• 제목/요약/키워드: Wavelength conversion

검색결과 207건 처리시간 0.027초

Computer-simulation with Different Types of Bandgap Profiling for Amorphous Silicon Germanium Thin Films Solar Cells

  • 조재현;이준신
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.320-320
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    • 2014
  • Amorphous silicon alloy (a-Si) solar cells and modules have been receiving a great deal of attention as a low-cost alternate energy source for large-scale terrestrial applications. Key to the achievement of high-efficiency solar cells using the multi-junction approach is the development of high quality, low band-gap materials which can capture the low-energy photons of the solar spectrum. Several cell designs have been reported in the past where grading or buffer layers have been incorporated at the junction interface to reduce carrier recombination near the junction. We have investigated profiling the composition of the a-SiGe alloy throughout the bulk of the intrinsic material so as to have a built-in electrical field in a substantial portion of the intrinsic material. As a result, the band gap mismatch between a-Si:H and $a-Si_{1-x}Ge_x:H$ creates a barrier for carrier transport. Previous reports have proposed a graded band gap structure in the absorber layer not only effectively increases the short wavelength absorption near the p/i interface, but also enhances the hole transport near the i-n interface. Here, we modulated the GeH4 flow rate to control the band gap to be graded from 1.75 eV (a-Si:H) to 1.55 eV ($a-Si_{1-x}Ge_x:H$). The band structure in the absorber layer thus became like a U-shape in which the lowest band gap was located in the middle of the i-layer. Incorporation of this structure in the middle and top cell of the triple-cell configuration is expected to increase the conversion efficiency further.

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Characteristics of ITO/Ag-Pd-Cu/ITO Multilayer Electrodes for High Efficiency Organic Solar Cells

  • Kim, Hyo-Jung;Kang, Sin-Bi;Na, Seok-In;Kim, Han-Ki
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.257.1-257.1
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    • 2014
  • We investigated characteristics of ITO/Ag-Pd-Cu (APC)/ITO multilayer electrodes prepared by direct current magnetron sputtering for use as an anode in organic solar cells (OSCs). To optimize electrical properties of ITO/APC/ITO multilayer, we fabricated the ITO/APC/ITO multilayer at a fixed ITO thickness of 30 nm as a function of APC thickness. Compare to the surface of Ag layer on ITO, the APC had a smooth surface morphology. At optimized APC thickness of 12 nm, the ITO/APC/ITO multilayer exhibited a sheet resistance of $6{\Omega}/square$ and optical transmittance of 84.15% at a wavelength of 550 nm which is comparable to conventional ITO/Ag/ITO multilayer. However, the APC-based ITO multilayer showed a higher average transmittance in a visible region than the Ag-based ITO multilayer. The higher average transmittance of ITO/APC/ITO multilayer indicated the multilayer is suitable anode for organic solar cells with P3HT:PCBM active layer. OSCs fabricated on the optimized ITO/ACP/ITO multilayer exhibited a better performance with a fill factor of 64.815%, a short circuit current of $8.107mA/cm^2$, an open circuit voltage of 0.59 V, and power conversion efficiency (3.101%) than OSC with ITO/Ag/ITO multilayer (2.8%).

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Enhancement of Power Conversion Efficiency from Controlled Nanostructure in Polymer Bulk-Hetero Junction Solar Cells

  • Wang, Dong-Hwan;Park, O-Ok;Park, Jong-Hyeok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.76-76
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    • 2011
  • Polymer-fullerene based bulk heterojunction (BHJ) solar cells can be fabricated in large area using low-cost roll-to-roll manufacturing methods. However, because of the low mobility of the BHJ materials, there is competition between the sweep-out of the photogenerated carriers by the built-in potential and recombination within the thin BHJ film [12-15]. Useful film thicknesses are limited by recombination. Thus, there is a need to increase the absorption by the BHJ film without increasing film thickness. Metal nanoparticles exhibit localized surface plasmon resonances (LSPR) which couple strongly to the incident light. In addition, relatively large metallic nanoparticles can reflect and scatter the light and thereby increase the optical path length within the BHJ film. Thus, the addition of metal nanoparticles into BHJ films offers the possibility of enhanced absorption and correspondingly enhanced photo-generation of mobile carriers. In this work, we have demonstrated several positive effects of shape controlled Au and Ag nanoparticles in organic P3HT/PC70BM, PCDTBT/PC70BM, Si-PCPDTBT/PC70BM BHJ-based PV devices. The use of an optimized concentration of Au and Ag nanomaterials in the BHJ film increases Jsc, FF, and the IPCE. These improvements result from a combination of enhanced light absorption caused by the light scattering of the nanomaterials in an active layer. Some of the metals induce the plasmon light concentration at specific wavelength. Moreover, improved charge transport results in low series resistance.

