• Title/Summary/Keyword: Water pollutants

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Comparison of Liquid-Liquid Extraction and Solid-Phase Extraction Coupled with GC/MS for Determination of Priority Pollutants in Water (액체 추출법과 고체상 추출법에 의한 수질 중 유해물질 농축법 비교)

  • Yook, Keun-Sung;Hong, Sa-Moon;Kim, Jong-Ho
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.441-453
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    • 1994
  • Two extraction methods, liquid-liquid extraction(LLE) and solid-phase extraction(SPE), coupled with GC/MS were compared as preconcentration procedures for priority pollutants in water. Among the semi-volatile priority pollutants, 11 acid and 44 base/neutral compounds were spiked in reagent water. With LLE, which is a modification of EPA Method 625, the overall mean recovery of the 54 compounds was 91% with a mean relative standard deviation(RSD) of 4.6%. With SPE, the overall mean recovery of the 52 compounds was 53% with a mean RSD of 8.9%. The detection limits of both methods were in the range of $1{\sim}5{\mu}g/l$.

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Water Quality Behavior by the Sluice Gate Operation of Freshwater Lake (배수갑문 방류시점 및 방류량에 따른 담수호의 수질변화)

  • 김선주;김성준;김필식;이창형
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.1
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    • pp.91-101
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    • 2003
  • Boryeong Seadike located at southwestern seashore of Korean peninsula completed in 1997. Sluice gate operation can be an important factor to maintain lake water quality and reduce retaining time of pollutants within lake. The lake water quality simulation model, WASPS was adopted and tested to find out proper gate operation timing and discharge amount. From the simulation of sluice gate operation, the results showed that the later the time of discharge for loosing 1 day successively to 6 days, the better the quality of water. Discharge amount showed relatively minor changes of water quality. This means that pollutants flowed into lake from watershed do not have enough time to mix up with deep water when the gate opened at early time. About 3 days delay of discharge caused the dilution effect to stabilize the lake water quality in case of Boryeong freshwater lake.

Runoff Characteristics of Major Pollutants at the Inflow Stream to Lake Sap-Kyo in Rainy Periods (삽교호 유입하천에서 강우시 주요 오염물질의 유출 특성)

  • Park, Jae-Young;Kim, Young-Chul;Oh, Jong-Min
    • Korean Journal of Ecology and Environment
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    • v.34 no.1 s.93
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    • pp.62-69
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    • 2001
  • This study was investigated discharge and water quality for rainy days at the inflow streams (Gog-Kyo, Mu-Han, Sap-Kyo and Nam-Won) into Lake Sap-Kyo from June to November of 1999. The eventual aim of this study was to improve the water quality of Lake Sap-Kyo. Therefore, in order to reduce inflow pollutants loading into Lake Sap-Kyo, we investigated characteristics of stormwater runoff and estimated pollutant loading for the rainy season. The results of that Sap-Kyo stream is $5.75\;m^3/sec$ flow and influences water quantity of Lake Sap-Kyo greatly during the dry weather. Gog-Kyo stream influence to quantity of Lake Sap-Kyo greatly for the rainy days. Gog-Kyo stream and Sap-Kyo stream are $12.13\;m^3/sec$ and $8.49\;m^3/sec$, respectively. The reason is that the watershed area of Gog-Kyo stream is larger than other streams. When we prepare to plan management to improve the water quality of Lake Sap-Kyo, we have to consider that runoff characteristics by land use. Among the annual total pollutants loading inflow Lake Sap-Kyo, the ratio of non-point pollutants loading estimated that SS, BOD, T-N and T-P are 62%, 43%, 41% and 27%, respectively. Therefore, in order to improve water quality of Lake Sap-Kyo, we have to reduce non-point pollutants loading.

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A Study on the Emission Characteristics of Water Pollutants in Wastewater Discharge Facilities and Drainpipes of Yeongsangang (영산강수계 주요 산업단지 폐수배출시설과 배수로에 대한 수질오염물질 배출특성 연구)

