• 한국해양학회지:바다
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• 제13권4호
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• pp.348-353
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• 2008

산소안정동위원소는 추적자로서의 뛰어난 특성에도 불구하고 분석상의 어려움으로 해양수괴 연구에 많이 활용되지 못하고 있다. 물시료에 함유된 산소의 안정동위원소비를 측정하기 위해 가장 많이 사용하는 방법은 $H_2O/CO_2$ 평형기를 이용해 시료인 물을 이산화탄소와 동위원소평형을 이루게 한 뒤, 이산화탄소의 동위원소 비율을 측정하는 것이다. 이러한 자동 $H_2O/CO_2$ 평형기를 이용한 물 시료 분석시의 정밀도는 ${\pm}0.1%o$, 해양에서 이를 적용하기 위해서는 정밀도를 보다 높이는 것이 요구된다. 따라서 본 연구에서는 분석상의 오차를 감소시킬 수 요인들을 파악하여 분석장치의 보완 및 분석방법의 개선으로 정밀도 최소 0.05%o 향상시킴으로서 산소동안정동위원소의 변화폭이 작은 해양에서도 추적자로서 활발히 응용될 수 있도록 기여하고자 하였다. $H_2O/CO_2$ 평형기를 이용하는 경우 가장 큰 문제점은 시료가스가 전처리 장치로부터 질량분석기까지 이동해야 하는 거리가 멀고 평형가스가 팽창해야 하는 부피가 크다는 것이다. 그러므로 단순히 압력 차를 이용해서 가스를 이동시킬 경우, 가벼운 동위원소종이 선택적으로 이동되는 동위원소 분별작용이 일어날 수 있고, 분석 장치 전체의 부피가 플라스크에 담긴 시료가스의 부피에 비해 크기 때문에 시료가스가 충분히 혼합되지 않을 수가 있다는 점이다. 이러한 점을 보완하기 위해 액체질소 트랩과 고진공 균일도를 향상시켰다. 동일한 해수시료를 기존방법과 보완방법을 이용하여 각각 14번씩 분석한 결과 평균 측정값은 0.023, 0.024%o 서로 거의 동일한 값을 보였으나 표준편차는 각각 ${\pm}0.081$, ${\pm}0.021%o$ 네 배가량 개선된 결과를 보이고 있다. 그 결과 해양에서의 동위원소 분석시 발생할 수 있는 중요한 오차 요인을 현저하게 감소시킴으로서 동위원소 변화폭이 작은 해양수괴 연구에 크게 기여할 수 있을 것으로 기대된다.

• 한국응용과학기술학회지
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• 제37권4호
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• pp.649-658
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• 2020

본 연구는 여대생 900명을 대상으로 물 섭취량과 커피 섭취량에 따른 건강체력 및 비만에 대한 차이를 알아보고자 하였다. 측정은 건강체력요인 체력에 근력(악력, 배근력), 근지구력(윗몸일으키기),유연성(앉아앞으로굽히기) 심폐지구력(하버드스텝)을 측정하였고, 체성분 측정기기 Inbody를 이용하여 신체조성(세포내액, 세포외액, 단백질, 무기질, 체수분량, 근육량, 제지방량, 체지방량)과 비만(BMI, 체지방률, 복부지방률, 비만도)의 각 항목을 측정하였다. 자료처리는 SPSS를 이용하여 이원변량분석과 일원변량분석을 실시하였다. 그 결과 건강체력과 비만에 대한 물과 커피 섭취량 집단 간 상호작용은 나타나지 않았다. 각 독립변인 별 일원변량분석을 실시한 결과 건강체력요인 중 체력요인은 물과 커피 섭취량에 따른 유의미한 차이는 나타나지 않았다. 그러나 신체조성(세포내액, 단백질, 무기질, 체수분량, 근육량, 제지방량)에서 물7잔 이상 섭취 집단이 1~4잔 섭취 집단보다 유의미하게 높았으며, 커피는 3~4잔 섭취 집단이 미섭취 집단에 비하여 유의미하게 높았다. 비만요인의 경우 물 섭취량에 따라 유의미한 차이는 나타나지 않았지만, 커피의 경우 비만도에서 3~4잔 섭취 집단이 미섭취 집단에 비하여 비만도가 높게 나타나, 커피는 물과 달리 비만과 관련이 있음을 알았다. 차후 물과 커피와 같은 다양한 음료 섭취에 대한 성별, 연령대별 차이에 관한 연구가 진행되어 진다면 보다 나은 건강을 위한 개인별 특성에 따른 수분 섭취방법으로 활용될 수 있을 것이다.

