• Title/Summary/Keyword: Water quenching

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Glass Forming Ability of Bulk Amorphous Alloy Scrap by Fluxing (플럭스처리에 의한 벌크비정질합금 스크랩의 비정질형성능)

  • Kang, Bok-Hyun;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.30 no.3
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    • pp.94-99
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    • 2010
  • When the returned scrap of bulk amorphous alloy is remelted, impurities such as oxides and intermetallic compounds increase. Glass forming ability of its scrap is deteriorated remarkably. Melt fluxing technique is introduced to enhance the glass forming ability during melting and freezing of bulk amorphous alloys. Cu and Zr based alloys are chosen. Small pieces of these alloy scraps and $B_2O_3$ flux are put together in a quartz tube. Cyclic heating and cooling are done by induction heating and water quenching or air cooling. Melting fluxing was effective for both Cu-based and Zr-based alloy, and their glass forming abilities were improved with increasing the number of fluxing.

Study on Cooling Characteristic Improvement in Underwater Wet Arc Welding of TMCP Steelplate (TMCP강의 습식수중 아크용접부의 냉각특성 개선에 관한 연구)

  • 김민남
    • Journal of Ocean Engineering and Technology
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    • v.6 no.2
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    • pp.113-124
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    • 1992
  • The offshore industry created a need for quality wet weld repairs. Wet welding is a fast method of repair providing sound, structural quality welds. It requires less support equipment than a similar underwater dry weld repair or the alternative mechanical connections. Compared to welds made in air, underwater wet welds are plagued by increased hardness due to rapid quenching by the surrounding water. In this paper is described the experimntal study of improving the cooling rates of wet welds of TMCP steel plate by shielding around weld arc surroundings. The principal results of this experimental investigation can be summarized as follows : By shielding around weld arc surrounding, the cooling rates resulting from wet welds on TMCP steel plate could be lower than that of nonshielded wet welds and the fesibility on high quality of mecanical properties of wet weld on TMCP steel plate was carried out with shielded weld arc surrounding.

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Developed Inherent Strain Method Considering Phase Transformation of Mild Steel in Line Heating (선상가열시 강의 상변태를 고려한 개선된 고유변형도 기반의 등가하중법)

  • Ha, Yun-Sok;Jang, Chang-Doo
    • Journal of the Society of Naval Architects of Korea
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    • v.41 no.6
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    • pp.65-74
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    • 2004
  • The inherent strain method is known to be very efficient in predicting the deformation of steel plate by line heating. However, in the actual line heating process in shipyard, the rapid quenching changes the phase of steel. In this study, In order to consider additional effects under phase transformation, inherent strain regions were assumed to expand. Also, when calculating inherent strain, material properties of steel in heating and cooling are applied differently considering phase transformation. In this process, a new method which can reflect thermal volume expansion of martensite is suggested.8y the suggested method, it was possible to predict the plate deformations by line heating more precisely.

Quantitative Vapor Phase Exciplex Fluorescence Measurements at High Ambient Temperature and Pressure

  • Kim, Tongwoo;Jaal B. Ghandhi
    • Journal of Mechanical Science and Technology
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    • v.17 no.1
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    • pp.157-167
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    • 2003
  • The exciplex fluorescence technique with the TMPD (tetamethyl-Ρ-phenylene-diamine) / naphthalene dopant system was applied in a combustion-type constant-volume spray chamber. A detailed set of calibration experiments has been performed in order to quantify the TMPD fluorescence signal. It has been demonstrated that the TMPD fluorescence intensity was directly proportional to concentration, was independent of the chamber pressure, and was not sensitive to quenching by either water vapor or carbon dioxide. Using a dual heated-jet experiment, the temperature dependence of TMPD fluorescence up to 1000 K was measured. The temperature field in the spray images was determined using a simple mixing model, and an iterative solution method was used to determine the concentration and temperature field including the additional effects of the laser sheet extinction. The integrated fuel vapor concentration compared favorably with the measured amount of injected fuel when all of the liquid fuel had evaporated.

Fluorescence Quenching of Green Fluorescent Protein during Denaturation by Guanidine

  • Jung, Ki-Chul;Park, Jae-Bok;Maeng, Pil-Jae;Kim, Hack-Jin
    • Bulletin of the Korean Chemical Society
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    • v.26 no.3
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    • pp.413-417
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    • 2005
  • Fluorescence of green fluorescent protein mutant, 2-5 GFP is observed during denaturation by guanidine. The fluorescence intensity decreases exponentially but the fluorescence lifetime does not change during denaturation. The fluorescence lifetime of the denatured protein is shorter than that of native form. As the protein structure is modified by guanidine, solvent water molecules penetrate into the protein barrel and protonate the chromophore to quench fluorescence. Most fluorescence quenchers do not affect the fluorescence of native form but accelerate the fluorescence intensity decay during denaturation. Based on the observations, a simple model is suggested for the structural change of the protein molecule during denaturation.

