• Title/Summary/Keyword: Water Vapor Density

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Analysis of Stomatal Traits of Non-woody Plant Species Present in a Riparian Park Area in Nakdong River (낙동강 수변 공원 지역에 서식하는 초본 식물의 기공 형질 분석)

  • Myeong-geun Song;Ki-jung Nam
    • Korean Journal of Ecology and Environment
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    • v.56 no.4
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    • pp.384-392
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    • 2023
  • Stomatal pore is an important physiological trait that is closely linked to photosynthesis and transpiration as carbon dioxide and water vapor move through it between the atmosphere and plants. The present study investigated stomatal traits, such as stomatal density, index and size, of herbaceous native and alien plant species living in a riparian park on the Nakdong River to understand how those traits vary and to know if successful settlement of alien plants is attributed to those traits. There was no difference in stomatal density, index and size between native and alien plants with kidney-shaped stomata, suggesting that an empty ecological niche is not an essential prerequisite for the successful settlement of alien plants. Stomatal density showed a negative correlation with leaf thickness and leaf dry weight content (LMDC), but there was no correlation with Specific leaf area (SLA). All plants with kidney-shaped stomata had amphistomatous leaves, and the density and size of dumbell-shaped stomata were lower than those of kidney-shaped stomata.

A NEW PRESSURE GRADIENT RECONSTRUCTION METHOD FOR A SEMI-IMPLICIT TWO-PHASE FLOW SCHEME ON UNSTRUCTURED MESHES (비정렬 격자 기반의 물-기체 2상 유동해석기법에서의 압력기울기 재구성 방법)

  • Lee, H.D.;Jeong, J.J.;Cho, H.K.;Kwon, O.J.
    • Journal of computational fluids engineering
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    • v.15 no.2
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    • pp.86-94
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    • 2010
  • A thermal-hydraulic code, named CUPID, has been developed for the analysis of transient two-phase flows in nuclear reactor components. A two-fluid three-field model was used for steam-water two-phase flows. To obtain numerical solutions, the finite volume method was applied over unstructured cell-centered meshes. In steam-water two-phase flows, a phase change, i.e., evaporation or condensation, results in a great change in the flow field because of substantial density difference between liquid and vapor phases. Thus, two-phase flows are very sensitive to the local pressure distribution that determines the phase change. This in turn puts emphasis on the accurate evaluation of local pressure gradient. This paper presents a new reconstruction method to evaluate the pressure gradient at cell centers on unstructured meshes. The results of the new scheme for a simple test function, a gravity-driven cavity, and a wall boiling two-phase flow are compared with those of the previous schemes in the CUPID code.

IMPROVEMENT OF A SEMI-IMPLICIT TWO-PHASE FLOW SOLVER ON UNSTRUCTURED MESHES (비정렬 격자계에서의 물-기체 2상 유동해석코드 수치 기법 개선)

  • Lee, H.D.;Jeong, J.J.;Cho, H.K.;Kwon, O.J.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.380-388
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    • 2010
  • A thermal-hydraulic code, named CUPID, has been developed for the analysis of transient two-phase flows in nuclear reactor components. A two-fluid three-field model was used for steam-water two-phase flows. To obtain numerical solutions, the finite volume method was applied over unstructured cell-centered meshes. In steam-water two-phase flows, a phase change, i.e., evaporation of condensation, results in a great change in the flow field because of substantial density difference between liquid and vapor phases. Thus, two-phase flows are very sensitive to the local pressure that determines the phase change. This in turn puts emphasis on the accurate evaluation of local pressure gradient. This paper presents a new numerical scheme to evaluate the pressure gradient at cell centers on unstructured meshes. The results of the new scheme for a simple test function a gravity-driven cavity, and a wall boiling two-phase flow are compared with those of the previous schemes in the cupid code.