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반응성 메조겐을 이용한 폴리머 광도파로 편광 변환기 (Integrated Optical Wave Plates Fabricated by Incorporating Reactive Mesogen in Polymer Waveguide)

  • 도현수;추우성;오민철
    • 한국광학회지
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    • 제22권5호
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    • pp.219-222
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    • 2011
  • 광도파로에 일체형으로 제작 가능한 편광 변환기는 다양한 기능의 광집적회로를 구성하기 위한 필수적인 부품이다. 반응성 메조겐은 액정디스플레이의 파장판 제작을 위하여 널리 사용되는 재료이며, 본 연구에서는 반응성 메조겐과 폴리머 광도파로를 이용하여 집적형 편광 변환기를 제작하였다. 반응성 메조겐과 액정을 혼합한 용액을 광도파로에 직교하게 형성된 홈에 삽입하고 전계를 인가하여 액정 분자를 특정 방향으로 정렬 한 뒤 UV 를 조사하여 RM 분자를 경화시켜주면 광도파로를 가로지르는 파장판을 형성할 수 있다. 파장판의 특성은 두께를 결정짓는 홈의 폭과 액정 분자의 정렬 상태 및 복굴절 크기에 의해 결정된다. 폴리머 광도파로의 중앙에 제작된 편광변환기는 1550 nm 파장에서 편광변환효율이 90 %에 이르게 됨을 확인하였다.

Bias-Dependent Photoluminescence Analysis on InGaN/GaN MQW Solar Cells

  • Shim, Jae-Phil;Jeong, Hoonil;Choi, Sang-Bae;Song, Young Ho;Jho, Young-Dahl;Lee, Dong-Seon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.347-348
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    • 2013
  • To obtain high conversion efficiency in InGaN-based solar cells, it is critical to grow high indium (In) composed InGaN layer for increasing sun light absorption wavelength rage. At present, most InGaN-based solar cells adopt InGaN/GaN multi-quantum-well (MQW) structure for high crystalline quality of InGaN with high In composition. In this study, we fabricated and compared the performances of two types of InGaN/GaN MQW solar cells which have the 15% (SC 15) and 25% (SC 25) of In composition at quantum well layer. Although both devices showed similar dark current density and leakage current, SC 15 showed better performance under AM 1.5G illumination as shown in Fig. 1. It is interesting to note that SC 25 showed severe current density decrease as increasing voltages. As a result, it lowered short circuit current density and fill factor of the device. However, SC 15 showed steady current density and over 75 % of fill factor. To investigate these differencesmore clearly, we analyzed their photoluminescence (PL) spectra under various applied voltages as shown in Fig. 2. At the same time, photocurrent, which was generated by PL excitation, was also measured as shown in Fig. 3. Further, we investigated the relationship between piezoelectric field and performance of InGaN based solar cell varying indium composition.

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다전극 DFB-LD의 광 쌍안정 특성에 관한 연구 (A Study on the Optical Bistable Characteristic of a Multi-Section DFB-LD)

  • 김근철;정영철
    • 대한전자공학회논문지SD
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    • 제39권8호
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    • pp.1-11
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    • 2002
  • 다전극 DFB-LD는 외부에서 주입되는 광의 파워에 따라서 발진하는 광출력이 쌍안정성을 보임에 따라, 이를 파장 변환에 활용하거나, 광논리 소자로 활용할 수 있는 가능성이 있다. 본 논문에서는 연산자 분리 시영역 모델을 이용하여 다전극 DFB-LD에서의 광 쌍안정 특성에 대하여 연구하였다. 다전극 DFB-LD에 불균등하게 전류를 인가하여 쌍안정 현상이 발생함을 확인하고, 흡수 영역으로 입력광을 입사하였을 때 발생하는 출력광 파워의 쌍안정 현상도 확인하였다. 그리고 수 ns의 스위칭 시간과 수 pj의 스위칭 에너지를 가진 set 또는 reset 광 펄스의 인가에 의하여 flip-flop 특성을 보임에 따라 광 메모리 소자로서의 동작도 확인하였다. 또한 캐리어 생존시간과 이득 곡선 기울기 등의 조절로서 LD 광 출력의 반응 시간을 줄일 수 있는 가능성을 확인하였다.

Green synthesis of fluorescent carbon dots from carrot juice for in vitro cellular imaging

  • Liu, Yang;Liu, Yanan;Park, Mira;Park, Soo-Jin;Zhang, Yifan;Akanda, Md Rashedunnabi;Park, Byung-Yong;Kim, Hak Yong
    • Carbon letters
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    • 제21권
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    • pp.61-67
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    • 2017
  • We report the use of carrot, a new and inexpensive biomaterial source, for preparing high quality carbon dots (CDs) instead of semi-conductive quantum dots for bioimaging application. The as-derived CDs possessing down and up-conversion photoluminescence features were obtained from carrot juice by commonly used hydrothermal treatment. The corresponding physiochemical and optical properties were investigated by electron microscopy, fluorescent spectrometry, and other spectroscopic methods. The surfaces of obtained CDs were highly covered with hydroxyl groups and nitrogen groups without further modification. The quantum yield of as-obtained CDs was as high as 5.16%. The cell viability of HaCaT cells against a purified CD aqueous solution was higher than 85% even at higher concentration ($700{\mu}g\;mL^{-1}$) after 24 h incubation. Finally, CD cultured cells exhibited distinguished blue, green, and red colors, respectively, during in vitro imaging when excited by three wavelength lasers under a confocal microscope. Offering excellent optical properties, biocompatibility, low cytotoxicity, and good cellular imaging capability, the carrot juice derived CDs are a promising candidate for biomedical applications.

