• Title/Summary/Keyword: Water Quality Analysis

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Toxic Effects of Metal Plating Wastewater on Daphnia magna and Euglena agilis (Daphnia magna와 Euglena agilis를 이용한 도금폐수 독성평가)

  • Lee, Junga;Park, Da Kyung
    • Korean Journal of Environmental Biology
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    • v.34 no.2
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    • pp.116-123
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    • 2016
  • The ecotoxicity tests for metal plating wastewater were conducted using Daphnia magna (D. magna) and Euglena agilis (E. agilis). Evaluation for sources of toxicity was performed by 1) Correlation analysis between the concentration of individual metals in the metal plating wastewater and the toxic effects on D. magna, 2) Toxicant identification evaluation methods including graduated pH method, EDTA procedure and sodium thiosulfate procedure, 3) Comparison of toxic effect value ($EC_{50}$ or $LC_{50}$) of individual metal on D. magna and it's concentration in the metal plating wastewater. To evaluate the possibility of E. agilis, a Korean domestic organism, as a test model organism for metal plating waste water, E. agilis toxicity test was also assessed using on-line euglena ecotoxicity system (E-Tox system). Based on toxicant characterization test using D. magna, it was expected that SS, oxidants and heavy metals are responsible for toxicity of metal plating waste water. Especially Cu, Hg, and Ag were the major cationic metals that caused toxicity. E. agilis is less sensitive than D. magna based on the $EC_{50}$ value however it shows prompt response to toxic test substances. E. agilis shows even a significant effect on the cell swimming velocity within 2 min to toxic metal plating wastewater. Our study demonstrates that E. agilis test can be a putative ecotoxicity test for assessing the quality of metal plating waste water.

Properties analysis of environment friendly calcareous deposit films electrodeposited at various temperature conditions in natural seawater (천연해수 중 온도 변화에 따라 전착한 환경친화적인 석회질 피막의 특성 분석)

  • Lee, Chan-Sik;Kang, Jun;Lee, Myeong-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.779-785
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    • 2015
  • Cathodic protection is recognized as the most cost-effective and technically appropriate corrosion prevention method for the submerged zone of offshore structures, ships, and deep-sea facilities. When cathodic protection is applied, the cathodic currents cause dissolved oxygen reduction, generating hydroxyl ions near the polarized surface that increase the interfacial pH and result in enhanced carbonate ion concentration and precipitation of an inorganic layer whose principal component is calcium carbonate. Depending on the potential, magnesium hydroxide can also precipitate. This mixed deposit is generally called "calcareous deposit." This layer functions as a barrier against the corrosive environment, leading to a decrease in current demand. Hence, the importance of calcareous deposits for the effective, efficient operation of marine cathodic protection systems is recognized by engineers and scientists concerned with cathodic protection in submerged marine environments. Calcareous deposit formation on a marine structure depends on the potential, current, pH, temperature, pressure, sea-water chemistry, flow, and time; deposit quality is significantly influenced by these factors. This study determines how calcareous deposits form in sea water, and assesses the interrelationship of formation conditions (such as the sea water temperature and surface condition of steel), deposited structure, and properties and the effectiveness of the cathodic protection.

Analysis of Numerical Experiment for Field Application of Cylindrical Slit Type Block Breakwater (실린더 슬릿형 소파블록 방파제의 실해역 적용을 위한 수치실험분석)

  • Park, Sang-Gil;Lee, Joong-Woo;Nam, Ki-Dae;Kim, Pill-Sung
    • Journal of Navigation and Port Research
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    • v.33 no.10
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    • pp.703-707
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    • 2009
  • In order to evaluate applicability of cylindrical slit type block breakwater to the field water, which was designed from the previous physical model study, it is analyzed the calmness of harbor area by the numerical model experiment. For a small fishery port in southern coast of Korea a SWAN model using the wave action balance equation was formulated. The reflection and transmission coefficients induced by the physical model test were introduced to the numerical model. The model response with cylindrical slit type breakwater was compared with the impermeable breakwater case and the possibility of water quality improvement through the water circulation by the new structure was investigated. For numerical simulation, parameters of deepwater design wave from the prediction report II for overall deepwater design wave by KORDI were used and wind parameters from the 50years return period observed for 37years(1970~2006) were adopted in the numerical model. The response of west breakwater in Mijo port applying the NE and NNE waves, which were dominant in this area, was analyzed. It was found that the transmission characteristic of designed cylindrical slit breakwater was well presented in the numerical model.

