• Title/Summary/Keyword: Water quenching

Search Result 217, Processing Time 0.025 seconds

Solubilization by $\beta$-Cyclodextrin: A Fluorescence Quenching Study

  • Panda, M.;Mishra, A.K.
    • Journal of Photoscience
    • /
    • v.9 no.3
    • /
    • pp.75-79
    • /
    • 2002
  • Solubility of carbon tetrachloride ($CCl_4$) in water increases appreciably in presence of $\beta$-cyclodextrin ($\beta$CD). $CCl_4$ is a very good quencher of 1-naphthol (1ROH) fluorescence. By studying the quenching of fluorescence of 1ROH included in $\beta$CD cavity, it was found that there is an increase in the availability of $CCl_4$ around $\beta$CD in the aqueous medium. This could help to rationalize the enhanced solubility of $CCl_4$.

  • PDF

A Study on the Film Boiling-Quenching Process of the Hot Surface for the Heat Treatment of Metals (1st Report, Cooling Curves and Transient Boiling Heat Transfer during the Quenching Process of Carbon Steel) (金屬熱處理를 위한 高溫面의 膜沸騰急冷却에 관한 硏究 (第1報, 炭素鋼 켄칭 過程의 冷却曲線과 過渡沸騰熱傳達))

  • Yun, Seok-Hun;Hong, Yeong-Pyo;Kim, Gyeong-Geun;Jeong, Dae-In
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.15 no.3
    • /
    • pp.57-65
    • /
    • 1991
  • The quenching of steels by water is one of the important problems in engineering for the applications of heat treatment or continuous casting process, but the fundamental researches by the theoretical approaches have not been satisfactorily improved yet. The very rapid cooling problems by the thermal conduction including the latent heat of phase transformation in steel and the transient boiling heat transfer of water on the surface of the steel covering from $850^{\circ}C$ to $20^{\circ}C$ are the key problems of heat treatment. The present quenching experiments are performed for the cylindrical specimens of carbon steel, S45C of diameters (12-30). Nonlinear transient heat conduction and transient boiling heat transfer problem of water on the surface of specimens is analyzed by the numerical method of inverse heat conduction problem. The conditions for the calculation are that the initial temperature of specimens is $820^{\circ}C$ and the cooling water in bath are $20^{\circ}C$,$40^{\circ}C$,$60^{\circ}C$,$80^{\circ}C$,$95^{\circ}C$ with no agitation.

  • PDF

Development of High-Temperature Heat Flux Gauge for Steel Quenching (강재 급속냉각용 고온 열유속게이지 개발)

  • Lee, Jungho
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.23 no.6
    • /
    • pp.323-330
    • /
    • 2010
  • The present study was motivated by increasing demands on quantitative measurements of the heat flux through the water cooling and quenching process of hot steel. The local heat flux measurements are employed by a novel experimental technique that has a function of high-temperature heat flux gauge in which test block assemblies are directly used to measure the heat flux variation during water cooling and quenching of hot steel. The heat flux can be directly achieved by Fourier's law and is also compared with numerical estimation which is solved by inverse heat conduction problem (IHCP). The high-temperature heat flux gauge developed in this study can be applicable to measure cooling rate and history during the actual cooling applications of steelmaking process. In addition, the measurement uncertainty of heat flux is calculated by a quantitative uncertainty analysis which is based on the ANSI/ASME PTC 19.1-2005 standard.

Removal of residual ozone in drinking water treatment using hydrogen peroxide and sodium thiosulfate (과산화수소와 티오황산나트륨을 이용한 정수처리공정에서의 잔류오존 제거)

  • Kwon, Minhwan;Kim, Seohee;Ahn, Yongtae;Jung, Youmi;Joe, Woo-Hyun;Lee, Kyunghyuk;Kang, Joon-Wun
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.29 no.4
    • /
    • pp.481-491
    • /
    • 2015
  • The aim of this study was to evaluate the chemical quenching system for residual ozone and to determine the operating condition for the quenching system. Hydrogen peroxide ($H_2O_2$) and sodium thiosulfate ($Na_2S_2O_3$) were investigated as quenching reagents for ozone removal, and the tendency of each chemical was notably different. In the case of $H_2O_2$, the degradation rate of ozone was increased as the concentration of $H_2O_2$ increase, and temperature and pH value have a significant effect on the degradation rate of ozone. On the other hand, the degradation rate of ozone was not affected by the concentration of $Na_2S_2O_3$, temperature and pH value, due to the high reactivity between the ${S_2O_3}^{2-}$ and ozone. This study evaluates the decomposition mechanism of ozone by $H_2O_2$ and $Na_2S_2O_3$ with consideration for the water quality and reaction time. Furthermore, the removal test for the quenching reagents, which can be remained after reaction with ozone, was conducted by GAC process.

Fluorescence Quenching of Norfloxacin by Divalent Transition Metal Cations

  • Park, Hyoung-Ryun;Seo, Jung-Ja;Shin, Sung-Chul;Lee, Hyeong-Su;Bark, Ki-Min
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.9
    • /
    • pp.1573-1578
    • /
    • 2007
  • Fluorescence quenching of norfloxacin (NOR) by Cu2+, Ni2+, Co2+ and Mn2+ was studied in water. The change in the fluorescence intensity and lifetime was measured as a function of quencher concentration at various temperatures. According to the Stern-Volmer plots, the NOR was quenched both by collisions and complex formation with the same quencher. However, the static quenching had a more important effect on the emission. Large static and dynamic quenching constants support significant ion-dipole and orbital-orbital interactions between NOR and cations. The both quenching constants by Cu2+ were the largest among quenchers. Also, quenching mechanism of Cu2+ was somewhat different. The change in the absorption spectra due to the quencher provided information on static quenching. The fluorescence of NOR was relatively insensitive to both the dynamic and static quenching compared with other quinolone antibiotics. This property can be explained by the twisted intramolecular charge transfer.

