect of immobilized lipase on weak base styrene resin using polyethyleneimine (PEI) with cross-linking. Two procedures were used in this study. The first one, "mono-layer" lipase immobilization, involves washing PEI after adsorption. The second procedure, "multi-layer" lipase immobilization, has no washing before the cross-linking step. Treverlite XS-100200 (weak base styrene resin) was immersed with PEI solution (2.2 mg/mL). Lipase AH (from Burkholderia cepacia) was adsorbed onto the support coated with PEI before cross-linking with glutaraldehyde. Structured lipid was synthesized by immobilized lipase-catalyzed interesterification using canola oil, palmitic ethyl ester (PEE), and stearic ethyl ester (StEE). Total fatty acid contents of triacylglycerol (TAG) in structured lipids were analyzed to investigate activity, properties, and reusability of immobilized lipases. Activities of immobilized lipases on the multi-layer and mono-layer increased at a high concentration (8 mg/mL) of lipase solution used for immobilization. The results show that immobilized lipase with the mono-layer method at pH 8.0 on resin had the highest total saturated fatty acid content (26.17 area%). Activity of immobilized lipase with the multi-layer method at pH 7.5 on support was lower than that of the mono-layer, but total saturated fatty acid content was 16.79 area% higher than that of lipase AH (15.01 area%).

• Transactions on Electrical and Electronic Materials
• /
• v.7 no.1
• /
• pp.16-20
• /
• 2006

In this paper, we investigated the effects of short-term oxygen plasma treatment of semiconducting silicone layer to improve interfacial performances in joints prepared with a insulating silicone materials. Surface characterizations were assessed using contact angle measurement and x-ray photoelectron spectroscopy (XPS), and then adhesion level and electrical performance were evaluated through T-peel tests and electrical breakdown voltage tests of treated semi-conductive and insulating joints. Plasma exposure mainly increased the polar component of surface energy from $0.21\;dyne/cm^2$ to $47\;dyne/cm^2$ with increasing plasma treatment time and then leveled off. Based on XPS analysis, the surface modification can be mainly ascribed to the creation of chemically active functional groups such as C-O, C=O and COH on semi-conductive silicone surface. This oxidized rubber layer is inorganic silica-like structure of Si bound with three to four oxygen atoms ($SiO_x,\;x=3{\sim}4$). The oxygen plasma treatment produces an increase in joint strength that is maximum for 10 min treatment. However, due to brittle property of this oxidized layer, the highly oxidized layer from too much extended treatment could be act as a weak point, decreasing the adhesion strength. In addition, electrical breakdown level of joints with adequate plasma treatment was increased by about $10\;\%$ with model samples of joints prepared with a semi-conducting/ insulating silicone polymer after applied to interface.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.19 no.2
• /
• pp.153-157
• /
• 2006

In this work, the effects of plasma treatment on surface properties of semiconductive silicone rubber were investigated in terms of X-ray photoelectron spectroscopy (XPS) and contact angles, The adhesion characteristics of semiconductive-insulating interface layer of silicone rubber were studied by measuring the T-peel strengths, The results of the chemical analysis showed that C-H bonds were broken due to plasma discharge and Silica-like bonds(SiOx, x=3${\~}$4) increased, It is thought that semiconductive silicone rubber surfaces treated with plasma discharge led to an increase in oxygen-containing functional groups, resulting in improving the degree of adhesion of the semiconductive-insulating interface layer of silicone rubber. However, the oxygen plama for 20 minute produces a damaged oxidized semiconductive silicone rubber layer, which acts as a weak layer producing a decrease in T-peel strength, These results are probably due to the modifications of surface functional groups or polar component of surface free energy of the semiconductive silicone rubber.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.18 no.4
• /
• pp.933-945
• /
• 1994

A shock-wave in a supersonic flow can be theoretically determined by a given pressure ratio at upstream and downstream flowfields, and then the obtained shock-wave is stable in its position. Under the practical situation in which the shock-wave interacts with the boundary layer along a solid wall, it cannot, however, be stable even for the given pressure ratio being independent of time and oscillates around a time-mean position. In the present study, oscillations of a weak normal shock-wave in a supersonic diffuser were measured by a Line Image Sensor(LIS), and they were compared with the data of the wall pressure fluctuations at the foot of the shock-wave interacting with the wall boundary layer. LIS was incorporated into a conventional schlieren optical system and its signal, instantaneous displacement of the interacting shock-wave, was analyzed by a statistical method. The results show that the displacement of an oscillating shock-wave increase with the upstream Mach number and the dominant frequency components of the oscillating shock-wave are below 200 Hz. Measurements indicated that shock-wave oscillations may not entirely be caused by the boundary layer separation. The statistical properties of oscillations appeared, however, to be significantly affected by shock-induced separation of turbulent boundary layer.