• Journal of Korean Society of Environmental Engineers
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• v.33 no.3
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• pp.202-211
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• 2011

In this study the seasonal and spatial pattern of mercury (Hg) concentrations in multimedia environments were investigated in Lake So-Yang. Total mercury (TM) in water column greatly enhanced as turbidity and particulate organic carbon (POC) increased due to the severe runoff, suggesting that most of Hg existed as particulate Hg in Lake Soyang. We also collected 22 species of fish in Lake Soyang and Han River, and the average total mercury in fish was 0.073 ppm, lower than both Korean (0.5 ppm) and EPA criteria (0.3 ppm). However when considering the amount of fish intake for Korean the Hg criterion in fish must be more stringent than current value, and the advisory for fish consumption should be made. Hg in fish considerably varied with sampling sites, having the highest in the upper region (Yang-gu) and the lowest in downstream (Han River). This spatial variation was possibly derived by "bloom dilution" associated with high phosphorus loading or elevated DOC concentrations, or both. Total mercury in sediment varied from 69.9 to $98.3{\mu}g/kg$, which was relatively lower than those measured in Voyageurs National Park in Minnesota in USA ($102{\sim}364{\mu}g/kg$).

• The Journal of Engineering Geology
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• v.14 no.3 s.40
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• pp.259-272
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• 2004

The purpose of this study is to investigate the effect of hydrochemical variation of groundwater on the gas tigtness in an unlined oil storage cavern. The groundwater chemistry is greatly influenced by the seawater mixing, the water curtain and the dissolution of grounting cements. The chemical composition of groundwater greatly varies ac-cording to both the location of monitoring wells and the sampling period. Most of groundwater shows alkaline pH and high electrical conductivity. The chemical types of groundwater show the dominant order as follows : Na-Cl type > Ca-Cl type > $Ca-HCO_3(CO_3)$ type. Thermodynamic equilibrium state between chemical composition of groundwater and major minerals indicates that carbonate minerals except clay minerals can be precipitated as a secondary mineral. It means that the secondary precipitates can not greatly exerts the clogging effect into fracture aperture in rock mass around oil storage cavern. The content of total organic carbon (TOC) shows a slightly increasing trend from initial stage to late stage. The $EpCO_2$ was computed so as to assess the gas contribution on the $CO_2$ in groundwater. The $EpCO_2$ of 0$\~$41.3 indicates that the contribution of oil gas on $CO_2$ pressure in groundwater system can be neglected.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.6
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• pp.675-687
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• 2005

In this study, the cyclone/denuder/filter pack sampling system was used to measure the daily concentrations of water soluble inorganic compounds of fine ($D_{p}< 2.5\;{\mu}m$) and coarse ($D_{p}<10{\mu}m$m) size fractions of aerosol and related gases at Gosan super site during ABC-EAREX 2005. The mean concentrations for $HNO_{3},\;HNO_{2},\;NH_{3}$, were 0.39, 0.08, and $0.29\;{\mu}g/m^3$. respectively. Average concentrations of sulfate, nitrate, and ammonium in $PM_{2.5}$ were 3.39, 1.06, and $1.04\;{\mu}g/m^3$, which occupied about $26\%$ of total $PM_{2.5}$ mass. In particular, more than half of these ionic species were found in size of less than $2.5\;{\mu}m$. Gas phase nitric acid concentrations have shown high correlation coefficient with $HNO_{2}$(R=0.80) and $O_{3}$(R=0.78), implying the active photochemical reactions from its precursors. Equivalent molar ratios between major ion components, $NH_{4}\;^{+}/nss\;SO_4\;^{2-},(0.83\;for\;PM_{2.5},\;0.86\;for\;PM_{10})$, revealed that the existing forms of the secondary aerosols were probably $(NH_{4})_{2}SO_{4}\;and\;(NH_{4})_{3}H\;(SO_{4})_{2}$. Especially, $(NH_{4}\;^{+}+K^{+}+Ca^{2+}+Mg^{2+})/(NO_{3}\;^{-}+nss\;SO_{4}\;^{2-}) (0.99\;for\;PM_{2.5},\;1.05\;for\;PM_{10})$ indicated that some of them existed not only as $NH_{4}NO_{3}$ but also as $CaSO_{4}\;or\;KNO_{3}$, which pointed out the probability of influences from the abundant soil components during Asian dust (AD) periods. These neutralized types of secondary aerosols showed that pollutants could be aged and transported from a distance.

