• Title/Summary/Keyword: Water diffusion coefficient

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Experimental Study on the Penetration Depth and Concentration of Corrosion Inhibitor Using Press-in Method Into the Inside of Concrete (콘크리트 내부로의 압입공법을 사용한 방청제의 침투깊이 및 농도에 관한 실험적 연구)

  • Cho, Hyeong-Kyu;Yoo, Jo-Hyeong;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.5 s.57
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    • pp.160-168
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    • 2009
  • After steel bar was corroded it removes concrete contaminated, it does steel bar corrosion protection, repairing method and corrosion inhibitor spreading method are difficult to secure corrosion protection performance. Accordingly, in this research before Research and Development to penetrate corrosion inhibitor to high pressure by steel bar position, it measures penetration depth through corrosion inhibitor high pressure penetration experiment and amount of nitrite by position and then it predicts penetration depth in accordance with water-cement ratio, pressure, pressure time and it computed water-cement ratio, pressure, pressure time to be more than 0.6 mol ratio of chloride ion and nitrite to have outstanding corrosion protection performance. As a result of experiment, water-cement ratio gives the biggest influence to penetration of corrosion inhibitor and also the more depth of specimen becomes deep, concentration of penetrated corrosion inhibitor does not equal and becomes low.

Evaluation of the Impact of Land Surface Condition Changes on Soil Moisture Field Evolution (지표면 조건의 변화에 따른 토양수분의 변화 평가)

  • Yu, Cheol-Sang
    • Journal of Korea Water Resources Association
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    • v.31 no.6
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    • pp.795-806
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    • 1998
  • Soil moisture is affected by regional climate, soil characteristics and land surface condition, etc,. Especially, the changes in land surface condition is more than other factors, which is mainly due to rapid urbanization and industrialization. This study is to evaluate how the change of land surface condition impacts on soil moisture field evolution using a simple model of soil moisture dynamics. For the quantification of soil moisture field, the first half of the paper is spared for the statistical characterization based on the first- and second-order statistics of Washita '92 and Monsoon '90 data. The second half is for evaluating the impact of land cover changes through simulation study using a model for soil moisture dynamics. The model parameters, the loss rate and the diffusion coefficient, have been estimated using the observed data statistics, where the changes of surface conditions are considered into the model by applying various parameter sets with different second-order statistics. This study is concentrated on evaluating the impact due to the changes of land surface condition variability. It is because we could easily quantify the impact of the changes of its areal mean based on the linear reservoir concept. As a result of the study, we found; (1)as the variability of land surface condition, increases, the soil moisture field dries up more easily, (2)as the variabilit y of the soil moisture field is the highest at the beginning of rainfall and decreases as time goes on to show the variability of land surface condition, (3)the diffusion effect due to surface runoff or water flow through the top soil layer is limited to a period of surface runoff and its overall impact is small compared to that of the loss rate field.

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Reduction of Skin Irritation by the Control of Skin Permeation of Methyl Paraben

  • Seong-Hoon Jeong;Mun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.108-114
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    • 1997
  • The skin permeation study has two meanings in cosmetics. One is how to promote the skin permeation of active meterials for improving their bioavailabilities and the other is how to decrease it of irritants for reducing their skin side effects. In this study, we selected methyl paraben, one of the preservatives, as a model irritant and tried to reduce the skin irritation by the decrease of skin permeation. Furthermore, the relationship between skin permeation and skin primary irritation was discussed. For in vitro skin permeation experiments, Franz type diffusion cells and the excised skin of female hairless mouse from 8 weeks old were used. The donor compartment was charged with oil only or O/W emulsion containing 0.3% MP. We selected 19 oils, including esters, triglycerides, plant oils, hydrocarbons, and alchols, which are broadly used in cosmetics. We evaluated with female guinea pig. The skin permeahility of MP from the oils showed following order: ester oils > triglycerides > plant oils > hydrocarbons > alcohols. We considered that this result was based on the different effect of each oil on the barrier function of stratum corneum. In O/W emulsion containing each oil, the skin permeability of MP decreased as the oil/water partition coefficient of MP increased. The skin primary irritation increased as the skin permeability of MP increased. In conclusion, we suggest that the skin irritation could be reduced by the decrease of skin permeability of MP, which may be obtained by the good selection of oils in cosmetic preparations.

