• Title/Summary/Keyword: Water film

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The Effects of Deposition Temperature of Pt Top Electrodes on the Electrical Properties of PZT Thin Films (Pt 상부 전극 증착온도가 PZR 박막의 전지적 특성에 미치는 영향)

  • Lee, Kang-Woon;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.8 no.11
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    • pp.1048-1054
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    • 1998
  • The effects of deposition temperature of Pt top electrodes on the electrical properties of Pb(Zr,Ti))$O_3$, (PZT) thin film were investigated. When the Pt top electrodes were deposited at substrate temperatures of $200^{\circ}C$ or above,the ferroelectric properties of the PZT thin film under the Pt electrode were severely degraded. Whereas those of the PZT film where the Pt electrodes were not deposited were not degraded. Water vapors which remained in the vacuum chamber were dissociated into hydrogen atoms by the catalysis of Pt top electrode, and those hydrogen atoms diffused into the PZT film and produced oxygen vacancies at high substrate temperature, resulting in the degradation of the ferroelectric properties of the PZT film located under the Pt electrode. Since the water vapors could not be dissociated into hydrogen atoms without the catalysis of Pt. the degradation of the PZT film did not take place where the Pt electrode were not deposited. The degraded feroelectric properties could be recovered by rapid thermal annealing (RTA) treatment. On the other hand. leakage current characteristics were improved with increasing the deposition temperature of Pt top electrodes.

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Humidity Dependence of the Residual Stress of Diamond-like Carbon Film (습도에 따른 다이아몬드성 카본필름의 잔류응력 변화에 대한 연구)

  • Lee Young-Jin;Kim Tae-Young;Lee Kwang-Ryeol;Yang In-Sang
    • Journal of the Korean Vacuum Society
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    • v.13 no.4
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    • pp.157-163
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    • 2004
  • Dependence of residual compressive stress of diamond-like carbon (DLC) films on relative humidity was investigated. Polymeric, graphitic and diamond-like carbon films were prepared by r.f.-PACVD using methane or benzene with the negative self bias voltage of the substrate ranging from -100 to -800 V. In-situ measurements of the residual stress were carried out in an environment chamber where the relative humidity was varied from 10% to 90%. In dense DLC film of high residual compressive stress and hardness, we could not observe any change in the residual compressive stress with relative humidity. However, in the cases of graphitic and polymeric DLC films, abrupt change in the residual stress occurred by changing the relative humidity. The quantity of the stress change was inversely proportional to the film thickness, which means that the stress change with humidity is not due to the penetration of the water molecule into the film structure, but due to surface interaction between water molecules and film surface.

Desalinization Effect of Off-season Crop Cultivation in Long-term Oriental Melon Cultivated Plastic Film House Soils (휴경기 후작물 재배에 의한 참외 장기연작 비닐하우스 토양의 제염 효과)

  • Byeon, Il-Su;Chung, Jong-Bae
    • Korean Journal of Environmental Agriculture
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    • v.34 no.4
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    • pp.253-259
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    • 2015
  • BACKGROUND: During the off-season, the cultivation of Chinese cabbage and water dropwort is often used to desalinize plastic film house soils. The objective of this study was to verify the effect of double-cropping systems on the salt removal in oriental melon cultivated plastic film house soils.METHODS AND RESULTS: Electrical conductivity (EC) and soluble salt contents were measured in soils collected from plastic film houses of oriental melon cultivation before and after the off-season crop cultivation. Also the same measurements were performed in the next oriental melon season to estimate the desalinization effect of double-cropping systems. During the cultivation of Chinese cabbage under open-field condition, ECeof surface soil was reduced from 6.0 to 0.8 dS/m. Double-cropping of water dropwort in flooded soil was also efficient in removing the salts accumulated during oriental melon cultivation. In the house soils where salts were removed during the off-season crop cultivation, soil ECewas maintained below 3 dS/m during the next oriental melon cultivation season.CONCLUSION: The off-season cropping under open-field or flooded condition was effective in desalinization of plastic film house soils. Since the salt removal effect is not expected to last for several years, the double-cropping system should be introduced every season to maintain soil EC below the critical level.