• Asian-Australasian Journal of Animal Sciences
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• v.28 no.9
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• pp.1303-1308
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• 2015

This study was conducted to investigate changes in blood enzyme parameters and to evaluate the relationship between insulin-like growth factor-1 (IGF-1), antler growth and body weight during the antler growth of sika deer (Cervus nippon). Serum enzyme activity and IGF-1 concentrations were measured in blood samples collected from the jugular and femoral veins at regular intervals during the antler growth period. Blood samples were taken in the morning from fasted stags (n = 12) which were healthy and showed no clinical signs of disease. Alfalfa was available ad libitum and concentrates were given at 1% of body weight to all stags. The experimental diet was provided at 9 am with water available at all times. There were no significant differences in alkaline phosphatase, aspartate aminotransferase, and alanine aminotransferase during antler growth, but alkaline phosphatase concentrations increased with antler growth progression, and the highest alkaline phosphatase concentration was obtained 55 days after antler casting. Serum IGF-1 concentrations measured from blood samples taken from the jugular vein during antler growth, determined that levels of IGF-1 was associated with body weight and antler growth patterns. Serum IGF-1 concentrations were higher at the antler cutting date than other sampling dates. Antler length increased significantly during antler growth (p<0.001), and there was a similar trend to between right and left beams. Body weight increased with antler growth but was not significant. Consequently it appeared that serum alkaline phosphatase concentration was related to antler growth and both antler growth and body weight were associated positively with IGF-1 concentrations during antler growth.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.25 no.2
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• pp.115-132
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• 1992

This study was conducted to clarify the distribution pattern of macrobenthic soft-bottom dwelling animals near the shellfish farming ground in Chinhae Bay, Korea Sampling was seasonally performed with van Veen grab$(0.1m^2)$ from October 1990 to July 1991. Benthic animals collected during the study comprised 107 species which amounted to 6,978 individuals: 52 species from polychaetes$(48.6\%)$, 34 species from crustaceans$(31.8\%),$ 14 species from molluscs$(13.1\%)$ and 7 species from other faunal groups$(6.5\%)$. The dominant species were four polychaetes and one amphipod: Lumbrineis longifolia, Capitella capitate, Mediomastus sp., Sigambra tentaculata and Erictonius pugnax. The study area could be divided into 3 regions based on the faunal similarity which was closely related to the content of organic matter in the surface sediment. The benthic community located near the shellfish farming ground showed large spatial and seasonal variations in species diversity and evenness in contrast to the stable values off the farming area. The oxygen deficient water mass below 2 ml/l In thi bottom layer during the summer stressed and depauperated the benthic community in the autumn of 1990. However, the benthic community did recover during the winter. It is postulated that the cyclic phenomenon of summer mortality followed by winter recovery may be a common characteristic in benthic communities subjected to a high level of organic pollution.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.17 no.6
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• pp.529-535
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• 1984

This study aims at obtaining the basic data for the development of pen shell culture at Yoja Bay, the southwest coast of Korea. The authors dealt with the annual gonadal changes of the pen shell, Atrina pectinata japonica, to find out the gametogenesis, reproductive cycle and spawning season, and to investigate the fluctuation in the larval occurence in Yoja Bay. From July 1983 to June 1984, an average of 20 individuals as specimens were monthly collected by commercial fishing dredge near Manwol island located at the mouth of Yoja Bay. The degree of gonadal development was determined by the histological observations as resting spent stage, early developmental stage, after developmental stage, early spawning stage, after spawning stage and degenerative stage. According to these degrees of gonadal development, annual reproductive cycle of the pen shell population was determined. From July to August, the gonads were changed through degenerative into resting stage and, in September and October, they became entirely empty gonads. From November they showed the first sign of gametogenesis developing very slowly. Nevertheless, the developing gametes did not increase in number probably owing to a phagocytic phenomenon by phagocytes which appeared in the gonad during this stage. Some individuals started spawning in April and in May majarity of individuals were in spawning stage. In June, majority of the individuals showed signs of degenerative stage. Therefore, the authors came to a conclusion that the pen shells in Yoja Bay spawn chiefly in May. And this is also supported by the result of the survey on the planktonic occurrences of the pen shell larvae. Namely, there were no larvae at all in April, only a few in May and many in June by vertical water sampling.

• The Korean Journal of Malacology
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• v.27 no.4
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• pp.291-297
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• 2011

In an attempt to improve the substrate condition for Manila clam (Ruditapes philippinarum) culture, crushed oyster (Crassostrea gigas) shells were spread on the muddy tidal flat of Namseong-ri, Podu-myeon, Goheung-gun, Jeollannam-do in April 2008. To test the suitability of the crushed oyster shell added substrate, seed clams were transplanted from Taehwa river estuary in Ulsan city in June 2008. Over 23 months of sampling, the mean grain size and the sorting in the experimental site containing the crushed oyster shell were significantly higher than the control site. The ignition loss, water content, chemical oxygen demand (COD) and acid-volatile sulfide (AVS) level were also significantly higher in the crushed oyste shell added substratum. Survival of the clams transplanted to the crushed oyster shell added substratum was significantly higher and all the clams transplanted to the normal muddy substratum died in August 2009, 13 months after the transplantation. At the end of the experiment in April 2010, the transplanted clams reached 36.10 mm in shell length and 8.92 g in total weight with survival of 43.5%. Our study suggested than crushed oyster shell added in the mud dominant substratum greatly improved living condition and survivability of clams.