A Study on the Effectiveness Verification of Hydrological Cycle of Pervious Pavement using LID Simulator (LID 효율성 검증기기를 이용한 투수성 블록의 수문순환 효율성 검증에 관한 연구)

  • Kim, Mi Eun;Jang, Young Su;Nam, Chil Ho;Shin, Hyun Suk
    • Journal of Korea Water Resources Association
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    • v.48 no.5
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    • pp.321-330
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    • 2015
  • In recent, the impacts of urbanization on hydrology and water quality can be minimized with the use of Low Impact Development (LID) practices in urban areas. But, there are no ways to verify or to show the quantitative effectiveness with LID practices. This study designed and developed to perform experiments in natural or artificial representation of hydrological cycle, which is called rainfall-runoff simulator to be able to quantify factors in hydrological system. This simulator was applied to a pervious pavement block. The study conducted analysis of effectiveness for a pervious pavement block by comparing the results with a general pavement block. The result from the pervious pavement block showed remarkably reduction effect on surface runoff with increase of rainfall intensity and more duration time. Also, the simulator was possible to control no surface runoff by a rainfall intensity at 50 mm/hr for an hour. The research indicated possibility and effectiveness for LID practices. This might be widely available to apply to LID practices verification. Therefore, the study is possible to make use of practical standards on fundamental studies.

Quality Characteristics of Domestic Strong Wheat Flour (시판 강력분 우리밀의 품질 특성)

  • Kwak, Han Sub;Kim, Mi Jeong;Kim, Oui-Woung;Kim, Sang Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.5
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    • pp.616-621
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    • 2017
  • The objective of this study was to investigate the physicochemical properties of domestic strong wheat flour (DSWF). Three commercial DSWFs (D1, D2, and D3) were compared with imported strong wheat flour (ISWF). DSWFs had higher moisture content, crude protein content, lightness, and whiteness than ISWF. DSWFs showed lower solvent retention capacity and water absorption index than ISWF. DSWFs also showed significantly higher water solubility index than ISWF (P<0.05). Setback values by rapid visco analysis were significantly higher in D1 and D2 than in ISWF and D3, which means ISWF and D3 were better in retarding retrogradation. Differential scanning calorimetry results showed that ISWF required 6.2 J/g of energy for phase transition, whereas DSWFs needed 6.67~7.13 J/g. The farinograph results showed that ISWF had higher water absorption, longer dough stability time, and significantly higher softening of dough at 20 min than DSWF (P<0.05). Dough resistance and extensibility were higher in ISWF than in DSWFs.

Development of Functional Hanji Added Citrus Peel(I) - Hanji added Korean citrus peel - (감귤박을 첨가한 기능성 한지제조 기술개발(제1보) - 한국산 감귤박 첨가 한지 -)

