• Title/Summary/Keyword: Water Vapor

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Effect of an Al underlayer on the Growth of mm-long Thin Multi-walled Carbon Nanotubes in Water-Assisted Thermal CVD

  • Choi, In-Sung;Jeon, Hong-Jun;Lee, Han-Sung;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.26-26
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    • 2009
  • Vertically aligned arrays of mm-long multi-walled carbon nanotubes (MWCNTs) on Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). The growth of CNTs was investigated by changing the experimental parameters such as growth temperature, growth time, gas composition, annealing time, catalyst thickness, and Al underlayer thickness. The 0.5-nm-thick Fe served as catalyst, underneath which Al was coated as a catalyst support as well as a diffusion barrier on the Si substrate. We grew CNTs by adding a little amount of water vapor to enhance the activity and the lifetime of the catalyst. Al was very good at producing the nm-size catalyst particles by preventing "Ostwald ripening". The Al underlayer was varied over the range of 15~40 nm in thickness. The optimum conditions for the synthesis parameters were as follows: pressure of 95 torr, growth temperature of $815^{\circ}C$, growth for 30 min, 60 sccm Ar + 60 sccm $H_2$ + 20 sccm $C_2H_2$. The water vapor also had a great effect on the growth of CNTs. CNTs grew 5.03 mm long for 30 min with the water vapor added while CNTs were 1.73 mm long without water vapor at the same condition. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy. High-resolution transmission electron microscopy showed that the as-grown CNTs were of ~3 graphitic walls and ~6.6 nm in diameter.

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A Study on Moisture Related Properties and Human Sensations of Underwear (1) -A Study on Water and Water Vapor Transport characteristics of Underwear Fabrics- (시판 내의류소재의 수분특성 및 착용감에 관한 연구 (I) -시판 내의류 소재의 수분특성-)

  • 이순원
    • Journal of the Korean Home Economics Association
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    • v.26 no.4
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    • pp.1-13
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    • 1988
  • The purpose of this study is to investigate water and after vapor transport characteristics of underwear fabrics. Experimental materials were cotton woven fabric and cotton knitted fabric, nylon tricot (untreated and hydrophilic finished) and cotton/polyester/cotton triple layer. Cotton knitted fabric have three types of knit structure (interlock, rib, plain stitch) and knit with either 38's or 60's combed yarn. And cotton woven fabric have plain weave with 60's combed yarn. As experimental methods, vapor cup test, dynamic method, vertical wicking test and transplanar uptake test were used. The results are as follows. 1) In cotton specimens, the order of water vapor transpiration (wvt) was plain > rib > interlock in the same yarn diameter. The knit fabric of thinner yarn showed the better wvt among the same knit structure. 2) In cotton specimens, the order of water absorbency was interlock > rib > plain in the same yarn diameter. the knit fabric of thicker yarn showed the better absorbency among the same knit structure. 3) When knit fabric (60's plain) is compared with woven fabric 960's plain), knit fabric showed faster rate of wvt, more amount of uptake and slower rate of water uptake than woven fabric did. 4) When compared untreated nylon with hydrophilic finished nylon, hydrophilic finished nylon showed much more water absorbency than untreated nylon did, but showed same rate of wvt. 5) The water transport characteristics of triple layer underwear fabric showed that the thinner and the lighter one, the better wvt and absorbency did.

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Separation of Menthol/Water Mixture with Surface-Modified Hydrophobic Membrane (표면개질한 소수성 막을 이용한 menthol/water 혼합물의 분리)

  • Han, Sang-Oh;Song, Kun-Ho;Lee, Kwang-Rae
    • Journal of Industrial Technology
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    • v.22 no.A
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    • pp.249-254
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    • 2002
  • The surface of tube-type alumina substrate was modified with a silane coupling agent in order to modify the membrane surface with hydrophobicity. Contact angle of water drops on modified membrane was greater than $90^{\circ}$. The modified membrane was tested in pervaporation and vapor permeation for the recovery of menthol from dilute menthol/water mixture. With increasing menthol concentration in the feed at $45^{\circ}C$, permeation rate of menthol in pervaporation and vapor permeation increased from $0.039(g/m^2hr)$ to $0144(g/m^2hr)$ and from. $0.077(g/m^2hr)$ to $0.297(g/m^2hr)$ respectively. When feed concentration is 0.005(g/L) at $45^{\circ}C$, separation factor for menthol in pervaporation and vapor permeation is 20,7 and 40.5 respectively.

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Decomposition of Trchloroethylene/Air Mixture by Electron Beam Irradiation in a Flow Reactor (전자빔을 이용한 흐름반응기에서의 Trichloroethylene/Air 분해)

  • ;;;Tatiana Stuchinskaya
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.97-104
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    • 2001
  • Decomposition of trichloroethlyene(TCE) in electron beam irradiation was examined on order to obtain information on the treatment of VOC in air. Air containing vaporized TCE has been studied in a flow reactor with different reaction environments, at various initial TCE concentration and in the presence and absence of water vapor. Maximum decomposition was observed in oxygen reaction environment and the degree of decomposition was about 99% at 20kGy for 2,000ppm initial TCE. The concentration of TCE exponentially decreased with dose in air and pure oxygen. The effect of water vapor on TCE decomposition efficiency was examined. The decomposition rate of TCE in the presence of water vapor (5,600 ppm) was approximately 10% higher than that in the absence of water vapor. Dichloroacetic acid, dichloroacethyl chloride and dichloroethyl ester acid were identified as primary products of this reaction adn were decomposed and oxidized to yield CO and $CO_2$. Perchloroethylene, hexachloroethane, chloroform and carbon tetrachloride were also observed as highly chlorinat-ed by products.