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Kinetic Modeling of Dewatering of Potato Slice When Soaked in Concentrated Solution (고농도 용액에 침지시 감자 절편의 동력학적 탈수 모델링에 관한 연구)

  • 최동원;신해헌
    • The Korean Journal of Food And Nutrition
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    • v.13 no.5
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    • pp.477-482
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    • 2000
  • For the purpose of explaining the dewatering phenomena of potato slice soaked in concentrated solution three models were proposed. Earlier model cannot explain the dewatering phenomena of potato slice in concentrated solution because of limiting its condition which is necessary to build a model. Therefore other three models were suggested and a model based on Fick\`s second law of mass transport at infinite plate conditions and numerical analysis was test model for explaining dewatering phenomena of potato soaked in concentrated solution. Apparent diffusion coefficient of water could be readily estimated from model III, and it could explain adequately the difference of the dewatering phenomena of various soaking conditions.

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Performance Analysis for Open-loop Geothermal System with Spill-way technology by Real-scale Experiment (관정간 도수통로를 설치한 개방형 지열 시스템의 냉방성능 실험)

  • Kim, Hong kyo;Bae, Sangmu;Nam, Yujin;Jeoun, Oun;Oh, Jong Hyun;Lee, Byong Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.30 no.4
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    • pp.186-194
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    • 2018
  • A ground-source heat pump system (GSHP) is more energy efficient than other heat-source systems because it uses annual constant underground and water temperatures. Especially, two-well geothermal systems using groundwater as the heat source can achieve higher performance than closed-loop geothermal systems. However, performance of two-well geothermal systems is decreased by occurring overflow according to scale during long-term operations. Therefore, this study presents a two-well pairing geothermal system that controls the groundwater level of a diffusion well. In addition, a two-well pairing geothermal system and an SCW geothermal system were installed, and a comparative analysis of cooling performance depending on system operation under the same load conditions was conducted. The result was that the average heat pump coefficient of performance (COP) of the two-well pairing system was 6.5, and the entire system COP was 4.3.

The Characteristics of Bioremediation for VOCs in Soil Column (VOCs처리를 위한 미생물의 토양복원화 특성)

  • 손종렬;장명배
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.9-12
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    • 2002
  • Diffusive transport of volatile organic compounds(VOCs) and their degradation by bacteria in unsaturated soils are couple by poorly understood mass transfer kinetics at the gas/water interface. Determination of the fate of VOCs in unsaturated soil is necessary to evaluate the feasibility of natural attenuation as a VOC remediation strategy. The objective of this study was to develop a mechanistically based mathematical model that would consider the interdependence of VOC transport, microbial activity, and sorptive interaction in a moist, unsaturated soil. Because the focus of the model was on description of natural attenuation, the advective VOC transport that is induced in engineered remediation processes such as vapor extraction was not considered. The utility of the model was assessed through its ability to describe experimental observations form diffusion experiments using toluene as a representative VOC in well-defined soil columns that contained a toluene degrading bacterium, Pseudomonas Putida, as the sole active microbial species. The coefficient for gas-liquid mass-transfer, K$\sub$LA/, was found to be a key parameter controlling the ability of bacteria to degrade VOCs. This finding indicates that soil size and geometry are likely to be important parameters in assessing the possible success of natural attenuation of VOCs in contaminated unsaturated soils.

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Physical Properties and Dyeing Behaviors of Cellulosic Fabrics Treated with Liquid Ammonia (액체암모니아 처리한 셀룰로오스계 직물의 물성 및 염색성)

  • 배소영;이문철;김경환;일본명
    • Textile Coloration and Finishing
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    • v.7 no.1
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    • pp.10-22
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    • 1995
  • Cellulosic fabrics, i.e. rayon, polynosic, and linen were treated with liquid ammonia at -33.4$^{\circ}C$. The fine structures, bending properties, tensile strength, wrinkle recoveries, and dyeing properties of the treated fabrics were studied. Dyeing was carried out with two direct dyes, C. I. Direct Red 2 and Blue 1. The liquid ammonia treatment for three fabrics brought about the transition of crystal lattices and the decrease of crystallinity; transforming cellulose I structure of original linen to cellulose I and III structure, and cellulose II structure of original rayon and polynosic to cellulose II and III structure. Moisture regain of liquid ammonia- treated polynosic and linen was higher than that for untreated, and water absorbency of liquid ammonia-traeated fabrics was all lower than that of untreated. Also, bending properties of treated fabrics were not improved compared with those of untreated ones. The rayon treated with liquid ammonia was increased not only the apparent diffusion coefficient and the rate of dyeing but also equilibrium dye adsortion, whereas polynosic and linen were increased only equilibrium dye adsortion. It is suggested that the pore sizes of liquid ammonia-treated rayon, polynosic, and linen are much smaller than that of liquid ammonia-treated cotton.

