• Title/Summary/Keyword: Water Dispersion

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Preparation of Polystyrene-Polyetherimide Core-Shell Particles by Dispersion Polymerization (분산중합에 의한 폴리스티렌-폴리에테르이미드 코어-셀 입자의 합성)

  • Ahn, Byung Hyun
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.526-530
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    • 2014
  • Polystyrene-poly(etheramic acid) core-shell particles were prepared by dispersion polymerization of styrene using poly(etheramic acid) obtained by the reaction of 2,2'-bis[4-(3,4-dicarboxyphenoxy) phenyl]propane dianhydride and 3,5-diamniobenzoic acid as a stabilizer. 4-Vinylbenzyltrimethylammonium chloride was used as a comonomer to increase the binding efficiency of poly(etheramic acid). When the ethanol-water mixture (7 : 3) was used as a reaction medium, particles were stabilized well and the size distribution of particles was fairly narrow. The particle size increased with the amount of styrene. The particles polymerized in the dimethylformamide-water mixture had a broad size range. Polystyrene-poly(etheramic acid) core-shell particles were transformed to polystyrene-polyetherimide core-shell particles by the chemical imidization of shells.

Development of a Guided Wave Technique for the Inspection of a Feeder Pipe in a Pressurized Heavy Water Reactor

  • Cheong, Yong-Moo;Lee, Dong-Hoon;Kim, Sang-Soo;Jung, Hyun-Kyu
    • Corrosion Science and Technology
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    • v.4 no.3
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    • pp.108-113
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    • 2005
  • One of the recent safety issues in the pressurized heavy water reactor (PHWR) is the cracking of the feeder pipe. Because of the limited accessibility to the cracked region and a high dose of radiation exposure, it is difficult to inspect all the pipes with the conventional ultrasonic method. In order to solve this problem, a long-range guided wave technique has been developed. A computer program to calculate the dispersion curves in the pipe was developed and the dispersion curves for the feeder pipes in PHWR plants were determined. Several longitudinal and/or flexural modes were selected from the review of the dispersion curves and an actual experiment has been carried out with the specific alignment of the piezoelectric ultrasonic transducers. They were confirmed as L(0,1)) and/or flexural modes(F(m,2)) by the short time Fourier transformation(STFT) and were sensitive to the circumferential cracks, but not to the axial cracks in the pipe. An electromagnetic acoustic transducers(EMAT) was designed and fabricated for the generation and reception of the torsional guided wave. The axial cracks were detected by a torsional mode(T(0,1)) generated by the EMAT.

Synthesis and Characterization of Silver Nanofluid Using Pulsed Wire Evaporation Method in Liquid-Gas Mixture (액상/기상중 전기선 폭발법을 이용한 은 나노유체의 제조 및 특성평가에 관한 연구)

  • Kim, Chang-Kyu;Lee, Gyoung-Ja;Rhee, Chang-Kyu
    • Korean Journal of Materials Research
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    • v.19 no.9
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    • pp.468-472
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    • 2009
  • The silver nanofluids were synthesized by the pulsed wire evaporation (PWE) method in a liquid-gas mixture. The size and microstructure of nanoparticles in the deionized water were investigated by a particle size analyzer (PSA), transmission electron microscope (TEM), and scanning electron microscope (SEM). Also, the synthesized nanofluids were investigated in order to assess the stability of dispersion of nanofluid by the zetapotential analyzer and dispersion stability analyzer. The results showed that the spherical silver nanoparticle formed in the deionized water and mean particle size was about 50 nm. Also, when explosion times were in the range of 20$\sim$200 times, the absolute value of zeta potential was less than -27 mV and the dispersion stability characteristic of low concentration silver nanofluid was better than the high concentration silver nanofluid by turbiscan.