The Design and Hot-firing tests of a Water-cooled High Pressure Sub-scale Combustor (물냉각 고압 축소형 연소기의 설계 및 연소시험)

  • Lee, Kwang-Jin;Kim, Jong-Gyu;Lim, Byoung-Jik;Ahn, Kyu-Bok;Seo, Seong-Hyeon;Han, Yeoung-Min;Choi, Hwan-Seok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.3
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    • pp.1-6
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    • 2007
  • A 3-tonf-class high pressure sub-scale combustor was designed and manufactured to study the performance improvement of combustor. The combustor consists of a combustion chamber with film cooling, thermal barrier coating and water cooling channels to prevent thermal demage of the hardware and an injector head with 37 coaxial swirl injectors. Hot-firing tests were carried out at the design point with varying flow rate for film cooling. The test result revealed that the increase of film cooling flow rate decreases the combustion performance, but in the cases of similar film cooling flow rates, the combustion performance is dependent on the mixture ratio of main injector excluding the film cooling flow rate.

Experimental investigation of two-phase flow and wall heat transfer during reflood of single rod heater (단일 가열봉의 재관수 시 2상유동 및 벽면 열전달에 관한 실험적 연구)

  • Park, Youngjae;Kim, Hyungdae
    • Journal of the Korean Society of Visualization
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    • v.18 no.3
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    • pp.23-34
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    • 2020
  • Two-phase flow and heat transfer characteristics during the reflood phase of a single heated rod in the KHU reflood experimental facility were examined. Two-phase flow behavior during the reflooding experiment was carefully visualized along with transient temperature measurement at a point inside the heated rod. By numerically solving one-dimensional inverse heat conduction equation using the measured temperature data, time-resolved wall heat flux and temperature histories at the interface of the heated rod and coolant were obtained. Once water coolant was injected into the test section from the bottom to reflood the heated rod of >700℃, vast vapor bubbles and droplets were generated near the reflood front and dispersed flow film boiling consisted of continuous vapor flow and tiny liquid droplets appeared in the upper part. Following the dispersed flow film boiling, inverted annular/slug/churn flow film boiling regimes were sequentially observed and the wall temperature gradually decreased. When so-called minimum film boiling temperature reached, the stable vapor film between the heated rod and coolant was suddenly collapsed, resulting in the quenching transition from film boiling into nucleate boiling. The moving speed of the quench front measured in the present study showed a good agreement with prediction by a correlation in literature. The obtained results revealed that typical two-phase flow and heat transfer behaviors during the reflood phase of overheated fuel rods in light water nuclear reactors are well reproduced in the KHU facility. Thus, the verified reflood experimental facility can be used to explore the effects of other affecting parameters, such as CRUD, on the reflood heat transfer behaviors in practical nuclear reactors.

Characterization of LLDPE/CaCO3 Composite Drawn Film (연신된 LLDPE/CaCO3 composite film의 특성분석)

  • Lee, Jungeon;Park, Jae Min;Jung, Jae Hoon;Kim, Tae Young;Han, Myung Dong;Seo, Jang Min;Seo, Min Jeong;Yang, Seong Baek;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.34 no.1
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    • pp.68-75
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    • 2022
  • The breathable film refers to a high-functional film that allows gas and water vapor to pass through very fine and sophisticated pores but not liquid. In this research, the breathable film was prepared based on linear low-density polyethylene (LLDPE) and CaCO3 particles by extrude method. The LLDPE composite film containing CaCO3 particles had excellent mechanical properties and functionalties. The drawing is a technologically simple and excellent method for improving the mechanical properties of composite films. In this work, the effects of draw ratio on morphology, crystallinity, pore size distribution, mechanical properties, and water vapor permeability of the films were examined. The results revealed that both surface morphology and breathability were affected by the influence of chain orientation and crystal growth with increasing the draw ratio. The mechanical properties were improved with increasing the draw ratio.

