• 약학회지
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• 제35권3호
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• pp.182-189
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• 1991

Systematic study on the extraction of ion pair by the use of picric acid (PCA) as an ion pair forming reagent to the aliphatic amines has not be done by spectrophotometric method. The extraction of ion pair by the use of PCA and 23 kinds of the aliphatic amines was examined. The procedure is as follows; Elving's buffer solution (pH 1.3~10, ionic strength 0.5) each amine solution, and PCA solution were taken into a test tube. The mixture was shaken mechanically with chlorform. The organic phase was filtered through a filter paper to remove water droplets. The absorbance was examined at $\lambda_{max}$ against a reagent blank. Primary and secondary whose carbon number were more than 7 or 6, respectively, are extractable as ion pairs with PCA, while tertiary amines and quaternary ammonium salts are also extractable without the correlation of carbon number. It was considered that the ion pair extraction of primary and secondary amines was affected by the number of carbon of amines, but its extraction of tertiary amines or quaternary ammonium salts was affected by kind of aliphatic amines rather than pKa values or carbon number of amines.

• Elastomers and Composites
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• 제55권2호
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• pp.114-119
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• 2020

The effect of a greenhouse-covering material on its indoor environment and on the characteristics of cherry tomatoes grown in it was investigated. The conventional polyethylene (PE) film on the greenhouse roof was replaced by a polycarbonate (PC) sheet, while maintaining the main structural frame intact. Color changes and the formation of water droplets on the PC surface were avoided by applying coextrusion and coating layers. When compared to the PE greenhouse, the PC greenhouse enabled increased light transmittance and thus a higher indoor temperature during both summer and winter. The thermal insulating property of the PC sheet effectively reduced the heating loss by approximately 55% during winter. The cherry tomatoes grown in the PC greenhouse exhibited superior fruit characteristics in terms of size, weight, and sugar content. The total amount of cherry tomatoes produced per unit area (1,000 ㎡) in the PC greenhouse was found to be greater by approximately 19% compared to that in the PE greenhouse.

• 전기학회논문지
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• 제63권5호
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• pp.671-675
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• 2014

This paper presents a fabrication of hydrophilic Poly(dimethylsiloxane) (PDMS) with periodic wrinkling surface. The proposed periodic wrinkling surface was fabricated using the sequential processes of typical curing process of PDMS, cutting process, platinum deposition process, and wrinkling transfer process. The surface morphology of the fabricated wrinkling surface was observed by using optical and dynamic atomic force microscopy and discussed. The measured period and amplitude of wrinkling was about $2.2{\mu}m$ and $0.31{\mu}m$, respectively. And, the contact angles of water droplets on the wrinkled surface were measured in order to understand effect of the wrinkling surface on surface modification of hydrophobic PDMS. Our new finding was that the proposed wrinkling surface was hydrophilic and the measured contact angle was about $62^{\circ}$. Moreover, it was found out from the simple cell culture test that the fabricated wrinkling surface was more effective for cell spreading and adhesion than the case of native PDMS substrate.

• 설비공학논문집
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• 제12권1호
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• pp.95-101
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• 2000

The effect of surface contact angle on the behavior of frost formation in a fin-tube heat exchanger is investigated experimentally. It is shown that both heat exchangers with hydrophilic and hydrophobic surfaces appear to have a better thermal performance than bare aluminium heat exchanger, but the improvements are very small. There is a little increase in the amount of the frost deposited onto the heat exchanger with both hydrophilic and hydrophobic surface. However, the effect of contact angle on the frost density is observed ; the frost with high density forms on the heat exchanger with hydrophilic surface ; and the frost with low density is deposited onto the heat exchanger with hydrophobic surface when compared with the frost deposited onto the heat exchanger with bare aluminium surface. This may be attributed to the fact that the shape of water droplets which condense on the surface of heat exchanger at the early stage of frosting varies with contact angle, and thus makes a difference on the structure of frost formation. From the experiments with different relative humidity of inlet air, it is shown that the variations of operating parameter make no influence on the effect of surface contact angle on the frosting behavior in the heat exchanger.

• 설비공학논문집
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• 제15권8호
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• pp.619-629
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• 2003

A grease filter is used to remove grease generated from a cooking appliance in a kitchen. Since the inertial impaction is a dominant particle removal mechanism of the grease filter, the performance of the filter is greatly affected by the geometry. This numerical study has been conducted to investigate the effect of geometry on the performance of grease filters for four models having nominal flowrate of 100 m$^3$/h. Four models were designed by changing the shape of impaction surface, the length of eyelid, and the number of eyelids of the grease filter. The flow field and particle trajectories in the grease filter with a flow chamber were simulated using the commercial code of STAR-CD. The difference of air velocity and pressure distributions among four models was discussed in detail. The collection efficiency curves and the pressure drops of four models were also compared. It was found that the grease filter model with flat top surfaces shows highest performance among four models, having high particle collection efficiency and relatively low pressure drop. The cutoff diameter of this model representing 50-% collection efficiency is about 7.1 ${\mu}{\textrm}{m}$ for water droplets at 100 m$^3$/h.