A Study on the Fabrication of Amorphous Magnetostrictive Wire (아몰퍼스 자왜 와이어의 제작에 관한 연구)

  • 김대주;정왕일;조남희;신용진;강재덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.99-101
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    • 1996
  • This paper is concerned with the fabrication of (Fe,Co)-Si-B amorphous magneto-strictive wire which attracts strong attention as a new sensor material. First, we put the ingot of (Fe$\sub$1-x/Co$\sub$x/)$\sub$77/Si$\sub$8/B$\sub$15/ composition into quartz tube. Then, under the condition of 400MHz and 8kW, we melt and mix the in-got in the high frequency induction furnance. After that, we obtain the magnetostrictive wire of 100∼150$\mu\textrm{m}$ in diameter by injection and rapid quenching within the high rotating water. Finally, we find that the wire is under the amorphous state.

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Elucidation of photo-induced electron transfer in a loop-forming peptide: Dye-Ala-Gly-Gln-Tyr

  • Lee, Hwiin;Kim, Jeongyun;Kwon, Yong-Uk;Lee, Minyung
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.59-62
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    • 2015
  • We investigated photo-induced electron transfer (PET) in a dye-labeled peptide, fluorophore-Ala-Gly-Gln-Tyr, employing time-resolved fluorescence. As an effort to develop new functional dyes, we studied an acriflavine derivative for the electron-acceptor in the excited state from tyrosine, an electrondonor in the ground-state. The pH dependence of the fluorescence lifetime of the model peptide indicates that electron transfer between the excited dye and tyrosine occurs when the tyrosine is deprotonated. The proton-coupled electron transfer appears to be sequential rather than concerted. We also report direct time measurements on the end-to-end loop formation processes of the peptide in water.

Microstructure and Fracture Path of Cr-Mn-N Steel upon Aging Treatment

  • Lee, Se-Jong;Sung, Jang-Hyun;Ralls, K.M.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.3
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    • pp.21-30
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    • 1991
  • Microstructural analysis was conducted to observe the effect of aging treatments in a Cr-Mn austenitic stainless steel containing nitrogen, and the amount, size, shape and distribution of precipitates were investigated. It was found that on water quenching from $1000^{\circ}C$ after holding 3 h at that temperature, the steel contained no precipitates observable by optical microscopy. Precipitation of phases begins at places most favorable for the formation of nuclei-in the boundaries of grains and twins. Precipitates were studied in detail by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Chemical compositions of precipitates were examined by the use of scanning transmission electron microscopy (STEM) together with an energy dispersive X-ray (EDX) microanalysis. Also chromium depletion adjacent to grain boundary precipitates was investigated by the use of Auger electron spectroscopy (AES) for a direct examination of the fracture surface chemistry.

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Study of Photocatalytic Activity and Phostability of ZnO Particles Coated with UV-stable Polydimethylsiloxane

  • Jeong, Myung-Geun;Seo, Hyun-Ook;Kim, Kwang-Dae;Kim, Dae-Han;Kim, Young-Dok;Lim, Dong-Chan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.188-188
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    • 2012
  • ZnO particles with a size range of 50-150 nm were coated with polydimethylsiloxane (PDMS) with a thin film thickness of 3-4 nm using a simple ambient-pressure chemical vapor deposition methods. Surfaces consisting of the PDMS-coated ZnO nanoparticles were found to be superhydrophobic with a water contact angle higher than $160^{\circ}$. The superhydrophobicity was sustained in the presence of UV light. Photocatalytic activity and photocorrosion of ZnO were nearly completely quenched in the presence of PDMS coating. It is suggested that our PDMS-coating can be of potential interest for the application of ZnO in UV protection agents and energy and electronic devices.

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Surface Characteristics of Hydroxyapatite Coated Surface on Nano/Micro Pore Structured Ti-35Ta-xNb Alloys

  • Jo, Chae-Ik;Choe, Han-Choel
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.185-185
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    • 2014
  • In this study, we investigated surface characteristics of hydroxyapatite coated surface on nano/micro pore structured Ti-35Ta-xNb alloys. This paper was focus on morphology and corrosion resistance of Anodic oxidation. To prepare the samples, Ti-35Ta-xNb (x= 0, 10 wt. %) alloys were manufactured by arc melting and heat-treated for 12 h at $1050^{\circ}C$ in Ar atmosphere at $0^{\circ}C$ water quenching. Micro-pore structured surface was performed using anodization with a DC power supply at 280 V for 3 min, nanotube formed on Ti-35Ta-xNb alloys was performed using DC power supply at 30 V in 60 min at room temperature. Surface morphology and structure were examined by field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction.

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