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A Study on Production of Nitrogen Oxides in Plasma Reactors

  • Lim, Gye-Gyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E3
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    • pp.91-99
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    • 2001
  • Plasma reactor was used to generate a high potential difference between two surfaces of concentric pyrex tubes by electrical current. The annular gap of the reactor was calculated by trial and error from the breakdown voltage equation and set at 0.45 cm. The overall objective of this research was to know the effects of the frequency, humidity, and residence time on the formation of nitrogen oxides in a plasma reactor. The primary voltage varied from 50 to 90 volts and the frequency was varied in increments of 10 Hz from 60 to 650 Hz at the primary voltage of 90. The increase in the secondary voltage was not linear but exponential at high frequencies. At a maximum concentration of about 745 ppm, the frequency and secondary voltage was 600 Hz and 4,200 volts, respectively. All tests for the effects of humidity on NO$_{x}$ production were performed at the optimal setting of 90 colts and 600 Hz frequency. Since the NO$_{x}$ production was not an one dimensional phenomenon, competing reactions were assumed to occur in the discharge chamber. The sharp peak concentration of 1,810 ppm was observed at 38% of relative humidity, The enhanced production was choked off, and the production rate rapidly dropped to 3 ppm at above 40% of relative humidity. It is assumed that the corona attacks the most vulnerable molecules in the reaction chamber before attacking other more lightly bonded molecules, possibly at humidities above 38% and the optimized 90 volt setting. Thus, there was not enough energy left after attacking all water molecules to decompose an appreciable amount of $N_2$. If nitrogen breakdown does not occur, then oxides of nitrogen are not likely to be produced.ced.

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Evaluation on the Rlationship between Wear Ratio and Polarization Characteristics of Anti-Fouling Paint (방오도료 도막의 마모율과 분극특성의 상관관계에 관한 평가)

  • Jeong, Jae-Hun;Moon, Kyung-Man;Won, Jong-Pil;Park, Dong-Hyun;Kim, Yun-Hae;Kim, Hyun-Myung;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Corrosion Science and Technology
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    • v.13 no.1
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    • pp.15-19
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    • 2014
  • Recently, anti-fouling paints which does not include the poison components such as tin(Sn), copper(Cu) have been increasingly developed in order to inhibit the environmental contamination of the sea water. Moreover, the wear ratios of these anti-fouling paints are very important problem to prolong their life time in economical point of view. In this study, five types of anti-fouling paints as self polishing type were investigated on the relationship between their polarization characteristics and wear ratios. It was verified that there was apparently a good relationship between the wear ratio and polarization characteristics, for example, the wear ratio increased with increasing the impedance ratio, and increased or decreased with the corrosion potential shifting in the negative or positive direction respectively. In addition, the wear ratio decreased with decreasing the corrosion current density. Consequently, it is suggested that we can qualitatively expect the wear ratio by only measuring the polarization characteristics. Therefore, before the examination of the wear ratio was actually carried out in the field, the evaluation of polarization property in the laboratory may give a available reference data for their developments.

Development of Watershed-based Surface Soil Information System based on Web GIS (Web GIS기반의 수계기반 표토정보 시스템 개발)

  • Sung, Yunsoo;Lee, Dongjun;Lim, Kyoung Jae;Yang, Jae E;Lee, Seoro;Kim, Jonggun
    • Journal of Soil and Groundwater Environment
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    • v.22 no.6
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    • pp.94-103
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    • 2017
  • Surface soil is one of the most important resources that have many functions for human needs such as conservation of water resource, purification of contaminated materials, and productivity of food or energy. However, the surface soil is a limited resource that cannot be recovered readily for a long time once it is lost by erosion. In Korea, the Ministry of Environment enacted the notification on the investigation of surface soil erosion and corresponding countermeasures. As the results, database of soil quality assess criteria (biomass, groundwater recharge, habitat, carbon storage, buffer, and soil loss) was established, and the web-based system that can evaluate surface soil conditions was developed. However, non-experts have difficulties in using the system because the system requires in-depth knowledge about soil qualities. In this study, the Web Geographic Information System (GIS) watershed-based surface soil information system was developed to improve usability of the system and accessibility of soil quaility database. The system provides the current condition of surface soil characteristics and GIS-based soil data at selected locations. The users are able to download soil quality data in different districts, watersheds, and special regions allocated by TauDEM module. The system developed in this study would valuable surface soil information for studies of soil quality and its environmental effects, and thereby contributing to establishing more appropriate and robust soil conservation laws.