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Water vapor in high-mass star-forming regions and PDRs: the Herschel/HIFI view

  • Choi, Yunhee;van der Tak, Floris F.S.;van Dishoeck, Ewine F.;Bergin, Edwin A.
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.42.2-43
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    • 2015
  • Massive stars play a major role in the interstellar energy budget and the shaping of the galactic environment. The water molecule is thought to be a sensitive tracer of physical conditions and dynamics in star-forming regions because of its large abundance variations between hot and cold regions. Herschel/HIFI allows us to observe the multiple rotational transitions of H2O including the ground-state levels, and its isotopologues toward high-mass star-forming regions in different evolutionary stages. Photodissociation regions (PDRs) are also targeted to investigate the distribution of water and its chemistry. We present line profiles and maps of H2O using data from two guaranteed-time key programs "Water In Star-forming regions with Herschel" and "Herschel observations of EXtra-Ordinary Sources". We analyze the temperature and density structures using LTE and non-LTE methods. We also estimate turbulent and expansion velocities, and abundance of water in the inner and outer envelopes using the 1D radiative transfer code. Around high-mass protostars we find H2O abundances of ~10-8-10-9 for the outer envelope and ~10-4-10-5 for the inner envelope, and expansion and turbulent velocities range from 1.0 km s-1 to 2.0 km s-1. The abundances and kinematic parameters of the sources do not show clear trends with evolutionary indicators. The Herschel/HIFI mapping observations of H2O toward the Orion Bar PDR show that H2O emission peaks between the shielded dense gas and the radicals position, in agreement with the theoretical and the observational PDR structure. The derived H2O abundance is ~10-7 and peaks at the depth of AV ~8 mag from the ionization front. Together with the low ortho-to-para ratio of H2O (~1) presented by Choi et al. (2014), our results show that the chemistry of water in the Orion Bar is dominated by photodesorption and photodissociation.

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Removal of Hydrogen Fluoride from Waterjet Plasma Wastewater by Electrocoagulation (전해응집법에 의한 불화수소 함유 워터젯 플라즈마 폐수처리)

  • Lee, Chae Hong;Chun, Young Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.10
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    • pp.702-708
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    • 2012
  • Tetrafluoromethane ($CF_4$) has been used as etching and Chemical Vapor Deposition (CVD) gases for semiconductor manufacturing processes. These gases need to be removed efficiently because of their strong absorption of infrared radiation and long atmospheric lifetimes which cause the global warming effect. Also, the wastewater including the fluorine is caused by of the ground water pollution. Long-term consumption of water containing excessive fluoride can lead to fluorosis of the teeth and bones. The wastewater including the fluorine among the by-product which is generated by using the waterjet plasma after destroying $CF_4$ by HF is generated. The system which can remove the hydrogen fluoride among the wastewater by using the electrocoagulation using this wastewater the aluminum electrode was developed. The operating condition such as initial pH, electrocoagulation time, wastewater flow rate, current density were investigated experimentally using a electrocoagulation. Through the parametric studies, the highest hydrogen fluoride destruction of 85% was achieved at 3.5 initial pH, 10 min electrocoagulation time, 10 mL/min wastewater flow rate and $159A/m^2$ current density.

A Study on Synthetic Method and Material Analysis of Calcium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Calcium Ammine Chloride의 합성방법 및 물질분석 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.199-207
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    • 2015
  • Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

Significant Structure of Liquid Water (물의 구조와 성질)

  • Pak, Hyung-Suk;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.8 no.2
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    • pp.68-74
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    • 1964
  • Water has the melting point, the boiling point, the heat of fusion, and the heat of vaporization all much higher than would be normally expected from the hydrogen compounds of the other members of the oxygen family. Another unique characteristic of ice-Ⅰ is its volume decrease which takes place in its melting. A number of significant efforts have been made in the past to explain these properties quantitatively. The authors, reasoning from the unusually great free surface energy of water and the characteristic volume change on melting, propose the structural model of liquid water as follows. On melting, fluidized vacancies of a molecular size are introduced. Thereupon, for the unusually great surface energy density, molecules surrounding the vacancies become to have close packed arrangement. But molecules not in direct contact with vacancies should still possess the original structure i. e., ice-Ⅰ. When a molecule adjacent to a vacancy jumps into the vacancy, the molecule attains the gaslike degree of freedom. Using the above model, the authors had developed the liquid partition function of water by applying the theory of significant structures in liquids. Molar volume, vapor pressure, entropy of fusion and entropy of vaporization were calculated over a wide temperature range. The results show good agreement with experimental observations.