  • Kim, Hae-Gong;Lim, Hyun-A;Kim, So-Young;Kang, Sool-Saeng;Lee, Hyo-Yeon;Yun, Pil-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.1 s.119
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    • pp.38-47
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    • 2007
  • This study was carried out to develop a new application field and obtain the basic data of citrus peel as waste in Jeju island and traditional Hanji for producing functional Hanji. The results measuring physical and optical properties, water vapor permeance and antibacterial activity are as follows. It was revealed that apparent density go as down but bulk raise up in the structural view of Hanji with increasing of the addition various Korean citrus peel (citrus unshiu, cheonggyun and hanrabong peel, and citrus unshiu peel powder) percentages, and that the density of Hanji added citrus unshiu peel was higher, but bulk was lower in compared with Hanji added other kinds of peel. Those Hanji added citrus unshiu peel, cheonggyun peel, hanrabong peel and citrus unshiu powder were very great not only in the strength (breaking length, burst index, tear index and folding endurance) but also in water vapor permeant rate in comparison with Hanji. The pHs of Hanji were neutrality (7 to 8). The brightness of the Hanji added various citrus peel percentages was low in compared to Hanji, and the 40% addition of hanrabong peel was the lowest. When 40% hanrabong peel was added to Hanji, it was very yellow in the color degree. When cheonggyun peel was added to Hanji manufacture, water vapor permeant rate was highly effective. It is known that vacant space of intrafiber was reduced by image analysis of Hanji and the additions of peel of citrus unshiu, cheonggyun and hanrabong were distributed equally in the interior of Hanji. The antibacterial activity of Hanji added citrus unshiu peel is more than 98%. After all, it would be able to increase utilization of Hanji, extensively. Namely, production of high quality Hanji added functional materials is expected for new valuable industry of citrus peel and Hanji.

Analysis of Discharge and Water Quality change of Doam Reservoir by Climate Change (기후변화에 따른 도암댐유역의 유출 및 수질변화 분석)

  • Kim, Jung-Min;Kim, Young-Do;Kang, Boo-Sik
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.908-908
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    • 2012
  • 국내 기후 특성상 하절기에 집중되는 강우로 인해 댐의 건설을 홍수조절, 용수확보 및 전력생산 등의 목적에 있어서 불가피하다. 이와 같은 저수지와 하류하천은 댐 수문 개폐에 따라 흐름변화로 인하여 수체의 거동 및 수질 변화가 발생하며, 일반적인 하천과는 다른 특성을 지니게 된다. 또한 수심이 깊은 저수지의 경우에는 흐름방향과 더불어 수심 방향의 특성도 중요하며, 수리 및 수질 모형의 연계를 통한 3차원적인 해석을 필요로 한다. 유역 내 지상 또는 대기에서 발생한 모든 오염물질은 강우에 의해 하천과 호수와 같은 수체로 유입되며, 강우가 발생했을 때 유역의 토지피복 상태와 수리, 지형, 강우강도, 토양의 특성에 의해 하천으로 유입되는 오염물질의 농도와 부하특성이 달라진다. 비점오염물질의 축적이 가능한 호수나 저수지에서는 비점오염원의 유입이 더 큰 문제가 되며, 유량이 극히 미미한 하천의 경우에는 강우초기에 일시에 집중적으로 유입되는 초기 오염 부하량이 문제가 된다. 강우유출수의 하천 유입은 강우 현상과 밀접한 관계를 맺고 있으므로 그 제어가 쉽지 않다. 이러므로 이를 총괄하는 유역통합관리기술이 필요로 하며, 기존의 유역통합관리기술은 댐 상류유역을 중심으로 개발되고 있으며, 댐 상류유역과 저수지, 하류하천으로 구분되어 연구되어 왔다. 또한 각각의 모형이 개별적으로 적용되어 통합적인 평가시스템이 표준화되지 않은 관계로 댐 상하류 모니터링 자료가 연계된 실무 적용이 이루어지지 않고 있다. 따라서 하천 수리 수문학적 역학구조를 이해하고 그 특성에 적합하게 평가할 수 있는 표준화된 시스템이 구축되어야 한다. 또한 효과적인 유역통합관리를 위해서는 하천의 현재 뿐만 아니라 장래에 대한 예측부분도 포함되어야 한다. 본 연구에서는 댐 유역에서의 유출과 수질 변화를 모의하고 이를 이용하여 저수지 내에서의 오염물질 거동에 대해서 해석하였다. 또한 기후변화에 따른 유역, 저수지 및 하천에 미치는 영향을 고려하기 위하여 고해상도 지역기후전망 모의자료를 이용하여 수문학적 스케일로 통계적 상세화한 후 지역별 상세수문시나리오를 생산하여 미래 예측에 활용하였다. 기후변화 시나리오의 상세화를 통한 상세지역의 기후를 예측하고, 예측된 기상자료를 이용하여 유역모델을 모의하여 미래의 유출 및 수질 변화를 파악할 수 있는 기술 개발로 인해 저수지의 운영에 도움을 주고, 주수지의 치수증대 사업 등 유출의 변화에 따른 하류하천 변화를 파악할 수 있고, 기후변화에 따른 하류하천에 대한 홍수기 때 치수, 이수 및 방재에 대하여 기초자료를 제공할 수 있을 것으로 판단된다.