An investigation on the improvement of neutron radiography system of the Tehran research reactor by using MCNPX simulations

  • Amini, Moharram;Zamzamian, Seyed Mehrdad;Fadaei, Amir Hossein;Gharib, Morteza;Feghhi, Seyed Amir Hosein
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3413-3420
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    • 2021
  • Applying the available neutron flux for medical and industrial purposes is the most important application of research reactors. The neutron radiography system is used for non-destructive testing (NDT) of materials so that it is one of the main applications of nuclear research reactors. One of these research reactors is the 5 MW pool-type light water research reactor of Tehran (TRR). This work aims to investigate on materials and location of the beam tube (BT) of the TRR radiography system to improve the index parameters of BT. Our results showed that a through-type BT with 20 cm thick carbon neutron filter, 1.2 cm and 9.4 cm of the diameter of inlet (D1) and output (D2) BT, respectively gives thermal neutron flux almost 25.7, 5.6 and 1.1 times greater than the former design of the TRR (with D1 = 1.8 cm and D1 = 9.4 cm), previous design of the TRR with D1 = 3 cm and D1 = 9.4 cm, and another design with D1 = 5 cm and D1 = 9.4 cm, respectively. Therefore, the design proposed in this paper could be a better alternative to the current BT of the TRR.

Optically Managing Thermal Energy in High-power Yb-doped Fiber Lasers and Amplifiers: A Brief Review

  • Yu, Nanjie;Ballato, John;Digonnet, Michel J.F.;Dragic, Peter D.
    • Current Optics and Photonics
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    • v.6 no.6
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    • pp.521-549
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    • 2022
  • Fiber lasers have made remarkable progress over the past three decades, and they now serve far-reaching applications and have even become indispensable in many technology sectors. As there is an insatiable appetite for improved performance, whether relating to enhanced spatio-temporal stability, spectral and noise characteristics, or ever-higher power and brightness, thermal management in these systems becomes increasingly critical. Active convective cooling, such as through flowing water, while highly effective, has its own set of drawbacks and limitations. To overcome them, other synergistic approaches are being adopted that mitigate the sources of heating at their roots, including the quantum defect, concentration quenching, and impurity absorption. Here, these optical methods for thermal management are briefly reviewed and discussed. Their main philosophy is to carefully select both the lasing and pumping wavelengths to moderate, and sometimes reverse, the amount of heat that is generated inside the laser gain medium. First, the sources of heating in fiber lasers are discussed and placed in the context of modern fiber fabrication methods. Next, common methods to measure the temperature of active fibers during laser operation are outlined. Approaches to reduce the quantum defect, including tandem-pumped and short-wavelength lasers, are then reviewed. Finally, newer approaches that annihilate phonons and actually cool the fiber laser below ambient, including radiation-balanced and excitation-balanced fiber lasers, are examined. These solutions, and others yet undetermined, especially the latter, may prove to be a driving force behind a next generation of ultra-high-power and/or ultra-stable laser systems.

The radiation shielding proficiency and hyperspectral-based spatial distribution of lateritic terrain mapping in Irikkur block, Kannur, Kerala

  • S. Arivazhagan;K.A. Naseer;K.A. Mahmoud;N.K. Libeesh;K.V. Arun Kumar;K.ChV. Naga Kumar;M.I. Sayyed;Mohammed S. Alqahtani;E. El Shiekh;Mayeen Uddin Khandaker
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3268-3276
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    • 2023
  • The practice of identifying the potential zones for mineral exploration in a speedy and low-cost method includes the use of satellite imagery analysis as a part of remote sensing techniques. It is challenging to explore the iron mineralization of a region through conventional methods which are a time-consuming process. The current study utilizes the Hyperion satellite imagery for mapping the iron mineralization and associated geological features in the Irikkur region, Kannur, Kerala. Along with the remote sensing results, the field study and laboratory-based analysis were conducted to retrieve the ground truth point and geochemical proportion to verify the iron ore mineralization. The MC simulation showed for shielding properties indicate an increase in the linear attenuation coefficient with raising the Fe2O3+SiO2 concentrations in the investigated rocks where it is varied at 0.662 MeV in the range 0.190 cm-1 - 0.222 cm-1 with rising the Fe2O3+SiO2 content from 57.86 wt% to 71.15 wt%. The analysis also revealed that when the γ-ray energy increased from 0.221 MeV to 2.506 MeV, sample 1 had the largest linear attenuation coefficient, ranging from 9.33 cm1 to 0.12 cm-1. Charnockite rocks were found to have exceptional shielding qualities, making them an excellent natural choice for radiation shielding applications.

