• 한국항만학회지
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• 제12권2호
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• pp.303-312
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• 1998

It is necessary to quantitatively asses the influence of tidal currents to analysis the coastal current patterns before or after constructing offshore structures like as breakwaters. This assesment can be made through the use of simulation models designed to reproduce the water movements of the area. And it is very important to predict a phenomenon of pollutant dispersion in the area. In this study, in order to predict the changes of sea water quality for the port development plan, Ilgwang harbour, located at the east coast of Pusan, the numerical computations were carried out. The flow patterns were investigated before and after the development of the harbour bay and coastal area connected on it. The computational models are an extension of earlier work on the flow which used the ADI Method (Alternating Direction Implicit Method) in appling to Osaka Bay by KANEKO et al. The transport of pollutant constituents depends upon the currental characteristics of the water-transporting medium. In the currental flow model, water velocities and water levels are computed throughout the regions of it. These value are then used in the mass-balance equation to obtain the pollutant-constituent transport. As a result of this research, the present water quality of Ilgwang harbour and the coastal areas connected on it was proved out some good condition. The changes of sea water quality due to the port development plan of the Ilgwang habour bay and the coastal area were not large compared with the present condition, but it will be likely able to get worse by increasing the semi-enclosed areas in the harbour bay. In order to improve the water quality of the area after development, the method to activate tidal exchange in the area can be needed, as a mitigation technique.

• 한국태양에너지학회 논문집
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• 제21권3호
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• pp.9-18
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• 2001

This paper reports on an theoretical study of heat transfer from evaporative cooling system by the flow of recirculated water over the roof. In this system tile water is distributed at the top of the pitched roof, collected at the bottom by a gutter and recirculated by a pump. To analysis the system, the energy balance equations are developed and solved using a finite difference method. The calculation results show a good agreement with the measured ones obtained from our experiment. Based on the results, it was seen that the roof-evaporative cooling system reduced the heat flux significantly compared with the conventional roof structure even in the hot-humid summer climate of Korea.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2022년도 학술발표회
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• pp.149-149
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• 2022

Accurate quantitative evaluation of baseflow contribution to streamflow is imperative to address seasonal drought vulnerability, flood occurrence and groundwater management concerns for efficient and sustainable water resources management in watersheds. Several baseflow separation algorithms using recursive filters, graphical method and tracer or chemical balance have been developed but resulting baseflow outputs always show wide variations, thereby making it hard to determine best separation technique. Therefore, the current global shift towards implementation of artificial intelligence (AI) in water resources is employed to compare the performance of deep learning models with conventional hydrograph separation techniques to quantify baseflow contribution to streamflow of Piney River watershed, Tennessee from 2001-2021. Streamflow values are obtained from the USGS station 03602500 and modeled to generate values of Baseflow Index (BI) using Web-based Hydrograph Analysis (WHAT) model. Annual and seasonal baseflow outputs from the traditional separation techniques are compared with results of Long Short Term Memory (LSTM) and simple Gated Recurrent Unit (GRU) models. The GRU model gave optimal BFI values during the four seasons with average NSE = 0.98, KGE = 0.97, r = 0.89 and future baseflow volumes are predicted. AI offers easier and more accurate approach to groundwater management and surface runoff modeling to create effective water policy frameworks for disaster management.

• 분석과학
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• 제29권4호
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• pp.179-185
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• 2016