• 한국농공학회논문집
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• 제55권6호
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• pp.167-175
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• 2013

The objective of this study was to investigate the nutrient load balance in the reservoir irrigated paddy block during growing seasons. Idong reservoir irrigation paddy block of 10.3 ha in size was selected to collect hydrologic and water quality data. Irrigation, canal flows, and paddy field drainage were measured using a water level gauge, while water samples were collected and analysed for water quality. The water balance analysis showed that 81 % and 75 % of total outflow were through paddy and irrigation canal drainage during 2011 and 2012, respectively. The water quality of paddy field drainage varied greatly depending on rice cultivation stage ranging from 0.05 to 24.55 mg/L and from 0.01 to 0.76 mg/L for T-N and T-P, correspondently. Paddy field drainage loads during May through June account for 64 % and 76 % in 2012 and 2013, while 82 % and 81 % for T-P in 2011 and 2012, respectively. The Pearson correlation analysis showed that rainfall was significantly correlated with nutrient loads during July through August due to runoff, and irrigation was related with nutrient loads of drainage during some period of July through September due to irrigation return flow. This study results showed characteristics of inflow and outflow nutrient loads from plentiful irrigated paddy block.

• 대한조선학회논문집
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• 제54권4호
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• pp.329-334
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• 2017

As the motion response of heave for floating bodies on the water surface is relatively large near the natural frequency, it is necessary to predict its value accurately from the stage of initial design. Bodies accelerating in fluid experience force acted upon by the fluid, and this force is quantified by using the concept of added mass. For predicting the natural frequency of heave we need to know the added mass, which is given as a function of frequency, and hence the natural frequency can be obtained through only by iteration process, as was pointed out by Lee (2008). His method was applied to circular cylinders, and two dimensional cylinders of Lewis form by making use of the Ursell-Tasai method in the previous works, Lee and Lee (2013), Kim and Lee (2013), and Song and Lee (2015). In this work, a similar algorithm employing the concept of strip method is adopted for predicting the heave natural frequency of KCS(KRISO Container Ship), and the obtained computational result was compared with other existing experimental data, and the agreement seems reasonable. Furthermore, through the error analysis, it is shown that why the frequency corresponding to the local minimum of the added mass and the natural frequency are very close. And it seems probable that we can predict the heave natural frequency if we know only the local minimum of added mass and the corresponding frequency under a condition, which holds for ship-like bodies in general.

• 대한기계학회논문집B
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• 제33권8호
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• pp.596-603
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• 2009

The performance of proton exchange membrane fuel cell (PEMFC) is seriously changed by the humidification condition which is intrinsic characteristics of the PEMFC. Typically, the humidification of fuel cell is carried out with internal or external humidifier. A membrane humidifier is applied to the external humidification of residential power generation fuel cell due to its convenience and high performance. In this study, a simple static model is constructed to understand the physical phenomena of the membrane humidifier in terms of geometric parameters and operating parameters. The model utilizes the concept of shell and tube heat exchanger but the model is also able to estimate the mass transport through the membrane. Model is constructed with FORTRAN under Matlab/$Simulink^{(R)}$ $\Box$environment to keep consistency with other components model which we already developed. Results shows that the humidity of wet gas and membrane thickness are critical parameters to improve the performance of the humidifier.

• Mass Spectrometry Letters
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• 제13권4호
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• pp.158-165
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• 2022

Many therapeutic class drugs such as beta-blocker, corticosteroids, NSAIDs, etc are prohibited substances in the horse racing industry. Liquid chromatography-tandem mass spectrometry (LC-MS/MS) technology makes it possible to isolate drugs from interference, enables various drug analyses in complex biological samples due to its sensitive sensitivity, and has been successfully applied to doping control. In this paper, we describe a rapid and sensitive method based on solid-phase extraction (SPE) using solid phase cartridge and LC-MS/MS to screen for different class's 35 drug targets in equine plasma. Plasma samples were pretreated by SPE with the NEXUS cartridge consisted non-polar carbon resin and minimum buffer solvent. Chromatographic separation of the analytes was performed on ACQUITY HSS C18 column (2.1 × 150 mm, 1.8 ㎛). The elution gradient was conducted with 5 mM ammonium formate (pH 3.0) in distilled water and 0.1% formic acid in acetonitrile at a flow rate of 0.25 mL/min. The selected reaction monitoring (SRM) mode was used for drug screening with multiple transitions in the positive ionization mode. The specificity, limit of detection, recovery, and stability was evaluated for validation. The method was found to be sensitive and reproducible for drug screening. The method was applied to plasma sample analysis for the proficiency test from the Association of Racing Chemist.