MOF-Derived FeCo-Based Layered Double Hydroxides for Oxygen Evolution Reaction

  • Fang Zheng;Mayur A. Gaikwad;Jin Hyeok Kim
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.377-384
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    • 2023
  • Exploring earth-abundant, highly effective and stable electrocatalysts for electrochemical water splitting is urgent and essential to the development of hydrogen (H2) energy technology. Iron-cobalt layered double hydroxide (FeCo-LDH) has been widely used as an electrocatalystfor OER due to its facile synthesis, tunable components, and low cost. However, LDH synthesized by the traditional hydrothermal method tends to easily agglomerate, resulting in an unstable structure that can change or dissolve in an alkaline solution. Therefore, studying the real active phase is highly significant in the design of electrochemical electrode materials. Here, metal-organic frameworks (MOFs) are used as template precursors to derive FeCo-LDH from different iron sources. Iron salts with different anions have a significant impact on the morphology and charge transfer properties of the resulting materials. FeCo-LDH synthesized from iron sulfate solution (FeCo-LDH-SO4) exhibits a hybrid structure of nanosheets and nanowires, quite different from other electrocatalysts that were synthesized from iron chloride and iron nitrate solutions. The final FeCo-LDH-SO4 had an overpotential of 247 mV with a low Tafel-slope of 60.6 mV dec-1 at a current density of 10 mA cm-2 and delivered a long-term stability of 40 h for the OER. This work provides an innovative and feasible strategy to construct efficient electrocatalysts.

Thin Film Nanocomposite Based Nanofiltration Membrane for Wastewater Treatment: Fabrication and Dyes Removal (폐수처리용 박막나노복합체 기반 나노여과막: 제조 및 염료제거)

  • Dohoon Park;Rajkumar Patel
    • Membrane Journal
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    • v.34 no.3
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    • pp.182-191
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    • 2024
  • This review addresses the pressing need for effective wastewater treatment methodologies by exploring advanced thin-film nanocomposite (TFN) nanofiltration membranes aimed at efficient dye removal from industrial effluents. Utilizing insights from recent research, the review focuses on the fabrication of TFN membranes incorporating innovative materials such as nanocarbons, silica nanospheres, metal-organic frameworks (MOFs), and MoS2. The primary goals are to enhance dye removal efficiency, improve antifouling properties, and maintain high selectivity for dye/salt separation. By leveraging the distinct advantages of these nanomaterials-including large surface areas, mechanical robustness, and specific pollutant interaction capabilities-this review aims to overcome the limitations of current nanofiltration technologies and provide sustainable solutions for water treatment challenges.

Recent Progress in Air Conditioning and Refrigeration Research - A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2004 and 2005 - (공기조화, 냉동 분야의 최근 연구 동향 -2004년 및 2005년 학회지 논문에 대한 종합적 고찰-)