전착법을 이용한 Cu2O 박막 형성 및 공정 조건에 따른 특성 변화 (Influence of Process Conditions on Properties of Cu2O Thin Films Grown by Electrodeposition)

  • 조재유;하준석;류상완;허재영
    • 마이크로전자및패키징학회지
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    • 제24권2호
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    • pp.37-41
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    • 2017
  • $Cu_2O$는 초저가 태양전지의 흡수층으로 적용될 수 있는 물질 중 하나로 direct band gap($E_g={\sim}2.1eV$)을 갖고 있으며 최대 650 nm 파장의 빛을 흡수 할 수 있는 높은 흡수율을 가지고 있다. 또한 무독성, 풍부한 매장량으로 낮은 비용 등의 여러 장점을 가지며 간단하고 저렴한 방법으로 대량으로 제작이 가능하다. 본 연구에서 Au가 증착된 $SiO_2/Si$ 기판 위에 전착법을 통해 $Cu_2O$ 박막을 제작하였다. 우리는 용액의 pH와 작업전극에 인가되는 전위, 용액의 온도와 같은 공정조건을 바꾸어주었고 최종적으로 XRD와 SEM 사진 분석을 통해 박막의 특성을 확인하였다.

Experiment of Drifting Mobilities of Holes and Electrons in Stabilized a-Se Film

  • Kang, Sang-Sik;Park, Ji-Koon;Park, Jang-Yong;Kim, Jae-Hyung;Nam, Sang-Hee
    • Transactions on Electrical and Electronic Materials
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    • 제4권6호
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    • pp.9-12
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    • 2003
  • The electrical properties of stabilized amorphous selenium typical of the material used in direct conversion x-ray imaging devices are reported. Carrier mobility was measured using time-of-flight (TOF) measurements to investigate the transport properties of holes and electrons in stabilized a-Se film. A laser beam with pulse duration of 5 ns and wavelength of 350nm was illuminated on the surface of a-Se with thickness of 400 $\mu\textrm{m}$. The photo induced signals of a-Se film as a function of time were measured. The measured transit times of hole and electron were about 8.73${\mu}\textrm{s}$ and 229.17${\mu}\textrm{s}$, respectively. The hole and electron drift mobilities decreases with increase of electric field up to 4V/$\mu\textrm{m}$. Above 4V/$\mu\textrm{m}$, the measured drift mobilities exhibited no observable dependence with respect to electric field. The experimental results showed that the hole and electron drifting mobility were 0.04584 $\textrm{cm}^2$ V$\^$-1/s$\^$-1/ sand 0.00174 $\textrm{cm}^2$V$\^$-1/s$\^$-1/ at 10 V/$\mu\textrm{m}$.

적색/청색광의 비율 및 수확 전 광질변환이 어린잎상추의 생육 및 안토시아닌 함량에 미치는 영향 (Effects of Red/Blue Light Ratio and Short-term Light Quality Conversion on Growth and Anthocyanin Contents of Baby Leaf Lettuce)

  • 이준구;오상석;차선화;장윤아;김승유;엄영철;정승룡
    • 생물환경조절학회지
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    • 제19권4호
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    • pp.351-359
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    • 2010
  • 식물공장 내 생육과 안토시아닌 함량을 동반 제고시킬 수 있는 최적 광조사 방법을 구명하고자 적색광과 청색광의 비율 및 단기간 광질변화 조건을 달리하여 어린잎 상추의 생육 및 안토시아닌 색소발현 양상을 비교 평가하였다. 적색광 단일파장에서 어린잎 상추의 생육이 가장 좋았으며 혼합광, 청색광 및 형광등의 순으로 생육이 억제되었다. 어린잎 상추의 엽내 총 안토시아닌 함량은 청색광과 적색광의 혼합광(R57-B43) 처리에 의해 적색광 단일광원 조건에 비해 4.1배, 형광등(FL) 조건에 비해 6.9배 각각 증가되었다. 청색광의 혼합비율이 43%까지 순차적으로 높아짐에 따라 생육은 억제되었으나 상대 엽록소 함량과 적색도의 발현은 크게 증가하는 경향을 보였다. 수확전 9일간 적색 단일광으로의 광질변환시 생육은 크게 증진된 반면 색소는 급격하게 소실되었으며 반대로 혼합광으로의 광질변환시에는 생육속도는 감소한 대신 안토시아닌 색소함량은 형광등과 적색광에 비해 크게 높아졌다. 따라서 수확 전의 단기간 광질변환 시 적색광의 비율이 높은 광원조건에서 생육을 촉진시킨 후 적색과 청색의 동등 혼합광원으로 변환할 경우 생산성을 유지하면서 고품질의 고색도 상추를 생산할 수 있을 것으로 판단되었다.