• 제목/요약/키워드: Water mass analysis

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수동급기 직접 메탄올 연료전지의 동적 모델 (Dynamic Model of a Passive Air-Breathing Direct Methanol Fuel Cell)

  • 하승범;장익황;차석원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.33-36
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    • 2008
  • The transient behavior of a passive air breathing direct methanol fuel cell (DMFC) operated on vapor-feeding mode is studied in this paper. It generally takes 30 minutes after starting for the cell response to come to its steady-state and the response is sometimes unstable. A mathematical dynamic one-dimensional model for simulating transient response of the DMFC is presented. In this model a DMFC is decomposed into its subsystems using lumped model and divided into five layers, namely the anodic diffusion layer, the anodic catalyst layer, the proton exchange membrane (PEM), the cathodic catalyst layer and the cathodic diffusion layer. All layers are considered to have finite thickness, and within every one of them a set of differential-algebraic governing equations are given to represent multi-components mass balance, such as methanol, water, oxygen and carbon dioxide, charge balance, the electrochemical reaction and mass transport phenomena. A one-dimensional, isothermal and mass transport model is developed that captures the coupling between water generation and transport, oxygen consumption and natural convection. The single cell is supplied by pure methanol vapor from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The water is not supplied from external source because the cell uses the water created at the cathode using water back diffusion through nafion membrane. As a result of simulation strong effects of water transport were found out. The model analysis provides several conclusions. The performance drop after peak point is caused by insufficiency of water at the anode. The excess water at the cathode makes performance recovery impossible. The undesired crossover of the reactant methanol through the PEM causes overpotential at the cathode and limits the feeding methanol concentration.

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작동매체에 따른 2중효용 흡수식 시스템의 성능해석 (Thermodynamic Analysis of Double-effect Absorption Heat Pump System with New Working Pairs)

  • 원승호;이영수
    • 설비공학논문집
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    • 제3권4호
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    • pp.250-255
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    • 1991
  • Performance analysis of double-effect absorption heat pump system has been done to find improved working pairs (or mixture) by computer simulation. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio are investigated to compare three aqueous solutions [LiCl-water, LiSCN-LiBr-water, LiCl-$CaCl_2$-$Zn(NO_3)_2$-water] which was developed for only cooling, with conventional LiBr-water solution. It is found that the performances of the new aqueous solutions are better than that of LiBr-water solution not only in cooling systems, but also in heating systems. Theoretical thermodynamic performance data can be used in heat recovery systems by basic design data.

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1, 2종 흡수식 히트펌프의 작동 매체에 따른 성능 해석[I] (Thermodynamic Analysis of an Absorption Heat Pump System with New Working Pairs[I])

  • 원승호;이원용;정헌생
    • 설비공학논문집
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    • 제1권3호
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    • pp.219-227
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    • 1989
  • Performance analysis of an absorption heat pump system for solar energy recovery has been done by computer simulation to find improved working pairs. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio have been calculated to compare two aqueous solutions [LiCl-water, $LiCi-CaCl_2-Zn(NO_3)_2$-water] which were developed for cooling by others, with the conventional LiBr-water solution. As a result of this analysis, the performances of the new aqueous solutions were found to be better than that of LiBr-water solution not only in cooling systems, but also in heating and in heat transformer systems. Their theoretical thermodynamic performance data were given here with.

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LC-MS/MS를 이용한 곽향정기산(藿香正氣散) 추출물 중 20종 성분의 함량분석 (Quantitative Analysis of the Twenty Marker Components in Gwakhyangjeonggi-san using Ultra-Performance Liquid Chromatography with Mass Spectrometer)

  • 서창섭;신현규
    • 생약학회지
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    • 제45권2호
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    • pp.113-120
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    • 2014
  • Generally, Gwakhyangjeonggi-san has been used for treatment of diarrhea-predominant irritable bowel syndrome. In this study, an ultra-performance liquid chromatography-electrospray ionization-mass spectrometer method was established for the simultaneous quantification of marker compounds 1-20 in Gwakhyangjeonggi-san water extract. All analytes were separated by gradient elution using two mobile phases on a UPLC BEH $C_{18}$ ($100{\times}2.1mm$, $1.7{\mu}m$) column and maintained at $45^{\circ}C$. The injection volume was $2.0{\mu}L$ and the flow rate was 0.3 mL/min with detection at mass spectrometer. Regression equations of the compounds 1-20 were acquired with $r^2$ values ${\geq}0.9950$. The values of limit of detection and quantification of all analytes were 0.01-2.79 ng/mL and 0.03-8.37 ng/mL, respectively. The amounts of the compounds 1-20 in Gwakhyangjeonggi-san water extract were not detected $-3,236.67{\mu}g/g$. The established LC-MS/MS methods will be valuable to improve quality control of traditional herbal formula, Gwakhyangjeonggi-san.

