• 한국물환경학회지
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• 제32권6호
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• pp.628-648
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• 2016

Increased attention has been paid to the presence of veterinary antibiotics in various environmental matrices due to their toxicological behavior in the ecosystem and development of antibiotic-resistant strains of pathogenic bacteria. In the this review, 37 target antimicrobials were selected based on annual sales of antibiotics for livestock in South Korea 2014. Also, extraction and clean-up methods for the determination of the antibiotic residues in liquid samples including water, milk, and honey were comprehensively reviewed in the literature. Solid-phase extraction (SPE) was commonly used as a pre-treatment method for the samples. Most of the analytes were extracted in acidic conditions (2.5~4.0) except for aminoglycosides, which were extracted in neutral conditions (7.0~8.0). ${\beta}-Lactams$ showed the highest recoveries in neutral pH due to their degradation characteristics in acidic media. Starta-X, Oasis HLB, and Oasis MCX were frequently applied as an SPE cartridge and Oasis HLB showed the highest recoveries for the majority of antibiotic classes. The homogenized honey and milk were extracted by mixing with acids for deproteinization. Solids and other interfering substances in the extract were eliminated by centrifugation followed by membrane filtration or SPE before injection into HPLC.

• 한국물환경학회지
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• 제32권6호
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• pp.649-669
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• 2016

This study explored the analytical conditions for 21 veterinary antibiotics which have been popularly sold in South Korea in 2014 but have not yet been targeted in EPA method 1694. Most of the selected antibiotics were separated by a reverse-phase C18 column with a combination of (buffered) water and organic polar solvent, which was commonly methanol and acetonitrile in the gradient elution mode. Volatile additives such as formic acid, ammonium acetate and ammonium formate were usually added to the mobile phases to minimize asymmetrical and tailing of antibiotics' peaks and to increase their ionization in mass spectrometry. The analytical methods of aminoglycoside antibiotics were distinct from those of the other antibiotics in terms of adoption of ion-pair chromatography (IPC) and hydrophilic interaction liquid chromatography (HILIC) capable of retaining and separating extremely polar compounds due to their hydrophilicity. Trifluoroacetic acid or heptafluorobutyric acid was frequently added to the mobile phase as an ion-pair reagent for the IPC. Tandem mass spectrometry was numerously applied to the detection of antibiotics using positive electrospray ionization (ESI) and the selected reaction monitoring (SRM) mode. All reviewed analytical methods had been/were validated by evaluating recovery, limits of detection and quantification, decision limit or detection capability of the methods.

• 한국환경과학회지
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• 제28권12호
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• pp.1085-1099
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• 2019

We investigated the spatial and temporal variation in characteristics and pollution assessment of sediments in the watersheds of Andong-Dam and Imha-Dam, in Korea. Surface sediments were collected from six sites once a year for three years (2015-2017), and analyzed for organic matter (water content, IL, COD, TOC, TN, and TP), grain size, and concentration of trace metals (Al, Li, Zn, Cr, Pb, Cu, Ni, and As). Organic matter generally tended to increase, and was higher in the Andong watershed compare to Imha watershed. Surface sediments were mainly composed of silt. Coarse sediments were mainly distributed at the site adjacent to Andong-Dam, and showed fining after coarsening. Fine sediment were mainly distributed at the site adjacent to Imha-Dam, and were gradually coarsening. Concentration of trace metals generally tended to increase, and was higher for sites in watershed of Andong watershed (PLI > 1) than for sites in Imha watershed (PLI < 1). Trace metals in the study area were considered to be affected by fine sediment (silt), and contamination of trace metals was somewhat affected by Pb, and greatly affected by Zn and As.