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Effect of Lugol's Iodine Preservation on Cyanobacterial Biovolume and Estimate of Live Cell Biovolume Using Shrinkage Ratio (Lugol's Iodine Solution 첨가 후 보존 기간별 남조류 세포부피 변화 및 수축비를 이용한 생세포 부피 산정)

  • Park, Hae-Kyung;Lee, Hyeon-Je;Lee, Hae-Jin;Shin, Ra-Young
    • Journal of Korean Society on Water Environment
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    • v.34 no.4
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    • pp.375-381
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    • 2018
  • The monitoring of phytoplankton biomass and community structure is essential as a first step to control the harmful cyanobacterial blooms in freshwater systems, such as seen in rivers and lakes, due to the process of eutrophication and climate change. In order to quantify the biomass of phytoplankton with a wide range in size and shape, the measurement of cell biovolume along with cell density is required for a comprehensive review on this issue. However, most routine monitoring programs preserve the gathered phytoplankton samples before analysis using chemical additives, because of the constraint of time and the number of samples. The purpose of this study was to investigate the cell biovolume change characteristics of six cyanobacterial species, which are common bloom-causing cyanobacteria in the Nakdong River, after the preservation with Lugol's iodine solution. All species showed a statistically significant difference after the addition of Lugol's iodine solution compared to the live cell biovolume, and the cell biovolume decreased to the level of 34.0 ~ 56.3 % at maximum in each species after the preservation. The nonlinear regression models for determining the shrinkage ratio by a preservation period were derived by using the cell biovolume measured until 180 days preservation of each target species, and the equation to convert the cell biovolume measured after preservation for a certain period to the cell biovolume of viable cell was derived using that formula. The conversion equation derived from this study can be used to estimate the actual cell biovolume in the natural environment at the time of sampling, by using the measured biovolume after the preservation in the phytoplankton monitoring. Moreover this is expected to contribute to the final interpretation of the water quality and aquatic ecosystem impacts due to the cyanobacterial blooms.

The Water Quality Analysis on Climate Change and Dam construction (기후변화와 저수지 건설에 따른 수질분석)

