• Title/Summary/Keyword: Water resistance.

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Synthesis and Characterization of Acrylic-Modified Water-Reducible Alkyd Resin 2. Modification by MA and TMPTA Graft Copolymerization (수용성 아크릴 변성 알키드 수지의 합성과 물성 2. MA 및 TMPTA 공중합체에 의한 변성)

  • Cho, Young-Ho;Kang, Ki-Joon;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.698-705
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    • 1994
  • The basic medium oil modified alkyd resin was synthesized from linseed oil fatty acid(LOFA), phthalic anhydride(PAA), maleic anhydride(MA) and trimethylol propane(TMP) by condensation polymerization at $230^{\circ}C$. MA/TMPTA modified water-reducible alkyd resins were synthesized with TMPTA graft copolymerization onto the basic resin at $180^{\circ}C$. Acid value of the resin was controlled by the addition amount of MA and N,N-dimethylethanol amine(DMEA) was used as a neutralizing agent to prepare of the water-reducible alkyd resin. The effect of TMPTA on the graft copolymerization of the resin was studied by measuring molecular weight glass transition temperature(Tg), viscosity, graft efficiency, and gel contents of melanin cured film. Heat resistance, UV resistance and water resistance of cured film of MA/TMPTA modified resin was compared to those of TMA/TMPTA modified alkyd resin. The molecular weight, viscosity gel contents and graft efficiency of water reducible alkyd resin were increased according to the TMPTA graft copolymerization, but Tg was decreased. The viscosity was lower when the solid contents reached 40% than that of 30% content and also and also became lower with the extent of neutralization ratio, The heat resistance, UV resistance and water resistance of the MA/TMPTA modified alkyd resis were better than those of TMA/TMPTA modified alkyd resin but the storage stability of the TMA/TMPTA alkyd resis was better than that of MA/TMPTA modified alkyd resin.

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The Development of Water-Soluble Black Coloring Agent and Its Application (수용성 흑색 착색제의 개발과 이의 응용)

  • Kim, M.G.;Jung, B.H.;Moon, M.J.;Kim, S.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.5
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    • pp.213-218
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    • 2002
  • In order to develop the economic and environmental water-soluble black coloring agent, some adequate chemical mixtures were mixed and this solution was applied to coat quenched and tempered 51B20 steel bolt. Some basic properties of the solution and characteristics of the coated film in addition to the corrosion resistance were investigated. The developed 100 kg of water-soluble black coloring agent solution was a chemical mixture consisted of 10 kg of aqueous coloring agent, 40 kg of surface active agent, 0.3 kg of anti-foam agent and $50{\ell}$ of water. The coated film of the bolt was composed of hard layer of about $2{\mu}m$ and the disbondable soft layer of about $4{\mu}m$ above the hard layer. Many surface active agents peaks and a few hydrophilic peaks were observed in the coated film. Surface roughness value of the coated bolt was lower than that of the non-coated bolt. Corrosion resistance of the coated bolt considerably improved and also relatively showed a good polarization resistance at test condition of $40^{\circ}C$ colorizing temperature and 5% the solution concentration in 3% NaCl anodic polarization test. Initial appearance time of the surface rust was greatly retarded owing to the coated film in salt spray test.

Changes in the Process Efficiency and Product Properties of Pulp Mold by the Application of Oil Palm EFB (오일팜 EFB 섬유 적용에 따른 펄프몰드 공정효율 및 제품품질 변화)

  • Kim, Dong-Seop;Sung, Yong Joo;Kim, Chul-Hwan;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.67-74
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    • 2016
  • The demand of environmental friendly packaging materials such as pulp mold has been increased. The application of the oil palm biomass, EFB (Empty Fruit Bunch) fiber as natural raw materials to the pulp mold could increase the usability of the pulp mold by the reduced production cost brought from the relatively low cost of EFB. The effects of the EFB(Empty Fruit Bunch) fibers on the properties of pulp mold and on the process efficiency were evaluated in this study. The pulp mold samples were prepared with mixture ONP (Old news paper) and EFB by using laboratory wet pulp molder. The changes in the drying efficiency were measured with the changes in the solid contents of pulp mold samples during drying process. The efficiency of the surface coating treatment on the pulp mold depending on the condition of the pulp mold samples were also evaluated in order to improve the water resistance properties of pulp mold. The addition of EFB increased the drying efficiency by providing the bulkier structure and the higher water contact angle, which indicated the better water resistance properties. The water resistance were improved by the surface coating treatments and the application of surface coating on the pulp mold at the higher moisture contents resulted in the higher improvement in the water resistance. The bulkier structure originated from the application of EFB fiber reduced the effects of the surface coating, which could be overcome by the control of surface coating process.