A Study on Temperature Measurement for Quenching of Carbon Steel (탄소강 담금질 공정의 온도 측정방법에 대한 고찰)

  • Kim, D.K.;Jung, K.H.;Kang, S.H.;Im, Y.T.
    • Transactions of Materials Processing
    • /
    • v.19 no.1
    • /
    • pp.25-31
    • /
    • 2010
  • To achieve desired microstructure and mechanical property of a manufacturing product, heat treatment process is applied as a secondary process after forging. Especially, quenching process is used for improving strength, hardness, and wear resistance since phase transformation occurs owing to rapid heat transfer from the surface of the specimen. In the present paper, a study on surface temperature measurement for water quenching of eutectoid steel was investigated. In order to determine the temperature history in experiments, three different measuring schemes were used by varying installation techniques of K-type thermocouples. Depending on the measured temperature distribution at the surface of the specimen, convective heat transfer coefficients were numerically determined as a function of temperature by the inverse finite element analysis considering the latent heat generation due to phase transformation. Based on the inversely determined convective heat transfer coefficient, temperature, phase, and hardness distributions in the specimen after water quenching were numerically predicted. By comparing the experimental and computational hardness distribution at three different locations in the specimen, the best temperature measuring scheme was determined. This work clearly demonstrates the effect of temperature measurement on the final mechanical property in terms of hardness distribution.

Effect of Cooling Rate on the Behavior of the Embrittlement in Zircaloy-4 Cladding (냉각속도가 지르칼로이-4 피복관의 취성에 미치는 영향)

  • Kim, Jun Hwan;Lee, Myoung Ho;Choi, Byoung Kwon;Jeong, Yong Hwan
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.18 no.2
    • /
    • pp.112-118
    • /
    • 2005
  • Study was focused on the effect of the cooling rate on the embrittlement behavior of Zircaloy-4 cladding simulated Loss Of Coolant Accident (LOCA) environment. Claddings were oxidized at given temperature and given time followed by various water quenching in the range of $0.6^{\circ}C$ and $100^{\circ}C$ per second. Cladding failed after water quenching above the threshold oxidation. Threshold oxidation was decreased as the cooling rate increased, which is due to the matensite structure formed during fast cooling rate.

The bibliographical study on drug-processing about Pyritum (자연동(自然銅)의 수치법(修治法)에 대한 문헌적(文獻的) 고찰(考察))

  • Min, Pyoung-gee;Seo, Young-bae
    • Journal of Haehwa Medicine
    • /
    • v.10 no.1
    • /
    • pp.47-53
    • /
    • 2001
  • In the result of investigating traditional chinese medical literatures to understand drug-processing about Pyritum, we could reach conclusions as follows: 1. Pyritum are divided into fresh Pyritum, calcining Pyritum, tempered Pyritum with vinegar by methods of drug-processing. 2. The methods of drug-procession about Pyritum like calcination, quenching, refining drugs with water or medicinal broth of Glycyrrhizae Radix(licorice), boiling with medicinal broth of Glycyrrhizae Radix(licorice) were used complicately. 3. Calcining Pyritum are grinded easily, convenient to apply a pill and powder and As, S are easily removed. Quenching Pyritum act on liver channel and then are reinforced the effects of relieving blood stasis, Pain and gushed out effecive ingredients. Refining Pyritum with water are reinforced the effect of tranquilizing the mind and clearing heat. above results indicates that using calcination, quenching and refining drugs with water together is the best method of drug-processing about Pyritum.

  • PDF

Arcing and Quenching of the Contacts Contaminated with Sea Water (해수로 오염된 처점의 개간이-크의 발생과 소멸)

  • 조광현;박상길;박정후
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.34 no.4
    • /
    • pp.135-143
    • /
    • 1985
  • The failure and erosion of relay contacts mainly depend on the presence of particles deposited on the contact surface in various contaminated atmospheres. In this paper, the effects of sea water and circuit parameters on the arcing and quenching of magnet relay contacts are studied. The sea water pollutants of relay contact surface have led to increase the arcing numbers on making contact, and the mean arc durations on breaking contacts. Moreover, the maximum surge voltage and mean arc duration between relay contacts are also varied significantly by the circuit parameters. The effects of the spark quenching circuits using condenser of diode on the arcing of contacts are also discussed.

  • PDF

Effect of Repeated Quenching Heat Treatment on Microstructure and Dry Sliding Wear Behaviour of Low Carbon PM Steel

  • Gural, Ahmet;Tekeli, Suleyman;Ozyurek, Dursun;Guru, Metin
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09a
    • /
    • pp.570-571
    • /
    • 2006
  • The mixed atomized iron powders with 0.3% graphite and 1% Ni powders were cold pressed and sintered at $1200^{\circ}C$ for 30 min under pure Ar gas atmosphere. Some of the sintered specimens were intercritically annealed at $760^{\circ}C$ and quenched in water (single quenching). The other sintered specimens were first fully austenized at $890^{\circ}C$ and water quenched. These specimens were then intercritically annealed at $760^{\circ}C$ and re-quenched in water. The experimental results showed that the wear coefficient effectively decreased in the double quenched specimen.

  • PDF