Investigation of Dispersion and Storage Processes of Pollutants in Natural Streams (자연하천에서 오염물질의 확산 및 저장에 관한 연구)

  • 서일원;유대영
    • Water for future
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    • v.28 no.6
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    • pp.107-118
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    • 1995
  • Mathematical models have been developed in which storage-relaease processes of pollutants are modeled to explain storage effect of variations of flow and channel geometry on mixing and transport of polluted releases in natural channels including low flow conditions. The models were tested by using the laboratory dispersion data. Comparisons between concentration-time curves predicted by using the proposed model incorporating two different submodels show that Storage-Diffusion Model seems to be superior in explaining physical processes inside the storage zone to the Storage-Exchange Model even though accuracies of simulation results by two models are about the same. The proposed model shows significant improvement over the conventional one-dimensional dispersion model in predicting natural mixing processes in open channels.

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Dispersion of Heavy Metals in the Geochemical Environment around the Geumwang Gold-Silver Mine (금왕 금·은광산 주변 지구화학적 환경에서의 중금속 원소들의 분산)

  • Park, Jong-Jin;Kim, Myeong-Kyun;Chon, Hyo-Taek
    • Economic and Environmental Geology
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    • v.30 no.5
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    • pp.407-416
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    • 1997
  • Soil, tailings, stream sediment and surface water samples collected in the vicinity of the Geumwang Au-Ag mine were analyzed in order to investigate the pollution level of heavy metals and to determine the dispersion patterns. Although the maximum concentrations of soils collected at the flotation plant and tailings dam were 9,270 ppm As, 17 ppm Cd, 1,480 ppm Cu, 10,080 ppm Pb and 18,400 ppm Zn, dispersion of heavy metals were limited in the vicinity of the flotation plant and tailings dam. This may be due to high pH values (> 8.0) of the soils by flotation solution for mineral processing. The pH values of water samples near the flotation plant and tailings dam were over 8.0 and Cd, Cu and Zn concentrations were not detected. The waters in the vicinity of Geumwang mine generally belong to a $Ca^{2+}-SO_{4}{^{2-}}$ $(HCO_3{^-})$ type.

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Temporal and Spatial Spreading Characteristic of Drift Soil due to the Reclamation in the Pusan Port (해양 매립 및 준설토 투기에 따른 부유사 확산의 시.공간적 특성에 관한 연구)

  • 김용원;김종인;윤한삼;홍도웅
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.10a
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    • pp.196-203
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    • 2000
  • In this study, the evaluation method of diffusion characteristics of Suspended Soli&SS) and the generation limit(source and thick) are investigated, which is significantly affecting on marine examined by construction works such as dredging and reclamation. Dispersion characteristics of SS is examined by hydraulic tests and numerical works in consideration with the Pusan Port. Hydraulic model test was performed in 2-D wave flume to find the limit wave conditon of re-suspension of solid as well as the time dependent characteristics of settlement The results obtainded in the study are as follows; 1) The quantituative evaluation af SS is the basic parameter of marine environmental impact assessment in related with the port development The SS increases as the water content of sea bed solid increases and the density decreases. 2) The sea bed solid in Sinsundai area, Pusan Port has the water content range of 83~157% 3) The ratio of suspension velocity against settlement velocity is about 0.25 and SS concentration converges as the wave heigh. 4) The SS increases 2 time when time step increases 3 time(10 sec to 30 sec) in numerical simulation It means that the effect of the time step should be checked in detail to stable. The diffusion The diffusion coefficient are Affiected senstively in the dispersion process while sea ved friction coefficinet have not strong relation in the simulated area

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Investigation on the Adsorption Features of Humic Acid on Carbon Nanotubes (탄소나노튜브의 휴믹산 흡착특성에 관한 기초연구)

  • Lee, Sun-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.520-524
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    • 2004
  • As a feasibility study for the application of carbon nanotubes to the treatment of environmental pollutants, the adsorption characteristics of humic acid on carbon nanotubes has been investigated. The dispersion features of carbon nanotubes in aquatic environment were investigated by measuring the variation of their electrokinetic potentials with pH, and the effects of some dispersants on their dispersion features were also examined. Under the experimental conditions, humic acid was observed to mostly adsorb on nanotubes within a few minutes and reach the equilibrium state within about one hour. The adsorption features of humic acid on nanotubes were found to follow the Freundlich model better than the Langmuir Model. Humic acid adsorbed on carbon nanotubes endothermically and the change of enthalpy in adsorption reaction was estimated to be ca. 18.37kJ/mol at standard state. The entropic change in adsorption reaction for humic acid was ca. 0.0503kJ/mol at standard state and the activation energy for adsorption was also estimated based on the change of rate constants with temperature. FT-IR investigations showed that the functional groups such as alcohol, ester, and aromatics existing in the chemical structure of humic acid might work as the bridge in its adsorption on nanotubes.