Vacuum Pressure Treatment of Water-Soluble Melamine Resin Impregnation for Improvement of Mechanical Property, Abrasion Resistance and Incombustibility on Softwood (목재의 기계적 성질, 내마모성 및 난연성 개선을 위한 진공가압 멜라민 수지함침처리)

  • Oh, Seung-Won;Park, Hee Jun
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.6
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    • pp.792-797
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    • 2015
  • In this study, three softwood species were treated with water-soluble melamine resin by different concentration and treatment time under vacuum pressure for improving mechanical property, abrasion resistance, and incombustibility. After the treatment, a compreg was manufactured and then evaluated on physical properties. Additionally, incombustibility of compreg was determined by comparing with a wood that was treated by spraying a water-soluble fire retardant on surface. As concentration of resin increased, bending strength and Brinell hardness increased as well as abrasion resistance, but there was no correlation on treatment and mechanical properties by treatment time. The wood impregnated by water-soluble melamine resin under vacuum pressure showed better incombustibility than that of a water-soluble fire retardant sprayed wood. Therefore, this treatment could be used for improving incombustibility of wood.

Effects of Treatment of Cellulase and Alkali on Physical Properties and Dyeability of Ramie/Man-Made Fiber Mixture Fabrics (셀룰라아제와 알칼리 처리에 의한 저마/인조섬유 교직물의 물성과 염색성 변화)

  • 김순심;최종명
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.5
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    • pp.891-900
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    • 2001
  • The purpose of this study were to evaluate the physical properties and dyeability of cellulase and alkali(NaOH, KOH) treated ramie/man-made fiber mixture fabrics. The mixture fabrics were plain weave made by rayon and polyester fiber as warp yarn, and ramie as weft yarn. The crease resistance, drape, tensile strength, and water absorbancy were measured for test fabrics. The K/S value of dyed fabrics were calculated using color difference meter. Also colorfastness to washing and sunlight of dyed fabrics were evaluated. The results obtained from this study were as follows: Thickness and weight per unit area of alkali treated two mixture fabrics(rayon/ramie, polyester/ramie) increased compared to those of untreated fabrics, but cellulase treated fabrics did not changed a little. And alkali treated rayon/ramie mixture fabrics showed more change than polyester/ramie mixture fabrics on the thickness and weight. Tensile strength and water absorbancy of cellulase treated fabrics decreased compared to those of untreated, but crease resistance increased. Crease resistance, tensile strength(warp direction), water absorbancy and drape of NaOH treated rayon/ramie mixture fabrics decreased compared to those of untreated, but tensile strength(weft direction) increased. Water absorbancy and drape of NaOH treated polyester/ramie mixture fabrics decreased compared to those of untreated, but crease resistance and tensile strength(weft direction) increased. Tensile strength of KOH treated two mixture fabrics increased compared to that of untreated, but water absorbancy and drape decreased. Total hand of cellulase and alkali treated rayon/ramie mixture fabrics was improved compared to untreated. Dyeability of treated mixture fabrics was increased compared to untreated.

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Fundamental Study for Predicting Ship Resistance Performance Due to Changes in Water Temperature and Salinity in Korea Straits (대한해협에서의 수온 및 염도변화를 고려한 선박의 저항성능 예측을 위한 기초 연구)

  • Seok, Jun;Jin, Song-Han;Park, Jong-Chun;Shin, Myung-Soo;Kim, Sung-Yong
    • Journal of Ocean Engineering and Technology
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    • v.29 no.6
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    • pp.418-426
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    • 2015
  • Recently, shipping operators have been making efforts to reduce the fuel cost in various ways, such as trim optimization and bulb re-design. Furthermore, IMO restricts the hydro-dioxide emissions to the environment based on the EEDI (Energy Efficiency Design Index), EEOI (Energy Efficiency Operational Indicator), and SEEMP (Ship Energy Efficiency Management Plan). In particular, ship speed is one of the most important factors for calculating the EEDI, which is based on methods suggested by ITTC (International Towing Tank Conference) or ISO (International Standardization Organization). Many shipbuilding companies in Korea have carried out speed trials around the Korea Straits. However, the conditions for these speed trials have not been exactly the same as those for model tests. Therefore, a ship’s speed is corrected by measured environmental data such as the seawater temperature, density, wind, waves, swell, drift, and rudder angle to match the conditions of the model tests. In this study, fundamental research was performed to evaluate the ship resistance performance due to changes in the water temperature and salinity, comparing the ISO method and numerical simulation. A numerical simulation of a KCS (KRISO Container ship) with a free-surface was performed using the commercial software Star-CCM+ under three conditions that were assumed based on the water temperature and salinity data in the Korea Straits. In the simulation results, the resistance increased under low water temperature & high salinity conditions, and it decreased under high water temperature & low salinity conditions. In addition, the ISO method showed the same result as the simulation.