  • Kim, Dong-Il;Choi, Hyun-Gu;Park, Tae-Won;Han, Kun-Yeun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.193-193
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    • 2011
  • 국제기구인 정부간 기후변화협의체(Intergovernmental Panel on Climate Change, 이하 IPCC)에서는 기후변화가 기온 상승에 따른 증발산량의 증가, 강수량 및 유출량의 시공간적 분포의 변동 등을 초래하여 수자원의 효율적 관리 및 안정적인 공급에 어려움을 증대시킬 것으로 전망하였다. 또한 IPCC 4차 보고서에 따르면 21세기말 지구의 평균기온은 현재보다 최대 $6.3^{\circ}C$정도 더 상승할 것으로 전망하였다. 전구평균기온이 $3.0^{\circ}C$ 증가할 경우 아시아에서만 연간 700만 명이상이 홍수피해 위기에 직면할 것으로 예상되고 있다. 국내의 경우 기온은 전구평균기온에 비해 2배 이상 높은 $1.5^{\circ}C$ 정도 상승하였으며, 최근 50년간의 강우일수는 감소한 반면 일강수량이 80mm 이상인 호우일수의 발생빈도는 증가되고 있다고 보고되었다. 또한 최근의 물수지 해석과 관련하여 거시적인 관점에서 기온 및 강수량 증가에 따른 물순환 과정을 모의하고, 농업용수, 댐건설, 도시화, 토지이용의 변화 등 인위적인 환경 변화 및 기후변화에 따른 유출량의 변화를 정량화하려는 연구들이 수행되고 있다(한국건설기술원, 2007). 이를 위하여 단기적이 아니라 장기적인 측면에서 유출분석을 할 필요가 있으나, 현재까지 보유하고 있는 실측 자료의 한계 및 이러한 조사를 위해 요구되는 시간 및 비용의 한계 때문에, 유출해석 모형을 주로 이용하고 있다. 본 연구에서는 장래 건설예정인 미계측 호소의 유량과 수질을 모의하기 위하여 하천, 하구, 호소 및 해역에 고루 적용할 수 있는 3차원 수리 동력학적인 모델인 EFDC 모형과 시간의 변화에 따른 수질을 모의하는데 가장 널리 이용하는 WASP 모형을 도입하였다. 향후, 내성천의 영주댐 건설과 같은 큰 변화가 발생하였을 기후 변화의 영향을 파악하기 위하여 EFDC와 WASP모형을 이용하여 대상유역에 대한 유출량과 수온의 변화를 통하여 A2, B1 기후변화 시나리오별로 2020년, 2050년, 2080년의 수질(BOD, TN, TP)변화를 분석하여 보았다. 연구의 결과는 다음과 같이 나타났다. EFDC 및 WASP 모형의 연계를 통한 기후 변화 시나리오에 따른 미래의 저수지 수질예측 모의를 수행한 결과, BOD, TN, TP 등 수질농도 변화는 2020년에서 2080년도로 갈수록 BOD, TN 다소 증가하는 경향을 나타내었고, TP농도는 감소하였다. 시나리오별 변화 특성은 TN, TP 농도는 A2 시나리오가 다소 높고, BOD 농도는 B1 시나리오가 A2보다 높은 것으로 나타났다. EFDC와 WASP을 이용하여 미계측 호소에 대한 기후변화 시나리오별로 적용하여 수질변화를 예측하여 보았는데, 향후 기후변화에 따른 기온, 유량변화와 수질 항목간의 상간관계 정립 및 수질 모의의 불확실성 등에 대한 추가 연구가 필요할 것으로 판단된다.

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Correlation between Characteristics of SOD in Coastal Sewage and Predictive Factor (연안 저질 SOD의 특성과 유발 영향인자에 대한 상관관계)

  • Kim, Beom-Geun;Khirul, Md Akhte;Kwon, Sung-Hyun;Cho, Dae-Chul
    • Korean Journal of Environment and Ecology
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    • v.33 no.5
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    • pp.596-604
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    • 2019
  • This study conducted a sediment culture experiment to investigate the effects of sediment oxygen demand (SOD) and environmental factors on sediment and water quality. We installed a leaching tank in the laboratory, cultured it for 20 days, and analyzed the relationship between P and Fe in the sediment. As a result, the dissolved oxygen of the water layer decreased with time, while the oxidation-reduction potential of the sediment progressed in the negative direction to form an anaerobic reducing environment. The SOD was measured to be 0.05 mg/g at the initial stage of cultivation and increased to 0.09 mg/g on the 20th day, indicating the tendency of increasing consumption of oxygen by the sediment. The change is likely to have caused by oxygen consumption from biological-SOD, which is the decomposition of organic matter accumulated on the sediment surface due to the increase of chl-a, and chemical-SOD consumed when the metal-reducing product produced by the reduction reaction is reoxidized. The correlation between SOD and causality for sediment-extracted sediments was positive for Ex-P and Org-P and negative for Fe-P. The analysis of the microbial community in the sediment on the 20th day showed that anaerobic iron-reducing bacteria (FeRB) were the dominant species. Therefore, when the phosphate bonded to the iron oxide is separated by the reduction reaction, the phosphate is eluted into the water to increase the primary productivity. The reduced substance is reoxidized and contributes to the oxygen consumption of the sediment. The results of this study would be useful as the reference information to improve oxygen resin.