An Effect of Heat Input on Thermal Storage for Horizontal Thermal Storage Tank with Heat pipe (열 파이프용 수평 축열조에서의 열 입력이 축열에 미치는 영향)

  • Pak, Ee-Tong;Jeong, Un-Chul
    • Solar Energy
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    • v.16 no.2
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    • pp.39-47
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    • 1996
  • The horizontal thermal storage tank with heat pipe which is suitable for the sensible heat storage system is able to store a hot water from the heat source such as heating pad efficiently and to supply a hot water to load rapidly. And arrangement of heating pad play an important role in thermal flow and thermal storage efficiency. In this experiments, number of heating pad is ranged from three, five and nine, and when there is no change on number of heating pad, arrangements are two types of concentration-type and dispersion-type. Strong entrainment take place in the case of concentration-type of heating pad, and rapid temperature rise(${\Delta}{\doteqdot}1.6{\sim}3.2^{\circ}C$) in the tank is obtainable on the concentration-type than dispersion-type. In the constant number of heating pad, the concentration-type has the higher efficiency with about $5{\sim}6%$ than the dispersion-type Therefore, concentration-type of heating pad is an efficient design in constant number of heating pad.

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Recent Topics on Cavitation Research

  • Kato Hiroharu
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.1-4
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    • 2002
  • This article presents the unique characteristics of cavitation, those are very high pressure and very high temperature even in a very short time. Such the high-pressure causes the destruction of material, which sometimes brings a severe problem to fluid machinery. However, if we look the cavitation from the different direction, such the high pressure can be used to various applications. The author presents two examples of the utilization of cavitation recently done at the Toyo University. Those are 'dispersion of spilled oil' and 'killing planktons'.

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Effect of Temperature on the Surface Tensions in the Detergency System(I) -Change of Surface Tension Components of Washing Liquids- (온도가 세척계의 표면장력에 미치는 영향(제1보) -세액의 표면장력 성분변화를 중심으로-)

  • Chae, Chung-Hee;Kim, Sung-Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.4
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    • pp.511-517
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    • 1993
  • Changes of the surface and interface tension with temperature for washing liquids and alkanes were measured by FACE surface tensiometer. Using the extended Fowkes' equation, the dispersion and polar force components of the surface tension were estimated. The results were as follows : 1. The surface tensions of washing liquids and alkanes decreased almost linearly with the increase of temperature. 2. The interface tensions of 0.25% DBS/alkane increased slowly with the increase of temperature. In the case of nonionic surfactant solutions, however, the interface tensions with alkanes varied with the number of hydrophilic ethylene oxide(EO) groups. 3. Of the surface tension of water at $20^{\circ}C$, the dispersion force component was 25.3 dyn/cm and the polar force component was 47.8 dyn/cm. As the temperature increased, both the polar and dispersion force components decreased in a similar fashion. 4. The dispersion force component of surface tension of 0.25% DBS solution was 30.0 dyn/cm, and the polar force component was 2.2 dyn/cm at $20^{\circ}C$. The two components decreased with the increase of temperature. 5. As the temperature increased, the dispersion force component of surface tension decreased and the polar force component increased significantly for 0.25% NPPG-7.5EO solution. In the case of 025% NPPG-10EO, both the dispersion and polar force components decreased slowly, but the polar force component is expected to increase from $60^{\circ}C$. However, the polar force component of surface tension decreased with the increase of temperature for 025% NPPG-15EO solution, and at the temperature higher than $60^{\circ}C$ the surface tension is expected to be composed of only dispersion force component.

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