• Title/Summary/Keyword: Water Electrolysis Experiment

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A Study on Active Ion Transport Technology to Improve Water Electrolysis System Performance (수전해 시스템 성능 향상을 위한 능동 이온수송 기술 연구)

  • HYEON-JUNG KIM;HAO GUO;SANG-YOUNG KIM
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.2
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    • pp.132-140
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    • 2023
  • In this study, rotary magnet holder (RMH) was manufactured to analyze the ion transport effect according to the rotating magnetic field for the hydrogen production efficiency by alkaline water electrolyte. In the experiment, the voltage signal according to the magnet arrangement inside the RMH, the rotation speed, and the rotation time was measured using the voltage measurement module. As a result of the voltage signal measurement experiment, the average potential difference increased as the rotation speed of the RMH increased. Through the results of the voltage signal measurement experiment, the most efficient magnet arrangement (case 2) was applied to the RMH to conduct a water electrolysis experiment. A 20% NaOH aqueous solution was filled in the electrolytic cell, and a direct current 2 V constant voltage was applied to measure the current value according to the RMH rotation to compare the hydrogen generation amount. When rotating at 100 RPM, the hydrogen production efficiency increased by 8.06% compared to when not rotating. Considering the area exceeding +25 mA, which was not measured at the beginning of the experiment, an increase in hydrogen production of about 10% or more can be expected.

Characterization of Electrochemical Ammonia Electrolysis Using a Platinum Electrode for Anodic Reaction (Pt포일 양극을 이용한 전기화학적 암모니아 수전해 특성 연구)

  • CHOI, JEONGMIN;KIM, HAKDEOK;SONG, JUHUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.337-342
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    • 2022
  • In this study, a water electrolysis was studied to investigate the effect of ammonia on current density and H2 gas production. A H type cell with three electrodes was used and KOH solution was used as electrolyte. The conventional platinum foil was used for working electrode, whereas nickel foam was used for counter electrode. CV experiment was performed to see the activity of ammonia oxidation reaction. In addition, CP experiment was done to examine the dependence of Faraday efficiency of hydrogen on current density and NH3 concentration. The CV result shows the 0.5M NH3 concentration required for highest current density and reliable operation. The CP result shows the increased current density leads to higher H2 generation. The higher H2 production and subsequent energy efficiency was observed for 0.5M NH3 using a Pt/13%Rh coil for a cathode as compared to those in water electrolysis.

A Study on Analysis of the Hydrogen-Oxygen Gas Generator (수산화가스 발생기의 모델링 및 특성해석)

  • Kang, B.H.;Lee, J.M.;Mok, H.S.;Choe, G.H.
    • Proceedings of the KIEE Conference
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    • 2001.04a
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    • pp.198-201
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    • 2001
  • The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electrical for the high efficiency of water electrolysis equipment. First, chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated. For basic experiment, unit electrode of singular electrolysis electrode is manufactured and experimented, results are compared and analyzed with simulation, and the electrolysis is electrically equivalent.

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Ventilation Performance Study on Hydrogen Leakage Characteristics of Container Packaged Water Electrolysis Production System (컨테이너 패키지형 그린수소 수전해 생산 시스템의 수소 누출 특성에 관한 환기 성능 연구)

  • SOOIN KWON;BYUNGSEOK JIN;CHEEWOO LEE;SEONGYONG EOM;GYUNGMIN CHOI
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.3
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    • pp.324-335
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    • 2024
  • The container package type sealed water electrolysis production system installs mechanical balance of plant and electrical balance of plant as an integrated unit to enable independent operation within the package module. The auxiliary equipment required to operate the water electrolysis system must be integrated to reduce the installation area and shorten the installation time. At this time, as leak risk factors are placed in a dense space, when a hydrogen gas leak accident occurs, it can have a mutual influence on other adjacent facilities, so it contains various risk factors. In this study, when a gas leak occurs in a container packaged water electrolysis system, possible sources of leakage in the system according to the KS C IEC 60079-10-1:2015 and KGS GC101 standards were identified, and the leak rate and leak characteristics were calculated. did. The hazardous area and its range were calculated according to ventilation and dilution characteristics. In order to optimize ventilation characteristics, design of experiment was used to analyze the influence to evaluate the adequacy of ventilation, and overseas ventilation standards were analyzed and compared. In addition, the optimal ventilation structure and characteristics of the container packaged water electrolysis system were presented according to the results of the experimental design method.

Characteristics of Electrolytic Ion Water Generation due to the electrical-conductivity of a liquid medium (액상 매질의 전기전도도 변화에 의한 전해이온수 발생 특성)

  • Shin, Dong-Hwa;Ju, Jae-Hyun
    • Journal of the Korean Society of Industry Convergence
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    • v.20 no.4
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    • pp.257-263
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    • 2017
  • The following thesis researched into the characteristics of electrolytic ion water with different levels of electrical conductivity by adding NaCl into tap water which is for experimental use in multi-layered electrolytic ion water generator. Electrolytic ion water is generated by underwater electrolysis and the electrolysis generator has a simple structure, is easy to control and is highly utilized in industries. Electrolytic ion water is useful in many areas since it has a superior sterilizing power, has no possibility of secondary pollution itself as water and removes active oxygen. In the experiment, we used tap water with NaCl excluded and water with three different levels of electrical conductivity by changing NaCl concentration levels into three levels. The features of current and voltage in electrolytic ion water represented a form of quadric instead of the linear characteristic following ohm's law. As well, as the electric conductivity of water and applied voltage increased, we were able to generate much stronger acid water and alkali water.