  • Lee, Jae-Young;Min, Hwa-In;Choi, Kyung-Chug;Ju, Hyun-Jin;Kim, Gyeong-Soo;Yun, Seol-Hee;Lee, Jae-Choon
    • Journal of the Korean Society for Environmental Technology
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    • v.19 no.6
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    • pp.586-599
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    • 2018
  • To learn about the discharge facility management of industrial complexes and the discharge characteristics of water pollutants in drainage, 11 sites were selected, including 16 discharge companies of Hanam Industrial Complex and High-Tech Scientific Industrial Complex and 4 drainages of the industrial complexes. Through the analysis, it was found that 12(75 %) of the 16 discharge companies had specific hazardous substances other than those registered at the time of installation and registration of the wastewater discharge facilities. In terms of other pollutants, 11 of the 16 companies(about 69 %) were found to have pollution items that differed from those included in approved and reported items lists. In addition, Formaldehyde, Mn, Zn, and Ba were discharged from 11 out of the 16 companies. Significantly, one of the specific hazardous water pollutants, Cu, was detected in all discharge facilities at levels from 0.029 to 0.929 mg/L. Even in major complexes drainages and the main stream of the Yeongsangang. As, Dichloromethane, and Chloroform were detected. However, it cannot be conclusively claimed that it is probable that these substances were actually discharged from the above facilities because research was only done in a limited range(Class 1 to Class 3), and therefore, further research is required. In the future, it will be necessary to expand the research scope of the discharge companies in order to establish a database of water pollutants, and to improve permits and reported items based on discharged substances.

Assessment of Micro Organic Pollutants Removal Using Advanced Water Treatment Process and Nanofiltration Process (고도처리공정과 나노여과공정에서의 미량유해물질 제거 평가)

  • Kang, Joon-Seok;Choi, Yang-Hun;Kwon, Soon-Buhm;Yu, Young-Beom
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.579-587
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    • 2014
  • Various kinds of micro organic pollutants have frequently been detected from a water system. Therefore, it is considered to be very important part in the drinking water treatment system. And the research about removal process and processing efficiency have been being conducted briskly. In this study, the removal efficiency was evaluated using advanced water treatment process and nanofiltration process. The removal efficiency of nanofiltration process was very different according to physical and chemical characteristics of materials. The molecular weight of cutoff was the most influential factor in the removal efficiency. And when pKa value was higher than pH of raw water or Log Kow value was below 2, the removal efficiency of material was decreased. In case of oxidation reaction, the bigger the molecular weight of material was and the more hydrophobic a material was, the less oxidation reaction occurred. And the removal efficiency was decreased. Most unoxidized materials were removed by absorption. And the more actively oxidation reaction occurred by $H_2O_2$, the more absorption reaction increased.

36hrs Continuous Monitoring Methodology for Effluent and Receiving Water Quality (하천 수질에 대한 36시간 연속 모니터링 기법 연구)

  • 박정규;정홍배;문성환;류태권;류제영;황인영
    • Environmental Analysis Health and Toxicology
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    • v.16 no.4
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    • pp.153-159
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    • 2001
  • The main point source of pollution of the Keumho river in Taegu, Korea, stems from waste from the areas of industrial complexes . Although it is widely accepted that pollutants in waste water negatively effects general water quality, it is difficult to evaluate the effluent effect because of varying conditions in ambient water and inconclusive knowledge of causative pollutants. To analyze the water in relation to the industrial effluent in the area, pH. temperature, conductivity, and Microtox toxicity of various river samples were measured. Water samples were collected every 2 hours for 36 hours from Keumho river and Dalseo stream. Data from continuous monitoring for 36 hours showed that effluent in Keumho river originated from Dalseo stream, which is near adjacent to industrial complexes. Change in toxicity and other factors tested during the 36 hours indicated that continuous monitoring was necessary for a satisfactory effluent toxicity test Furthermore, in addition to water quality monitoring, it was concluded that sediment toxicity also needed to evaluate effluent effects.

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Applicability of Water Quality Indicators as Target Pollutants for Total Maximum Daily Loads (수질오염총량관리를 위한 대상물질 적용성 분석)

  • Park, Jun Dae;Oh, Seung Young;Park, Jae Hong
    • Journal of Korean Society on Water Environment
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    • v.29 no.4
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    • pp.531-539
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    • 2013
  • In order to apply a water quality indicator as a certain target pollutant, the indicator should have the representability of an index for the management of Total Maximum Daily Loads (TMDLs). Scientific groundwork and treatment technologies also should be provided for the application of the indicator. This study analyzed the applicability of major water quality indicators for target pollutants. The results showed that four water quality indicators of TOC, T-N, SS & T-Coli can be considered as target pollutants besides existing BOD and T-P. These indicators can be applied with the preparations such as essential basic data, pollution load estimation framework as well as legal criteria setting when the need is raised. As the importance of TOC, which is considered as a replacement of BOD, is emphasized, technical and institutional terms are being prepared in order to determine TOC as another target pollutant in the near future. It could be considered to combine TOC with BOD for the time being during the $3^{rd}$ stage of TMDLs in view of the present conditions for the management of TOC. TOC can be the most effective index for the organic matter and help to be managed more systematically in the waterbodies where rivers and lakes are mutually connected.