물 시료 중에 잔류하는 β-차단제 3종(아테놀롤, 메토프롤롤, 프로프라놀롤)과 β-락탐계 항생제 6종(아목시실린, 페니실린G, 세파클러, 세파드록실, 세파렉신, 세프라딘)을 다른 두 종류의 카트리지를 사용하여 효과적인 분석방법을 정립하였다. 고분자 친수성-친유성 균형 카트리지(Hydrophile-lipophile balance, HLB)와 강한 양이온 교환 혼합 모드인 고분자 흡수 카트리지(Mixed mode cation exchange, MCX)를 사용하여 자동고체상 추출장치(Solid-phase extraction, SPE)로 전처리를 하였다. 충분한 크로마토그래피 분리를 위해 XDB-C₁₈ (1.8 μm; 3.0 mm × 100 mm) 컬럼을 사용하였다. 정량을 위한 검정곡선의 상관계수(r²)가 0.995 이상으로 우수한 직선성을 나타내었다. 방법검출한계(Method detection limits, MDL)와 정량한계(Limit of quantitation, LOQ)는 각각 1.1~3.9 ng/L와 5~13 ng/L이었다. 이 분석방법으로 한강으로 유입되는 지천과 원수를 실태 조사 한 결과 N.D.~0.209 μg/L 농도로 검출되었다.

• 한국조경학회지
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• 제43권4호
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• pp.98-111
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• 2015

도시개발과 기후변화로 인해 증가하는 도시침수, 지하수 고갈, 하천오염 그리고 도시 열섬 현상 등의 환경문제는 도시 물순환 회복을 통해 경감시킬 수 있다. 효과적인 물순환 회복 계획수립을 위해서는 개별 사업이나 소규모 시설에 대해 물수지 현황과 변화를 면적으로 나타낼 수 있는 지도형태의 분석틀이 필요하다. 이를 위해, 토양-식생 기반의 물수지 모델 BAGLUVA의 구조를 분석하고, BAGLUVA 모델의 수문요소와 입력자료와 관련된 우리나라 관련 연구결과에 대해 조사하였다. BAGLUVA 모델은 기후, 토지이용, 지형, 토양수문 그리고 관개 등의 5가지 부문으로 구성된다. 5가지 구성요소의 상호 연계 구조와 개별 입력데이터 그리고 지형 계수, 최대증발산 비율, 유효근권 등의 개념과 적용 방법을 비교 분석하였다. 그리고, 실제 증발산량-잠재증발산량-강수량 간의 관계를 매개하는 Bagrov 계수의 산정 방식을 나타내었다. 면적단위의 토지이용별 물순환지도(Hydrotope Map)를 통해, 임의의 소규모 지역 물수지 현황을 효과적으로 파악할 수 있다. 그리고, 물순환 보전 및 관리를 위한 분산형 빗물관리, 저영향개발(LID) 시설의 계획 설계 상의 목표량 설정을 공정하고 용이하게 수행할 수 있다. 또한, 수자원 관리를 조경 및 도시계획에 통합시키는 유용한 도구이다.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.531-538
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• 2013

A mass balance method established in this laboratory was applied to determine the purity of an endosulfan-II pure substance. Gas chromatography-flame ionization detector (GC-FID) was used to measure organic impurities. Total of 10 structurally related organic impurities were detected by GC-FID in the material. Water content was determined to be 0.187% by Karl-Fischer (K-F) coulometry with an oven-drying method. Non-volatile residual impurities was not detected by Thermal gravimetric analysis (TGA) within the detection limit of 0.04% (0.7 ${\mu}g$ in absolute amount). Residual solvents within the substance were determined to be 0.007% in the Endosulfan-II pure substance by running GC-FID after dissolving it with two solvents. The purity of the endosulfan-II was finally assigned to be ($99.17{\pm}0.14$)%. Details of the mass balance method including interpretation and evaluating uncertainties of results from each individual methods and the finally assayed purity were also described.