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Conceptual Modeling Coupled Thermal-Hydrological-Chemical Processes in Bentonite Buffer for High-Level Nuclear Waste Repository (고준위 방사성폐기물 처분장에서 벤토나이트 완충제에 대한 열-수리-화학 작용 개념 모델링)

  • Choi, Byoung-Young;Ryu, Ji-Hun;Park, Jinyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.1
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    • pp.1-9
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    • 2016
  • In this study, thermal-hydrological-chemical modeling for the alteration of a bentonite buffer is carried out using a simulation code TOUGHREACT. The modeling results show that the water saturation of bentonite steadily increases and finally the bentonite is fully saturated after 10 years. In addition, the temperature rapidly increases and stabilizes after 0.5 year, exhibiting a constant thermal gradient as a function of distance from the copper tube. The change of thermal-hydrological conditions mainly results in the alteration of anhydrite and calcite. Anhydrite and calcite are dissolved along with the inflow of groundwater. They then tend to precipitate in the vicinity of the copper tube due to its high temperature. This behavior induces a slight decrease in porosity and permeability of bentonite near the copper tube. Furthermore, this study finds that the diffusion coefficient can significantly affect the alteration of anhydrite and calcite, which causes changes in the hydrological properties of bentonite such as porosity and permeability. This study may facilitate the safety assessment of high-level radioactive waste repositories.

Development of Three Dimensional Chloride Ion Penetration Model Based on Finite Element Method (유한요소법을 이용한 3차원 염해 침투 예측 모델의 개발)

  • Choi, Won;Kim, Hanjoong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.5
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    • pp.43-49
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    • 2015
  • Most of agricultural structures located in seashore could not avoid rapid deterioration of concrete because chloride-ion and $CO_2$ gradually penetrate into concrete. However, since most of models can be able to describe the phenomenon of penetration by using one or two dimensional models based on finite difference method (FDM), those modes can not simulate the real geometry and it takes a lot of computational time to complete even the calculation. To overcome those weaknesses, three dimensional numerical model considering time dependent variables such as surface concentration of chloride and diffusion coefficient of domain based on finite element method (FEM) was suggested. This model also included the neutralization occurred by the penetration of $CO_2$. Because the model used various sizes of tetrahedral mesh instead of equivalent rectangular mesh, it reduced the computational time to compare with FDM. As this model is based on FEM, it will be easily extended to execute multi-physics simulation including water evaporation and temperature change of concrete.

Preparation and Characterization of Crosslinked Sodium Alginate Membranes for the Dehydration of Organic Solvents

  • Goo, Hyung Seo;Kim, In Ho;Rhim, Ji Won;Golemme, Giovanni;Muzzalupo, Rita;Drioli, Enrico;Nam, SangYong
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.55-60
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    • 2004
  • In recent years, an increasing interest in membrane technology has been observed in chemical and environmental industry. Membrane technology has advantages of low cost, energy saving and environmental clean technology comparing to conventional separation processes. Pervaporation is one of new advanced membrane technology applied for separation of azeotropic mixtures, aqueous organic mixtures, organic solvent and petrochemical mixtures. Sodium alginate composite membranes were prepared for the enhancement of long-term stability of pervaporation performance of water-ethanol mixture using pervaporation. Sodium alginate membranes were crosslinked with CaCl$_2$ and coated with polyelectrolyte chitosan to protect washing out of calcium ions from the polymer. The surface structures of PAN and hydrolysed PAN membrane were confirmed by ATR Fourier transform infrared (FT-IR). A field emission scanning electron microscopy (FE-SEM; Jeol 6340F) operated at 15 kV. Concentration profiles for Ca in the membrane surface and membrane cross-section were taken by an energy dispersive X-ray (EDX) analyser (Jeol) attached to the field emission scanning electron microscopy (Jeol 6340F). Pervaporation experiments were done with several operation run times to investigate long-term stability of the membranes.