• 한국표면공학회지
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• 제52권1호
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• pp.37-42
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• 2019

Electrodeposited zinc layer is widely used as a sacrificial anode for a corrosion protection of steel. In this study, we modified the surface of electrodeposited zinc to have a hydrophobicity, which shows various advanced functionalities, such as anti-corrosion, anti-biofouling, anti-icing and self-cleaning, due to its repellency to liquids. Superhydrophobicity was realized on electrodeposited zinc layer with a hydrothermal treatment, creating nanostructures on the surface, and following Teflon coating. The superhydrophobic surface shows a great repellency to water with high surface tension, while liquid droplets with low surface tension easily adhered on the superhydrophobic surface. However, immiscible lubricant-impregnated superhydrophobic surface shows a great repellency to various liquids, regardless of their surface tension. Therefore, it is expected that the lubricant-impregnated surface can be an alternative of superhydrophobic surface, which have a drawback for some liquids with a low surface tension.

• 한국기계가공학회지
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• 제19권11호
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• pp.109-115
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• 2020

Surfaces with various roughnesses were produced through laser processing, and the anisotropy and hydrophobicity of the surfaces were examined in the context of the microstructures. The fine particles transferred to the glass surface exhibited different sizes, and the roughness increased. Due to the change in the roughness, the liquid could not penetrate the space between the fine particles, and it was thus exposed to the air. We analyzed this phenomenon using the combined Wenzel and Cassie-Baxter models. Excessive fine particle formation on the substrate tended to increase the roughness and surface energy. The silver-glass-air contact analysis could clarify the mechanism of the reduction of the contact angle and differences in the metastable and stable states when the particles did not completely cover the glass substrate. The formation of microstructures with fine particles through the laser selective deposition led to the generation of an anisotropic surface as the water droplets diffused toward the glass substrate with a relatively high surface energy level.

• 한국분무공학회지
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• 제27권4호
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• pp.188-194
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• 2022

In this study, the behavior of water droplet impacting on a thin horizontal orifice was investigated. The impact behavior modes, transition velocities and diameters of daughter droplets were analyzed by changing the droplet velocity, orifice diameter and orifice thickness. Four typical modes of impacting droplet on an orifice were observed. The single-droplet and double-droplet transition velocities increased with increasing the orifice thickness and decreased with increasing the orifice diameter. On the other hand, the multi-droplet transition velocity decreased and then increased as the orifice diameter increased. At thin orifice thickness, the single droplet diameter approximated the orifice diameter, and increasing the orifice thickness produced a droplet larger than the orifice diameter. In the case of double droplet mode, the diameter of the first droplet showed a similar tendency like the single droplet mode, but the diameter of the second droplet was smaller than that of the first droplet, and the difference between them was affected more by the orifice thickness.

• Corrosion Science and Technology
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• 제21권6호
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• pp.476-486
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• 2022

Recently, aluminum 6061 instead of copper alloy is used for cooling heat exchangers used in the internal combustion of engines due to its economic feasibility, lightweight, and excellent thermal conductivity. In this study, aluminum 6061 alloy was anodized with oxalic acid, phosphoric acid, or chromic acid as an anodizing electrolyte at the same concentration of 0.3 M. After the third anodization, FDTS, a material with low surface energy, was coated to compare hydrophobic properties and anti-icing characteristics. Aluminum was converted into an anodization film after anodization on the surface, which was confirmed through Energy Dispersive X-ray Spectroscopy (EDS). Pore distance, interpore distance, anodization film thickness, and solid fraction were measured with a Field Emission Scanning Electron Microscope (FESEM). For anti-icing, hydrophobic surfaces were anodized with oxalic acid, phosphoric acid, or chromic acid solution. The sample anodized in oxalic acid had the lowest solid fraction. It had the highest contact angle for water droplets and the lowest contact hysteresis angle. The anti-icing contact angle showed a tendency to decrease for specimens in all solutions.

• ETRI Journal
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• 제44권4호
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• pp.686-694
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• 2022

Fog screens offer a great advantage to be used as scattering screens in three-dimensional displays. In the absence of a fixed rigid form, fog screens work as screens without any physical obstruction. The density of water droplets can be regulated to adjust the screen's transparency and scattering level. This study proposes a method for crosstalk reduction between adjacent viewing windows by decreasing the divergence of view of the projector, with concentration lenses. By applying the Scheimpflug principle, we also reduce the keystone effect, which occurs when the fog screen is slanted with respect to the optical axis. In this study, we have realized a tabletop multiview fog display without any structures on the table and established that the proposed method is feasible for decreasing crosstalk effectively.