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Hydrogen Generation by Electrical Discharge across Water-Vapor Interface (물-수증기 계면을 통한 전기방전에 의한 수소 제조)

  • Kang, Gou-Jin;Lee, Soo-Chang;Choi, Yong-Man;Lee, Woong-Moo
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.4
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    • pp.155-160
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    • 1997
  • Generation of hydrogen and oxygen gas from water is mostly accomplished by electrolysis. In this report, a scheme is presented regarding the gas generation based on plasmolysis. Unlike electrolysis water dissociation by electrical discharge (plasmolysis) requires a high voltage to cause either electron emission or electron capture, and subsequent ionization of involved molecular species. When electrical discharge is initiated between electrodes separated by water-vapor interface, a very large electric field(~100kV/cm) is developed at the tip of the electrode placed in the vapor phase. It is found that the efficiency of plasmolysis depends on the polarity of the electrode placed in the vapor phase. Also presented is the scheme of hydrogen and oxygen generation by such electrical discharge.

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Uniaxial Compressive Strength of Rock under Non-atmospheric Environments

  • Jeong, Hae-Sik;Obara, Yuzo
    • Proceedings of the KSEG Conference
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    • 2003.04a
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    • pp.131-135
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    • 2003
  • In order to investigate the influence of surrounding environment on strength of rock, the uniaxial compression test under non-atmospheric environments was conducted on Kumamoto andesite. The environments used in this study are water vapor, organic vapor environments as methanol, ethanol and acetone and inorganic gas environments as oxygen, nitrogen and argon. From the experimental results, it is clarified that water is the most effective agent which promotes stress corrosion of rock. Furthermore, the strength of rock increases with decreasing water vapor pressure. From the relation between uniaxial compressive strength and water vapor pressure, the stress corrosion index of Kumamoto andesite is estimated 24.

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Estimation of Water Vapor Vertical Profiles in the Atmosphere Using GPS Measurements (GPS 관측 자료를 이용한 대기 수증기 연직 분포 추정)

  • Ha, Jihyun;Park, Kwan-Dong
    • Atmosphere
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    • v.19 no.3
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    • pp.289-296
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    • 2009
  • Measurements of the three-dimensional water vapor distribution in the atmosphere are important for forecast and analysis of meteorological phenomenon. In this study, two Global Positioning System (GPS) campaign networks were installed in Jeju Island and Kangwon-do to construct the vertical water vapor profile solely based on GPS measurements. We implemented a layer model to get the wet refractivity profile and compared the result with radiosonde measurements. The result showed that the vertical profiles from GPS and radiosonde agree well. The bias, root-mean-square error (RMSE) and standard deviation of GPS wet refractivities compared with radiosonde measurements were in the range of 6.6~11.1 mm $km^{-1}$, 11.9~13.9 mm $km^{-1}$, and 4.3~12.3 mm $km^{-1}$, respectively.

Analysis on Characteristics of Radiosonde Bias Using GPS Precipitable Water Vapor

  • Park, Chang-Geun;Baek, Jeong-Ho;Cho, Jung-Ho
    • Journal of Astronomy and Space Sciences
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    • v.27 no.3
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    • pp.213-220
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    • 2010
  • As an observation instrument of the longest record of tropospheric water vapor, radiosonde data provide upper-air pressure (geopotential height), temperature, humidity and wind. However, the data have some well-known elements related to inaccuracy. In this article, radiosonde precipitable water vapor (PWV) at Sokcho observatory was compared with global positioning system (GPS) PWV during each summertime of year 2007 and 2008 and the biases were calculated. As a result, the mean bias showed negative values regardless of the rainfall occurrence. In addition, on the basis of GPS PWV, the maximum root mean square error (RMSE) was 5.67 mm over the radiosonde PWV.

Radiation Effects on the Flame Structure and Extinction Limit of Counterflow Partially Premixed Methane Flames Diluted with Water Vapor in the Air Stream (공기류측에 수증기가 첨가된 대향류 메탄 부분예혼합화염의 화염구조 및 소화한계에 미치는 복사효과)

  • Park, Ji-Woong;Oh, Chang Bo;Kim, Ook Joong
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.325-328
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    • 2012
  • Radiation effects on the partially premixed methane flames diluted with water vapor in the air stream were numerically investigated. OPPDIF code and GRI-v3.0 were used in the numerical simulation. Adiabatic condition was compared with two different radiation models, optically-thin and WSGGM models. It was found that the radiation effect on the flame structure for the equivalence ratio (${\Phi}$) of 2.5 was less than ${\Phi}=1.5$. Extinction limit was not affected significantly, however, local flame structure was markedly influenced by the radiation models as increasing the water vapor concentration.

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Evaluation on Water Vapor Pressure and Restrained Stress of Concrete by Ring-Type Restrained Condition (링형 강관 구속 조건에 의한 콘크리트의 수증기압력과 구속응력 평가)

  • Kim, Do-Yeon;Kim, Gyu-Yong;Lee, Sang-Kyu;Son, Min-Jae;Baek, Jae-Wook;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.27-28
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    • 2018
  • In this study, water vapor pressure and restrained stress were evaluated by ring-type restrained condition for compressive strength 60 and 80MPa concrete. Experimental results show that the 80MPa concrete has higher water vapor pressure and restraint stress than the 60MPa concrete, resulting in spalling occurrence. It is because, the higher the compressive strength of the concrete, the more dense the internal structure is formed.

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