An Experimental Study on the Application of Electrolysis to Nightsoil Treatment Plant Effluent, as a Means of Advanced Treatment Techonology (전해처리법(電解處理法)에 의한 분뇨(糞尿) 2차 처리수(處理水)의 고도처리(高度處理)에 관한 연구(硏究))

  • Chung, Kyeong Jin;Kim, Dong Min;Lee, Dong Houn
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.2
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    • pp.77-83
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    • 1995
  • The effluent from conventional nightsoil treatment plants contains nutrients, color and chlorides, in addition to residual organics and suspended solids, and thereby causes substantial pollution problems in receving water resources. In order to verify the usefullness of electrolysis in removing those residual pollutants from such conventional nightsoil treatment plant effluent, a bench scale experiment was conducted using sufficiently dilluted human nightsoil as experiment feeds. The result showed mean removals of 45% of total phosphorus and 85% of color, in addition 87% of residual BOD, 47% of residual COD and 85% of residual SS. The optimum electric current was found to be 15 ampere and the optimum hydraulic residence time 21/2 hour.

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The Effect of Emission Control Using Electrolytic Seawater Scrubber

  • An, Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.3
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    • pp.373-377
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    • 2009
  • It is well known that SOx and NOx concentration has a considerable influence on the $N_2O$ emission of the greenhouse gas properties. The quantity of SOx generated during combustion, on fuel specific basis, is directly related to the sulfur content of the fuel oil. However, restricting the fuel oil sulfur content is only a partial response to limiting the overall quantity of SOx emissions, as there remains no over control on the fuel oil consumption other than the commercial pressure which have always directed the attention. This study was carried out as a new basic experiment method of emission control, manly targeted to the vessel. In the experiment, where the scrubbing was achieved through spray tower with high alkaline water made from the electrolysis of seawater, the combined action was to neutralize the exhaust gases (SOx, PM, CO etc.), dilute it, and wash it out. The results showed that SOx reduction of around 95 percent or over could be achieved when using in the high alkaline water, and also leaded to a reduction in the stability of the each pollutant components including the PM (Particulate Matter). The results suggest that the seawater electrolysis method has a very effective reduction of emissions without heavy cost, or catalysts particularly on board.

Thermal-flow Analysis of the Cooling System in the Medicated Water Electrolysis Apparatus (냉이온수기 냉각시스템에 관한 열유동 해석)

  • Jeon, Seong-Oh;Lee, Sang-Jun;Lee, Jong-Chul;Kim, Youn-Jea
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.3
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    • pp.33-38
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    • 2011
  • Medicated water electrolysis apparatus, which electrolyzes water into acidic water and alkaline water, was in the spotlight as becoming known the effect of alkaline water. It is known as good for health as removing active oxygen in the human's body and promoting digestion. But, the customers could not get that desired water temperature because these apparatuses are directly connected with a water pipe. So, the cooling system was developed for controlling the temperature of the alkaline water. One of the typical way is to store water in water tank and control the temperature. But, in this way, storing water can be polluted impurities coming from outside. For protecting this pollution, the cooling system based on indirect heat exchange method through phase change between water and ice was developed. In this study, we have calculated efficiency of the cooling system with phase change by experiment and commercial CFD(Computational Fluid Dynamics) code, ANSYS CFX. To consider the effect of latent heat that is generated by melting ice, we have simulated two phase numerical analyses used enthalpy method and found the temperature, velocity, and ice mass distribution for calculating the efficiency of cooling. From the results of numerical analysis, we have obtained the relationship between the cooling efficiency and each design factor.

Optimization of Electro-UV-Ultrasonic Complex Process for E. coli Disinfection using Box-Behnken Experiment (Box-Behnken법을 이용한 E. coli 소독에서 전기-UV-초음파 복합 공정의 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.3
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    • pp.149-156
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    • 2011
  • This experimental design and response surface methodology (RSM) have been applied to the investigation of the electro-UV-ultrasonic complex process for the disinfection of E. coli in the water. The disinfection reactions of electro-UV-ultrasonic process were mathematically described as a function of parameters power of electrolysis ($X_1$), UV ($X_2$), and ultrasonic process ($X_3$) being modeled by use of the Box-Behnken technique, which was used for fitting 2nd order response surface model. The application of RSM yielded the following regression equation, which is empirical relationship between the residual E. coli number (Ln CFU) in water and test variables in coded unit: residual E. coli number (Ln CFU) = 23.69 - 3.75 Electrolysis - 0.67 UV - 0.26 Ultrasonic - 0.16 Electrolysis UV + 0.05 Electrolysis Ultrasonic + 0.27 $Electrolysis^2$ + 0.14 $UV^2$ - 0.01 $Ultrasonic^2$). The model predictions agreed well with the experimentally observed result ($R^2$ = 0.983). Graphical 2D contour and 3D response surface plots were used to locate the optimum range. The estimated ridge of maximum response and optimal conditions for residual E. coli number (Ln CFU) using 'numerical optimization' of Design-Expert software were 1.47 Ln CFU/L and 6.94 W of electrolysis, 6.72 W of UV and 14.23 W of ultrasonic process. This study clearly showed that response surface methodology was one of the suitable methods to optimize the operating conditions and minimize the residual E. coli number of the complex disinfection.

A Study on Analysis of the Hydrogen-Oxygen Gas Generator Using Pulse Power Supply (펄스전원에 의한 수산화가스 발생기에 관한 연구)

  • 이정민;강병희;목형수;최규하
    • The Transactions of the Korean Institute of Power Electronics
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    • v.6 no.5
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    • pp.377-385
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    • 2001
  • The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electricity for the Hydrogen-Oxygen gas generator, Firstly chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated through Faraday's laws of electrolysis. After that, pulse power supply is designed for basic experiment which could be applied to the analysis of Hydrogen-Oxygen gas generator. In the basis of above steps, comparison and analysis of Hydrogen-Oxygen gas generator was conducted as variable frequency using pulse Power supply.

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