Application of Optimum Multiparameter Analysis on Seawater Mixing in the South Sea of Korea Using Ra Isotopes

  • Lee Tongsup;Yang Han-Soeb;Kim Hyang-Bae
    • Fisheries and Aquatic Sciences
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    • 제3권2호
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    • pp.143-150
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    • 2000
  • Assuming that summer surface waters in the South Sea (northern East China Sea) are formed mostly by a mixing of three source water (Changjiang Discharge Water; Kuroshio Water and Yellow Sea Surface Water) we apply optimum multiparameter (OMP) analysis to calculate the mixing ratio of each source water to a given surface water. Since OMP requires more parameters than the number of water types (three in this study), we utilize two radium isotopes of dissolved $^{226}Ra\;and\;^{228}Ra$ along with temperature and salinity. Parameter values of each source water are deduced from in situ and historical data. Results with three source of waters on the surface waters are quite promising with less than $1\%$ of unanswered portions. Results not only reproduce the measured temperature and salinity faithfully but also discern the water masses of similar T and S according to their source water mixing. Extending OMP analysis to a whole water column obviously requires more parameters because more source waters are involved in the water mass formation. Original OMP routine utilized dissolved oxygen and nutrients. However, they seem to be perturbed too much by biological activities in the case of shallow waters. We discussed the use of other potential parameters. Also the benefit of parameter substitution is briefly introduced for the future OMP application on shallow waters.

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선박용 디젤엔진의 배기가스 열회수 시스템 (II) - R245fa 및 Water 의 작동유체에 대한 엑서지 분석 - (Exhaust-Gas Heat-Recovery System of Marine Diesel Engine (II) - Exergy Analysis for Working Fluids of R245fa and Water -)

  • 최병철;김영민
    • 대한기계학회논문집B
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    • 제36권6호
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    • pp.593-600
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    • 2012
  • 대형 선박의 추진용 디젤엔진에서 버려지는 배기가스의 열을 회수하기 위한 랭킨사이클이 적용된 발전시스템에 대하여 R245fa 및 water의 작동유체에 따른 그 엑서지 특성을 분석하였다. 그 이론적인 계산 결과로, R245fa에 대하여 터빈입구의 압력이 증가할수록 엑서지 효율 및 시스템의 엑서지 효율이 증가하였고, 엑서지 파괴율은 주로 응축기 및 증발기에서 상대적으로 높게 나타났다. 그리고 질량유량의 증가에 따라 시스템의 엑서지 효율이 증가하는 특성을 보였다. Water의 경우에, 증발기에서의 엑서지 파괴율은 R245fa의 경우와 유사하게 나타났지만, 터빈입구의 압력 및 질량유량 비율의 변동에 대하여 열원에 대한 엑서지 손실률이 가장 큰 폭으로 변동하였다.

Analytical solution of seismic stability against overturning for a rock slope with water-filled tension crack

  • Zhang, Yanjun;Nian, Tingkai;Zheng, Defeng;Zheng, Lu
    • Geomechanics and Engineering
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    • 제11권4호
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    • pp.457-469
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    • 2016
  • Steep rock slope with water-filled tension crack will happen to overturn around the toe of the slope under seismic loading. This failure type is completely different from the common toppling failure occurring in anti-dipping layered rock mass slopes with steeply dipping discontinuities. This paper presents an analytical approach to determine the seismic factor of safety against overturning for an intact rock mass slope with water-filled tension crack considering horizontal and vertical seismic coefficients. This solution is a generalized explicit expression and is derived using the moment equilibrium approach. A numerical program based on discontinuous deformation analysis (DDA) is adopted to validate the analytical results. The parametric study is carried out to adequately investigate the effect of horizontal and vertical seismic coefficients on the overall stability against overturning for a saturated rock slope under two water pressure modes. The analytical results show that vertically upward seismic inertia force or/and second water pressure distribution mode will remarkably decrease the slope stability against overturning. Finally, several representative design charts of slopes also are presented for the practical application.

Anchorage mechanism and pullout resistance of rock bolt in water-bearing rocks

  • Kim, Ho-Jong;Kim, Kang-Hyun;Kim, Hong-Moon;Shin, Jong-Ho
    • Geomechanics and Engineering
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    • 제15권3호
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    • pp.841-849
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    • 2018
  • The purpose of a rock bolt is to improve the mechanical performance of a jointed-rock mass. The performance of a rock bolt is generally evaluated by conducting a field pullout test, as the analytical or numerical evaluation of the rock bolt behavior still remains difficult. In this study, wide range of field test was performed to investigate the pullout resistance of rock bolts considering influencing factors such as the rock type, water bearing conditions, rock bolt type and length. The test results showed that the fully grouted rock bolt (FGR) in water-bearing rocks can be inadequate to provide the required pullout resistance, meanwhile the inflated steel tube rock bolt (ISR) satisfied required pullout resistance, even immediately after installation in water-bearing conditions. The ISR was particularly effective when the water inflow into a drill hole is greater than 1.0 l/min. The effect of the rock bolt failure on the tunnel stability was investigated through numerical analysis. The results show that the contribution of the rock bolt to the overall stability of the tunnel was not significant. However, it is found that the rock bolt can effectively reinforce the jointed-rock mass and reduce the possibility of local collapses of rocks, thus the importance of the rock bolt should not be overlooked, regardless of the overall stability.