• 한국지하수토양환경학회지:지하수토양환경
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• 제26권6호
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• pp.186-195
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• 2021

In Korea, groundwater quality is monitored through National Groundwater Quality Monitoring Network (NGQMN) administered by Ministry of Environment. For a given contaminant, compliance to groundwater quality standards is assessed on a annual basis by monitoring the number of incidents that concentration exceeds the regulatory limit. However, this approach provides only a fractional information about groundwater quality degradation, and more crucial information such as location and severity of the contamination cannot be obtained. For better groundwater quality management on a watershed, a more spatially informative and intuitive method is required. This study presents two statistical methods to convert point-wise monitoring data into information on groundwater quality status of a watershed by using a proposed grading scale. The proposed grading system is based on readily available reference standards that classify the water quality into 4 grades. The methods were evaluated with NO₃^-, Cl^-, and total coliform data in Geum River basin. The analyses revealed that groundwater in most watersheds of Geum River basin is good for domestic or/and drinking with no treatment. But, there was notable quality degradation in Bunam seawall and So-oak downstream standard watersheds contaminated by NO₃^- and Cl^-, respectively.

• 한국물환경학회지
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• 제22권5호
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• pp.807-814
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• 2006

Sapkyo Lake Watershed occupies about 19.3% of total area of Chungnam Province, and it is necessary to make a plan of counter-measure for the maintenance of public waterbody sound as well as to ensure water resources due to urbanization and industrialization in this area so densely populated and excessively developed. Conventionally water quality management has been enforced by concentration-based system which is not considered the carrying capacity of receptors, hence there are no proper measures for the prevention of an excessive pollutant load over a waterbody. So even though emission sources abide by the conventional permission regulation, then the quantity of wastewater is increased continuously and encountered water shortage to use finally. Therefore this research focused on the review of introduction of total water quality management system in Sapkyo Lake watershed to maintain public waterbody sound and to ensure water resources. By doing this research in introduction of the system in advance, it can contribute to establish the methodology on systematic water quality management. Also the application of this system in Sapkyo Lake watershed can promote the sustainable development of the area by harmonizing the environment and regional economy ultimately.

• The Korean Journal of Ecology
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• 제24권4호
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• pp.253-258
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• 2001

Land use pattern in the Wangsuk river watershed was investigated on the bases of physiognomic vegetation maps made from the aerial photograph interpretation and field check. Landscape structure was analyzed using a GIS program supported by ArcView. Landscape structure depended on the geographical position of the river, such as the upper, middle and lower river. Watersheds of the upper and middle rivers were dominated by forests composed of secondary forest and plantation. But agricultural fields dominated that of the middle and lower river. Urban area and agricultural fields increased in from the upper toward the lower river watersheds. In addition to, a transformation of agricultural pattern into an institutional agriculture was characteristic in the middle and lower river basins. Water qualities of the Wangsuk river were usually better in the order of the upper, middle, and lower river, but they were fluctuated according to the site. Such fluctuation would due to self-purification of the river and land use pattern of the watershed as the non-point source. In this viewpoint, a strategy to manage the water quality in the level of watershed is urgently required.

• 한국환경과학회지
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• 제28권1호
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• pp.37-54
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• 2019

The groundwater quality through livestock excreta survey based on "Act of the management and use of livestock excreta" was investigated by selecting sampling sites within 1 km of the farmland without considering hydrogeological units. However, these sites can be affected by various pollution sources such as chemical fertilizers and livestock excretions. Additionally, the effects of pollution sources on groundwater quality in the sites cannot be clearly distinguished from naturally occurring backgrounds. In this study, a method was developed to select the sampling sites for groundwater quality through livestock excreta survey in order to understand the effects of pollution sources especially livestock excreta. First, the concentrations of nitrate within the radius of 200 m, 300 m, 500 m and 750 m, respectively, from the farms regarded as pollution sources in hydrogeological units were compared in 2016-2017. All the nitrate concentrations at 200 - 500 m from the farms exceeded a background concentration, 13.3 mg/L. Those at 750 m and the background concentrations measured by the Ministry of Environment were comparable. Therefore, the appropriate radius was suggested as 500 m for livestock excretions survey. In this study, the areas within 500 m from the farms could be considered under the influence of livestock excretions, while those beyond 500 from the pollution sources as background in hydrogeological units. The developed method was validated by applying it to the sites selected based on both administrative divisions and watersheds for livestock excretion survey. The average densities for the developed method were 0.82 and 0.39 points/km2, respectively, which were considered as appropriate levels according to those of the European Environmental Agency.