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Emission Characteristics of VOCs in Drying Process for Plywood Manufacturing (합판 제조용 목재 건조공정에서의 휘발성 유기화합물(VOCs) 배출특성)

  • Jang, Jeong-Gook;Kim, Mi-Ran
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1381-1390
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    • 2008
  • Emission characteristics of volatile organic compounds (VOCs) were investigated in the flue gas emitted from wood drying process for plywood manufacturing. The moisture content of raw timber was average 48%, and its density was $831.55kg/m^3$. But the moisture content of dried wood is needed less than around 10%, thus the moisture contents of flue gas should be remarkably high(about 18.2 V/V%). Therefore, the vapor in flue gas is equivalent to 320 ton-vapor/day when 1100 ton-wood/day is treated in the wood drying process. The temperature of flue gas ranges from $140^{\circ}C\;to\;150^{\circ}C$ in each dryer stack with exception of the input site of wood(about $110^{\circ}C$). The velocity of flue gas in each stack ranges from 1.7 to 9.7m/sec. In order to assess the concentrations and attribution rate of odorous compounds, it was analyzed about 40 VOCs in the flue gases. It was found that the major odorous compounds were 8 compounds, and the concentrations of major VOCs(ppm) were as follows; benzene: $0.054{\sim}0.052$, toluene: $1.011{\sim}2.547$, ethylbenzene: $0.472{\sim}2.023$, m,p-xylene: $0.504{\sim}3.245$, styrene: $0.015{\sim}0.148$, o-xylene : $0.271{\sim}1.097$, ethanol: $11.2{\sim}32.5$, ${\alpha}$-pinene: $0.908{\sim}10.578$, ${\beta}$-pinene: $0.982{\sim}14.278$. The attribution rate of terpenes (${\alpha}$-pinene, ${\beta}$-pinene) was about 60.56%, and that of aromatics and alcohols was about 22.77%, and 16.67%, respectively. It is suggested that the adequate control device should be used to control both the water soluble and non-soluble compounds because both compounds were mixed in flue gas.

Simulation on Isothermal Expansion of Water Oversaturated Perlite (퍼라이트의 팽창에 관한 등온 상태 전산 모사)

  • Kim, Ji-Hwan;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.424-432
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    • 2007
  • With the aiming to improve the comprehension of an expansion process of perlite, a numerical study has been carried out, concerning a water vapor bubble growth in a softened perlite melt. Isothermal case of the model is investigated and compared with the experimental results. Water content is an intrinsic parameter in a perlite expansion. With increasing water content, the expansion time is faster. But it can not be changed easily in an industrial process. Initial temperature is a changeable parameter in an industrial process. Higher initial temperature hastens the expansion time and this can be a key parameter in an industrial process. Experimental results are observed by SEM. Increasing initial temperature, perlite shape becomes close to sphere. Calculated bubble growth results are compared with experimental results. Packing density is measured and compared with simulated results. These results indicate that some other factors are applied on the model during heat transformation to work.

Al2O3 High Dense Single Layer Gas Barrier by Neutral Beam Assisted Sputtering (NBAS) Process

  • Jang, Yun-Seong;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.157-157
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    • 2015
  • Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low water vapor transition rate (WVTR) of $1{\times}10^{-6}g/m^2day$. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2day$) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study NBAS process was introduced to deposit enhanced film density single gas barrier layer with a low WVTR. Fig. 1. shows a schematic illustration of the NBAS apparatus. The NBAS process was used for the $Al_2O_3$ nano-crystal structure films deposition, as shown in Fig. 1. The NBAS system is based on the conventional RF magnetron sputtering and it has the electron cyclotron resonance (ECR) plasma source and metal reflector. $Ar^+$ ion in the ECR plasma can be accelerated into the plasma sheath between the plasma and metal reflector, which are then neutralized mainly by Auger neutralization. The neutral beam energy is controlled by the metal reflector bias. The controllable neutral beam energy can continuously change crystalline structures from an amorphous phase to nanocrystal phase of various grain sizes. The $Al_2O_3$ films can be high film density by controllable Auger neutral beam energy. we developed $Al_2O_3$ high dense barrier layer using NBAS process. We can verified that NBAS process effect can lead to formation of high density nano-crystal structure barrier layer. As a result, Fig. 2. shows that the NBAS processed $Al_2O_3$ high dense barrier layer shows excellent WVTR property as a under $2{\times}10^{-5}g/m^2day$ in the single barrier layer of 100nm thickness. Therefore, the NBAS processed $Al_2O_3$ high dense barrier layer is very suitable in the high efficiency OLED application.

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