Effect of the Antler (Deer Horn) Water Extract on the Stress Resistance in Mice (녹용수침액(鹿茸水浸液)이 Mouse의 Stress 방어작용에 미치는 영향(影響))

  • Ko, Geun-Il
    • Journal of Pharmaceutical Investigation
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    • v.11 no.2
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    • pp.11-15
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    • 1981
  • Antler, deer horn, occupies a particular place in oriental folk medicine as so called tonic remedy. In order to study on the effects of Antler water extract on stress resistance in mice, quantitative response was measured for the change of spontaneous activity by chemical stress drugs in the control group or the Antler water extract pretreated group. Spontaneous activity in mice was measured by counting the number of interruptions of light. The results of experiment were summerized as follows; I) In case of administrating Antler water extract 10mg/kg, 20mg/kg, 50mg/kg, and 100mg/kg, no significant change was observed in spontaneous activity in comparison with the control group. II) In case of administrating Antler water extract for 5 days or 10 days, no significant change was observed in spontaneous activity by chemical stress drugs, caffein and chloropromazine, in comparison with the control group.

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A Study on Waterproofing and Anticorosive Performance Evaluation of Surface treatment material used wi th Glass Fiber, Inorganic and Organic Material for Water Tank (수조구조물의 방수.방식 공사용 유기.무기 소재 및 섬유보강형 바탕처리재의 성능평가에 관한 연구)

  • 오상근;박봉규;주웅일;박성진
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2001.11a
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    • pp.70-75
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    • 2001
  • There is a problem to be solved for improvement of durability and safety for concrete When the waterproofing and anticorrosive work of main concrete are design, the material a of construction need to be correctly applied to appropriate circumstance conditions. Epoxy mostly been used for concrete water tank structure. Lately, lots of subjects on adaption res in mortar for waterproofing and anticorrosive are under discussion. Then, we attempt to approach by evaluating and comparing every capabilities with waterproofing materials in this experiment. Capability evaluation items include the bond age and curing conditions, the bond strength after accelerated weathering test and fret impact resistance, a mount of water, seepage quan Through the experiment analysis, we found that waterproofingtity, drinking water chemicals resistance. and anticorrosive resin mortar used with glass fiber cloth, inorgar material is dominantly superior to other waterproofing materials. According to this paper, we suggest the resin mortar as a new surface treatment material water tank structure.

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A Study on the Freeze-Thaw Resistance of Water-permeable Concretes (투수성 콘크리트의 동결융해 저항성에 관한 연구)

  • 은재기;김완기;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.433-438
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    • 2000
  • The purpose of this study is to examine the resistance of water-permeable concretes to freezing and thawing action. The water-permeable concretes with cement-aggregate ratio of 1:5.5(by weight) and two kinds of admixture content [SP : superplasticizer(0, 1.0%), HPAE : high performance air entraining agent(0.5, 1%)] used OPC(ordinary portland cement) as binder were prepared, and then tested for relative dynamic modulus of elasiticity, mass change, length change and durablity factor. It's been concluded from the test results that the superior relative dynamic modulus of elasiticity and durability factor of water-permeable concretes were obtained at superplaciticizer 1.0% after 300 cycles. The water-permeable concretes used superplasiticizer 1.0% having relative durability factor of 88% after 300 cycles.

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To examine the construction plan of the lightening rod equipment for the intake tower of D-dam (D댐의 취수탑 피뢰설비 구축방안 검토)

  • Hong, Sung-Taek;Lee, Eun-Chun;Shin, Gang-Wook;Lee, Nam-Young
    • Proceedings of the KIEE Conference
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    • 2003.07a
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    • pp.290-292
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    • 2003
  • The intake tower of D-dam located in a mountainous area positioned in the left side of the dam and its structure installed alone on the water surface then, can become target of direct lightening. To protect the intake tower from the direct lightening and indirect-lightening, lightening rod installed in the top area of the intake tower and ground pole laid under the surrounding ground. however, because the surrounding ground almost consists of a rock, it is very difficult to obtain the grounding resistance. It is main object to examine the construction plan of the optimum lightening rod equipment and ground pole with measuring the earth specific resistance of the around of the intake tower which is the scheduled area to lay the ground pole with the Wenner's 4-electric pole method and the Schlumberger's method. and using the analysis tool, ESII.

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