• 한국물환경학회지
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• 제32권6호
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• pp.589-599
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• 2016

Implemented since 2004, TPLC (Total Pollution Load Control) is the most powerful water-quality protection program. Recently, uncertainty of prediction using steady state model increased due to changing water environments, and necessity of a dynamic state model, especially the watershed model, gained importance. For application of watershed model on TPLC, it needs to be feasible to adjust the relationship (mass-balance) between discharged loads estimated by technical guidance, and arrived loads based on observed data at the watershed outlet. However, at HSPF, simulation is performed as a semi-distributed model (lumped model) in a sub-basin. Therefore, if the estimated discharged loads from individual pollution source is directly entered as the point source data into the RCHRES module (without delivery ratio), the pollutant load is not reduced properly until it reaches the outlet of the sub-basin. The hypothetic RCHRES generated using the HSPF BMP Reach Toolkit was applied to solve this problem (although this is not the original application of Reach Toolkit). It was observed that the impact of discharged load according to spatial distribution of pollution sources in a sub-basin, could be expressed by multi-segmentation of the hypothetical RCHRES. Thus, the discharged pollutant load could be adjusted easily by modification of the infiltration rate or characteristics of flow control devices.

• 환경영향평가
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• 제17권4호
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• pp.235-242
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• 2008

To develop a watershed management plan for protection of the lake water quality, the linkages among land use activities, stream water quality, and lake water quality must be understood. This study conducted to develop a Decision Support System(DSS) for the reservoir water quality managers and a comprehensive watershed management plan. This DSS has three main components; database, interactive decision model, and data delivery interface system. Graphic User Interface(GUI) was developed as the interface medium to deliver the data and modeling results to the end users. Water quality management scenarios in Yongdam reservoir consist of two parts. One is the watershed management, and the other is water quality management in the reservoir. The watershed management scenarios that were evaluated include as follows : a removal of point sources, control of waste water treatment plant, reductions in nonpoint sources, and the management of developed land. Water quality management scenarios in the reservoir include to install a curtain wall and to operate an algae removal system. The results from the scenario analysis indicate that the strategy of the reservoir water quality management can promise the best effectiveness to conserve the quality of reservoir water. It is expected that many local agencies can use this DSS to analyze the impact of landuse changes and activities on the reservoir watershed and can benefit from making watershed management decisions.

• 환경정책연구
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• 제7권3호
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• pp.121-140
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• 2008

불투수면 비율은 유역의 건전성 정도를 나타내는 중요한 척도로 활용되고 있으며 특히 유역의 수환경 특성을 파악하는 모델에서 이용되어 왔다. 불투수면은 총불투수면과 유효불투수면의 두 가지 있으며, 이들은 각 유역의 토지이용 특성에 따라 그 구성이 다양하다. 이중 총 불투수면은 기존의 토지이용도나 토지피복도를 사용하여 손쉽게 구할 수 있는 반면 유효불투수면은 물 흐름을 필지별로 파악하여야 하기 때문에 산정에 많은 노력과 비용이 소요된다. 본 연구에서는 우리나라 사례지역에 대해 총불투수면과 유효불투수면을 산정하여 그 특성을 상호 비교해 보고 유역관리에 있어 유효 및 총 불투수면 비율의 적용방안을 모색하고자 하였다. 사례지역 분석결과 유효불투수면 면적은 39.7%로 총 불투수면 면적 43%에 비해 약 3%적었다. 불투수면이 수환경에 미치는 영향을 분석하기 위한 기초 자료로 활용하기 위함임을 고려할 때 비용과 시간적 측면에서 볼 때 총불투수면을 유역의 대표적인 불투수면 비율로 사용할 수 있을 것으로 판단된다.