Preparation of Coating Film with Antibacterial and Antifogging Function on PET Substrate (PET 기재 위에 항균성과 김서림 방지 기능을 갖는 코팅 도막 제조)

  • Ho Chan Kwon;Ki Chang Song
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.439-445
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    • 2023
  • In this study, silver nanoparticles were synthesized by reducing silver nitrate with PVA, and the solution prepared by adding carboxymethyl cellulose (CMC) to the silver nanoparticles was coated on a PET substrate to prepare a coating film with antibacterial and antifogging function. When the coating films were in contact with water vapor at 80 ℃, the uncoated PET substrate was blurred due to the scattering of light due to the occurrence of fog, while the coating film coated with silver nanosol with CMC remained transparent despite contact with water vapor, showing excellent antifogging function. In addition, the antibacterial properties of the coating films were measured by film adhesion method for Staphylococcus aureus, gram-positive bacteria, and Escherichia coli, gram-negative bacteria. The uncoated PET substrate showed a large number of colonies of Staphylococcus aureus and Escherichia coli, while the coating film coated with the silver nanosol greatly inhibited the growth of Staphylococcus aureus and Escherichia coli, resulting in excellent antibacterial effect.

Measurement of Proton Beam Dose-Averaged Linear Energy Transfer Using a Radiochromic Film

  • Seohyeon An;Sang-il Pak;Seonghoon Jeong;Soonki Min;Tae Jeong Kim;Dongho Shin;Youngkyung Lim;Jong Hwi Jeong;Haksoo Kim;Se Byeong Lee
    • Progress in Medical Physics
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    • v.33 no.4
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    • pp.80-87
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    • 2022
  • Purpose: Proton therapy has different relative biological effectiveness (RBE) compared with X-ray treatment, which is the standard in radiation therapy, and the fixed RBE value of 1.1 is widely used. However, RBE depends on a charged particle's linear energy transfer (LET); therefore, measuring LET is important. We have developed a LET measurement method using the inefficiency characteristic of an EBT3 film on a proton beam's Bragg peak (BP) region. Methods: A Gafchromic EBT3 film was used to measure the proton beam LET. It measured the dose at a 10-cm pristine BP proton beam in water to determine the quenching factor of the EBT3 film as a reference beam condition. Monte Carlo (MC) calculations of dose-averaged LET (LETd) were used to determine the quenching factor and validation. The dose-averaged LETs at the 12-, 16-, and 20-cm pristine BP proton beam in water were calculated with the quenching factor. Results: Using the passive scattering proton beam nozzle of the National Cancer Center in Korea, the LETd was measured for each beam range. The quenching factor was determined to be 26.15 with 0.3% uncertainty under the reference beam condition. The dose-averaged LETs were measured for each test beam condition. Conclusions: We developed a method for measuring the proton beam LET using an EBT3 film. This study showed that the magnitude of the quenching effect can be estimated using only one beam range, and the quenching factor determined under the reference condition can be applied to any therapeutic proton beam range.

Photolithography process investment of water soluble photoresist and Organic thin film by using it. (수용성 포토레지스트와 이를 이용한 유기 박막의 photolithography 공정 연구)

  • Kim, Kwang-Hyun;Kim, Gun-Ju;Ryu, Ki.-Sung;Kim, Tae-Ho;Song, Jung-Kun
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.497-500
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    • 2004
  • In this paper, we developed a new photolithography process which used a water-soluble photoresist instead of organic solvent soluble photoresist, defined pentacene thin film. And pentacene OTFTs were fabricated with the water- soluble photolithography process.

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Evaporation Characteristics of a Water Droplet Containing Sodium Acetate Trihydrate as an Additive (첨가제로 아세트산 나트륨-3수화물을 함유한 물 액적의 증발 특성)

  • Park, Jae-Man;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.61-68
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    • 2004
  • The evaporation phenomena of waterr droplet which has sodium acetate trihydrate($CH_3COONa{\cdot}3H_2O$) as a fire suppression additive were studied. Solutions of sodium salt up to 50% and heated stainless-steel surface were used in the experiment. The evaporation process was recorded using a charge-coupled-device camera at 120 frames per second. The average evaporation rate of the sodium acetate trihydrate soluation was lower than that of pure water at a given surface temperature and decreased with the concentration increase due to the precipitation of salt in the liquid film and change of surface tension. The variation of liquied film diameter was measured by time and it was increased by the hot surface temperature increase.