Water Deficit of Pitch Pines Caused by Superficial Rooting and Air Pollutants in Seoul and Its Vicinity

  • Joon-Ho kim;Rhyu, Tae-Cheol
    • Journal of Plant Biology
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    • v.37 no.3
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    • pp.309-316
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    • 1994
  • To make regional comparisons of water status of pitch pine, the temporal changes of water status in pitch pine were investigated at different areas; urban Seoul (heavily polluted area), surburb of Seoul (lightly polluted area), and rural area (control). The effects of air pollutants, acid rain and chemical properties of soil on water deficit in pitch pine were also investiaged. Water content of needles growing at polluted areas were usually lower than that at unpolluted area. Water saturation deficit of needles growing at polluted areas were usually higher than that at unpolluted area especially in dry season. These results indicated that water in needles growing at polluted areas were usually more deficient than that at unpolluted area, and were more deficient in April than other months. At polluted areas, the older the needles were, the more quickly transpirated the water in the needle was. At unpolluted areas, however, water in old needles was not so quickly transpirated as those at polluted areas. Water potential of needles of pitch pine seedlings treated with simulated acid rain (SAR) of pH 3.5 decreased more quickly than that of needles treated with SAR of pH 5.6. Loss of water through epicuticular layer was greater in the following order: magnesium deficiency+100 $\mu$M aluminium>100$\mu$M aluminium>magnesium deficiency>control. In addition to Mg deficiency and Al toxicity, growth decline of pitch pine widely occurring in polluated Seoul could to a large extent be due to cuticle degredation and abnormal vertical distribution of fine roots, which lead to water stress, particularly in dry seasons.

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Effect for CSOs Storage Construction - Analysis of Storm Water Run-off Characteristics in combined sewer system (합류식 하수관거 월류수 저장 시설에 대한 효과 - 강우시 합류식 하수관거에서의 오염물질 유출특성 분석)

  • Park, Jin-Kyu;Lee, Nam-Hoon;Kim, Hae-Ryong;Lee, Woong;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.6
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    • pp.949-957
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    • 2011
  • This aim of study was to investigate the characteristics of discharge of pollutants as well as the correlation between flow rate and water quality constituents in a combined sewer system according to the characteristics of rainfall. For the loading rates for each pollutant, the median concentrations of all pollutants except T-N was increased when a CSO took place. The loading rates of BOD, COD, SS, T-N, T-P, Cu and Zn at the CSOs were 328-1255, 25-129, 83-2009, 4-12, 14-51, 5-11 and 5-13 times higher than the DWF (Dry Whether Flow), respectively. Especially, SS loading rate was found to be highest in all pollutants. On the other hand, the range of the first flush coefficient, b for water quality constituents such as BOD, COD, SS, T-N, T-P, Cu and Zn were 0.537-0.878, 0.589-0.888, 0.516-1.062, 0.852-1.031, 0.649-0.954, 0.975-1.015 and 0.900-1.114, respectively. In term of correlation between flow rate and pollutant concentrations, SS concentration was highly correlated to flow rate. However, there was an inverse correlation between EC (Electrical Conductivity) and flow rate because of the high dilution of flow rate. In case of correlation between pollutants, there was a high correlation between SS and T-P.

Comparative risk analysis for priority ranking of environmental problems in Seoul

  • Kim, Ye-Shin;Lee, Yong-Jin;Park, Hoa-Sung;Lim, Young-Wook;Shin, Dong-Chun
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.169-169
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    • 2003
  • In Korea, there is no CRA studies and has not well known CRA and not well established their methodologies. Therefore, objectives of this study is to establish the framework of CRA consisting of health risk, economic risk and perceived risk and the detail methodologies of three main component of estimating and comparing those risks for on the three environmental problems of air pollution, indoor air pollution and drinking water contamination which being subjective to the eight sub-problems of hazardous ai. pollutants (HAPs), regulated pollutants (representative as PM10) and Dioxins (PCDDS/ PCDFs) in air pollution, and indoor ai. pollutants (IAPs) and Radon in indoor air pollution, and drinking water pollutants (DWPs), disinfection-by- products(DBPs) and radionuclides in drinking water contamination in Seoul, Korea. And then, their problems set priorities by individual and integrated risk. As a results, ranking of health risk were the following order of indoor air pollution, air pollution and then drinking water contamination, in three environmental problems and of radon, PM10, IAPs, HAPs, DWPs, Dioxins, DBPs, and then radionuclides in eight sub-problems. And that of economic risk were the same order. In the contrary, ranking of perceived risk were the following order of air pollution, drinking water contamination, and then indoor air pollution, and of HAPs, Dioxins, radionuclides, PM10, DWPs, IAPs, Radon and then DBPs.

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