• 한국지하수토양환경학회지:지하수토양환경
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• 제26권1호
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• pp.1-7
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• 2021

Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

• 분석과학
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• 제17권2호
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• pp.117-129
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• 2004

본 연구에서는 극성이 높고, 휘발성이 낮아 GC나 GC/MS로 분석이 곤란한 환경매체 중의 아미트롤을 LC/ESI/MS를 사용하여 분석한 결과 다음과 같은 결론을 얻었다. 분자량이 84인 아미트롤은 LC/ESI/MS 방식에서는 m/z 85인$(M+H)^+$형태로 나타났으며, 피크강도는 30V에서 (SIR mode) 최대를 나타내었다. 질량 스펙트럼 비를 정성확인에 적용하기 위하여 실험한 결과 아미트롤은 m/z 85 와 m/z 58 이온으로 나타났으며, 50V에서 이 비는 1 : 7.03~7.58 로 나타났다. 동위원소 비를 이용한 정성확인은 isotope MS나 HR/MS가 주로 사용되나, 본 연구에서는 정성확인을 위한 보조수단으로 이용하고자 실험한 결과 아미트롤의 동위원소는 $86([M+H])^+$ 형태로 나타났으며, 시료에서(30V) m/z 85와 m/z 86의 질량 스펙트럼 비는 27.1~28.6 : 1(이론적 비 26.6 : 1)로 나타났다. 단계별 표준액을 시료의 전 처리 방법과 동일하게 처리하여 분석한 검량선의 직선성은 $y=1.09354e^6X+26947.2$이었으며, $r^2=0.99$로 나타났다. 분석의 정도관리를 위한 회수율검정과 반복 재현성을 알아보기 위한 실험에서 수질시료의 회수율은 77.64~83.44%, 토양시료에서는71.11~79.44%로 나타났으며, 각 농도 단계별 반복(5회)실험결과 상대표준편차 값은 10%이하를 나타내었다.

• 한국강구조학회 논문집
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• 제14권6호
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• pp.765-772
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• 2002

초고층 건물의 가속도 레벨을 줄이기 위해서 TMD, TLD, VED와 같은 다양한 진동제어장치들이 많은 국내외 연구자들에 의해 연구되고 있다. TLD는 다른 제진장치에 비해 설치의 간편함 및 유지비용이 저렴한 장점이 있다. 그러나 물의 요동을 평가함에 있어서 어려움이 있으므로 동조액체댐퍼의 동적특성에 대한 실험 및 해석적 검증이 필요하다. 본 연구에서는 TLD를 100층 규모의 초고층건물에 설치할 경우를 상정하여 자유진동실험과 백색잡음을 이용한 강제진동실험을 통하여 TLD의 제진성능을 확인하고자 하였다. TLD의 질량비, 감쇠네트수, TLD 형상비 등을 주요실험변수로 설정하였으며, 물탱크를 설치한 건물의 반응값들이 건물 단독인 경우보다 적게 나타남을 알 수 있었다. 또한 질량비, 감쇠네트, 형상비가 커질수록 감쇠성능이 개선됨을 알 수 있었다.

• 한국대기환경학회지
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• 제21권3호
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• pp.343-355
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• 2005

Cloud/fog water was collected at Daegwallyeong, a typical clean environmental area, by using an active fog sampler during the foggy period in 2002, The pH ranged from 3,7 to 6,5 with a mean of 5,0, but the pH calculated from average concentrations of $H^+$ was 4.4. $SO_4^{2-},\;NO_3^-\;and\;NH_4^+$ were predominant ions with average concentrations of 473,3, 463,3 and $576,0\;{\mu}eq/L$, respectively, This showed that cloud/fog water was slightly acidified, but the concentrations of major pollutants were as high as those for polluted area, suggesting effect from long range transported pollutants, Samples were categorized into four groups (E, W, S, N) by applying 48-h back trajectory analysis using the Hybrid Single-Particle Largrangian Integrated Trajectory (HYSPLIT) model. Concentrations of seasalt $(Na^+\;and\;Cl^-)$ were the highest for group E, indicating large input of seasalts by air masses transported from the East Sea. The concentrations of $SO_4^{2-}$ were slightly higher in group W but the difference was not significant. However, the concentrations of $NO_3^-$ were significantly higher in group W than those in other three groups, The median values of cloud/fog water pH for group N and W were below 4,5, which is significantly lower than median values in group E and group S, This suggests that the acidifying pollutants were transported from the Asia continents and Seoul metropolitan area cause acidification of the cloud/fog water in Daegwallyeong.