• Microbiology and Biotechnology Letters
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• v.31 no.2
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• pp.177-181
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• 2003

Eleven bacterial strains which are able to utilize terephthalic acid as a carbon and an energy source for growth were isolated from the soil of 7 water quality evaluation points in Kyonggi area of Korea. Phthalic acid isomer degrading activity of the isolates from the 4 contaminated points was higher than those from the 3 clean points. Among 11 isolates, 4 isolates which have high terephthalic acid degrading activity and degrade two phthalic acid isomers were identified by partal 16S rDNA sequence determination. One of them was identified as Pseudomonas putida, and the others as Comamonas testosteroni. Thus a large number of phthalic acid isomer degrading bacteria in domestic soil were inferred as C. testosteroni. On the basis of these results, the PCR detection of C. testosteroni in soil was applied to monitor soil contamination by phthalic acid isomers. The DNA of C. test-osteroni extracted from 4 g soil was directly detected by PCR with C. testosteroni specific primer pair. The amount of PCR products was different according to sampling sites and more PCR products were obtained from contaminated sites than those from clean sites (Gulpo-chun＞Anyang-chun＞Hwangguji-chun>Shin-chun＞Huk-chun＞Pukhan-river>Kapyeong-chun). This result was coincided with that of the viable cell counts for terephthalic acid degrading bacteria.

• Journal of Korean Society for Atmospheric Environment
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• v.27 no.3
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• pp.313-325
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• 2011

From October 2009 to June 2010, major greenhouse gases (GHG: $N_2O$, $CH_4$, $CO_2$) soil emission were measured from upland cabbage field at Kunsan ($35^{\circ}$56'23"N, $126^{\circ}$43'14"E), Korea by using closed static chamber method. The measurements were conducted mostly from 10:00 to 18:00LST during field experiment days (total 28 days). After analyzing GHG concentrations inside of flux chamber by using a GC equipped with a methanizer (Varian CP3800), the GHG fluxes were calculated from a linear regression of the changes in the concentrations with time. Soil parameters (e.g. soil moisture, temperature, pH, organic C, soil N) were also measured at the sampling site. The average soil pH and soil moisture were ~pH $5.42{\pm}0.03$ and $70.0{\pm}1.8$ %WFPS (water filled pore space), respectively. The ranges of GHG flux during the experimental period were $0.08\sim8.40\;mg/m^2{\cdot}hr$ for $N_2O$, $-92.96\sim139.38mg/m^2{\cdot}hr$ for $CO_2$, and $-0.09\sim0.05mg/m^2{\cdot}hr$ for $CH_4$, respectively. It revealed that monthly means of $CO_2$ and $CH_4$ flux during October (fall) were positive and significantly higher than those (negative value) during January (winter) when subsoil have low temperature and relatively high moisture due to snow during the winter measurement period. Soil mean temperature and moisture during these months were $17.5{\pm}1.2^{\circ}C$, $45.7{\pm}8.2$%WFPS for October; and $1.4{\pm}1.3^{\circ}C$, $89.9{\pm}8.8$ %WFPS for January. It may indicate that soil temperature and moisture have significant role in determining whether the $CO_2$ and $CH_4$ emission or uptake take place. Low temperature and high moisture above a certain optimum level during winter could weaken microbial activity and the gas diffusion in soil matrix, and then make soil GHG emission to the atmosphere decrease. Other soil parameters were also discussed with respect to GHG emissions. Both positive and negative gas fluxes in $CH_4$ and $CO_2$ were observed during these measurements, but not for $N_2O$. It is likely that $CH_4$ and $CO_2$ gases emanated from soil surface or up taken by the soil depending on other factors such as background concentrations and physicochemical soil conditions.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.6
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• pp.616-625
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• 2017

Measurements using five real-time particle samplers were compared to measurements using three NRM (National Reference Method system) filter-based samplers(Gravimetric method) at Incheon, Korea, between May and August, 2014. The purpose of this study was to suggest the quality assurance/quality control (QA/QC) method of each instrument for use in a real-time continuous particle sampler to measure the mass of airborne particles with an aerodynamic diameter less than $2.5{\mu}m$ ($PM_{2.5}$). Five real-time particle samplers of BAM1020, FH62C_14, TEOM, PM-711 and SPM-613 were evaluated by comparing its measured 23 hr average $PM_{2.5}$ concentrations with those measured with NRM filter-based samplers simultaneously. The parameters(e.g. Inlet heating condition, Slope factor, Film response, Intercept, Background, Span value) of the real-time samplers were optimized respectively by conducting test performance evaluation during 7 days in field sampling. For example, inlet heating temperature of TEOM sampler controls $35{\sim}40^{\circ}C$ to minimize the fluctuation of the real-time measurement data and background value of BAM1020 is the key factor affecting the accuracy of $PM_{2.5}$ mass concentration. We classified the $PM_{2.5}$ concentration according to relative humidity (80%) to identify water absorbed in aerosols by measuring the ${\beta}$-ray samplers(BAM1020, FH62C_14) and TEOM. ${\beta}$-ray samplers were not strongly affected by relative humidity that the difference of the average $PM_{2.5}$ concentration was about 5%. On the other hand, The TEOM sampler overestimated $PM_{2.5}$ mass concentration about 15% at low relative humidity (<80%).