  • Choi, Yong-Don;Kang, Yong-Tae;Kim, Nae-Hyun;Kim, Man-Hoe;Park, Kyoung-Kuhn;Park, Byung-Yoon;Park, Jin-Chul;Hong, Hi-Ki
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.1
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    • pp.94-131
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    • 2007
  • A review on the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering in 2004 and 2005 has been done. Focus has been put on current status of research in the aspect of heating, cooling, air-conditioning, ventilation, sanitation and building environment. The conclusions are as follows. (1) Most of fundamental studies on fluid flow were related with heat transportation of facilities. Drop formation and rivulet flow on solid surfaces were interesting topics related with condensation augmentation. Research on micro environment considering flow, heat, humidity was also interesting for comfortable living environment. It can be extended considering biological aspects. Development of fans and blowers of high performance and low noise were continuing topics. Well developed CFD and flow visualization(PIV, PTV and LDV methods) technologies were widely applied for developing facilities and their systems. (2) The research trends of the previous two yews are surveyed as groups of natural convection, forced convection, electronic cooling, heat transfer enhancement, frosting and defrosting, thermal properties, etc. New research topics introduced include natural convection heat transfer enhancement using nanofluid, supercritical cooling performance or oil miscibility of $CO_2$, enthalpy heat exchanger for heat recovery, heat transfer enhancement in a plate heat exchanger using fluid resonance. (3) The literature for the last two years($2004{\sim}2005$) is reviewed in the areas of heat pump, ice and water storage, cycle analysis and reused energy including geothermal, solar and unused energy). The research on cycle analysis and experiments for $CO_2$ was extensively carried out to replace the Ozone depleting and global warming refrigerants such as HFC and HCFC refrigerants. From the year of 2005, the Gas Engine Heat Pump(GHP) has been paid attention from the viewpoint of the gas cooling application. The heat pipe was focused on the performance improvement by the parametric analysis and the heat recovery applications. The storage systems were studied on the performance enhancement of the storage tank and cost analysis for heating and cooling applications. In the area of unused energy, the hybrid systems were extensively introduced and the life cycle cost analysis(LCCA) for the unused energy systems was also intensively carried out. (4) Recent studies of various refrigeration and air-conditioning systems have focused on the system performance and efficiency enhancement. Heat transfer characteristics during evaporation and condensation are investigated for several tube shapes and of alternative refrigerants including carbon dioxide. Efficiency of various compressors and expansion devices are also dealt with for better modeling and, in particular, performance improvement. Thermoelectric module and cooling systems are analyzed theoretically and experimentally. (5) According to the review of recent studies on ventilation systems, an appropriate ventilation systems including machenical and natural are required to satisfied the level of IAQ. Also, an recent studies on air-conditioning and absorption refrigeration systems, it has mainly focused on distribution and dehumidification of indoor air to improve the performance were carried out. (6) Based on a review of recent studies on indoor environment and building service systems, it is noticed that research issues have mainly focused on optimal thermal comfort, improvement of indoor air Quality and many innovative systems such as air-barrier type perimeter-less system with UFAC, radiant floor heating and cooling system and etc. New approaches are highlighted for improving indoor environmental condition as well as minimizing energy consumption, various activities of building control and operation strategy and energy performance analysis for economic evaluation.

Vacuum Web-coater with High Speed Surface Modification Equipment for fabrication of 300 mm wide Flexible Copper Clad Laminate (FCCL) (초고속 대면적 표면 처리 장치가 부착된 300 mm 폭 연성 동박적층 필림 제작용 진공 웹 코터)

  • Choi, H.W.;Park, D.H.;Kim, J.H.;Choi, W.K.;Sohn, Y.J.;Song, B.S.;Cho, J.;Kim, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.16 no.2
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    • pp.79-90
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    • 2007
  • Prototype of $800{\ell}$ vacuum web coater (Vic Mama) consisting of ion source with low energy less than 250 eV for high speed surface modification and 4 magnetron sputter cathodes was designed and constructed. Its performance was evaluated through fabricating the adhesiveless flexible copper clad laminate (FCCL). Pumping speed was monitored in both upper noncoating zone pumped down by 2 turbo pumps with 2000 l/sec pumping speed and lower surface modification and sputter zone vacuumed by turbo pumps with 450 1/sec and 1300 1/sec pumping speed respectively. Ion current density, plasma density, and uniformity of ion beam current were measured using Faraday cup and the distribution of magnetic field and erosion efficiency of sputter target were also investigated. With the irradiation of ion beams on polyimide (Kapton-E, $38{\mu}m$) at different fluences, the change of wetting angle of the deionized water to polyimide surface and those of surface chemical bonding were analyzed by wetting anglometer and x-ray photoelectron spectroscopy. After investigating the deposition rate of Ni-Cr tie layer and Cu layer was investigated with the variations of roll speed and input power to sputter cathode. FCCL fabricated by sputter and electrodeposition method and characterized in terms of the peel strength, thermal and chemical stability.