• Korean Journal of Hydrosciences
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• 제8권
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• pp.111-123
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• 1997

A one-dimensional eddy diffusion model and a mixed-layer model are developed and applied to simulate the vertical temperature profiles in lakes. Also the running result of each method are compared and analyzed. In an eddy diffusion model, molecular diffusivity is neglected and eddy diffusivity which does not need lake-specific fitting parameter and constant lake's level are applied. The heat exchanges at the water surface and the bottom are formulated by the energy balance and zero energy gradient, respectively. In a mixed-layer model, two layers approach which has a constant thickness is adopted. The application of these models which use explicit finite difference and Runge-Kutta methods respectively demonstrates that the models simulate water temperatures efficiently.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2017년도 학술발표회
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• pp.174-174
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• 2017

습지는 생산성이 높은 생태계이며 범람원, 수문저장, 오염원의 분해 및 침전의 기능과 동시에 동식물의 서식처를 제공하는 인간의 복지에 매우 유용한 자연공간이다. 습지의 생태적, 수문학적 기능을 유지하기 위해서는 습지 내 유량의 확보가 필수적이다. 따라서, 습지를 유지하고 관리하기 위해서는 유량 변동을 분석하여 유량 변동에 따른 습지 관리를 할 필요가 있다. 우리나라의 산지습지는 주변과 고립되어 있어 외부의 위협에 민감하고, 특이하며 다양한 생물상이 다양하게 분포되어 있어 생태학적 가치가 매우 크다. 특히 양산지역 산지에는 고산습지가 많아 멸종위기종, 천연기념물, 희귀동물이 살고 있는 청정지역이다. 본 연구에서는 다양한 야생생물이 분포하는 보전가치가 높은 산지습지인 경남 양산 장군습지를 대상으로 습지 내 유량 변동에 따른 습지 유지관리방안을 제안하고자 한다. 이를 위해, 습지유역으로 유입되는 물의 양과 유출되는 물의 양의 차이를 분석하는 물수지 방법을 적용하여 습지 내의 유량 변동을 분석하였다.

• 한국태양에너지학회 논문집
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• 제29권2호
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• pp.31-38
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• 2009

This study was conducted to forecast inner water temperature strata change by extracting deep water from a dam. For the methodology, the scope wherein the balance between the volume of low-temperature water intake through the virtual water intake opening as installed within the stored water area and the volume of water intake from the surrounding area is not destroyed was calculated through the CFD simulation technique using the computational fluid dynamics(CFD) interpretation method. This study suggested a supplementary method(diffuser) to avoid destroying the water temperature strata, and the effect was reviewed. In case of intake of the same volume, when the velocity of flow of water intake is reduced by increasing the pipe diameter, the destruction of water temperature strata can be minimized. When the area(height) where the intake of water is possible is low, a diffuser for interrupting the vertical direction inflow should be installed to secure favorable water intake conditions in case of water intake on the upper part. This study showed that there was no problem if the intake-enabled, low-temperature area was secured approximately 10m from the bottom when the scope that does not destroy the water temperature strata in case of water intake was forecast using the regression formula.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3275-3279
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• 2014

A mass balance method for purity assessment of thermolabile organic reference materials was established by combining several techniques, including liquid chromatography with UV/VIS detector (LC-UV), Karl-Fischer (K-F) Coulometry, and thermal gravimetric analysis (TGA). This method was applied to three fluoroquinolones like enrofloxacin, norfloxacin and ciprofloxacin. LC-UV was used to analyze structurally related organic impurities based on UV/VIS absorbance spectra obtained in combination with LC separation. For all three organic reference materials, the UV/VIS spectra of the separated impurities were similar to that of the major component of the corresponding materials. This indicates that the impurities are structurally related to the respective reference material sharing common chromophores. Impurities could be quantified by comparing their absorbances at the wavelength of maximum absorbance (${\lambda}_{max}$). The water contents of the reference materials were measured by K-F Coulometry by an oven-drying method. The total inorganic impurities contents were assayed from ash residues in TGA analysis with using air as a reagent gas. The final purities estimated from results of those analytical techniques were assigned as ($99.91{\pm}0.06$), ($97.09{\pm}0.17$) and ($91.85{\pm}0.17$)% (kg/kg) for enrofloxacin, norfloxacin and ciprofloxacin, respectively. The assigned final purities would be applied to the reference materials which will be used as calibrators for the certification of those compounds in matrix CRMs as starting points for the traceability of their certified values to SI units.